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NASA NTRS2018

Guidelines for Safe, High Performing Li-Ion Battery Designs for Manned Vehicles

New design features and test methods are in development at NASA to take advantage of the newest high power and energy dense commercial Li-ion cell designs and to achieve passively thermal runaway (TR) propagation resistant (PPR) designs for manned missions requiring high power/voltage. The goal is to minimize the parasitic mass and volume of the battery components; thus reaching a balance between high battery specific power (W/kg) and energy (Wh/kg) as well as power (W/L) and energy density (Wh/L). Current 18650 cell designs achieve greater than 275 Wh/kg, greater than 725 Wh/L, but present high risks of side wall breaching during TR which can defeat many other safety features resulting in nearly immediate TR propagation. This work seeks to better understand the phenomena of cell side wall breaches and to determine the effectiveness of promising battery design features for achieving safe, high performing battery designs for high voltage/power applications.

Darst, John J.↗

NASA NTRS2017

Habitable Moist Atmospheres on Terrestrial Planets near the Inner Edge of the Habitable Zone Around M Dwarfs

Terrestrial planets in the habitable zones (HZs) of low-mass stars and cool dwarfs have received significant scrutiny recently. Transit spectroscopy of such planets with the James Webb Space Telescope (JWST) represents our best shot at obtaining the spectrum of a habitable planet within the next decade. As these planets are likely tidally locked, improved 3D numerical simulations of such planetary atmospheres are needed to guide target selection. Here we use a 3D climate system model, updated with new water-vapor absorption coefficients derived from the HITRAN 2012 database, to study ocean-covered planets at the inner edge of the HZ around late M to mid- K stars (2600 K less than or equal to T(sub eff) less than or equal to 4500 K). Our results indicate that these updated water-vapor coefficients result in significant warming compared to previous studies, so the inner HZ around M dwarfs is not as close as suggested by earlier work. Assuming synchronously rotating Earth-sized and Earth-mass planets with background 1 bar N2 atmospheres, we find that planets at the inner HZ of stars with T(sub eff) greater than 3000 K undergo the classical ''moist greenhouse'' (H2O mixing ratio greater than 10(exp -3) in the stratosphere) at significantly lower surface temperature (approx. 280 K) in our 3D model compared with 1D climate models (approx. 340 K). This implies that some planets around low-mass stars can simultaneously undergo water loss and remain habitable. However, for stars with T(sub eff) less than or equal to 3000 K, planets at the inner HZ may directly transition to a runaway state, while bypassing the moist greenhouse water loss entirely. We analyze transmission spectra of planets in a moist greenhouse regime and find that there are several prominent H2O features, including a broad feature between 5 and 8 micron, within JWST MIRI instrument range. Thus, relying only on standard Earth-analog spectra with 24 hr rotation period around M dwarfs for habitability studies will miss the strong H2O features that one would expect to see on synchronously rotating planets around M dwarf stars, with JWST.

Kopparapu, Ravi kumar↗

NASA NTRS2014

On the Frequency of Potential Venus Analogs from Kepler Data

The field of exoplanetary science has seen a dramatic improvement in sensitivity to terrestrial planets over recent years. Such discoveries have been a key feature of results from the Kepler mission which utilizes the transit method to determine the size of the planet. These discoveries have resulted in a corresponding interest in the topic of the Habitable Zone and the search for potential Earth analogs. Within the solar system, there is a clear dichotomy between Venus and Earth in terms of atmospheric evolution, likely the result of the large difference (approximately a factor of two) in incident flux from the Sun. Since Venus is 95% of the Earth's radius in size, it is impossible to distinguish between these two planets based only on size. In this Letter we discuss planetary insolation in the context of atmospheric erosion and runaway greenhouse limits for planets similar to Venus. We define a "Venus Zone" in which the planet is more likely to be a Venus analog rather than an Earth analog. We identify 43 potential Venus analogs with an occurrence rate (η♀) of 0.32 (+0.05/-0.07) and 0.45 (+0.06/-0.09) for M dwarfs and GK dwarfs, respectively.

planetary systems↗

NASA NTRS2019

Metallized Plastic Current Collectors

Metallized plastic current collectors are an innovation patented by the Soteria Battery Innovation Group with the promise of isolating active material involved in an internal short by vaporizing and isolating the short from the rest of the cell electrode jellyroll or stack. Partnering with NREL, UCL, Coulometrics, and Soteria, NASA is leading a research effort into demonstrating the merits and understanding the phenomena of this safety innovation using prototype 18650 cylindrical cells vs control cells with standard metal foil current collectors. Cells with and without the plastic collector, with and without the on-demand internal short circuit device, and with polymer or cellulose separators were made. Safety evaluations were done with driving cells into thermal runaway (TR) with thermal and nail penetration triggers while inside our TR calorimeter and with ultra high speed X-ray videography provided at Synchrotrons. Preliminary results suggests that the thermally unstable plastic current collector innovation has great promise for preventing TR or reducing the severity of the TR output.

Li-ion cell↗

NASA NTRS2019

Characterization of Laptop Fires in Spacecraft

An accidental fire involving the Lithium-Ion (Li-ion) battery in a laptop computer is one of the most likely fire scenarios on-board a spacecraft. These fires can occur from a defect in the battery that worsens with time, over-charging the battery and leading to failure or accidental damage caused by thermal runaway. While this is a relatively likely fire scenario, very little is known about the how a laptop computer fire would impact a sealed spacecraft. The heat release would likely cause a pressure rise, possibly exceeding the pressure limit of the vehicle and causing a relief valve to open. The combustion products from the fire could pose a short-term and long-term health hazard to the crew and the fire itself could cause injury to the crew and damage to the spacecraft. Despite the hazard posed by a laptop fire, there is little quantitative data on the fire size, heat release and toxic product formation. This paper presents the results of initial attempts to quantify the fire resulting from a failed laptop fire tested at the NASA White Sands Test Facility (WSTF). The data from the testing is useful to attempt to determine the fire size and characteristics such as maximum heat release rate, total heat release, maximum temperatures and fire duration are determined. Using existing models and correlations for fires, the measured fire characteristics are extrapolated to laptop fires on a vehicle the approximate size of the Orion spacecraft.

Padilla, Rosa E.↗

NASA NTRS2019

Simulated Phase-dependent Spectra of Terrestrial Aquaplanets in M Dwarf Systems

Orbital phase-dependent variations in thermal emission and reflected stellar energy spectra can provide meaningful constraints on the climate states of terrestrial extrasolar planets orbiting M dwarf stars. Spatial distributions of water vapor, clouds, and surface ice are controlled by climate. In turn, water, in each of its thermodynamic phases, imposes significant modulations to thermal and reflected planetary spectra. Here we explore these characteristic spectral signals, based on 3D climate simulations of Earth-sized aquaplanets orbiting M dwarf stars near the habitable zone. By using 3D models, we can self-consistently predict surface temperatures and the location ofwater vapor, clouds, and surface ice in the climate system. Habitable zone planets in M dwarf systems are expected to be in synchronous rotation with their host star and thus present distinct differences in emitted and reflected energy fluxes depending on the observed hemisphere. Here we illustrate that icy, temperate, and incipient runaway greenhouse climate states exhibit phase-dependent spectral signals that enable their characterization.

Wolf, E. T.↗

NASA NTRS2019

Development of Solid State Electrolytes for Li-Metal Based High Capacity Battery

NASA future missions demand safe, high specific energy (>400 Wh/kg) batteries. Current state-of-the-art (SOA) lithium-ion batteries (LIBs) can only provide ~150-200 Wh/kg in energy capacity, which is unable to meet NASA's future energy goals, and also pose safety issues due to the use of liquid flammable electrolyte. There are intense on-going development activities to increase battery energy density. The use of Li metal as an anode material has emerged as one highly attractive option for achieving high-energy, next generation batteries. This is because Li has many advantages. It is the lightest metal, but also has the highest theoretical capacity. It also has the lowest potential, which boosts whole cell voltage, and Li metal is 100% active material and requires no binder. Thus, Li metal is an ideal anode material for high energy battery chemistries. Lithium metal based advanced battery chemistries are envisioned to be mission enhancing and, in many cases, mission enabling for future space and aeronautic applications. However, the reliable use of this exceptionally high capacity anode in a commercial rechargeable battery has not been achieved due to safety and reliability concerns resulting from thermal runaway and short-circuit issues due to dendritic growth on the Li metal anode from lithium plating during charge-discharge cycles. A solid state electrolyte, such as garnet/ceramic or solid polymer nanocomposite electrolyte, is a promising approach to make Li metal safely cycling. The solid state electrolyte is non-flammable and eliminates leakage and fire hazard by replacing the liquid flammable electrolyte. However, the low-ionic conductivity and high interfacial impedance are the key issues to be overcome. In this presentation, the research activities on solid state electrolyte development funded by the NASA Advanced Energy Storage System program and by the NASA Center Innovative Fund will be presented, and the progress and results will be also discussed.

Wu, James J.↗

NASA NTRS2019

Hazardous Product Detection and Environmental Clean-up Removal in Spacecraft Vehicles from Fire Induced Li-Ion Fires

A fire on-board the International Space Station (ISS) resulting from a commercial Surface Pro tablet Lithium-Ion (Li-ion) battery can be detrimental to the spacercraft and the astronauts. The Spacecraft Fire Safety Demonstration (Saffire) program is focused on identifying and quantifying the risks that potentially arise inside a space vehicle by conducting large fire experiments inside the Cygnus cargo vehicle upon re-entry to Earth. The potential candidate that will be flown on the ISS is a 4- cell Li-ion battery pack Surface Pro tablet (42 Wh). The tablets were tested at the White Sands Test Facility (WSTF) using a localized heating method to emulate the failing mechanism that leads the unit into thermal runaway. Measurements inside the test chamber were performed on aerosol mass concentrations and for specific toxic products (i.e. from CO, HCN, HCl and CO2). These toxic products depend on the size of the fire and energy content of the tablet. Comparisons will be made with the Dell XPS (97 Wh). The concentrations are then used to extrapolate to laptop fires on a vehicle at the approximate volumetric size of the Orion spacecraft. The presentation provides an analysis on the detection capability and the response time to trigger fire alarms aboard a vehicle by using the mass concentration levels. These results will consider the rate at which the life support system is able to filter the atmosphere in order to provide a hazardous free environment.

Padilla, Rosa E.↗

NASA NTRS2020

Possible Climate Histories of Venus Type Worlds

There are two well-known scenarios for Venus’ climate evolution. In one Venus had a long-lived magma ocean phase in its first 100Myr with a steam and CO2 dominated atmosphere. The faint young sun with its high XUV flux would cause photodissociation of the steam atmosphere and hydrodynamic escape would cause most of the hydrogen to escape & left-over oxygen would be absorbed by the magma ocean. Hence Venus would have started out hot and dry and the high D/H ratio measured by Pioneer Venus would be from this period of water loss. The other scenario is that Venus’ magma ocean lifetime would have been roughly the same length of time as Earth’s (~1Myr) and water would have condensed on its surface in its early history and had a short period of habitability before increasing solar insolation through time drove it into a runaway greenhouse. However, results from 2016 showed that if Venus remains in the slowly rotating climate dynamics regime (as seen in exoplanet related climate studies) its cloud albedo feedback would have kept it temperate for possibly billions of years. The only way to confirm which one of these scenarios occurred for Venus is to visit it and make the necessary measurements of noble and volatile gases. But exoplanet observations of young exo-Venus type worlds around young F,G,K dwarf stars may constrain which scenario is more probable for a population of such planets. We present a vision of Venus’ climate history that places it and its exoVenus cousins in an ‘Optimistic Venus Zone’ for ~3 billion years within the conventionally named ‘Venus Zone’ and hence encourage the exoplanet communit as possible habitable environments.

Way, M. J.↗

NASA NTRS2019

Venus as a Laboratory for Exoplanetary Science

The current goals of the astrobiology community are focused on developing a framework for the detection of biosignatures, or evidence thereof, on objects inside and outside of our solar system. A fundamental aspect of understanding the limits of habitable environments (surface liquid water) and detectable signatures thereof is the study of where the boundaries of such environments can occur. Such studies provide the basis for understanding how a once inhabitable planet might come to be uninhabitable. The archetype of such a planet is arguably Earth’s sibling planet, Venus. Given the need to define the conditions that can rule out bio-related signatures of exoplanets, Venus provides a unique opportunity to explore the processes that led to a completely uninhabitable environment by our current definition of the term. Here we review the current state of knowledge regarding Venus, particularly in the context of remote-sensing techniques that are being or will be employed in the search for and characterization of exoplanets. We discuss candidate Venus analogs identified by the Kepler and TESS exoplanet missions and provide an update to exoplanet demographics that can be placed in the potential runaway greenhouse regime where Venus analogs are thought to reside. We list several major outstanding questions regarding the Venus environment and the relevance of those questions to understanding the atmospheres and interior structure of exoplanets. Finally, we outline the path towards a deeper analysis of our sibling planet and the synergy to exoplanetary science.

Venus↗

NASA NTRSDate not supplied

Sensor-based Prognostics for Safe Batteries for Electric Aircraft

With a new start awarded under CAS for Fiscal Year 2020, the Sensor-based Prognostics to Avoid Runaway Reactions and Catastrophic Ignition project, or SPARRCI, aims to eliminate safety risks of lithium-ion and next-generation lithium-based batteries. SPARRCI is taking a deeper dive into the inner workings of battery cells by introducing miniature multifunctional sensors within the cells to detect early signs of failure. Combined with nondestructive evaluation techniques to gather complementary battery health data, battery data will be monitored in real-time via prognostics which will ultimately be able to identify when the cell is exhibiting abnormal behavior bordering on failure, with the ability to provide early warning such that the battery may be taken offline prior to catastrophic failure events.

Brianne Demattia↗

NASA NTRSDate not supplied

Solid-state battery designed for electric aviation

The demand for higher energy density batteries increases as the demand for portable electronic devices and electric automotive increases, as well as a variety of other applications requiring substantially higher power and energy than attainable with current lithium-ion capabilities which includes the areas of high performance vehicles, military applications, and electric aviation. However, the improvement of energy density is insufficient alone for enabling electric aviation when considering the high flammability and risk of thermal runaway inherent in current state-of-the-art liquid electrolytes. The development of high energy, high power, and safe batteries are required to enable hybrid and fully electric aircraft. Next generation chemistries such as lithium-sulfur provide high theoretical specific energy density suitable for electric aviation without as strict of volumetric requirements observed in the automotive industry. However, due to the phase transition during discharge where sulfur generates a series of soluble intermediate polysulfides, which are lost to the liquid electrolyte, cause detrimental side effects, and severely limit cycle life battery performance is severely reduced. Additionally, the low electrical conductivity of sulfur requires a large amount of inactive carbon dramatically increasing parasitic mass. The dissolution issue make sulfur a desirable candidate to pair with a solid-state electrolyte in order to avoid polysulfide dissolution and shuttling. In addition, inorganic solid-electrolytes have low flammability providing the improved safety required. Combining this chemistry with a solid-state electrolyte provides a path for achieving the energy and safety required for electric aviation. The development of scalable thin solid-state electrolytes paired with lithium-sulfur chemistry will be discussed and how their development will aid in enabling a unique application.

Donald A. Dornbusch↗

NASA NTRS2020

Increasing Activity in T CrB Suggests Nova Eruption Is Impending

Estimates of the accretion rate in symbiotic recurrent novae (RNe) often fall short of theoretical expectations by orders of magnitude. This apparent discrepancy can be resolved if the accumulation of mass by the white dwarf(WD)is highly sporadic, and most observations are performed during low states. Here we use a re-analysis of archival data from the Digital Access to a Sky Century @Harvard survey to argue that the most recent nova eruption in symbiotic RN T CrB, in 1946, occurred during—and was therefore triggered by—a transient accretion high state. Based on similarities in the optical light curve around 1946 and the time of the prior eruption, in 1866,we suggest that the WD in T CrB accumulates most of the fuel needed to ignite the thermonuclear runaways (TNRs) during accretion high states. A natural origin for such states is dwarf-nova like accretion-disk instabilities, which are expected in the presumably large disks in symbiotic binaries. The timing of the TNRs in symbiotic RNe could thus be set by the stability properties of their accretion disks. T CrB is in the midst of an accretion high state like the ones we posit led to the past two nova eruptions. Combined with the approach of the time at which a TNR would be expected based on the 80 yr interval between the prior two novae (2026 ± 3), the current accretion high state increases the likelihood of a TNR occurring in T CrB in the next few years.

Gerardo J M Luna↗

NASA NTRSDate not supplied

Thermal Control in Hypersonic Leading Edges Using Liquid Metal High Temperature Oscillating Heat Pipes

The desire to increase the range and speed of hypersonic vehicles requires sharp, shape-stable Wing Leading Edges (WLE) with performance capabilities well beyond the current state of the art. The concentrated heat flux on sharp leading edges can lead to runaway thermal and mechanical failures. Heat pipes provide a passive solution to minimize the peak temperature, thermal gradients, and resulting thermal stresses near the WLE. Conventional heat pipes have been shown to address these issues at conditions as high as Mach 8. Oscillating heat pipes (OHPs) could be used to extend this benefit to missions with higher Mach numbers since their heat transport capacity typically exceeds that of conventional heat pipes. In the current investigation, several identical liquid metal high-temperature oscillating heat pipes (LMHOHPs) were constructed and tested to demonstrate the concept. The LMHOHPs had six turns, internal diameters of 2 mm, and total lengths of 100 mm. They were additively manufactured from C103 niobium alloy and charged with lithium to reach a fill ratio of approximately 50%. The boundary conditions of the experiment were designed to resemble those of various hypersonic flight profiles. Testing was performed with a system consisting of flow-controlled acetylene torch heating and radiation dominated heat rejection. The LMHOHP’s performance was measured using temperature data from an infrared camera and pyrometer. The experimental results were used to evaluate the capability of C103/lithium LMHOHPs under various flight regimes. A heat transfer model of the LMHOHP was proposed and validated against test data. Insights from the model were then extrapolated to evaluate a Tungsten-RHC/Gallium LMHOHP with anticipated capabilities beyond that of the C103/lithium system.

Max Pawlick↗

NASA NTRSDate not supplied

Investigation of Rectifier Diode Failures in the NEXT-C Power Processing Unit

NASA's Evolutionary Xenon Thruster-Commercial (NEXT-C) project is tasked with developing flight electric propulsion systems, including both thrusters and power processing units (PPUs). In 2018, the beam supply in a NEXT-C engineering prototype PPU experienced an output rectifier diode failure during development thermal-vacuum testing. A failure investigation led by NASA GRC identified the root cause of the failure as a thermal runaway caused by increased reverse recovery losses in the diodes when the PPU was run at its maximum operating temperature. Significant reverse recovery performance variations were identified in diodes with the same part number but manufactured by different vendors. The failure investigation was able to collect evidence of the increased reverse recovery and replicate the diode failures in a controlled laboratory environment.

George L Thomas↗

NASA NTRSDate not supplied

Investigation of Rectifier Diode Failures in the NEXT-C Power Processing Unit

George L. Thomas↗

NASA NTRSDate not supplied

Robustness of Semi-Superjunction 4H-SiC Power DMOSFETs to Single-Event Burnout from Heavy Ion Bombardment

We compare the failure mechanism and performance of a silicon carbide (SiC) semi-superjunction (semi-SJ) power DMOSFET against pure SJ and conventional DMOSFET when struck by a single heavy ion. The Single-Event Burnout (SEB) failure mechanism was identified as the thermal runaway from second breakdown resulting in mesoplasma formation. The semi-SJ design shifts the mesoplasma location from the drift/substrate interface seen in the control device structures to a location along the center of the P-pillar and closer towards the DMOSFET surface, thus significantly improving the SEB threshold voltage. The SEB threshold voltage varies with pillar width and ratio of pillar thickness to drift layer thickness. A maximum value of SEB threshold voltage is reached when the pillar to drift layer ratio is 0.9 and the pillar width is 2.4 μm. The semi-SJ SEB/breakdown voltage ratio is 100% and 13% higher than the pure SJ and conventional DMOSFET, respectively. Using a new figure of merit (FOM), which accounts for the tradeoff between SEB threshold voltage and on-state performance, we find that the SiC semi-SJ DMOSFET achieves a FOM that is 1.8 and 8 times higher than SJ and conventional DMOSFET, respectively, making the semi-SJ a competitive candidate for radiation hardened applications.

SiC↗

NASA NTRSDate not supplied

A Snowball in Hell: The Potential Steam Atmosphere of TOI-1266c

The recent discovery of two planets orbiting TOI-1266 (Stef nsson et al., 2020) offers a rare opportunity to begin observing the simultaneous impacts of both a planet and host star evolving through time. While both planets’ masses are poorly constrained at present, planet c could ultimately fall into one of several categories, including that of a super-Venus or a warm sub-Neptune. This latter scenario would mean that TOI-1266c could still have a substantial water inventory if it originally formed beyond the ice line and migrated to its present location. If so, then planet c would be a long-lived analogue of Venus during its runaway greenhouse state, which is thought to have lasted millions of years (e.g., Zahnle & Kasting, 1986).

C. E. ‘Sonny’ Harman↗