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At least 379 records · Page 21

Investigation of the Mechanical Degradation of Zinc-Based Cold Spray Coatings for Steel Pipelines

Internal corrosion in wet natural gas is a big challenge in the oil and gas industry due to corrosive constituents such as carbon dioxide (CO2), hydrogen sulfide (H2S), other forms of sulfur, and water in the gas stream. To mitigate internal corrosion, zinc-based cold spray coatings were designed for use in natural gas pipelines to increase the lifespan of the pipeline network. However, one of the requirements in designing internal coatings is the resistance of the coatings to mechanical forces applied on the pipeline's internal wall during pigging operations. These forces are primarily compressive and shear/friction forces. This study examines material properties that must be considered when evaluating mechanical considerations. To determine the viability of the developed coatings with respect to the shear/friction forces, the shear adhesion and wear resistance of the materials have been evaluated. Shear adhesion testing was performed with modified clevises to determine the shear stress required to cause adhesion failure at the coating/substrate interface. Scanning electron microscopy was utilized to characterize the interfaces after failure. Wear testing was performed on coatings and pipeline materials utilizing pin-on-drum testing. These tests display the stress limitations and wear that the coatings can tolerate from pigging.

mechanical degradation↗

A Novel Microshear Geometry for Exploring the Influence of Void Swelling on the Mechanical Properties Induced by MeV Heavy Ion Irradiation

Small disks are often the specimen of choice for exposure in nuclear reactor environments, and this geometry invariably limits the types of mechanical testing that can be performed on the specimen. Recently, shear punch testing has been utilized to evaluate changes arising from neutron irradiation in test reactor environments on these small disk specimens. As part of a broader effort to link accelerated testing using ion irradiation and conventional neutron irradiation techniques, a novel microshear specimen geometry was developed for use with heavy-ion irradiated specimens. The technique was demonstrated in pure Cu irradiated to 11 and 110 peak dpa with 10 MeV Cu ions. At 11 peak dpa, the Cu specimen had a high density of small voids in the irradiated region, while at 110 peak dpa, larger voids with an average void swelling of ~20% were observed. Micropillar and microshear specimens both exhibited hardening at 11 dpa, followed by softening at 110 dpa. The close alignment of the new microshear technique and more conventional micropillar testing, and the fact that both follow intuition, is a good first step towards applying microshear testing to a wider range of irradiated materials.

36 MATERIALS SCIENCE↗

Assessment of Pre-Irradiation SiC CMC Joint Performance in Representative Cladding Geometries

Silicon carbide fiber reinforced, silicon carbide matrix composites (SiC-SiC) offer strength at high temperatures, corrosion resistance, and stability during irradiation, and are being developed by General Atomics as cladding for accident tolerant fuel (ATF) applications and advanced reactor concepts. Advanced joining techniques capable of withstanding harsh reactor environments are key to enable GA’s SiGAtm SiC-SiC composite. The objective of this work is to obtain joint-specific material properties for assemblies in representative planar and cladding geometries that will allow for the generation of a material properties database and more accurate simulation of SiC joint behavior across arange of temperatures and irradiation conditions. To support this, three different joint formulations are being assessed for mechanical and thermal performance pre and post irradiation in the High Flux Isotope Reactor (HIFR) at ORNL. GA has previously identified its hybrid SiC (HSiC) joint as the most promising and best suited joining approach for cladding applications [1]. Additionally, oxide and transeutectic phase (TEP) joints are being investigated to make the material property database more comprehensive as these joints have previously shown strength resilience under irradiation in planar geometries [2]. The thermal and mechanical data obtained in this work will address vital knowledge gaps, enabling more accurate modeling of joints in SiC-based components for accelerated material qualification.The scope of work presented here focuses on the mechanical and thermal performance of the joint material prior to irradiation in HFIR. Endplug push-out (EPPO) testing to determine joint strength in tube geometries, and shear strength testing for planar geometries have provided a benchmark for pre-irradiation mechanical performance. These results show that all three selected joint methodologies result in cladding joints capable of withstanding the expected joint stresses in a LWR reactor environment [3]. This has been accompanied by He leak testing of the joint regions on tube specimens to assess the suitability of each joint methodology for cladding applications. Here, only the HSiC formulation consistently met critical leak rate requirements suggesting that other joining strategies require additional development. Finally, pre-irradiation thermal testing has been completed to establish a baseline for comparison after irradiation. Subsequent irradiation of these joints types in HFIR will provide further detail on joint material properties and their appropriateness for nuclear applications.

Gonderman, Sean↗

NASA/LMSC coherent LIDAR airborne shear sensor: System capabilities and flight test plans

The primary objective of the NASA/LMSC Coherent Lidar Airborne Shear Sensor (CLASS) system flight tests is to evaluate the capability of an airborne coherent lidar system to detect, measure, and predict hazardous wind shear ahead of the aircraft with a view to warning flight crew of any impending dangers. On NASA's Boeing 737 Transport Systems Research Vehicle, the CLASS system will be used to measure wind velocity fields and, by incorporating such measurements with real-time aircraft state parameters, identify regions of wind shear that may be detrimental to the aircraft's performance. Assessment is to be made through actual wind shear encounters in flight. Wind shear measurements made by the class system will be compared to those made by the aircraft's in situ wind shear detection system as well as by ground-based Terminal Doppler Weather Radar (TDWR) and airborne Doppler radar. By examining the aircraft performance loss (or gain) due to wind shear that the lidar predicts with that actually experienced by the aircraft, the performance of the CLASS system as a predictive wind shear detector will be assessed.

Robinson, Paul↗

Low-temperature mechanical properties of glass/epoxy laminates

Selected mechanical properties of glass/epoxy laminate candidates for use in the electrical turn and ground insulation of the ITER Central solenoid (CS) modules were measured. Short-beam shear and flexural tests have been conducted on various E-glass cloth weaves/epoxy laminates at 295 and 77 K. Types of glass weave include 1581, 7500, 7781, and 38050, which represent both satin and plain weaves. The epoxy, planned for use for vacuum-pressure impregnation of the CS module, consists of an anhydride-cured bisphenol F resin system. Inter-laminar shear strength, flexural elastic modulus, and flexural strength have been measured. The data indicate that these properties are dependent on the volume percent of glass. Short-beam shear strength was measured as a function of the span-to-thickness ratio for all laminates at 77 K. Comprehensive fractography was conducted to obtain the failure mode of each short-beam shear test sample.

36 MATERIALS SCIENCE↗

Longitudinal shear behavior of several oxide dispersion strengthened alloys

Two commercial oxide dispersion strengthened (ODS) alloys, MA-753 and MA-754, and three experimental ODS alloys, MA-757E, MA-755E, and MA-6000E, were tested in shear at 760 C. Comparisons were made with other turbine blade and vane alloys. All of the ODS alloys exhibited less shear strength than directionally solidified Mar-M 200 = Hf or then conventionally cast B-1900. The strongest ODS alloy tested, MA-755E, was comparable in both shear and tensile strength to the lamellar directionally solidified eutectic alloy gamma/gamma prime - delta. Substantial improvements in shear resistance were found for all alloys tested when the geometry of the specimen was changed from one generating a transverse tensile stress in the shear area to one generating a transverse compressive stress. Finally, 760 C shear strength as a fraction of tensile strength was found to increase linearly with the log of the transverse tensile ductility.

Glasgow, T. K.↗

Longitudinal shear behavior of several oxide dispersion strengthened alloys

Two commercial oxide dispersion strengthened (ODS) alloys, MA-753 and MA-754, and three experimental ODS alloys, MA-757E, MA-755E, and MA-6000E, were tested in shear at 760 C. Comparisons were made with other turbine-blade and vane alloys. All of the ODS alloys exhibited less shear strength than directionally solidified Mar-M 200 + Hf or than conventionally cast B-1900. The strongest ODS alloy tested, MA-755E, was comparable in both shear and tensile strength to the lamellar directionally solidified eutectic alloy gamma/gamma-prime - delta. Substantial improvements in shear resistance were found for all alloys tested when the geometry of the specimen was changed from one generating a transverse tensile stress in the shear area to one generating a transverse compressive stress. Finally, 760-C shear strength as a fraction of tensile strength was found to increase linearly with the log of the transverse tensile ductility.

Glasgow, T. K.↗

Bioinspired Design Provides High-Strength Benzoxazine Structural Adhesives

A synthetic strategy to incorporate catechol functional groups into benzoxazine thermoset monomers was developed, leading to a family of bioinspired small-molecule resins and main-chain polybenzoxazines derived from biologically available phenols. Lap-shear adhesive testing revealed a polybenzoxazine derivative with greater than 5 times improved shear strength on aluminum substrates compared to a widely studied commercial benzoxazine resin. Derivative synthesis identified the catechol moiety as an important design feature in the adhesive performance and curing behavior of this bioinspired thermoset. Favorable mechanical properties comparable to commercial resin were maintained, and glass transition temperature and char yield under nitrogen were improved. Blending of monomers with bioinspired main-chain polybenzoxazine derivatives provided formulations with enhanced shear adhesive strengths up to 16 MPa, while alloying with commercial core-shell particle-toughened epoxy resins led to shear strengths exceeding 20 MPa. These results highlight the utility of bioinspired design and the use of biomolecules in the preparation of high-performance thermoset resins and adhesives with potential utility in transportation and aerospace industries and applications in advanced composites synthesis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Elastic Properties in Tension and Shear of High Strength Nonferrous Metals and Stainless Steel - Effect of Previous Deformation and Heat Treatment

A resume is given of an investigation of the influence of plastic deformation and of annealing temperature on the tensile and shear elastic properties of high strength nonferrous metals and stainless steels in the form of rods and tubes. The data were obtained from earlier technical reports and notes, and from unpublished work in this investigation. There are also included data obtained from published and unpublished work performed on an independent investigation. The rod materials, namely, nickel, monel, inconel, copper, 13:2 Cr-Ni steel, and 18:8 Cr-Ni steel, were tested in tension; 18:8 Cr-Ni steel tubes were tested in shear, and nickel, monel, aluminum-monel, and Inconel tubes were tested in both tension and shear. There are first described experiments on the relationship between hysteresis and creep, as obtained with repeated cyclic stressing of annealed stainless steel specimens over a constant load range. These tests, which preceded the measurements of elastic properties, assisted in devising the loading time schedule used in such measurements. From corrected stress-set curves are derived the five proof stresses used as indices of elastic or yield strength. From corrected stress-strain curves are derived the secant modulus and its variation with stress. The relationship between the forms of the stress-set and stress-strain curves and the values of the properties derived is discussed. Curves of variation of proof stress and modulus with prior extension, as obtained with single rod specimens, consist in wavelike basic curves with superposed oscillations due to differences of rest interval and extension spacing; the effects of these differences are studied. Oscillations of proof stress and modulus are generally opposite in manner. The use of a series of tubular specimens corresponding to different amounts of prior extension of cold reduction gave curves almost devoid of oscillation since the effects of variation of rest interval and extension spacing were removed. Comparison is also obtained between the variation of the several properties, as measured in tension and in shear. The rise of proof stress with extension is studied, and the work-hardening rates of the various metals evaluated. The ratio between the tensile and shear proof stresses for the various annealed and cold-worked tubular metals is likewise calculated. The influence of annealing or tempering temperature on the proof stresses and moduli for the cold-worked metals and for air-hardened 13:2 Cr-Ni steel is investigated. An improvement of elastic strength generally is obtained, without important loss of yield strength, by annealing at suitable temperature. The variation of the proof stress and modulus of elasticity with plastic deformation or annealing temperature is explained in terms of the relative dominance of three important factors: namely, (a) internal stress, (b) lattice-expansion or work-hardening, and (c) crystal reorientation. Effective values of Poisson's ratio were computed from tensile and shear moduli obtained on tubular specimens. The variation of Poisson's ratio with plastic deformation and annealing temperature is explained in terms of the degree of anisotropy produced by changes of (a) internal stress and (b) crystal orientation.

METALS - ELASTICITY↗

Effect of equal channel angular pressing on the mechanical and tribological behavior of Al-Zn-Mg-Cu alloy

Highlights: • The correlation of microstructure, mechanical and wear properties has been studied. • The correlation between tensile properties and shear properties has been also studied. • Mechanical and tribological properties have been improved through the ECAP process of the Al-7075 alloy. • The dominant wear mechanisms in the initial material were adhesive and oxidative wear as well as delamination. • Abrasive and oxidative wear were the dominant wear mechanisms in ECAP processed specimens. - Abstract: Microstructure, mechanical properties and wear behavior of severely deformed Al-7075 alloy by equal channel angular pressing (ECAP) were studied. Microhardness, tensile and shear strength tests were performed to evaluate the mechanical properties of the material. The relationship between tensile and shear strength was also extracted. In addition, with the aim of study the wear behavior, the wear tests were performed by using a pin-on-disk machine under different normal loads. The microscopic observations i.e. transmission electron microscopy (TEM) and scanning electron microscope (SEM), were used to analyze the microstructure of specimens as well as the surface, subsurface and debris of worn specimens. Mechanical properties results showed that the hardness and strength (tensile and shear) of the ECAP-processed alloy were higher than that of the annealed alloy and increased with the increment of pass number. The wear test data revealed that the wear rate and friction coefficient decreased with increasing ECAP passes. The SEM analysis of worn specimens demonstrated that the dominant wear mechanisms of the annealed alloy were adhesion wear and delamination and the dominant wear mechanisms of ECAP processed alloy were abrasive wear and plowing bands. Oxidative wear was also observed at both annealed and ECAPed alloy. Totally, these results demonstrated that ultrafine-grained structure fabricated by ECAP, improves the wear resistance of the Al-7075 alloy.

36 MATERIALS SCIENCE↗

High-Temperature Mechanical Properties of the P/M Extruded Mg-SiC{sub p} Composites

In the present study, pure magnesium reinforced with 0, 5, 10 and 15 vol.% SiC particulates was successfully prepared by powder metallurgy technique before being hot extruded. The average 14 μm grain size of the composite specimens remained almost unchanged after addition of SiC particles, while their dimensional stability was improved because of the reduction in the coefficient of thermal expansion (CTE) from 28.6 × 10{sup −6} K{sup −1} in pure Mg to 27.3, 25.3 and 23.4 × 10{sup −6} K{sup −1} in the Mg-5% SiC, Mg-10% SiC and Mg-15% SiC composites, respectively. Mechanical properties of the specimens were investigated in the temperature range of 298-498 K, implementing shear punch testing and hot hardness techniques. Depending on the test temperature, addition of SiC particles to the pure Mg matrix increased shear yield stress and ultimate shear strength of the materials by 5-25 and 6-23 MPa, respectively. The shear strength improvement was mainly attributed to the CTE mismatch strengthening mechanism (9.5-25.5 MPa), and to a lesser extent (1-4.5 MPa), to the load transfer mechanism. Finally, using the modified Clyne model, the contribution of different strengthening mechanisms to the total shear strength improvement in the composites was evaluated.

36 MATERIALS SCIENCE↗

Scattering insights into shear-induced scission of rod-like micelles

Understanding the scission of rod-like micelles under mechanical forces is crucial for optimizing their stability and behavior in industrial applications. This study investigates how micelle length, flexibility, and external forces interact, offering insights into the design of micellar systems in processes influenced by mechanical stress. Although significant, direct experimental observations of flow-induced micellar scission using scattering techniques remain scarce. Small angle neutron scattering (SANS) is used to explore the shear response of aqueous cetyltrimethylammonium bromide (CTAB) solutions with sodium nitrate. Rheological tests show shear thinning with no shear banding, ensuring a uniform flow field for reliable interpretation of scattering data. As shear rate increases, the scattering spectra show angular distortion, which is analyzed using spherical harmonic decomposition to characterize flow-induced scission and micelle orientation under shear. Two analysis steps are used: a model-independent spectral eigendecomposition reveals a decrease in micellar length, while regression analysis quantifies the evolution of the length distribution and mean length with shear rate. Additionally, micelle alignment increases with shear, quantified by the orientational distribution function. In conclusion, these findings provide experimental evidence for flow-induced alignment and scission, offering a new framework for understanding shear-induced phenomena in micellar systems.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Strength Tests of Thin-walled Duralumin Cylinders of Elliptic Section

This report is the fifth of a series presenting the results of strength tests of thin-walled cylinders and truncated cones of circular and elliptic section; it includes the results obtained from torsion tests on 30 cylinders, pure bending tests on 30 cylinders, and combined transverse shear and bending tests on 60 cylinders. All the cylinders tested were elliptic section with the ends clamped to rigid bulkheads. In the pure bending and combined transverse shear and bending tests the loads were applied in the plane of the major axis. The results of the tests on elliptic cylinders are correlated with the results of corresponding tests on circular cylinders and are presented in charts suitable for use in design.

STRESSED SKIN - CYLINDERS, ELLIPTIC - STRENGTH↗

Processing study of a polyimidesulfone adhesive

An adhesive bonding process cycle study was performed for a polyimidesulfone (PISO2) recently developed as a promising structural adhesive. The high molecular weight, linear aromatic system possesses properties which make it attractive as a processable, low-cost material for elevated temperature applications. The results of a study to better understand the parameters that affect the adhesive properties of the polymer for titanium alloy adherends are detailed. These include the tape preparation, the use of a primer, and press and simulated autoclave processing conditions. The polymer was characterized using Fourier Transform Infrared Spectroscopy, glass transition temperature determination, flow measurements, and weight loss measurements. The adhesive's strength determined by lap shear strength tests was used to evaluate the effects of the bonding process variations. Higher lap shear strengths were obtained at room temperature when a primer (PISO2) was used; however, the results were the same at 232 C (450 F) with or without a primer. The use of a vacuum (simulated autoclave cycle) during titanium bonding produced similar lap shear strengths to those specimens bonded without a vacuum.

Progar, D. J.↗

An evaluation of the interfacial bond properties between carbon phenolic and glass phenolic composites

The effects of moisture and surface finish on the mechanical and physical properties of the interfacial bond between the carbon/phenolic (C/P) and glass/phenolic (G/P) composite materials are presented. Four flat panel laminates were fabricated using the C/P and G/P materials. Of the four laminates, one panel was fabricated in which the C/P and G/P materials were cured simultaneously. It was identified as the cocure. The remaining laminates were processed with an initial simultaneous cure of the three C/P billets. Two surface finishes, one on each half, were applied to the top surface. Prior to the application and cure of the G/P material to the machined surface of the three C/P panels, each was subjected to the specific environmental conditioning. Types of conditioning included: (1) nominal fabrication environment, (2) a prescribed drying cycle, and (3) a total immersion in water at 160 F. Physical property tests were performed on specimens removed from the C/P materials of each laminate for determination of the specific gravity, residual volatiles and and resin content. Comparisons of results with shuttle solid rocket motor (SRM) nozzle material specifications verified that the materials used in fabricating the laminates met acceptance criteria and were representative of SRM nozzle materials. Mechanical property tests were performed at room temperature on specimens removed from the G/P, the C/P and the interface between the two materials for each laminate. The double-notched shear strength test was used to determine the ultimate interlaminar shear strength. Results indicate no appreciable difference in the C/P material of the four laminates with the exception of the cocure laminate, where 20 percent reduction in the strength was observed. The most significant effect and the ultimate strength was significantly reduced in the wet material. No appreciable variation was noted between the surface finishes in the wet laminate.

Jordan, Kelvin↗

Failure prediction of thin beryllium sheets used in spacecraft structures

In an attempt to predict failure for cross-rolled beryllium sheet structures, high order macroscopic failure criteria are used. These require the knowledge of in-plane uniaxial and shear strengths. Test results are included for in-plane biaxial tension, uniaxial compression for two different material orientations, and shear. All beryllium specimens have the same chemical composition. In addition, all experimental work was performed in a controlled laboratory environment. Numerical simulation complements these tests. A brief bibliography supplements references listed in a previous report.

Roschke, Paul N.↗

An Investigation on Microstructure Evolution, Mechanical Properties, and Strain Aging of Mg-1.8Zn-0.7Si-0.4Ca Biomedical Alloy Processed by Equal Channel Angular Pressing

The influence of equal channel angular pressing (ECAP) on microstructure and mechanical behavior, as well as, strain aging during ECAP and post-ECAP of Mg-1.8Zn-0.7Si-0.4Ca biomedical alloy was examined. The alloy in solid solution heat-treated condition was processed by ECAP with route B{sub C} at 350 and 400 °C. The specimens ECAPed at 350 °C were aged at 125 and 150 °C for different times. The hardness and shear punch test results indicated that performing ECAP at 350 °C for 4 passes increases the hardness and shear strength of the alloy from 48 HV and 110 MPa to 71 HV and 188 MPa, respectively. It was revealed that the average grain size of the alloy decreases from 78 µm to about 3 µm after 4 passes of ECAP. Three precipitates of CaMgSi, Ca{sub 2}Mg{sub 6}Zn{sub 3}, and Mg{sub 2}Si were detected in the solid solution specimen. After 4 passes of ECAP at 350 °C, Ca{sub 2}Mg{sub 6}Zn{sub 3} was completely dissolved and the morphology of Mg{sub 2}Si changed from Chinese script to fiber-shaped particles. Dynamic strain aging occurred at high-temperature ECAP, and the specimens were overaged during post-ECAP aging. Small MgZn particles were detected in the overaged sample.

36 MATERIALS SCIENCE↗

Investigation of Low-temperature Solders for Cryogenic Wind Tunnel Models

The advent of high Reynolds number cryogenic wind tunnels has forced alteration of manufacturing and assembly techniques and eliminated usage of many materials associated with conventional wind tunnel models. One of the techniques affected is soldering. Solder alloys commonly used for wind tunnel models are susceptible to low-temperature embrittlement and phase transformation. The low-temperature performance of several solder alloys is being examined during research and development activities being conducted in support of design and fabrication of cryogenic wind tunnel models. Among the properties examined during these tests are shear strength, surface quality, joint stability, and durability when subjected to dynamic loading. Results of these tests and experiences with recent models are summarized.

Firth, G. C.↗