Coherent Control of a Nuclear Spin via Interactions with a Rare-Earth Ion in the Solid State
Not Available
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
SEARCH · Engineering Papers
Results for “solid Earth”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
A high temperature thermal diffusivity determination procedure for solids and liquids
A new method for measuring the thermal diffusivity of materials at high temperatures is presented. The method is applicable to solids on Earth, and to liquids in the reduced gravity environment of space. It is especially suited to levitated liquid metals at elevated temperatures where thermal diffusivity data is not available. The method is applied in two parts, such that lumped analysis is valid in the first part, and Fourier's law of conduction is valid in the second. In both parts, the spherical specimen is assumed to have been heated to a desired temperature and cooled. An inverse conduction problem is then formulated and solved using Laplace transformation techniques. Using this solution, sample sizes, and experimentally obtained surface temperature history, the thermal diffusivity is determined by minimizing a function that satisifies the heat balance at the surface. Minimization is performed using a modified quasilinearization algorithm. Accuracy is very sensitive to error in the temperature data and increases with better curve fits to the temperature data. An error analysis is also performed, and the effect of errors in the various parameters on the evaluated thermal diffusivity is determined. An experimental study for solids on Earth is suggested, before development for implementation in space.
Bayazitoglu, Yildiz↗
Ce(III) and Ce(IV) Distribution in Acid Mine Drainage Solids: Implications for Rare Earth Element Recovery
For presentation at the Geological Society of America Annual Meeting, October 15-18, 2023.
Hoffman, Colleen↗
Temperatures inside Mars - Is the core liquid or solid
If internal heating in the mantle of Mars is similar to that in the earth, solid-state convection is the mechanism preventing large scale melting of the Martian mantle. Convection is efficient enough in transporting heat to preclude the existence of a liquid core and hence a dynamo-driven intrinsic magnetic field, if the viscosity of mantle material is lower than 10 to the 22nd to 10 to the 23rd sq cm/sec at temperatures in excess of about 1500 C. The Martian lithosphere is probably several hundred kilometers thick, intermediate in size between that of the earth and Moon.
Young, R. E.↗
Coarsening in Solid-Liquid Mixtures Studied on the Space Shuttle
Ostwald ripening, or coarsening, is a process in which large particles in a two-phase mixture grow at the expense of small particles. It is a ubiquitous natural phenomena occurring in the late stages of virtually all phase separation processes. In addition, a large number of commercially important alloys undergo coarsening because they are composed of particles embedded in a matrix. Many of them, such as high-temperature superalloys used for turbine blade materials and low-temperature aluminum alloys, coarsen in the solid state. In addition, many alloys, such as the tungsten-heavy metal systems, coarsen in the solid-liquid state during liquid phase sintering. Numerous theories have been proposed that predict the rate at which the coarsening process occurs and the shape of the particle size distribution. Unfortunately, these theories have never been tested using a system that satisfies all the assumptions of the theory. In an effort to test these theories, NASA studied the coarsening process in a solid-liquid mixture composed of solid tin particles in a liquid lead-tin matrix. On Earth, the solid tin particles float to the surface of the sample, like ice in water. In contrast, in a microgravity environment this does not occur. The microstructures in the ground- and space-processed samples (see the photos) show clearly the effects of gravity on the coarsening process. The STS-83-processed sample (right image) shows nearly spherical uniformly dispersed solid tin particles. In contrast, the identically processed, ground-based sample (left image) shows significant density-driven, nonspherical particles, and because of the higher effective solid volume fraction, a larger particle size after the same coarsening time. The "Coarsening in Solid-Liquid Mixtures" (CSLM) experiment was conducted in the Middeck Glovebox facility (MGBX) flown aboard the shuttle in the Microgravity Science Laboratory (MSL-1/1R) on STS-83/94. The primary objective of CSLM is to measure the temporal evolution of the solid particles during coarsening.
Caruso, John J.↗
Evolution of the lunar orbit with temperature- and frequency-dependent dissipation
The importance of the thermal evolution of the earth and the moon for the dynamical history of the earth-moon system is investigated using a model of coupled thermal-dynamical evolution of this system, in which the sun's gravity is ignored and only the gravitational interaction of the earth-moon system is included, along with oceanic dissipation. Results suggest that most of the lunar angular momentum was received from the earth via solid tides within the first few 100 million years after the formation of the earth and the moon, indicating that oceanic dissipation plays a minor role. It is suggested that solid tides, rather than ocean tides, might be most important to the lunar-orbit evolution.
Ross, M. N.↗
Solid state instrumentation concepts for earth resource observation
Late in 1980, specifications were prepared for detail design definition of a six band solid state multispectral instrument having three visible (VIS), one near infrared (NIR), and two short wave infrared (SWIR) bands. This instrument concept, known as the Multispectral Linear Array (MLA), also offered increased spatial resolution, on board gain and offset correction, and additional operational modes which would allow for cross track and stereoscopic viewing as well as a multialtitude operational capability. A description is presented of a summary of some of the salient features of four different MLA design concepts, as developed by four American companies. The designs ranged from the use of multiple refractive telescopes utilizing three groups of focal plane detectors electronic correlation processing for achieving spatial registration, and incorporating palladium silicide (PdSi) SWIR detectors, to a four-mirror all-reflective telecentric system utilizing a beam splitter for spatial registration.
Richard, H. L.↗
EXCHANGE Campaign 1: A Community-Driven Baseline Characterization of Soils, Sediments, and Water Across Coastal Gradients
The EXploration of Coastal Hydrobiogeochemistry Across a Network of Gradients and Experiments (EXCHANGE) program is a consortium of scientists working together to improve our understanding of how the two-way exchange of water between estuaries or large lake lacustuaries and the terrestrial landscape influence the state and function of ecosystems across the coastal interface. EXCHANGE Campaign 1 (EC1) focuses on the spatial variation in biogeochemical structure and function at the coastal terrestrial-aquatic interface (TAI). In the Fall of 2021, the EXCHANGE Consortium gathered samples from 52 TAIs. Samples collected from EC1 were analyzed for bulk geochemical parameters, bulk physicochemical parameters, organic matter characteristics, and redox-sensitive elements.Please download ec1_README.pdf for a complete list of available data in each .zip folder, package version history, and detailed information about the project. This README will serve as the central place for EC1 Data Package updates. Experimental setup and v1 methods are documented in Myers-Pigg and Pennington et al., 2023 (https://doi.org/10.1038/s41597-023-02548-7).EC1 Data Package Structure:ec1_README.pdfec1_methods.pdfec1_metadata_v3.zip...ec1_dd.csv...ec1_flmd.csv...ec1_sample_catalog.csv...ec1_metadata_kitlevel.csv...ec1_metadata_collectionlevel.csv...ec1_data_collectionlevel.csv...ec1_igsn_metadata.csvec1_soil_v3.zipec1_sediment_v3.zipec1_water_v3.zipec1_processingscripts_v3.zipThis data package is on v3 and was originally published May 2023 (v1). Subsequent updates will be published here with new version numbers. Please see the Change History section in ec1_README.pdf for detailed changes.---Acknowledging EXCHANGE: General Support and Data Product UseWe ask that users of EXCHANGE data add the following acknowledgement when publishing data in scholarly articles and data repositories:"This research is based on work supported by COMPASS-FME, a multi-institutional project supported by the U.S. Department of Energy, Office of Science, Biological and Environmental Research as part of the Environmental System Science Program."
54 ENVIRONMENTAL SCIENCES↗
Phosphonate functionalized magnetic mesoporous silica for rare earth element recovery from citrate assisted solid waste extracts
The growing high demand of rare earth elements (REEs) has prompted extensive research on REE recovery from waste streams. This study reports the synthesis and evaluation of phosphonate-functionalized magnetic mesoporous silica (MMS-PP) for REE recovery from the acidic extracts of solid wastes. MMS-PP was synthesized using surfactant template and post-synthesis methods, and tested using simulated and real extraction solutions from citrate-assisted REE extracts from municipal solid waste incineration (MSWI) ash. The organic-inorganic hybrid MMS-PP was evaluated for La recovery from 50 mM simulated citrate extract, with the adsorption capacity of 13.5 mg/g compared to ∼2.5 mg/g for non-functionalized MMS. The MMS-PP material exhibited fast adsorption within 10 min, good La selectivity against competing Na + and Ca 2+ , moderate selectivity against Al 3+ and Fe 3+ , high recyclability over multiple adsorption-desorption cycles, and equivalent efficiency for La, Ce, Nd, and Y recovery. Furthermore, the MMS-PP material also demonstrated 70–95% REE recovery from real citrate extracts of MSWI ash, and the spent MMS-PP material can be regenerated and reused for multiple cycles. Functionalized mesoporous materials in combination with organic-ligand assisted extraction can potentially provide a green, effective, and tunable solid-liquid separation platform for REE recovery from complex solid waste streams.
REE recovery↗
3D characterisation and quantification of an offshore freshened groundwater system in the Canterbury Bight
Although offshore freshened groundwater (OFG) systems have been documented in numerous continental margins worldwide, their geometry, controls and emplacement dynamics remain poorly constrained. Here we integrate controlled-source electromagnetic, seismic reflection and borehole data with hydrological modelling to quantitatively characterise a previously unknown OFG system near Canterbury, New Zealand. The OFG system consists of one main, and two smaller, low salinity groundwater bodies. The main body extends up to 60 km from the coast and a seawater depth of 110 m. We attribute along-shelf variability in salinity to permeability heterogeneity due to permeable conduits and normal faults, and to recharge from rivers during sea level lowstands. A meteoric origin of the OFG and active groundwater migration from onshore are inferred. However, modelling results suggest that the majority of the OFG was emplaced via topographically-driven flow during sea level lowstands in the last 300 ka. Global volumetric estimates of OFG will be significantly revised if active margins, with steep coastal topographies like the Canterbury margin, are considered.
54 ENVIRONMENTAL SCIENCES↗
Solid Metal-Liquid Metal Partitioning of Pt, Re, and Os: The Effect of Carbon
If the measured Os isotopic ratios are a signature from the Earth's outer core, understanding them is a unique opportunity to understand more about the Earth's core. The distribution of elements between the Earth's solid inner core and the liquid outer core will depend on their solid metal-liquid metal partition coefficients (D). Solid metal-liquid metal partitioning data are loosely consistent with the needed fractionations between Re-Os and Pt-Os to account for the Os isotopic signature; D(Os) is greater than both D(Re) and D(Pt), and the magnitude of the partition coefficients are similar to those needed [e.g. 7, 8]. The pressure in the core, the composition of the core, and the crystal structure of the solid Fe alloy in the inner core may influence the specific values of the partition coefficients. It may thus be possible to use these sensitivities of the partition coefficients to gain insight into the conditions within the Earth's core. In this abstract, we focus on the compositional influence of C, a potential component of the light element in the Earth's core [9], on the partitioning behaviors of Pt, Re, and Os.
Chabot, N. L.↗
Crystal Chemistry and Thermodynamics of HREE (Er, Yb) Mixing in a Xenotime Solid Solution
Rare earth elements (REEs), the 15 naturally occurring lanthanides plus yttrium and scandium, are ubiquitously used in modern life as they are critical components of many advanced devices and technologies. However, the demand for REEs is not equal, with the heavy rare earth elements (HREEs) having a higher demand. Xenotime (HREEPO 4 ) is an important HREE ore mineral and globally is an economical source of HREE. Most of the crystallographic and thermodynamic properties of xenotime endmembers have been elucidated by calorimetric, solubility, and high-pressure studies. Yet, in natural systems, endmembers are rarely encountered, and instead, REE solid solutions are more commonly observed. Here, we characterize the crystal chemistry, thermodynamics of HREE mixing, and high-temperature material behaviors and thermochemistry of a synthetic erbium (Er)-ytterbium (Yb) binary xenotime solid solution (Er (x) Yb (1-x) PO 4 ) using a suite of experimental techniques, including X-ray fluorescence spectroscopy, synchrotron X-ray powder diffraction implemented with Rietveld analysis, Fourier transform infrared spectroscopy coupled with attenuated total reflectance, Raman spectroscopy, thermogravimetric analysis coupled with differential scanning calorimetry, and high-temperature oxide melt drop solution calorimetry. Our results shed light on the formation of natural xenotimes and lay the foundation for their industrial applications as thermal coating materials.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Effects of dynamic long-period ocean tides on changes in earth's rotation rate
As a generalization of the zonal response coefficient first introduced by Agnew and Farrell (1978), the zonal response function kappa of the solid earth-ocean system is defined as the ratio, in the frequency domain, of the tidal change in earth's rotation rate to the tide-generating potential. Amplitudes and phases of kappa for the monthly, fortnightly, and nine-day lunar tides are estimated from 2 1/2 years of VLBI UT1 observations, corrected for atmospheric angular momentum effects using NMC wind and pressure series. Using the dynamic ocean tide model of Dickman (1988, 1989), amplitudes and phases of kappa for an elastic earth-ocean system are predicted. The predictions confirm earlier results which found that dynamic effects of the longer-period ocean tides reduce the amplitude of kappa by about 1 percent.
Nam, Young↗
Angular Momentum Exchanges Between the Earth and the Hydrosphere and Consequent Length of Day Variations
Explore the source record for details and available documents.
hydrosphere variations length of day exchanges sol↗
Basic investigation into the production of oxygen in a solid electrolyte process
Mission analyses indicated that by extracting oxygen from the Martian atmosphere, which consists primarily of carbon dioxide, the launch mass of a spacecraft can be reduced by such an amount that samples from the planet can be returned to earth. The solid electrolyte process for producing O2 from CO2 was investigated. A model of the thermodynamic and electrochemical processes in the electrolyte cell was postulated, thereby establishing the parameters influencing the effectiveness and efficiency of an in situ O2 production system. The major operating parameters were investigated over a wide range of temperature and pressure. Operating limits imposed by the solid electrolyte material, 8% yttria stabilized zirconia, were determined as a function of the operating temperature.
Richter, R.↗
Seismo-Acoustic Wave Simulation for the 2016 Kumamoto Earthquake
It is well known that underground explosions or earthquakes can generate infrasound in the atmosphere. Seismoacoustic coupling between the ground motions and atmosphere is a key mechanism for infrasound generation. Epicentral infrasound which is direct response to epicentral ground motions are extensively studied for event detection and discrimination. Diffracted infrasound generated from Rayleigh waves are often observed and reported. Recent studies suggested the surface topography is also important for infrasound generation, and mountains or topographic peaks can act as effective secondary infrasound sources. In this study, we perform full 3-D seismoacoustic simulations to understand a coupled seismic and acoustic wave generation by an earthquake and energy partitioning across the solid Earth-ocean-atmosphere system. By including the effects of realistic topography, bathymetry, and earthquake focal mechanism, we provide quantitative information about seismoacoustic wavefields and secondary infrasound sources across the solid-water, solid-air, and water-air interfaces. Acoustic wave transmission across water-air interface is also investigated by using synthetic waveforms. Our study suggests that shallow seas near the coastline or over elevated seafloors can transmit significant amount of energy from acoustic waves in water and can be effective secondary infrasound sources.
58 GEOSCIENCES↗
Enabling Multiple Small Satellite Near-Earth Asteroid Flyby Missions Using Small Solid Rocket Kick Stages with Rideshare Opportunities
The large number of Near-Earth Asteroids (NEA’s) provide almost daily launch opportunities to send small rideshare spacecraft to explore our nearest neighbors. Most asteroid missions require large spacecraft with a dedicated launch service. The large delta-V required for an interplanetary trajectory would typically preclude a NEA flyby rideshare unless it was going to the same target body as the primary mission. In this paper, a low-cost, compact, high energy kick stage with 3-axissteeringis proposed that would enable this mission type. This kick stage is compatible with an ESPA ring so that multiple NEA missions can be deployed as rideshares on a single launch.
William W Benson↗
Measuring temporal gravitational variations using SLR data
Redistribution of mass within the Earth system changes its gravitational field, and thus changes the orbits of Earth satellites. While these variations are small, Satellite Laser Ranging (SLR) to precise geodetic satellites such as Lageos-1, Lageos-2, Starlette, Ajisai, and Stella can detect these changes at their broadest spatial scales (currently greater than 10,000 km). The satellites sense only the combined variation in the solid Earth-ocean-atmosphere system; however, modeling of these different components has led to detection of long-wavelength variations in the distribution of atmospheric mass, changes in the amplitudes of atmospheric and oceanic tides, and secular variations caused by the post-glacial adjustment of the Earth's crust. The unambiguous detection of ocean mass redistribution by SLR has not been verified due largely to inadequacies in current ocean models. Great progress has been made in recent years in the determination of luni-solar tides and the braking they induce in the Earth-Moon-Sun system (leading to secular changes in the length-to-day and lengthening of the lunar orbit period) using a wide variety of techniques including ocean tide gauges, satellite altimetry, Lunar Laser Ranging, and near-Earth satellite orbit modeling. Recent investigations of the more complex and less predictable non-tidal temporal variations in the gravity field have generally proceeded along two fronts: 1) the determination of long-wavelength variations in the gravity field through the changing perturbations seen in the orbits of near-Earth satellites, and 2) the prediction of temporal variations in gravity using geophysical, atmospheric, and oceanic models. A convergence of these efforts is sought to better understand the source of observed changes in the Earth's gravitational field.
Nerem, Robert S.↗