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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Constraints on the thermal evolution of Venus inferred from Magellan data

The impact craters with diameters from 1.5 to 280 km compiled from Magellan observations indicate that the crater population on Venus has a completely spatially random distribution and the size/density distribution of craters with diameters greater than or equal to 35 km is consistent with a 'production' population with an age of 500 plus or minus 250 m.y. The similarity in size distribution from area to area indicates that the crater distribution is independent of crater size. Also, the forms of the modified craters are virtually identical to those of the pristine craters. These observations imply that Venus reset its cratering record by global resurfacing 500 m.y. ago, and resurfacing declined relatively fast. The fact that less than 40 percent of all craters have been modified and that the few volcanically embayed craters are located on localized tectonic regions indicate that only minor and localized volcanism and tectonism have occurred since the latest vigorous resurfacing event approximately 500 m.y. ago and the interior of Venus has been solid and possibly colder than Earth's. This is because the high-temperature lithosphere of Venus would facilitate upward ascending of mantle plumes and result in extensive volcanism if the venusian upper mantle were as hot as or hotter than Earth's. Therefore, the present surface morphology of Venus may provide useful constraints on the pattern of that vigorous convection, and possibly on the thermal state of the venusian mantle. We examine this possibility through numerical calculations of three-dimensional thermal convection models in a spherical shell with temperature- and pressure-dependent Newtonian viscosity, temperature-dependent thermal diffusivity, pressure-dependent thermal expansion coefficient, and time-dependent internal heat production rate solar magnitude.

Arkani-Hamed, Jafar↗
DOE OSTI2021

The coset construction for particles of arbitrary spin

When a Poincaré-invariant system spontaneously breaks continuous internal symmetries, Goldstones’ theorem demands the existence of massless, spin-zero excitations in a one-to-one correspondence with the broken symmetry generators. When a system spontaneously breaks Poincaré symmetry, however, the kinds of excitations that satisfy Goldstone’s theorem can be quite unusual. In particular, they may have any spin and need not be particles or even quasiparticles. The standard coset construction used to formulate effective actions of Goldstones, however, is rather restrictive and is incapable of generating the full spectrum of possibilities allowed by Goldstone’s theorem. We propose a (partial) remedy to this problem by postulating a novel coset construction for systems that spontaneously break Poincaré symmetry. This new construction is capable of generating effective actions with a wide range of Goldstone excitations — including fermionic degrees of freedom — even when all symmetries are bosonic. To demonstrate its utility, we focus on constructing effective actions for point particles of various spins. We recover the known result that a particle of spin s requires an \( \mathcal{N} \) = 2 s supersymmetric worldline reparameterization gauge symmetry, which we implement at the level of the coset construction. In the process, we discover that massless particles require a novel kind of inverse Higgs constraint that bears some resemblance to the dynamical inverse Higgs constraints that appear in certain fermi liquid effective field theories. We then consider particles that, in addition to quantum spin, have finite spatial extent and are free to rotate. We derive a novel action for such particles and find a ‘spin-orbital’ coupling between the intrinsic quantum spin and the physical-rotation degrees of freedom.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

The Spatiotemporal Evolution of Granular Microslip Precursors to Laboratory Earthquakes

Laboratory earthquake experiments provide important observational constraints for our understanding of earthquake physics. Here we leverage continuous waveform data from a network of piezoceramic sensors to study the spatial and temporal evolution of microslip activity during a shear experiment with synthetic fault gouge. We combine machine learning techniques with ray theoretical seismology to detect, associate, and locate tens of thousands of microslip events within the gouge layer. Microslip activity is concentrated near the center of the system but is highly variable in space and time. While microslip activity rate increases as failure approaches, the spatiotemporal evolution can differ substantially between stick-slip cycles. These results illustrate that even within a single, well-constrained laboratory experiment, the dynamics of earthquake nucleation can be highly complex.

58 GEOSCIENCES↗
DOE OSTI2026

Learning earthquake ground motions via conditional generative modeling

Predicting high-fidelity ground motions for future earthquakes is crucial for seismic hazard assessment and infrastructure resilience. Conventional empirical simulations suffer from sparse sensor distribution and geographically localized earthquake locations, while physics-based methods are computationally intensive and require accurate representations of Earth structures and earthquake sources. We propose an artificial intelligence (AI) spectrogram generator, Conditional Generative Modeling for Ground Motion (CGM-GM). CGM-GM leverages earthquake magnitudes and geographic coordinates of earthquakes and sensors as inputs, when postprocessed with phase information, capturing spatially continuous Fourier amplitude spectra (FAS) as well as properties such as P and S arrivals, and waveform durations, without explicit physics constraints. This is achieved through a probabilistic autoencoder that extracts latent distributions in the time-frequency domain and variational sequential models for prior and posterior distributions. We evaluate the performance of CGM-GM using small-magnitude earthquake records from the San Francisco Bay Area, a region with high seismic risks. Here, we report that CGM-GM demonstrates potential for complementing physics-based simulations and non-ergodic empirical ground motion models, as well as shows promise in seismology and beyond.

geophysics↗
DOE OSTI2023

Survey of AC-LGADs for future 4D trackers with a proton beam

We will present the first beam test results with centimeter-scale AC-LGAD strip sensors, using the Fermilab Test Beam Facility, and a study of the performance of AC-LGAD sensors as a function of their thickness. Sensors of this type are envisioned for applications that require large-area precision 4D tracking coverage with economical channel counts, including timing layers for the Electron Ion Collider (EIC), and space-based particle experiments. Long strip sensors with sparse readout offer better cost and performance for applications where channel count or electrical power density is a constraint. Thanks to the excellent signal to noise ratio in AC-LGADs, sparse readout can be exploited without significant degradation of spatial or time resolution, which is demonstrated in our studies. A survey of sensor designs is presented, with the aim of optimizing the electrode geometry for spatial resolution and timing performance. We will present our studies of the sensor geometry optimizatio n to maintain the desirable sensor performance characteristics with increasingly larger electrodes.

43 PARTICLE ACCELERATORS↗
DOE OSTI2023

First survey of centimeter-scale AC-LGAD strip sensors with a 120 GeV proton beam

We will present the first beam test results with centimeter-scale AC-LGAD strip sensors, using the Fermilab Test Beam Facility, and a study of the performance of AC-LGAD sensors as a function of their thickness. Sensors of this type are envisioned for applications that require large-area precision 4D tracking coverage with economical channel counts, including timing layers for the Electron Ion Collider (EIC), and space-based particle experiments. Long strip sensors with sparse readout offer better cost and performance for applications where channel count or electrical power density is a constraint. Thanks to the excellent signal to noise ratio in AC-LGADs, sparse readout can be exploited without significant degradation of spatial or time resolution, which is demonstrated in our studies. A survey of sensor designs is presented, with the aim of optimizing the electrode geometry for spatial resolution and timing performance. We will present our studies of the sensor geometry optimization to maintain the desirable sensor performance characteristics with increasingly larger electrodes.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1993

Observed redshifts in O V and downflows in the solar transition region

Spectrograms from HRTS are used to find an average net redshift of the O V lines at 1218 and 1371 A at all locations extending from disk center to solar limb. The observed shift in O V is compared with measurements of the O IV line at 1401 A and the Si IV line at 1402 A. Large variations in the shift are found along the instrument slit. Blueshifts are also observed with the sites of the largest upflow located in the sunspot umbrae and in a quiet region close to an active region. The present result could put new constraints on numerical models of flows in the solar transition region and will also be of importance for modeling stellar atmospheres. The spatial variation of line-of-sight velocities in the O V line at 1371A and the SI IV line at 1402 A is illustrated.

Brekke, P.↗
NASA NTRS1994

Astronomical observations of phenomena in disks

Astronomical constraints on disks around young stellar objects are reviewed in this abstract. Since disks around the youngest stars cannot generally be resolved spatially, most results are based on analyses of the infrared and radio emission from circumstellar dust and gas. At least half of all young stars seem to have substantial circumstellar disks at an age of approximately 10(exp 6) yr. The young objects without disks tend to be binary stellar systems, though not exclusively, and some close binaries may have outer disks that are not tidally disrupted. Probably most, if not all, stars formed originally with circumstellar disks, but evolutionary timescales may differ dramatically. All the results, disk disappearance, disk mass around young stars, and long-wavelength dust opacities, are subject to the additional uncertainty of the effects of infalling dusty envelopes, which produce the disks in the first place.

Hartmann, L.↗
NASA NTRS1999

The Dipper Satellite: A Medium-Class Explorer Mission to the Threshold of Space

The Dipper satellite will carry out an unprecedented, systematic, and focused in-situ exploration of the Earth's lower ionosphere and thermosphere below 200 km that will produce a pivotal base of knowledge that will significantly advance our understanding of knowledge that will significantly advance our understanding of how our near-space environment works. The satellite will carry comprehensive in-situ probes to measure vector electric and magnetic fields, plasma density and temperature, ion velocities, ion and neutral composition and winds, energetic particles including suprathermal electrons, gravity waves, and lightning bursts. The satellite will include a propulsion system and tapered body that will provide over 10,000 excursions to altitudes below 200 km with over 3000 dips to altitudes below 150 km. With this instrument complement, spacecraft, and orbit, the Dipper mission will gather the necessary combined electrodynamics and neutral dynamics measurements to provide an understanding of the Earth's critical boundary region where the ionized gases of space and the neutral gases of the atmosphere are coupled, and where impinging forces and momentum are deposited from the magnetosphere above and from the troposphere, stratosphere, and mesosphere below. In exploring those physical processes in the lower ionosphere which can only be measured in-situ, the Dipper mission addresses four main science objectives. The Dipper will: 1) reveal how ion-neutral coupling creates a global system of dynamo electric fields and currents; 2) provide first-hand understanding of how magnetospheric currents close in the ionosphere and reveal the effects on the upper atmosphere of magnetospheric energy and momentum deposition; 3) discover the degree of upwards coupling and energy deposition due to thunderstorm electric fields and determine their significance; 4) determine the dynamics and composition of the Earth's lower thermosphere, including its response to gravity, tidal, and planetary waves on a range of spatial scales. A proposal to design, build, operate, and analyze data from instruments on the Dipper spacecraft within the schedule and budget constraints of NASA's MIDEX program was submitted to NASA in 1998. This presentation summarizes the main features of the mission.

Pfaff, R. F., Jr.↗
NASA NTRS2011

Constraint Embedding Technique for Multibody System Dynamics

Multibody dynamics play a critical role in simulation testbeds for space missions. There has been a considerable interest in the development of efficient computational algorithms for solving the dynamics of multibody systems. Mass matrix factorization and inversion techniques and the O(N) class of forward dynamics algorithms developed using a spatial operator algebra stand out as important breakthrough on this front. Techniques such as these provide the efficient algorithms and methods for the application and implementation of such multibody dynamics models. However, these methods are limited only to tree-topology multibody systems. Closed-chain topology systems require different techniques that are not as efficient or as broad as those for tree-topology systems. The closed-chain forward dynamics approach consists of treating the closed-chain topology as a tree-topology system subject to additional closure constraints. The resulting forward dynamics solution consists of: (a) ignoring the closure constraints and using the O(N) algorithm to solve for the free unconstrained accelerations for the system; (b) using the tree-topology solution to compute a correction force to enforce the closure constraints; and (c) correcting the unconstrained accelerations with correction accelerations resulting from the correction forces. This constraint-embedding technique shows how to use direct embedding to eliminate local closure-loops in the system and effectively convert the system back to a tree-topology system. At this point, standard tree-topology techniques can be brought to bear on the problem. The approach uses a spatial operator algebra approach to formulating the equations of motion. The operators are block-partitioned around the local body subgroups to convert them into aggregate bodies. Mass matrix operator factorization and inversion techniques are applied to the reformulated tree-topology system. Thus in essence, the new technique allows conversion of a system with closure-constraints into an equivalent tree-topology system, and thus allows one to take advantage of the host of techniques available to the latter class of systems. This technology is highly suitable for the class of multibody systems where the closure-constraints are local, i.e., where they are confined to small groupings of bodies within the system. Important examples of such local closure-constraints are constraints associated with four-bar linkages, geared motors, differential suspensions, etc. One can eliminate these closure-constraints and convert the system into a tree-topology system by embedding the constraints directly into the system dynamics and effectively replacing the body groupings with virtual aggregate bodies. Once eliminated, one can apply the well-known results and algorithms for tree-topology systems to solve the dynamics of such closed-chain system.

Woo, Simon S.↗
NASA NTRS2008

Space-based Ornithology-Studying Bird Migration and Environmental Change in North America

Natural fluctuations in the availability of critical stopover sites coupled with anthropogenic destruction of wetlands, land-use change, and anticipated losses due to climate change present migratory birds with a formidable challenge. We have developed an individual-based, spatially explicit bird migration model that simulates the migration routes, timing and energy budgets of individual birds under dynamic weather and land surface conditions. Our model incorporates biophysical constraints, individual bird energy status, bird behavior, and flight aerodynamics. We model the speed, direction, and timing of individual birds moving through a user specified Lagrangian grid. The model incorporates environmental properties including wind speed and direction, topography, dynamic hydrologic properties of the landscape, and environmental suitability. The model is driven by important variables estimated from satellite observations of the land surface, by data assimilation products from weather and climate models, and biological field data. We illustrate the use of the model to study the impact of both short- and long-term environmental variatios, e.g. climate, drought, anthropogenic, on migration timing (phenology), spatial pattern, and fitness (survival and reproductive success). We present several theoretical simulations of the spring migration of Pectoral Sandpiper (Calidris melanotos) in North America with emphasis on the Central flyway from the Gulf of Mexico to Alaska.

Smith, James↗
NASA NTRS2014

Comparison of Land Skin Temperature from a Land Model, Remote Sensing, and In-situ Measurement

Land skin temperature (Ts) is an important parameter in the energy exchange between the land surface and atmosphere. Here hourly Ts from the Community Land Model Version 4.0, MODIS satellite observations, and in-situ observations in 2003 were compared. Compared with the in-situ observations over four semi-arid stations, both MODIS and modeled Ts show negative biases, but MODIS shows an overall better performance. Global distribution of differences between MODIS and modeled Ts shows diurnal, seasonal, and spatial variations. Over sparsely vegetated areas, the model Ts is generally lower than the MODIS observed Ts during the daytime, while the situation is opposite at nighttime. The revision of roughness length for heat and the constraint of minimum friction velocity from Zeng et al. [2012] bring the modeled Ts closer to MODIS during the day, and have little effect on Ts at night. Five factors contributing to the Ts differences between the model and MODIS are identified, including the difficulty in properly accounting for cloud cover information at the appropriate temporal and spatial resolutions, and uncertainties in surface energy balance computation, atmospheric forcing data, surface emissivity, and MODIS Ts data. These findings have implications for the cross-evaluation of modeled and remotely sensed Ts, as well as the data assimilation of Ts observations into Earth system models.

Modeling↗
NASA NTRS2021

Satellite Constraints on the Latitudinal Distribution and Temperature Sensitivity of Wetland Methane Emissions

Wetland methane (CH4) emissions comprise about one-third of the global CH4 source. The latitudinal distribution and climate sensitivity of wetland CH4 fluxes are the key determinants of the global CH4-climate feedback. However, large differences exist between bottom-up estimates, informed by ground-based flux measurements, and top-down estimates derived from spaceborne total column CH4. Despite the extensive coverage of satellite CH4 concentration observations, challenges remain with using top-down estimates to test bottom-up models, mainly because of the uncertainties in the satellite retrievals, the model representation errors, the variable prior emissions, and the confounding role of the posterior error covariance structures. Here, we use satellite-based top-down CH4 flux estimates (2010–2012) to test and refine 42 bottom-up estimates of wetland emissions that use a range of hypothesized wetland extents and process controls. Our comparison between bottom-up models and satellite-based fluxes innovatively accounts for cross-correlations and spatial uncertainties typically found in top-down inverse estimates, such that only the information from satellite observations and the atmospheric transport model is kept as a constraint. We present a satellite-constrained wetland CH4 ensemble product derived from assembling the highest-performance bottom-up models, which estimates global wetland CH4 emissions of 148 (117–189, 5th–95th percentile) Tg CH4 yr−1. We find that tropical wetland emissions contribute 72% (63%–85%) to the global wetland total. We also find that a lower-than-expected temperature sensitivity agrees better with atmospheric CH4 measurements. Overall, our approach demonstrates the potential for using satellites to quantitatively refine bottom-up wetland CH4 emission estimates, their latitudinal distributions, and their sensitivity to climate.

wetland ch4↗
NASA NTRS2014

Potential Multi-Component Structure of the Debris Disk Around HIP 17439 Revealed by Herschel DUNES

Context. The dust observed in debris disks is produced through collisions of larger bodies left over from the planet/planetesimal formation process. Spatially resolving these disks permits to constrain their architecture and thus that of the underlying planetary/planetesimal system. Aims. Our Herschel open time key program DUNES aims at detecting and characterizing debris disks around nearby, sun-like stars. In addition to the statistical analysis of the data, the detailed study of single objects through spatially resolving the disk and detailed modeling of the data is a main goal of the project. Methods. We obtained the first observations spatially resolving the debris disk around the sun-like star HIP 17439 (HD 23484) using the instruments PACS and SPIRE on board the Herschel Space Observatory. Simultaneous multi-wavelength modeling of these data together with ancillary data from the literature is presented. Results. A standard single component disk model fails to reproduce the major axis radial profiles at 70 μm, 100 μm, and 160 μm simultaneously. Moreover, the best-fit parameters derived from such a model suggest a very broad disk extending from few au up to few hundreds of au from the star with a nearly constant surface density which seems physically unlikely. However, the constraints from both the data and our limited theoretical investigation are not strong enough to completely rule out this model. An alternative, more plausible, and better fitting model of the system consists of two rings of dust at approx. 30 au and 90 au, respectively, while the constraints on the parameters of this model are weak due to its complexity and intrinsic degeneracies. Conclusions. The disk is probably composed of at least two components with different spatial locations (but not necessarily detached), while a single, broad disk is possible, but less likely. The two spatially well-separated rings of dust in our best-fit model suggest the presence of at least one high mass planet or several low-mass planets clearing the region between the two rings from planetesimals and dust.

sun-like stars↗
DOE OSTI2026

A low-latitude, high-elevation 10Be production-rate calibration from the Rwenzori Mountains, Uganda

Cosmogenic nuclide surface-exposure dating has become a key tool in geomorphology. Robust application of the technique relies on determination of local nuclide production rates using independently dated calibration sites. However, there are few existing calibration sites in certain regions, particularly in low-latitude, high-elevation regions where cosmogenic nuclide production is theoretically more sensitive to changes in Earth's magnetic field and atmospheric conditions. We present a new cosmogenic beryllium-10 (10Be) production-rate calibration from the equatorial Rwenzori Mountains in Uganda. The calibration is based on radiocarbon dating of basal lake sediments (∼21.3 kyr BP) from Lake Mahoma (2900 m asl) and measured 10Be concentrations from boulders on the crest of a moraine which dams the lake. Our results indicate a time-integrated 10Be production rate of 15.83 ± 0.81 at/g/yr at Lake Mahoma. We then use these calibration data and two public online calculators to calculate ages for moraines in a separate Rwenzori valley for which there exists a minimum-limiting radiocarbon age constraint (∼12 kyr BP) on surficial glacial sediments. This enables us to assess the performance of different parameters used to scale production rates spatially and temporally (e.g., scaling frameworks, geomagnetic field reconstructions, atmospheric models) for surface-exposure age calculation in the region. Our results highlight the sensitivity of low-latitude cosmogenic nuclide surface-exposure ages to discrete calculation parameters, such as scaling framework or reconstructions of Earth's magnetic field, and the utility of determining production rates at sites where limiting age data exists for other nearby landforms.

Anderson, N [Dartmouth College]↗
DOE OSTI2020

Strong chemical tagging with APOGEE: 21 candidate star clusters that have dissolved across the Milky Way disc

ABSTRACT Chemically tagging groups of stars born in the same birth cluster is a major goal of spectroscopic surveys. To investigate the feasibility of such strong chemical tagging, we perform a blind chemical tagging experiment on abundances measured from APOGEE survey spectra. We apply a density-based clustering algorithm to the 8D chemical space defined by [Mg/Fe], [Al/Fe], [Si/Fe], [K/Fe], [Ti/Fe], [Mn/Fe], [Fe/H], and [Ni/Fe], abundances ratios which together span multiple nucleosynthetic channels. In a high-quality sample of 182 538 giant stars, we detect 21 candidate clusters with more than 15 members. Our candidate clusters are more chemically homogeneous than a population of non-member stars with similar [Mg/Fe] and [Fe/H], even in abundances not used for tagging. Group members are consistent with having the same age and fall along a single stellar-population track in log g versus Teff space. Each group’s members are distributed over multiple kpc, and the spread in their radial and azimuthal actions increases with age. We qualitatively reproduce this increase using N-body simulations of cluster dissolution in Galactic potentials that include transient winding spiral arms. Observing our candidate birth clusters with high-resolution spectroscopy in other wavebands to investigate their chemical homogeneity in other nucleosynthetic groups will be essential to confirming the efficacy of strong chemical tagging. Our initially spatially compact but now widely dispersed candidate clusters will provide novel limits on chemical evolution and orbital diffusion in the Galactic disc, and constraints on star formation in loosely bound groups.

Price-Jones, Natalie↗
DOE OSTI2026

Explicit Monotone Stable Super-Time-stepping Methods for Finite Time Singularities

We explore a novel way to numerically resolve the scaling behavior of finite-time singularities in solutions of nonlinear parabolic PDEs. The Runge–Kutta–Legendre (RKL) and Runge–Kutta–Gegenbauer (RKG) super-time-stepping methods were originally developed for nonlinear complex physics problems with diffusion. These are multistage single step second-order, forward-in-time methods with no implicit solves. The advantage is that the time-step size for stability scales with stage number 𝑠 as $\mathcal{O}$⁡(𝑠 2 ). Many interesting nonlinear PDEs have finite-time singularities, and the presence of diffusion often limits one to using implicit or semi-implicit time-step methods for stability constraints. Finite-time singularities are particularly challenging due to the large range of scales that one desires to resolve, often with adaptive spatial grids and adaptive time steps. Here, in this study, we show two examples of nonlinear PDEs for which the self-similar singularity structure has time and space scales that are resolvable using the RKL and RKG methods, without forcing even smaller time steps. Compared to commonly used implicit numerical methods, we achieve a significantly smaller run time while maintaining comparable accuracy. We also prove numerical monotonicity for both the RKL and RKG methods under their linear stability conditions for the constant coefficient heat equation, in the case of infinite domain and periodic boundary condition, leading to a theoretical guarantee of the superiority of the RKL and RKG methods over traditional super-time-stepping methods, such as the Runge-Kutta-Chebyshev and the orthogonal Runge-Kutta-Chebyshev methods. Code can be found at https://github.com/ZT220501/SRK-Singularity.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2020

The potential role of organics in new particle formation and initial growth in the remote tropical upper troposphere

Abstract. Global observations and model studies indicate that new particle formation (NPF) in the upper troposphere (UT) and subsequent particles supply 40 %–60 % of cloud condensation nuclei (CCN) in the lower troposphere, thus affecting the Earth's radiative budget. There are several plausible nucleation mechanisms and precursor species in this atmospheric region, which, in the absence of observational constraints, lead to uncertainties in modeled aerosols. In particular, the type of nucleation mechanism and concentrations of nucleation precursors, in part, determine the spatial distribution of new particles and resulting spatial distribution of CCN from this source. Although substantial advances in understanding NPF have been made in recent years, NPF processes in the UT in pristine marine regions are still poorly understood and are inadequately represented in global models. Here, we evaluate commonly used and state-of-the-art NPF schemes in a Lagrangian box model to assess which schemes and precursor concentrations best reproduce detailed in situ observations. Using measurements of aerosol size distributions (0.003 < Dp < 4.8 µm) in the remote marine troposphere between ∼0.18 and 13 km altitude obtained during the NASA Atmospheric Tomography (ATom) mission, we show that high concentrations of newly formed particles in the tropical UT over both the Atlantic and Pacific oceans are associated with outflow regions of deep convective clouds. We focus analysis on observations over the remote Pacific Ocean, which is a region less perturbed by continental emissions than the Atlantic. Comparing aerosol size distribution measurements over the remote Pacific with box model simulations for 32 cases shows that none of the NPF schemes most commonly used in global models, including binary nucleation of sulfuric acid and water (neutral and ion-assisted) and ternary involving sulfuric acid, water, and ammonia, are consistent with observations, regardless of precursor concentrations. Through sensitivity studies, we find that the nucleation scheme among those tested that is able to explain most consistently (21 of 32 cases) the observed size distributions is that of Riccobono et al. (2014), which involves both organic species and sulfuric acid. The method of Dunne et al. (2016), involving charged sulfuric acid–water–ammonia nucleation, when coupled with organic growth of the nucleated particles, was most consistent with the observations for 5 of 32 cases. Similarly, the neutral sulfuric acid–water–ammonia method of Napari (2002), when scaled with a tuning factor and with organic growth added, was most consistent for 6 of 32 cases. We find that to best reproduce both nucleation and growth rates, the mixing ratios of gas-phase organic precursors generally need to be at least twice that of SO2, a proxy for dimethyl sulfide (DMS). Unfortunately, we have no information on the nature of oxidized organic species that participated in NPF in this region. Global models rarely include organic-driven nucleation and growth pathways in UT conditions where globally significant NPF takes place, which may result in poor estimates of NPF and CCN abundance and contribute to uncertainties in aerosol–cloud–radiation effects. Furthermore, our results indicate that the organic aerosol precursor vapors may be important in the tropical UT above marine regions, a finding that should guide future observational efforts.

54 ENVIRONMENTAL SCIENCES↗