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At least 379 records · Page 21

Separability in consistent truncations

The separability of the Hamilton-Jacobi equation has a well-known connection to the existence of Killing vectors and rank-two Killing tensors. This paper combines this connection with the detailed knowledge of the compactification metrics of consistent truncations on spheres. The fact that both the inverse metric of such compactifications, as well as the rank-two Killing tensors can be written in terms of bilinears of Killing vectors on the underlying “round metric,” enables us to perform a detailed analyses of the separability of the Hamilton-Jacobi equation for consistent truncations. We introduce the idea of a separating isometry and show that when a consistent truncation, without reduction gauge vectors, has such an isometry, then the Hamilton-Jacobi equation is always separable. When gauge vectors are present, the gauge group is required to be an abelian subgroup of the separating isometry to not impede separability. We classify the separating isometries for consistent truncations on spheres, S n , for n = 2, …, 7, and exhibit all the corresponding Killing tensors. These results may be of practical use in both identifying when supergravity solutions belong to consistent truncations and generating separable solutions amenable to scalar probe calculations. Finally, while our primary focus is the Hamilton-Jacobi equation, we also make some remarks about separability of the wave equation.

79 ASTRONOMY AND ASTROPHYSICS↗

Separation of Refined Silicon from Al-Si Alloys by Air Pressure Filtration

The separation of refined silicon from Al-Si alloys through a solvent refining process was studied. Purified silicon particles were separated by air pressure filtration using stainless steel sieves as the filtration media. After the efficient removal of impurities in the refining process, the effects of the mesh number (N), separation temperature (T), silicon content in the alloy (ω{sub (a)}), and pressure differential (p) on the separation efficiency were evaluated. At N = 80, T = 873 K (600 °C), ω{sub (a)} = 45 wt pct and p = 0.25 MPa, the recovery rate of refined silicon was 98.2 pct, and the residual aluminum in the separated silicon was less than 8 wt pct. The separation process was efficient when N = 60 to 150. It was advisable for the separation temperature to approach the eutectic temperature. Efficient filtration could be achieved when ω{sub (a)} = 35 to 55 wt pct. The filtration efficiency was improved with a higher pressure differential, and the separation was efficient at p ≥ 0.10 MPa. The results show that air pressure filtration is a promising method to separate refined silicon.

36 MATERIALS SCIENCE↗

An application of the theory of planned behaviour to study the influencing factors of participation in source separation of food waste

Highlights: ► Theory of planned behaviour (TPB) has been conducted to identify the influencing factors for participation in source separation of food waste using self administered questionnaires. ► The findings suggested several implications for the development and implementation of waste separation at home programme. ► The analysis indicates that the attitude towards waste separation is determined as the main predictors where this in turn could be a significant predictor of the repondent’s actual food waste separation behaviour. ► To date, none of similar have been reported elsewhere and this finding will be beneficial to local Authorities as indicator in designing campaigns to promote the use of waste separation programmes to reinforce the positive attitudes. - Abstract: Tremendous increases in biodegradable (food waste) generation significantly impact the local authorities, who are responsible to manage, treat and dispose of this waste. The process of separation of food waste at its generation source is identified as effective means in reducing the amount food waste sent to landfill and can be reused as feedstock to downstream treatment processes namely composting or anaerobic digestion. However, these efforts will only succeed with positive attitudes and highly participations rate by the public towards the scheme. Thus, the social survey (using questionnaires) to analyse public’s view and influencing factors towards participation in source separation of food waste in households based on the theory of planned behaviour technique (TPB) was performed in June and July 2011 among selected staff in Universiti Putra Malaysia, Serdang, Selangor. The survey demonstrates that the public has positive intention in participating provided the opportunities, facilities and knowledge on waste separation at source are adequately prepared by the respective local authorities. Furthermore, good moral values and situational factors such as storage convenience and collection times are also encouraged public’s involvement and consequently, the participations rate. The findings from this study may provide useful indicator to the waste management authorities in Malaysia in identifying mechanisms for future development and implementation of food waste source separation activities in household programmes and communication campaign which advocate the use of these programmes.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A novel process for separation of hazardous poly(vinyl chloride) from mixed plastic wastes by froth flotation

Highlights: • A novel method was proposed for separation of PVC by froth flotation. • Calcium hypochlorite treatment improves selectively surface wettablity. • Mechanism of surface treatment was examined by SEM, FTIR and XPS. •Binary plastics with different particle sizes were separated effectively. • Separation of PVC from mixed plastic wastes was obtained. - Abstract: A novel method, calcium hypochlorite (CHC) treatment, was proposed for separation of hazardous poly(vinyl chloride) (PVC) plastic from mixed plastic wastes (MPWs) by froth flotation. Flotation behavior of single plastic indicates that PVC can be separated from poly(ethylene terephthalate) (PET), poly(acrylonitrile-co-butadiene-co-styrene) (ABS), polystyrene (PS), polycarbonate (PC) and poly(methyl methacrylate) (PMMA) by froth flotation combined with CHC treatment. Mechanism of CHC treatment was examined by contact angle measurement, scanning electron microscopy, Fourier transform infrared and X-ray photoelectron spectroscopy. Under the optimum conditions, separation of PVC from binary plastics with different particle sizes is achieved efficiently. The purity of PC, ABS, PMMA, PS and PET is greater than 96.8%, 98.5%, 98.8%, 97.4% and 96.3%, respectively. Separation of PVC from multi-plastics was further conducted by two-stage flotation. PVC can be separated efficiently from MPWs with residue content of 0.37%. Additionally, reusing CHC solution is practical. This work indicates that separation of hazardous PVC from MPWs is effective by froth flotation.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Aqueous Interfaces in Chemical Separations

Chemical separations play a vital role in refinery and reprocessing of critical materials, such as platinum group metals, rare earths, and actinides. The choice of separation system─whether it is liquid–liquid extraction (LLE), sorbents, or membranes─depends on specific needs and applications. In almost all separation processes, the desired metal ions adsorb or transfer across an aqueous interface, such as the solid/liquid interface in sorbents or oil/water interfaces in LLE. Despite these separation technologies being extensively used for decades, our understanding of the molecular-scale mechanisms governing ion adsorption and transport at interfaces remains limited. This knowledge gap presents a significant challenge in meeting the increasing demands for these critical materials due to their growing use in advanced technologies. Fortunately, recent advancements in surface-specific experimental and computational techniques offer promising avenues to bridge this gap and facilitate the development of next-generation separation systems. Interestingly, unanswered questions regarding interfacial phenomena in chemical separations hold great relevance to various fields, including energy storage, geochemistry, and atmospheric chemistry. Therefore, the model interfacial systems developed for studying chemical separations, such as amphiphilic molecules assembled at a solid/water, air/water, or oil/water interface, may have far-reaching implications, extending beyond separations and opening doors to addressing a wide range of scientific inquiries. This perspective discusses recent interfacial studies elucidating amphiphile–ion interactions in chemical separations of metal ions. Finally, these studies provide direct, molecular-scale information about solute and solvent behavior at aqueous interfaces, including multivalent and complex ions in highly concentrated solutions, which play key roles in LLE of critical materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Kr/Xe Separation over a Chabazite Zeolite Membrane

Cryogenic distillation, the current conventional technology to separate Krypton and Xenon from air, and from nuclear reprocessing technologies, is an energy-intensive and expensive process. Membrane technology could potentially make this challenging industrial separation less energy intensive and economically viable. We demonstrate that chabazite zeolite SAPO-34 membranes effectively separated Kr/Xe gas mixtures at industrially relevant compositions. Control over membrane thickness and average crystal size led to industrial range permeances and high separation selectivities. Specifically, SAPO-34 membranes can separate Kr/Xe mixtures with Kr permeances as high as 361.4 GPU and separation selectivities of 34.8 for molar compositions close to typical concentrations of these two gases in air. In addition, SAPO-34 membranes separated Kr/Xe mixtures with Kr permeances as high as 525.7 GPU and separation selectivities up to 45.1 for molar compositions as might be encountered in nuclear reprocessing technologies. Molecular sieving and differences in diffusivities were identified as the dominant separation mechanisms.

Feng, Xuhui↗

Space shuttle engineering and operations support. Separation operational limits for ALT free flights 1 through 5

The orbiter/SCA separation operational limits for the current target conditions of ALT free flights 1 through 5 are analyzed. The separation operational limits are used to verify that no separation design constraints are violated. The operational limits represent the acceptable dispersions in attainment of separation target conditions which assure safe separation. Safe separation is based on satisfying all specified separation design criteria except orbiter altitude at ALT interface airspeed. Separation operational limits are defined for each of the five orbiter tailcones on ALT free flight missions based upon preflight aerodynamics. The effect of carrier pilot steering compensation due to off-nominal flight conditions is determined to be within the separation operational limits.

Seale, R. H.↗

Separability of agricultural crops with airborne scatterometry

Backscattering measurements were acquired with airborne scatterometers over a site in Cass County, North Dakota on four days in the 1981 crop growing season. Data were acquired at three frequencies (L-, C- and Ku-bands), two polarizations (like and cross) and ten incidence angles (5 degrees to 50 degrees in 5 degree steps). Crop separability is studied in an hierarchical fashion. A two-class separability measure is defined, which compares within-class to between-class variability, to determine crop separability. The scatterometer channels with the best potential for crop separability are determined, based on this separability measure. Higher frequencies are more useful for discriminating small grains, while lower frequencies tend to separate non-small grains better. Some crops are more separable when row direction is taken into account. The effect of pixel purity is to increase the separability between all crops while not changing the order of useful scatterometer channels. Crude estimates of separability errors are calculated based on these analyses. These results are useful in selecting the parameters of active microwave systems in agricultural remote sensing.

Mehta, N. C.↗

Analysis of transitional separation bubbles on infinite swept wings

A previously developed two-dimensional local inviscid-viscous interaction technique for the analysis of airfoil transitional separation bubbles, ALESEP (Airfoil Leading Edge Separation), has been extended for the calculation of transitional separation bubbles over infinite swept wings. As part of this effort, Roberts' empirical correlation, which is interpreted as a separated flow empirical extension of Mack's stability theory for attached flows, has been incorporated into the ALESEP procedure for the prediction of the transition location within the separation bubble. In addition, the viscous procedure used in the ALESEP techniques has been modified to allow for wall suction. A series of two-dimensional calculations is presented as a verification of the prediction capability of the interaction techniques with the Roberts' transition model. Numerical tests have shown that this two-dimensional natural transition correlation may also be applied to transitional separation bubbles over infinite swept wings. Results of the interaction procedure are compared with Horton's detailed experimental data for separated flow over a swept plate which demonstrates the accuracy of the present technique. Wall suction has been applied to a similar interaction calculation to demonstrate its effect on the separation bubble. The principal conclusion of this paper is that the prediction of transitional separation bubbles over two-dimensional or infinite swept geometries is now possible using the present interacting boundary layer approach.

Davis, R. L.↗

Large-Flow-Area Flow-Selective Liquid/Gas Separator

This liquid/gas separator provides the basis for a first stage of a fuel cell product water/oxygen gas phase separator. It can separate liquid and gas in bulk in multiple gravity environments. The system separates fuel cell product water entrained with circulating oxygen gas from the outlet of a fuel cell stack before allowing the gas to return to the fuel cell stack inlet. Additional makeup oxygen gas is added either before or after the separator to account for the gas consumed in the fuel cell power plant. A large volume is provided upstream of porous material in the separator to allow for the collection of water that does not exit the separator with the outgoing oxygen gas. The water then can be removed as it continues to collect, so that the accumulation of water does not impede the separating action of the device. The system is designed with a series of tubes of the porous material configured into a shell-and-tube heat exchanger configuration. The two-phase fluid stream to be separated enters the shell-side portion of the device. Gas flows to the center passages of the tubes through the porous material and is then routed to a common volume at the end of the tubes by simple pressure difference from a pumping device. Gas flows through the porous material of the tubes with greater ease as a function of the ratio of the dynamic viscosity of the water and gas. By careful selection of the dimensions of the tubes (wall thickness, porosity, diameter, length of the tubes, number of the tubes, and tube-to-tube spacing in the shell volume) a suitable design can be made to match the magnitude of water and gas flow, developed pressures from the oxygen reactant pumping device, and required residual water inventory for the shellside volume.

Vasquez, Arturo↗

Extraction and Separation Modeling of Orion Test Vehicles with ADAMS Simulation

The Capsule Parachute Assembly System (CPAS) project has increased efforts to demonstrate the performance of fully integrated parachute systems at both higher dynamic pressures and in the presence of wake fields using a Parachute Compartment Drop Test Vehicle (PCDTV) and a Parachute Test Vehicle (PTV), respectively. Modeling the extraction and separation events has proven challenging and an understanding of the physics is required to reduce the risk of separation malfunctions. The need for extraction and separation modeling is critical to a successful CPAS test campaign. Current PTV-alone simulations, such as Decelerator System Simulation (DSS), require accurate initial conditions (ICs) drawn from a separation model. Automatic Dynamic Analysis of Mechanical Systems (ADAMS), a Commercial off the Shelf (COTS) tool, was employed to provide insight into the multi-body six degree of freedom (DOF) interaction between parachute test hardware and external and internal forces. Components of the model include a composite extraction parachute, primary vehicle (PTV or PCDTV), platform cradle, a release mechanism, aircraft ramp, and a programmer parachute with attach points. Independent aerodynamic forces were applied to the mated test vehicle/platform cradle and the separated test vehicle and platform cradle. The aero coefficients were determined from real time lookup tables which were functions of both angle of attack ( ) and sideslip ( ). The atmospheric properties were also determined from a real time lookup table characteristic of the Yuma Proving Grounds (YPG) atmosphere relative to the planned test month. Representative geometries were constructed in ADAMS with measured mass properties generated for each independent vehicle. Derived smart separation parameters were included in ADAMS as sensors with defined pitch and pitch rate criteria used to refine inputs to analogous avionics systems for optimal separation conditions. Key design variables were dispersed in a Monte Carlo analysis to provide the maximum expected range of the state variables at programmer deployment to be used as ICs in DSS. Extensive comparisons were made with Decelerator System Simulation Application (DSSA) to validate the mated portion of the ADAMS extraction trajectory. Results of the comparisons improved the fidelity of ADAMS with a ramp pitch profile update from DSSA. Post-test reconstructions resulted in improvements to extraction parachute drag area knock-down factors, extraction line modeling, and the inclusion of ball-to-socket attachments used as a release mechanism on the PTV. Modeling of two Extraction parachutes was based on United States Air Force (USAF) tow test data and integrated into ADAMS for nominal and Monte Carlo trajectory assessments. Video overlay of ADAMS animations and actual C-12 chase plane test videos supported analysis and observation efforts of extraction and separation events. The COTS ADAMS simulation has been integrated with NASA based simulations to provide complete end to end trajectories with a focus on the extraction, separation, and programmer deployment sequence. The flexibility of modifying ADAMS inputs has proven useful for sensitivity studies and extraction/separation modeling efforts. 1

Fraire, Usbaldo, Jr.↗

Computational Study of Vortex-Induced Separation for a 5-Bladed Rotor

This work computationally investigated the rotor blade vortex-induced separation recently observed during an aerodynamic rotor test campaign in the NASA Langley Research Center 14- by 22-Foot Subsonic Tunnel. Two separate approaches (i.e., airfoil modification and blade tip modification) were studied to mitigate the vortex-induced separation. Low-fidelity tools based on blade element momentum theory were shown to mispredict the rotor inflow and were also shown to not capture the vortex-induced separation caused by perpendicular blade-vortex interaction. This misprediction was exploited to isolate the aerodynamic thrust deficit caused by the vortex-induced separation (i.e., 20%) from the thrust deficit due to inflow variation (i.e., 31%). High-fidelity tools were shown to reasonably predict aerodynamic forces within 13% and flow separation when compared to experimental results. The modified airfoil variant of the baseline rotor effectively mitigated the vortex-induced separation while the blade tip modified variant still showed separation, though the size and strength of the vortex was reduced. Acoustic predictions were underpredicted by 10 dB from preliminary measurements taken in the untreated wind tunnel. Broadband noise contributions from different rotor blade sections showed that self-noise due to flow separation and other turbulent boundary layer mechanisms was the dominant noise source for all three rotor cases, followed by blade-wake interaction noise caused by perpendicular blade-vortex interactions.

aerodynamics↗

Process and apparatus for separating solid mixtures

An elutriation column is installed in a separation tank. The elutriation column includes a vertical separation column having a first side feed arm and a second side overflow arm spaced above the first side feed arm. Water is forced upwardly through the vertical separation column at a controllable velocity. A solid feed mixture is fed through the first side feed arm to the vertical separation column. Water from the tank rising in the vertical separation column at the controlled velocity causes targeted floater materials to move upwardly in the vertical separation column and heavier sinker materials to continue to sink. The floater materials flow from an outlet in the side of the separation tank into the recovery tank. At a discharge, lower end of the vertical separation column, the heavier sinker materials are removed from the separation tank. A mechanism is provided for purging undesirable materials that can cause plugging from the feed arm.

Jody, Bassam J.↗

Separable Organic Evaluation: Waste Feed Delivery Impacts - 17563

The potential for separable organic materials to separate out from Hanford tank waste requires consideration for future Waste Feed Delivery operations. Separable organic materials are organic compounds of very limited solubility in bulk waste that can form a separate phase or layer. If the organic materials bound to waste separates during mixing and transfer operations, the feed batch would be disqualified under the Hanford Tank Waste Treatment and Immobilization Plant (WTP) waste acceptance criteria for 'no visible immiscible layer.' Sample data and process history were used to identify tanks with the potential to contain separable organic materials. Centrifuge testing was performed on available archived tank samples and on waste simulants developed to mimic characteristics of the archived tank samples. A separable layer formed during centrifuge testing of archived samples 241-C-204, 241-SY-102, and for all developed simulants tested. Due to the formation of a separable organic layer during the centrifugation studies, an impact assessment was performed. This impact assessment identified forty-four potential tanks of concern regarding the release of organic material bound to solids during waste disturbing activities. A Hanford Tank Waste Operations Simulator model run was modified to trace the origin of each batch to the WTP. The outputs of the model run indicated that a separable organic layer would form during High Level Waste Feed Delivery operations and would cascade to all tanks containing or receiving significant amounts of organic solvents/diluents. Hence, there is a potential for a ripple effect across the feed batches. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Mechanically and thermally robust microporous copolymer separators for lithium ion batteries

Next generation, multifunctional separators can enhance energy storage, power, and safety performance of lithium ion batteries but must be simple to fabricate and incorporate with existing roll-to-roll manufacturing. Here, this study presents a strategy to facilely prepare these separators using UV-initiated polymerization-induced phase separation (PIPS), wherein microporous polymer separators are fabricated directly from constituent monomers and ethylene carbonate (EC) porogen. This enables a wide compositional design space as co-monomers with specific chemical functionality can be readily incorporated into the PIPS precursor mixture. Herein, 1,4-butanediol diacrylate (BDDA) was copolymerized with poly(ethylene glycol) diacrylate (PEGDA) to increase the acrylate conversion in the photopolymerization and improve mechanical properties. By tuning the ratio of PEGDA and EC, separators with high porosity (41.3%) and effective ionic conductivity (2.09 mS cm –1 ) were prepared. Inclusion of PEGDA was essential to increasing the elastic modulus to > 345 MPa, which is required for cell assembly by roll-to-roll manufacturing. All separators prepared were shown to enable reversible cycling of lithium metal/LiNi 0.5 Mn 0.3 Co 0.2 O 2 half-cells for 100 cycles. Unlike conventional polyolefin separators, which were shown to melt at 160 °C and shrink by up to 29.8% at elevated temperatures, the PIPS separators possess exceptional, safety-enhancing thermomechanical properties, undergoing no phase transitions or thermal shrinkage.

25 ENERGY STORAGE↗

Protein-based approach for high-purity Sc, Y, and grouped lanthanide separation

Rare earth elements (REEs: Sc, Y, La- Lu) are irreplaceable components in many clean energy and consumer technologies. However, the extraction and subsequent separation of individual REEs from ore-based feedstocks remains a significant economic and environmental challenge. Here in this work, we investigated the intra-REE separation potential of lanmodulin (LanM), a natural protein from Methylorubrum extorquens that has emerged as a sustainable potential alternative to conventional solvent extraction-based separation. By determining the intra-REE selectivity of immobilized LanM and systematically testing pH-based and small chelator-based (i.e., citrate and malonate) desorption processes, we established the framework and methodology for achieving select individual and grouped REE separations from a mixed REE feedstock. We show that Sc forms the tightest complex with LanM among REEs but can be readily and selectively desorbed using malonate to generate high-purity Sc (>99 % purity, >99 % yield) in a single adsorption/desorption cycle. We further show that the intrinsic REE selectivity of LanM is sufficient to achieve heavy REE (HREE) separation from light and middle REEs (L-MREEs), yielding an yttrium-enriched product. This separation effect is further magnified by pairing LanM’s unique M-LREE preference with a HREE-preferring chelator in the desorption process, which enriches HREE and MREE fractions relative to low value, abundant La/Ce. Finally, by combining pH- and citrate-based desorption processes in a two-cycle separation scheme, we demonstrate the generation of fractions highly enriched in Y, Gd-Lu, Pr-Eu, and La-Ce. Collectively, these data support the application of a LanM-based approach for achieving impactful REE separations from mixed REE feedstocks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Simultaneously Blocking Chemical Crosstalk and Internal Short Circuit via Gel-Stretching Derived Nanoporous Non-Shrinkage Separator for Safe Lithium-Ion Batteries

The separator, an ionic permeable and electronic insulating membrane between cathode and anode, plays a crucial role in the electrochemical and safety performance of batteries. However, the commercial polyolefin separators not only suffer from inevitable thermal shrinkage at elevated temperature, but also fail to inhibit the hidden chemical crosstalk of reactive gases such as O 2 , leading to often reported thermal runaway (TR) and hence preventing large-scale implementation of high-energy-density lithium-ion batteries. Herein, a nanoporous non-shrinkage separator (GS-PI) was fabricated via a novel gel-stretching orientation approach to eliminate TR. In situ synchrotron small angle X-ray scattering during heating clearly showed that the as-prepared thin GS-PI separator exhibits superior mechanical tolerance at high temperature, thus effectively preventing internal short circuit. Meanwhile, the unique nanoporous structure design further blocks chemical crosstalk and the associated exothermic reactions. Accelerating Rate Calorimetry test revealed that the practical 1 Ah LiNi 0.6 Co 0.2 Mn 0.2 O 2 (NCM622)/graphite pouch cell using GS-PI nanoporous separator show a maximum temperature rise (dT/dt max ) of only 3.7 °C s -1 compared to 131.6 °C s -1 in the case of Al 2 O 3 @PE macroporous separator. Furthermore, despite the reduced pore size, the GS-PI separator demonstrates better cycling stability than conventional Al 2 O 3 @PE separator at high temperature without sacrificing specific capacity and rate capability.

25 ENERGY STORAGE↗

Topological origin of phase separation in hydrated gels

Depending on their composition, hydrated gels can be homogeneous or phase-separated, which, in turn, affects their dynamical and mechanical properties. However, the nature of the structural features, if any, that govern the propensity for a given gel to phase-separate remains largely unknown. Here, we argue that the propensity for hydrated gels to phase-separate is topological in nature. We employ reactive molecular dynamics simulations to model the early-age precipitation of calcium–alumino–silicate–hydrate (Csingle bondAsingle bondSsingle bondH) gels with varying compositions, i.e., (CaO) 1.7 (Al 2 O 3 ) x (SiO 2 ) 1 – x (H 2 O) 3.7 + x . By adopting topological constraint theory, we investigate the structural origin of phase separation in hydrated gels. We report the existence of a homogeneous-to-phase-separated transition, wherein Si-rich (x ≤ 0.10) Csingle bondAsingle bondSsingle bondH gels are homogeneous, whereas Al-rich (x > 0.10) Csingle bondAsingle bondSsingle bondH gels tend to phase-separate. Furthermore, we demonstrate that this transition is correlated to a topological flexible-to-rigid transition within the atomic network. Finally, we reveal that the propensity for topologically-overconstrained gels to phase-separate arises from the existence of some internal stress within their atomic network, which acts as an energy penalty that drives phase separation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗