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At least 379 records · Page 21

Multimodel Estimates of Atmospheric Lifetimes of Long-Lived Ozone-Depleting Substances: Present and Future

We have diagnosed the lifetimes of long-lived source gases emitted at the surface and removed in the stratosphere using six three-dimensional chemistry-climate models and a two-dimensional model. The models all used the same standard photochemical data. We investigate the effect of different definitions of lifetimes, including running the models with both mixing ratio (MBC) and flux (FBC) boundary conditions. Within the same model, the lifetimes diagnosed by different methods agree very well. Using FBCs versus MBCs leads to a different tracer burden as the implied lifetime contained in theMBC value does not necessarilymatch a model's own calculated lifetime. In general, there are much larger differences in the lifetimes calculated by different models, the main causes of which are variations in the modeled rates of ascent and horizontal mixing in the tropical midlower stratosphere. The model runs have been used to compute instantaneous and steady state lifetimes. For chlorofluorocarbons (CFCs) their atmospheric distribution was far from steady state in their growth phase through to the 1980s, and the diagnosed instantaneous lifetime is accordingly much longer. Following the cessation of emissions, the resulting decay of CFCs is much closer to steady state. For 2100 conditions the model circulation speeds generally increase, but a thicker ozone layer due to recovery and climate change reduces photolysis rates. These effects compensate so the net impact on modeled lifetimes is small. For future assessments of stratospheric ozone, use of FBCs would allow a consistent balance between rate of CFC removal and model circulation rate.

CH3CCl3↗

Multimodel Estimates of Atmospheric Lifetimes of Long-lived Ozone-Depleting Substances: Present and Future

We have diagnosed the lifetimes of long-lived source gases emitted at the surface and removed in the stratosphere using six three-dimensional chemistry-climate models and a two-dimensional model. The models all used the same standard photochemical data. We investigate the effect of different definitions of lifetimes, including running the models with both mixing ratio (MBC) and flux (FBC) boundary conditions. Within the same model, the lifetimes diagnosed by different methods agree very well. Using FBCs versus MBCs leads to a different tracer burden as the implied lifetime contained in the MBC value does not necessarily match a model's own calculated lifetime. In general, there are much larger differences in the lifetimes calculated by different models, the main causes of which are variations in the modeled rates of ascent and horizontal mixing in the tropical midlower stratosphere. The model runs have been used to compute instantaneous and steady state lifetimes. For chlorofluorocarbons (CFCs) their atmospheric distribution was far from steady state in their growth phase through to the 1980s, and the diagnosed instantaneous lifetime is accordingly much longer. Following the cessation of emissions, the resulting decay of CFCs is much closer to steady state. For 2100 conditions the model circulation speeds generally increase, but a thicker ozone layer due to recovery and climate change reduces photolysis rates. These effects compensate so the net impact on modeled lifetimes is small. For future assessments of stratospheric ozone, use of FBCs would allow a consistent balance between rate of CFC removal and model circulation rate

CFC↗

Data from: "Snowmelt Timing Regulates Community Composition, Phenology, and Physiological Performance of Alpine Plants"

This archive contains data that were used to support conclusions drawn in “Snowmelt Timing Regulates Community Composition, Phenology, and Physiological Performance of Alpine Plants”, by Winkler et al., 2018. Data were collected throughout the 2009 growing season on Niwot Ridge, Colorado, before the site became part of the Alpine Treeline Warming Experiment (ATWE). Geospatial files are included in this archive to provide additional locational context. The files in this data package consist of five comma-separated-values (.csv) files, one keyhole markup language (.kml) file, and two ESRI shapefiles (.shp). The .csv files can be opened by Microsoft Excel, R, or any simple text-editor software, such as TextEdit (MacOS) or Notepad (Windows). The .kml files can be opened by Google Maps or Google Earth, and the .shp files are compatible with GIS softwares such as ESRI’s ArcGIS suite, and QGIS.------------------------------------------------------------------------------------------------------------------------------------------------------------------------------We asked how plant community composition, phenology, plant water relations, and photosynthetic gas exchange of alpine-restricted and wide-ranging species differ in their responses to a ca. 40-day snowmelt gradient in the Colorado Rocky mountains (Lewisia pygmaea, Sibbaldia procumbens, and Hymenoxys grandiflora were alpine-restricted and Artemisia scopulorum, Carex rupestris, and Geum rossii were wide-ranging species). To do this, we measured percent cover and flowering initiation across 20 plots varying in snowmelt timing and measured net photosynthesis and stomatal conductance in multiple individuals of each target species in these plots in 2009.As hypothesized, species richness and foliar cover increased with earlier snowmelt, due to a greater abundance of wide-ranging species present in earlier melting plots. Flowering initiation occurred earlier with earlier snowmelt for 12 out of 19 species analyzed, while flowering duration was shortened with later snowmelt for six species (all but one were wide ranging species). We observed >50% declines in net photosynthesis from July to September as soil moisture and plant water potentials declined. Early-season stomatal conductance was higher in wide-ranging species, indicating a more competitive strategy for water acquisition when soil moisture is high. Even so, there were no associated differences in photosynthesis or transpiration, suggesting no strong differences between these groups in physiology.

54 ENVIRONMENTAL SCIENCES↗

Structure and Dynamics of Coronal Plasma

Brief summaries of the four published papers produced within the present performance period of NASA Grant NAGW-4081 are presented. The full text of the papers are appended to the report. The first paper titled "Coronal Structures Observed in X-rays and H-alpa Structures" was published in the Kofu Symposium proceedings. The study analyzes cool and hot behavior of two x-ray events, a small flare and a surge. It was found that a large H-alpha surge appears in x-rays as a very weak event, while a weak H-alpha feature corresponds to the brightest x-ray emission on the disk at the time of the observation. Calculations of the heating necessary to produce these signatures, and implications for the driving and heating mechanisms of flares vs. surges are presented. The second paper "Differential Magnetic Field Shear in an Active Region" has been published in The Astrophysical Journal. The study compared the three dimensional extrapolation of magnetic fields with the observed coronal structure in an active region. Based on the fit between observed coronal structure throughout the volume of the region and the calculated magnetic field configurations, the authors propose a differential magnetic field shear model for this active region. The decreasing field shear in the outer portions of the AR may indicate a continual relaxation of the magnetic field with time, corresponding to a net transport of helicity outward. The third paper "Difficulties in Observing Coronal Structure" has been published in the journal Solar Physics. This paper discusses the evidence that the temperature and density structure of the corona are far more complicated than had previously been thought. The discussion is based on five studies carried out by the group on coronal plasma properties, showing that any one x-ray instrument does see all of the plasma present in the corona, that hot and cool material may appear to be co-spatial at a given location in the corona, and that simple magnetic field extrapolations provide only a poor fit to the observed structure. The fourth paper "Analysis and Comparison of Loop Structures Imaged with NIXT and Yohkoh/SXT" has been published in Astronomy and Astrophysics. This paper analyzes and compares a variety of coronal loops, deriving loop pressure and emission measure from loop models. They are able to determine the volume filling factor in the corona, which is found to be in the range 0.001 to 0.01 for compact loops, and of order 1 for large structures. The small values suggest highly filamented structures, especially at lower temperatures.

Golub, Leon↗

Thermal balance of the atmospheres of Jupiter and Uranus

Two-dimensional, radiative-convective-dynamical models of the visible atmospheres of Jupiter and Uranus are presented. Zonally-averaged temperatures and heat fluxes are calculated numerically as functions of pressure and latitude. In addition to radiative heat fluxes, the dynamical heat flux due to large-scale baroclinic eddies is included and is parametrized using a mixing length theory which gives heat fluxes similar to those of Stone. The results for Jupiter indicate that the internal heat flow is non-uniform in latitude and nearly balances the net radiative flux leaving the atmosphere. The thermal emission is found to be uniform in latitude in agreement with Pioneer and Voyager observations. Baroclinic eddies are calculated to transport only a small amount of the meridional heat flow necessary to account for the uniformity of thermal emission with latitude. The bulk of the meridional heat transfer is found to occur very deep in the stable interior of Jupiter as originally proposed by Ingersoll and Porco. The relative importance of baroclinic eddies vs. internal heat flow in the thermal balance of Uranus depends on the ratio of emitted thermal power to absorbed solar power. The thermal balance of Uranus is compared to that of Jupiter for different values of this ratio.

Friedson, A. J.↗

Directly Measured Heating Rates of a Tropical Subvisible Cirrus Cloud

We present the first direct measurements of the infrared and solar heating rates of a tropical subvisible cirrus (SVC) cloud sampled off the east coast of Nicaragua on 25 July 2007 by the NASA ER-2 aircraft during the Tropical Composition, Cloud and Climate Coupling Experiment (TC4). On this day a persistent thin cirrus layer, with mostly clear skies underneath, was detected in real time by the cloud lidar on the ER-2, and the aircraft was directed to profile down through the SVC. Measurements of the net broadband infrared irradiance and spectrally integrated solar irradiance above, below, and through the SVC are used to determine the infrared and solar heating rates of the cloud. The lidar measurements show that the variable SVC layer was located between approximately 13 and 15 km. Its midvisible optical depth varied from 0.01 to 0.10 with a mean of 0.034 +/- 0.033. Its depolarization ratio was approximately 0.4, indicative of ice clouds. From the divergence of the measured net irradiances the infrared heating rate of the SVC was determined to be approximately 2.50 - 3.24 K/d and the solar heating rate was found to be negligible. These values are consistent with previous indirect observations of other SVC and with model-generated heating rates of SVC with similar optical depths. This study illustrates the utility and potential of the profiling sampling strategy employed here. A more fully instrumented high-altitude aircraft that also included in situ cloud and aerosol probes would provide a comprehensive data set for characterizing both the radiative and microphysical properties of these ubiquitous tropical clouds

Bucholtz, Anthongy↗

Extracting the Galactic Center excess’ source-count distribution with neural nets

The two leading hypotheses for the Galactic Center excess (GCE) in the Fermi data are an unresolved population of faint millisecond pulsars (MSPs) and dark-matter (DM) annihilation. The dichotomy between these explanations is typically reflected by modeling them as two separate emission components. However, point sources (PSs) such as MSPs become statistically degenerate with smooth Poisson emission in the ultrafaint limit (formally where each source is expected to contribute much less than one photon on average), leading to an ambiguity that can render questions such as whether the emission is PS-like or Poissonian in nature ill defined. We present a conceptually new approach that describes the PS and Poisson emission in a unified manner and only afterwards derives constraints on the Poissonian component from the so obtained results. For the implementation of this approach, we leverage deep learning techniques, centered around a neural network-based method for histogram regression that expresses uncertainties in terms of quantiles. We demonstrate that our method is robust against a number of systematics that have plagued previous approaches, in particular DM/PS misattribution. In the Fermi data, we find a faint GCE described by a median source-count distribution (SCD) peaked at a flux of ~ 4 x 10 -11 counts cm -2 s -1 (corresponding to ~ 3-4 expected counts per PS), which would require N ~ $\mathscr{O}$(10 4 ) sources to explain the entire excess (median value N = 29,300 across the sky). Although faint, this SCD allows us to derive the constraint η ρ ≤ 66% for the Poissonian fraction of the GCE flux η ρ at 95% confidence, suggesting that a substantial amount of the GCE flux is due to PSs.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Strangeness-correlations on the pseudocritical line in ( 2 + 1 )-flavor QCD

We present some lattice QCD results on first ( χ 1 i ) and second ( χ 2 i ) cumulants of and correlations ( χ 11 i j ) among net baryon-number ( B ), strangeness ( S ) and electric charge ( Q ) along the pseudocritical line [ T p c ( μ B ) ] in the temperature ( T )–baryon chemical potential ( μ B ) phase diagram of ( 2 + 1 )-flavor QCD. We point out that violations of sum rules among second order cumulants, which hold in the isospin symmetric limit of vanishing electric charge chemical potential, are small along the T p c ( μ B ) for the entire range of μ B covered in the RHIC beam energy scan. For the strangeness neutral matter produced in heavy-ion collisions this leads to a close relation between χ 11 B S and χ 11 Q S . We compare lattice QCD results for χ 11 B S / χ 2 S along the T p c ( μ B ) line with preliminary experimental measurements of χ 11 B S / χ 2 S for collision energies 7.7 GeV ≤ s N N ≤ 62.4 GeV . While we find good agreements for s N N ≥ 39 GeV , differences are sizeable at smaller values of s N N . Moreover, we compare lattice QCD results for the ratio of the strangeness ( μ S ) to baryon ( μ B ) chemical potentials, which define a strangeness neutral system with fixed electric charge to baryon number density, with experimental results obtained by the STAR collaboration for μ S / μ B using strange baryon yields on the freeze-out line. Finally, we determine the baryon chemical potential at the freeze-out ( μ B f ) by comparing χ 1 B / χ 2 B along the T p c ( μ B ) with the experimentally measured net-proton cumulants χ 1 p / χ 2 p . We find that { μ B f , T p c ( μ B f ) } are consistent with the freeze-out parameters of the statistical-model fits to experimentally measured hadron yields for s N N ≥ 11.5 GeV . Published by the American Physical Society 2024

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Effects of CO2 concentration and light intensity on photosynthesis of a rootless submerged plant, Ceratophyllum demersum L., used for aquatic food production in bioregenerative life support systems

In addition to green microalgae, aquatic higher plants are likely to play an important role in aquatic food production modules in bioregenerative systems for producing feed for fish, converting CO2 to O2 and remedying water quality. In the present study, the effects of culture conditions on the net photosynthetic rate of a rootless submerged plant, Ceratophyllum demersum L., was investigated to determine the optimum culture conditions for maximal function of plants in food production modules including both aquatic plant culture and fish culture systems. The net photosynthetic rate in plants was determined by the increase in dissolved O2 concentrations in a closed vessel containing a plantlet and water. The water in the vessel was aerated sufficiently with a gas containing a known concentration of CO2 gas mixed with N2 gas before closing the vessel. The CO2 concentrations in the aerating gas ranged from 0.3 to 10 mmol mol-1. Photosynthetic photon flux density (PPFD) in the vessel ranged from 0 (dark) to 1.0 mmol m-2 s-1, which was controlled with a metal halide lamp. Temperature was kept at 28 degrees C. The net photosynthetic rate increased with increasing PPFD levels and was saturated at 0.2 and 0.5 mmol m-2 s-1 PPFD under CO2 levels of 1.0 and 3.0 mmol mol-1, respectively. The net photosynthetic rate increased with increasing CO2 levels from 0.3 to 3.0 mmol mol-1 showing the maximum value, 75 nmol O2 gDW-1 s-1, at 2-3 mmol mol-1 CO2 and gradually decreased with increasing CO2 levels from 3.0 to 10 mmol mol-1. The results demonstrate that C. demersum could be an efficient CO2 to O2 converter under a 2.0 mmol mol-1 CO2 level and relatively low PPFD levels in aquatic food production modules. c2003 COSPAR. Published by Elsevier Science Ltd. All rights reserved.

Ecological Systems, Closed↗

Modeling ash deposition and shedding during oxy-combustion of coal/rice husk blends at 70% inlet O2

Abstract Co-firing rice husk (RH) and coal with carbon capture using oxy-combustion presents a net carbon negative energy production opportunity. In addition, the high fusion temperature of the non-sticky, silica rich, RH can mitigate ash deposition as well as promote shedding of deposits. To identify the optimum operating conditions, fuel particle sizes, and blend ratios that minimize ash deposition, a Computational Fluid Dynamic methodology with add-on ash deposition and shedding models were employed to predict outer ash deposition and shedding rates during co-combustion of coal/RH in AIR and O 2 /CO 2 (70/30 vol%, OXY70) oxidizer compositions. After ensuring that the fly-ash particle size distributions and particle Stokes numbers near the deposition surface were accurately represented (to model impaction), appropriate models for coal ash and RH ash viscosities that were accurate in the temperature region (1200–1300 K) of interest in this study were identified. A particle viscosity and kinetic energy (PKE) based capture criterion was enforced to model the ash capture. An erosion/shedding criterion that takes the deposit melt fraction and the energy consumed during particle impact into account was also implemented. Deposition rate predictions as well as the deposition rate enhancement (OXY70/AIR) were in good agreement with measured values. While the OXY70 scenario was associated with a significant reduction (60%–70%) in flue gas velocities, it also resulted in larger fly-ash particles. As a result, the PKE distributions of the erosive RH ash were similar in both scenarios and resulted in similar shedding rates.

Energy & Fuels↗

Development of a silicon carbide ceramic based counter-flow heat exchanger by binder jetting and liquid silicon infiltration for concentrating solar power

A silicon carbide ceramic counter-flow heat exchanger with integrated headers was printed by binder jetting additive manufacturing process. Multiple phenolic binder infiltration cycles (3 or 5) followed by pyrolysis were conducted to increase the net carbon content of the printed SiC specimens. Subsequently, to attain full densification, silicon melt infiltration was used. The microstructure and mechanical properties were comprehensively characterized on the densified material. The chemical compositions and visual distribution of the various regions in the specimens were determined via scanning electron microscopy, while X-ray diffraction and synchrotron µ-computed tomography were used to provide a quantitative assessment of the volume fractions of the identified phase regions. Microhardness measurements showed dependence on the local microstructure. The fracture strength of the material was correlated with the specimen density and agreed with the reported values in the literature. High-temperature exposure at 750 °C for up to 200h did not degrade the strength for the specimens with three phenolic-binder infiltrations; however, the strengths degraded for ones with five phenolic-binder infiltrations. The associated fracture toughnesses of the specimens were ~3.4 MPam 1/2 at room temperature and 750°C, and the thermal conductivities varied from >150 W/mK at room temperature to ~45 W/mK at 750°C. Hence, this study validated the use of the binder-jetting printed SiC ceramic materials for high-temperature heat exchanges. Lastly, we also present in this work the first successful fabrication of a binder-jetting printed one-piece dense SiC ceramic heat exchanger body with unblocked channels that can be used for the flow of heat transfer fluids.

36 MATERIALS SCIENCE↗

2023 Critical Materials Strategy

The global effort to curb carbon emissions is accelerating demand for clean energy technologies and the materials they rely on. Demand for these materials will only continue to grow, especially as some nations aim to achieve net zero emissions by 2050. While some major materials like steel, copper, and aluminum are already powering the fossil fuel economy, others are more minor materials with potential supply risks. These risks could jeopardize the ability to reduce greenhouse gas emissions within the desirable timeframe to avoid significant climate change. In some cases, it may be necessary to take action to improve the resilience of material supply chains and mitigate supply risks. Understanding the importance of individual materials to clean energy and the supply risks associated with them is necessary to identify which materials may serve as potential roadblocks to a clean energy future. The U.S. Department of Energy (DOE) issued a series of 13 supply chain deep dive assessment reports on various energy technologies in 2022 in response to President Biden’s Executive Order on America’s Supply Chains (E.O. 14017). These reports emphasized that supply chain bottlenecks can occur at any stage of the value chain from mining and refining to component and even sub-system manufacturing. The bottlenecks are a combination of factors such as material availability, equipment availability, work force availability and quality, logistics, regulatory framework, and market conditions. These bottlenecks were worsened during the global Covid-19 pandemic. Its lingering impacts have hindered capacity expansion for material supply chains and prevented product lead-time recovery. One approach to reduce supply chain risks for the United States is to have a strong domestic manufacturing sector with a diverse set of producers. Boosting responsible domestic production would require leveraging the latest science not only in material extraction but also in developing substitutes, recycling, reuse, and remanufacturing. This report is an updated analysis of previous Critical Materials Strategy (CMS) reports published by the DOE in 2010, 2011, and 2019 based on national and global priorities, technology advancement, and technology adoption trends. Like the CMS reports, this analysis presents the results of a formal material criticality assessment to identify which materials are critical to the continued deployment of clean energy technologies globally. The analysis in this report leveraged the DOE supply chain deep dive assessments to develop the initial list of materials to evaluate. This DOE Critical Materials Assessment (CMA) is conducted independently of criticality assessments performed by other U.S. government agencies, such as that conducted by the U.S. Geological Survey (USGS). This analysis complements the USGS critical minerals determination in three aspects. First, the DOE assessment is performed from a global perspective, while the USGS analysis focusses on the importance of minerals to the U.S. economy. Second, this report focuses on the importance of materials to clean energy technologies, rather than to the economy in general. Lastly, this study is forward looking to 2035 based on clean energy deployment scenarios, whereas the USGS assessment is retrospective. Materials evaluated in this report that do not appear in the USGS Critical Minerals List include copper, uranium, electrical steel, and SiC. A draft version of this report received ~80 public comments related to supporting data and methodological improvement. Those comments have been incorporated as much as possible where appropriate. Highlights of findings from this 2023 CMA include: Rare earth materials (neodymium, praseodymium, dysprosium, and terbium) used in magnets in electric vehicle (EV) motors and wind turbine generators continue to be critical. While dysprosium (Dy) and terbium (Tb) are both heavy rare earth elements that serve the same function in magnets, the criticality of Tb is slightly lower than that for Dy in the short term due to the widespread use of Dy in high-grade magnets and Tb’s present role as a substitute. Similarly, praseodymium (Pr) is critical in the medium term but only near critical in the short term because it is more substitutable in magnets than neodymium (Nd); Materials used in batteries for EVs and stationary storage are now considered to be critical. While cobalt (Co) was found to be critical in this and previous reports, lithium (Li) becomes critical in the medium term due to its broader use in various battery chemistries and the rampant growth of the EV industry. Natural graphite is a new addition in this assessment and is also found to be critical; Platinum group metals used in hydrogen electrolyzers, such as platinum (Pr) and iridium (Ir), are critical due to an increased focus on hydrogen technologies to achieve net zero carbon emissions, while those used in catalytic converters, such as rhodium (Rh) and palladium (Pd), were screened out due to the decreased importance of catalytic converters in the medium term; Gallium (Ga) continues to be critical due to its use in light-emitting diodes (LEDs). In addition, the use of Ga has increased in magnet manufacturing and in semiconductor in forms such as gallium arsenide (GaAs) or gallium nitride (GaN); Major materials like Aluminum (Al), copper (Cu), nickel (Ni), and silicon (Si) move from noncritical in the short term to near critical in the medium term due to their importance in electrification; Electrical steel is near critical due to its use in transformers for the grid and electric motors in EVs.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Deep Learning and Photogrammetric Reconstruction for Automated Crack Detection and Dimensional Measurement in Mining Operations

Surface crack detection and dimensional measurement at active mining sites present significant safety and operational challenges. Manual inspection methods are labor-intensive, spatially incomplete, and expose personnel to hazardous environments, while existing automated approaches have been developed primarily for concrete civil infrastructure and have not been validated on the complex, variable surfaces characteristic of mining environments. This dissertation presents an automated pipeline that integrates deep learning semantic segmentation with Structure-from-Motion photogrammetry to detect surface cracks and measure their aperture, length, and vertical displacement from standard RGB imagery acquired during routine Uncrewed Aerial Vehicle (UAV) survey operations, without requiring additional sensor hardware or manual measurement. The pipeline combines a U-Net architecture with an EfficientNet-B0 encoder, pretrained on the SDNET2018 concrete crack dataset and fine-tuned on a mining-specific dataset spanning laboratory concrete specimens, coal refuse impoundment embankments, and post-blast limestone quarry benches. Photogrammetric reconstruction is performed using COLMAP Structure-from-Motion and Multi-View Stereo, with crack segmentation masks projected into the reconstructed point cloud to enable three-dimensional vertical displacement measurement through local plane fitting and bimodal surface detection. The pipeline was validated across 36 controlled laboratory specimens at three imaging distances and four vertical displacement levels, achieving aperture measurement RMSE of 0.047 cm and R² of 0.954, and vertical displacement RMSE of 0.140 cm and R² of 0.966, against independent caliper measurements. Field application at a coal refuse impoundment in southwestern Pennsylvania detected 71 crack components across the embankment crest, with a dominant longitudinal crack exhibiting aperture values reaching 28 cm and a 95th percentile vertical displacement of 35.53 cm, consistent in magnitude and spatial distribution with simultaneously acquired LiDAR-derived estimates. Application across four post-blast limestone quarry bench datasets in California successfully characterized blast-induced fracture networks at ground sampling distances ranging from 0.59 to 1.23 cm/pixel, with detected crack geometries physically consistent with observable surface conditions at each site. The results demonstrate that deep learning-based crack detection and photogrammetric measurement can be integrated into routine UAV inspection workflows at mining sites, providing repeatable, scalable, and quantitative crack characterization across surface types, crack scales, and displacement magnitudes not previously addressed in the literature. The pipeline requires no dedicated surveying equipment beyond the UAV platforms already deployed at mine sites for survey and monitoring purposes, supporting practical adoption within existing operational workflows.

Crack detection, Dimensional Measurement↗

On the Global Oxygen Anomaly and Air-Sea Flux

A new climatology of monthly air-sea oxygen fluxes throughout the ice-free surface global ocean is presented. The climatology is based on weighted linear least squares regressions using heat flux monthly anomalies for spatial and temporal interpolation of historical O2 data. The seasonal oceanic variations show that the tropical belt (20 S - 20 N) is characterized by relatively small air-sea fluxes when compared to the middle to high latitudes (40 deg - 70 deg). The largest and lowest seasonal fluxes occur during summer and winter in both hemispheres. By means of an atmospheric transport model we show that our climatology is in better agreement with the observed amplitude and phasing of the variations in atmospheric O2/N2 ratios because of seasonal air-sea exchanges at baseline stations in the Pacific Ocean than with previous air-sea O2 climatologies. Our study indicates that the component of the air-sea O2 flux that correlates with heat flux dominates the large-scale air-sea O2 exchange on seasonal timescales. The contribution of each major oceanic basin to the atmospheric observations is described. The seasonal net thermal (SNO(sub T)) and biological (SNO(sub B)) outgassing components of the flux are examined in relation to latitudinal bands, basin-wide, and hemispheric contributions. The Southern Hemisphere's SNO(sub B) (approximately 0.26 Pmol) and SNO(sub T) (approximately 0.29 Pmol) values are larger than the Northern Hemisphere's SNO(sub B) (approximately 0.15 Pmol) and SNO(sub T) (approximately 0.16 Pmol) values (1 Pmol = 10(exp 15) mol). We estimate a global extratropical carbon new production during the outgassing season of 3.7 Pg C (1 Pg = 10(exp 15) g), lower than previous estimates with air-sea O2 climatologies.

Garcia, Hernan E.↗

E3SMv3 ‘Nephele’ Perturbed Parameter Ensemble Value-Added Product for ENA, SGP, NSA, and Global Means

Processed output from the E3SMv3 Nephele perturbed parameter ensemble (PPE). This product contains global means of present-day (using 2010 aerosol forcings) and preindustrial (using 1850 aerosol forcings) monthly and daily global-mean quantities, as well as hourly mean quantities at the E3SMv3 model grid cell closest to the ENA, SGP, and NSA ARM sites. In this PPE, the E3SMv3 model was run for 27 months in an atmosphere-only configuration with free tropospheric winds nudged to reanalysis. Each ensemble member represents a unique combination of 25 model parameter values (in the microphysics, convective microphysics, and aerosol schemes) that were perturbed randomly and simultaneously. The E3SMv3 default configuration is included as member 0. See https://doi.org/10.22541/essoar.174907165.57104591/v1 (in review) for more information on the Nephele PPE and the perturbed parameters.

Model atmospheric temperature↗

Free convection in the Matian atmosphere

The 'free convective' regime for the Martian atmospheric boundary layer (ABL) was investigated. This state occurs when the mean windspeed at the top of the ABL drops below some critical value U(sub c) and positive buoyant forces are present. Such forces can arise either from vertical temperature or water vapor gradients across the atmospheric surface layer. During free convection, buoyant forces drive narrow plumes that ascend to the inversion height with a return circulation consisting of broad slower-moving downdraughts. Horizontal pressure, temperature, windspeed, and water vapor fluctuations resulting form this circulation pattern can be quite large adjacent to the ground (within the surface layer). The local turbulent fluctuations cause non-zero mean surface stresses, sensible heat fluxes, and latent heat fluxes, even when the mean regional windspeed is zero. Although motions above the surface layer are insensitive to the nature of the surface, the sensible and latent heat fluxes are primarily controlled by processes within the interfacial sublayer immediately adjacent to the ground during free convection. Thus the distinction between aerodynamically smooth and rough airflow within the interfacial sublayer is more important than for the more typical situation where the mean regional windspeed is greater than U(sub c). Buoyant forces associated with water vapor gradients are particularly large on Mars at low pressures and high temperatures when the surface relative humidity is 100 percent, enhancing the likelihood of free convection under these conditions. On this basis, Ingersol postulated the evaporative heat losses from an icy surface on Mars at 237 K and current pressures would exceed the available net radiative flux at the surface, thus prohibiting ice from melting at low atmospheric pressures. Schumann has developed equations describing the horizontal fluctuations and mean vertical gradients occurring during free convection. Schumann's model was generalized to include convection driven by water vapor gradients and to include the effects of circulation above both aerodynamically smooth and rough surfaces.

Clow, G. D.↗

The Atmospheric Impact of the 1991 Mount Pinatubo Eruption

The 1991 eruption of Pinatubo produced about 5 cubic kilometers of dacitic magma and may be the second largest volcanic eruption of the century. Eruption columns reached 40 kilometers in altitude and emplaced a giant umbrella cloud in the middle to lower stratosphere that injected about 17 megatons of SO2, slightly more than twice the largest yielded by the 1982 eruption of El Chichon, Mexico. The SO2 formed sulfate aerosols that produced the largest perturbation to the stratospheric aerosol layer since the eruption of Krakatau in 1883. The aerosol cloud spread rapidly around the Earth in about 3 weeks and attained global coverage by about 1 year after the eruption. Peak local midvisible optical depths of up to 0.4 were measured in late 1992, and globally averaged values were about 0.1 to 0.15 for 2 years. The large aerosol cloud caused dramatic decreases in the amount of net radiation reaching the Earth's surface, producing a climate forcing that was two times stronger than the aerosols of El Chichon. Effects on climate were an observed surface cooling in the northern hemisphere of up to 0.5 to 0.6 C, equivalent to a hemispheric-wide reduction in net radiation of 4 watts per square meter and a cooling of perhaps as large as -0.4 C over large parts of the earth in 1992-93. Climate models seem to have predicted the cooling with a reasonable degree of accuracy. The Pinatubo climate forcing was stronger than the opposite warming of either the El Nino event or anthropogenic greenhouse gases in the period 1991-93. As a result of the presence of the aerosol particles, midlatitude ozone concentrations reached their lowest levels on record during 1992-93, the southern hemisphere 'ozone hole' increased in 1992 to an unprecedented size and ozone depletion rates were observed to be faster than ever before recorded. The atmospheric impact of the Pinatubo eruption has been profound, and it has sparked a lively interest in the role that volcanic aerosols play in climate change. This event has shown that a powerful eruption providing a 15 to 20 megaton release of SO2 into the stratosphere can produce sufficient aerosols to offset the present global warming trends and severely impact the ozone budget.

Self, Stephen↗

Modeling Variability of Plasma Conditions in the Io Torus

Telescopic observations an in situ measurements of the Io plasma torus show the density, temperature and composition to vary over time, sometimes up to a factor of 2. While previous models of the physical and chemical processes in the Io plasma torus have reasonably modeled the conditions of the Voyager 1 era, their authors have not addressed the observed variability nor explored the sensitivity of torus conditions to input parameters. In this paper we present a homogeneous torus model parameterized by five variables (transport timescale, neutral source strength, ratio of oxygen sulfur to atoms in the source, fraction of superthermal electrons, temperature of these hot electrons). The model incorporates the most recent data for ionization, recombination, charge exchange and radiative energy losses for the major torus species (S, S(sup +), S(sup ++), S(sup +++), O, O(sup +), O(sup ++). We solve equations of conservation of mass and energy to find equilibrium conditions for a set of input parameters. We compare model plasma conditions with those observed by Voyager 1 Voyager 2, and Cassini. Furthermore, we explore the sensitivity of torus conditions to each parameter. We find that (1) torus conditions are distinctly different for the Voyager 1, Voyager 2 and Cassini eras, (2) unique torus input parameters for any given era are poorly constrained given the wide range of solution space that is consistent with the range of observed torus conditions, (3) ion composition is highly sensitive to the specification of a non-thermal electron distribution, (4) neutral O/S source ratio is highly variable with model values ranging between 1.7 for Cassini to 4.0 for Voyager 1 conditions, (5) transport times range between 23 days for Voyager 2 to 50 days for Voyager 1 and Cassini, (6) neutral source strengths range between 7 to 30 x 10(sup -4) cm (sup -3) s(sup -1) which corresponds to a net production of 0.4 to 1.3 tons/s for a torus volume of 1.4 x 10(sup 31) cm(sup 3), or 38 R(sub j)(sup 3).

Delamere, P. A.↗