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At least 379 records · Page 21

Kinetics of gas-to-liquid and liquid-to-solid transfer of particles in metal-matrix composites

Analytical models for transfer of particles from gas to liquid and from liquid to solid are introduced. The model for calculation of the pushing/engulfment transition in directionally solidified particulate metal matrix composites, considers process thermodynamics, process kinetics, thermophysical properties and buoyant forces. Based on processing variables (solidification velocity and direction) and on material variables (interface energies, particle size, particle and liquid density, volume fraction of particles and particle/liquid thermal conductivity ratio) four types of behavior were predicted. Also, two numerical models for liquid-to-solid transfer are discussed, as well as the limitations of presently available models.

Stefanescu, D. M.↗

Preliminary AEM study of the microstructure and composition of metal particles in ordinary chondrites

The purpose of this study is to examine the microstructure and composition of the metal particles in ordinary chondrites using analytical electron microscopy (AEM) techniques. Since the phases produced within the metal particles are very fine, the application of various AEM techniques for structural and chemical characterization is critical. However, thin specimen preparation for AEM study has proven very difficult because of the matrix silicate which is present. This is the first AEM study of the metal particles in chondrites. A type 6 chondrite, Saint Severin (LL6), was selected for examination because the metal phases have been reheated into the single phase taenite region (greater than 700 C), and cooled slowly to lower temperatures. A combination of electron optical instruments was employed including a field emission gun (FEG) JEOL 840F high resolution scanning electron microscope (HRSEM), a JEOL 6300F FEG-HRSEM, a Philips 400T AEM, and a JEOL 733 electron probe microanalyzer (EPMA).

Yang, C. W.↗

Spin Forming of Aluminum Metal Matrix Composites

An exploratory effort between NASA-Marshall Space Flight Center (MSFC) and SpinCraft, Inc., to experimentally spin form cylinders and concentric parts from small and thin sheets of aluminum Metal Matrix Composites (MMC), successfully yielded good microstructure data and forming parameters. MSFC and SpinCraft will collaborate on the recent technical findings and develop strategy to implement this technology for NASA's advanced propulsion and airframe applications such as pressure bulkheads, combustion liner assemblies, propellant tank domes, and nose cone assemblies.

Lee, Jonathan A.↗

Non-destructive Evaluation of Bonds Between Fiberglass Composite and Metal

To assess the integrity and reliability of an adhesive joint in an automotive composite component, several non-destructive evaluation (NDE) methodologies are correlated to lap shear bond strengths. A glass-fabric-reinforced composite structure was bonded to a metallic structure with a two-part epoxy adhesive. Samples were subsequently cut and tested in shear, and flaws were found in some areas. This study aims to develop a reliable and portable NDE system for service-level adhesive inspection in the automotive industry. The results of the experimental investigation using several NDE methods are presented and discussed. Fiberglass-to-metal bonding is the ideal configuration for NDE via thermography using excitation with induction heating, due to the conductive metal and non-conductive glass-fiber-reinforced composites. Excitation can be either by a research-grade induction heater of highly defined frequency and intensity, or by a service-level heater, such as would be used for sealing windshields in a body shop. The thermographs thus produced can be captured via a high-resolution infrared camera, with principal component analysis and 2D spatial Laplacian processing. Alternatively, the thermographs can be captured by low resolution thermochromic microencapsulated liquid crystal film imaging, which needs no post-processing and can be very inexpensive. These samples were also examined with phased-array ultrasound. The NDE methods are compared to the lap shear values and to each other for approximate cost, accuracy, and time and level of expertise needed.

Zhao, Selina↗

Composite Lithium Metal Structure to Mitigate Pulverization and Enable Long‐Life Batteries

In lithium metal batteries, non‐uniform stripping of lithium results in pit formation, which promotes subsequent non‐uniform, dendritic deposition. This viscous cycle leads to pulverization of lithium which promotes cell shorting or capacity degradation, symptoms further exaggerated by high electrode areal loading and lean electrolytes. Here, to address this challenge, a composite lithium metal anode is engineered that contains uniformly distributed, nanometer‐sized carbon particles. This composite lithium is shown to strip more uniformly since the growth of non‐uniform pits is intercepted by the carbon particles. This mechanism is corroborated by a continuum electrochemical model. Subsequent lithium deposition on carbon particles is also found to be more uniform than on the surface with irregular pits. Notably, the pulverization rate of composite lithium is 26 times slower than that of commercial lithium. Moreover, in a Li‐S battery with sulfurized polyacrylonitrile cathode, the use of the composite anode extends the cycle life by three times when the areal capacity is 8 mAh cm −2 . The approach of using an engineered lithium composite structure to address challenges during both stripping and plating can inform future designs of lithium metal anodes for high areal capacity operations.

high areal capacity↗

Friction Stir Welding for Aluminum Metal Matrix Composites (MMC's) (Center Director's Discretionary Fund, Project No. 98-09)

This technical memorandum describes an investigation of using friction stir welding (FSW) process for joining a variety of aluminum metal matrix composites (MMC's) reinforced with discontinuous silicon-carbide (SiC) particulate and functional gradient materials. Preliminary results show that FSW is feasible to weld aluminum MMC to MMC or to aluminum-lithium 2195 if the SiC reinforcement is <25 percent by volume fraction. However, a softening in the heat-affected zone was observed and is known to be one of the major limiting factors for joint strength. The pin tool's material is made from a low-cost steel tool H-13 material, and the pin tool's wear was excessive such that the pin tool length has to be manually adjusted for every 5 ft of weldment. Initially, boron-carbide coating was developed for pin tools, but it did not show a significant improvement in wear resistance. Basically, FSW is applicable mainly for butt joining of flat plates. Therefore, FSW of cylindrical articles such as a flange to a duct with practical diameters ranging from 2-5 in. must be fully demonstrated and compared with other proven MMC joining techniques for cylindrical articles.

Lee, J. A.↗

Prediction of high temperature metal matrix composite ply properties

The application of the finite element method (superelement technique) in conjunction with basic concepts from mechanics of materials theory is demonstrated to predict the thermomechanical behavior of high temperature metal matrix composites (HTMMC). The simulated behavior is used as a basis to establish characteristic properties of a unidirectional composite idealized an as equivalent homogeneous material. The ply properties predicted include: thermal properties (thermal conductivities and thermal expansion coefficients) and mechanical properties (moduli and Poisson's ratio). These properties are compared with those predicted by a simplified, analytical composite micromechanics model. The predictive capabilities of the finite element method and the simplified model are illustrated through the simulation of the thermomechanical behavior of a P100-graphite/copper unidirectional composite at room temperature and near matrix melting temperature. The advantage of the finite element analysis approach is its ability to more precisely represent the composite local geometry and hence capture the subtle effects that are dependent on this. The closed form micromechanics model does a good job at representing the average behavior of the constituents to predict composite behavior.

Caruso, J. J.↗

Nondestructive evaluation of ceramic and metal matrix composites for NASA's HITEMP and enabling propulsion materials programs

In a preliminary study, ultrasonic, x-ray opaque, and fluorescent dye penetrants techniques were used to evaluate and characterize ceramic and metal matrix composites. Techniques are highlighted for identifying porosity, fiber alignment, fiber uniformity, matrix cracks, fiber fractures, unbonds or disbonds between laminae, and fiber-to-matrix bond variations. The nondestructive evaluations (NDE) were performed during processing and after thermomechanical testing. Specific examples are given for Si3N4/SiC (SCS-6 fiber), FeCrAlY/Al2O3 fibers, Ti-15-3/SiC (SCS-6 fiber) materials, and Si3N4/SiC (SCS-6 fiber) actively cooled panel components. Results of this study indicate that the choice of the NDE tools to be used can be optimized to yield a faithful and accurate evaluation of advanced composites.

Generazio, Edward R.↗

Numerical and Experimental Study of a Novel Additively Manufactured Metal-Polymer Composite Heat-Exchanger for Liquid Cooling Electronics

In order to meet increasing power-dissipation requirements of the electronics industry, compact, low-cost, and lightweight heat exchangers (HXs) are desired. With proper design, materials, and manufacture, polymer composite heat exchangers could meet these requirements. This paper presents a novel crossflow air-to-water, low-cost, and lightweight metal-polymer composite HX. This HX, which is entirely additively manufactured, utilizes a novel cross-media approach that provides direct heat exchange between air and liquid sides by using connecting fins. A robust numerical model was developed, which includes the dimensional effects of additive manufacturing. The study consists of a simplified 3D CFD model based on ellipsoidal-shaped staggered tube banks for the laminar range. It then uses an analytical approach to compute entire HX performance. The model is validated experimentally within 8% for thermal performance, 12% for air-side impedance, and 18% for water-side impedance. Finally, HX is compared with a conventional CPU radiator and performs within 10% of the conventional unit for reasonable flow rates and pressure-drop ranges. Moreover, HX also provides added design and cost advantages over the conventional unit, which makes the HX a potential candidate for electronic cooling applications.

30 DIRECT ENERGY CONVERSION↗

Computational simulation of microfracture in high temperature metal matrix composites

A computational simulation procedure, using three-dimensional finite element method and global strain energy release rates, is described to predict the microfracture process and identify/quantify the hierarchy of respective fracture modes in metal matrix composites. The procedure is used to predict the microfracture in unidirectional composites under longitudinal loads and accounts for the interphase strength in the in situ state. A novel procedure to computationally simulate the fiber pushthrough process is also described. In this simulation, the interface material is replaced by an anisotropic material with greatly reduced shear modulus in order to simulate the fiber pushthrough process using a linear analysis. Such a procedure is easily implemented and is computationally very effective.

Mital, Subodh K.↗

Investigation of Friction Stir Welding and Laser Engineered Net Shaping of Metal Matrix Composite Materials

The improvement in weld quality by the friction stir welding (FSW) process invented by TWI of Cambridge, England, patented in 1991, has prompted investigation of this process for advanced structural materials including Al metal matrix composite (Al-MMC) materials. Such materials can have high specific stiffness and other potential beneficial properties for the extreme environments in space. Developments of discontinuous reinforced Al-MMCs have found potential space applications and the future for such applications is quite promising. The space industry has recognized advantages of the FSW process over conventional welding processes such as the absence of a melt zone, reduced distortion, elimination of the need for shielding gases, and ease of automation. The process has been well proven for aluminum alloys, and work is being carried out for ferrous materials, magnesium alloys and copper alloys. Development work in the FSW welding process for joining of Al-MMCs is relatively recent and some of this and related work can be found in referenced research publications. NASA engineers have undertaken to spear head this research development work for FSW process investigation of Al-MMCs. Some of the reported related work has pointed out the difficulty in fusion welding of particulate reinforced MMCs where liquid Al will react with SiC to precipitate aluminum carbide (Al4C3). Advantages of no such reaction and no need for joint preparation for the FSW process is anticipated in the welding of Al-MMCs. The FSW process has been best described as a combination of extrusion and forging of metals. This is carried out as the pin tool rotates and is slowly plunged into the bond line of the joint as the pin tool's shoulder is in intimate contact with the work piece. The material is friction-stirred into a quality weld.

Ravinder M. Diwan↗

Tuning the mechanical properties of nanoglass-metallic glass composites with brick and mortar designs

We use molecular dynamics simulations to characterize the tensile deformation and failure of metallic glass (MG)-nanoglass (NG) composites designed with a brick and mortar architecture consisting of a 3 nm-grain-size NG matrix and a MG second phase. Results show that the overall strength of the matrix is significantly improved by the second phase without sacrificing the large NG matrix ductility. The mechanical synergy of the two phases is optimized by arranging the MG bricks in a staggered way, which effectively delocalizes the plastic deformation, hindering the buildup of local stress hot spots and the generation of critical shear bands.

36 MATERIALS SCIENCE↗

The prediction of lightning-induced voltages on metallic and composite aircraft

Various government agencies have put forth effort to enable the prediction of what lightning current will do to aircraft avionic systems. Ongoing and future efforts of predicting avionic voltages and currents caused by electromagnetic fields external to the aircraft are illustrated. The Intrasystem Analysis Program (IAP) was put to use to predict lightning-induced voltages on avionic systems. Presently funded programs are investigating the modification nonmetallic composite materials will cause to the metallic IAP program predictions. The various factors involved in designing prediction techniques are discussed.

Birken, J.↗

New class of tritium breeders for fusion applications: Metal-reinforced composite breeders

Commercial fusion reactors operating on a D-T fuel cycle will require a steady supply of tritium to maintain the burning plasma required for continuous power generation. Since tritium has a short half-life, there is negligible natural abundance which necessitates fusion reactors to produce their own source of tritium. Tritium is most easily produced by surrounding a fusion reactor core with lithium (Li), which reacts under the intense neutron flux leaving the reactor core to form tritium and helium. Due to the hazards and technical challenges associated with surrounding a fusion reactor core with many tons of molten Li, other Li-bearing tritium breeder materials have been pursued. Unfortunately, most of the liquid breeders historically examined are exceedingly corrosive to reactor structural materials while many solid breeders in the form of ceramics are forced to make tradeoffs between Li content and mechanical integrity. In this work, to break the historic limit between Li-density and mechanical integrity of traditional solid breeders, a new class of solid tritium breeders is developed: metal-reinforced composite (MERC) breeders. Specifically, the high Li-density of lithium oxide (Li 2 O) is exploited through the addition of a metal reinforcing phase, producing a composite breeder material exhibiting high splitting tensile strength and quasi-ductility with a Li-density greater than other leading solid breeder candidates, including lithium orthosilicate (Li 4 SiO 4 ) and lithium metatitanate (Li 2 TiO 3 ). Mechanical testing, microstructural characterization, and neutronic simulation results are presented and discussed in light of fusion reactor design considerations.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Finite element applications to explore the effects of partial bonding on metal matrix composite properties

The mechanics of materials approach (definition of E, G, Nu, and Alpha) and the finite element method are used to explore the effects of partial bonding and fiber fracture on the behavior of high temperature metal matrix composites. Composite ply properties are calculated for various degrees of disbonding to evaluate the sensitivity of these properties to the presence of fiber/matrix disbonding and fiber fracture. The mechanics of materials approach allows for the determination of the basic ply material properties needed for design/analysis of composites. The finite element method provides the necessary structural response (forces and displacements) for the mechanics of materials equations. Results show that disbonding of fractured fibers affect only E sub (111) and alpha sub (111) significantly.

Caruso, J. J.↗

Finite element applications to explore the effects of partial bonding on metal matrix composite properties

The mechanics of materials approach (definition of E, G, nu, and alpha) and the finite element method are used to explore the effects of partial bonding and fiber fracture on the behavior of high temperature metal matrix composites. Composite ply properties are calculated for various degrees of disbonding to evaluate the sensitivity of these properties to the presence of fiber/matrix disbonding and fiber fracture. The mechanics of materials approach allows for the determination of the basic ply material properties needed for design/analysis of composites. The finite element method provides the necessary structural response (forces and displacements) for the mechanics of materials equations. Results show that disbonding of fractured fibers affect only E-l(11) and alpha-l(11) significantly.

Caruso, J. J.↗

The influence of microstructure on the tensile behavior of an aluminum metal matrix composite

The relationship between tensile properties and microstructure of a powder metallurgy aluminum alloy, 2009 was examined. The alloy was investigated both unreinforced and reinforced with 15 v/o SiC whiskers or 15 v/o SiC particulate to form a discontinuous metal matrix composite (MMC). The materials were investigated in the as-fabricated condition and in three different hot-rolled sheet thicknesses of 6.35, 3.18, and 1.8 mm. Image analysis was used to characterize the morphology of the reinforcements and their distributions within the matrix alloy. Fractographic examinations revealed that failure was associated with the presence of microstructural inhomogeneities which were related to both the matrix alloy and to the reinforcement. The results from these observations together with the matrix tensile data were used to predict the strengths and moduli of the MMC's using relatively simple models. The whisker MMC could be modeled as a short fiber composite and an attempt was made to model the particulate MMC as a dispersion/dislocation hardened alloy.

Birt, Michael J.↗

Acoustic emission from composite-reinforced metals

Acoustic-emission (AE) count rates are presented for tensile loading of unidirectional boron-epoxy and for aluminum sheets reinforced with unidirectional boron-epoxy. It is shown that different prepreg materials have different characteristic AE patterns. Results from composite-reinforced metal specimens show that early failures are accompanied by a sharp increase in AE count rate at the knee of the bilinear stress-strain diagram. It is further shown that the count rates are a function of specimen fabrication and that higher total counts do not necessarily correspond to early failures.

Henneke, E. G., II↗