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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Silver nanowire-indium zinc oxide composite flexible transparent conducting electrodes made by spin-coating and photonic curing

Flexible transparent conducting electrodes (TCE) play a critical role in modern technologies. Eliminating the high-temperature annealing of vacuum- or solution-deposited films will increase production throughput and lower the cost of the final products. Photonic curing uses intense pulses of broadband light to induce material transformations instead of heat. In this work, we combine solution deposition and photonic curing, replacing thermal annealing, to fabricate flexible composite TCE films on plastic polyethylene terephthalate (PET) substrates. The composite TCE films are composed of spin-coated silver nanowire-indium zinc oxide layers. Further, the TCE films’ electrical, optical, and morphological properties are investigated and compared to those of commercially available PET/TCE. A sheet resistance of 15 Ω/sq and an average transmittance from 400 – 700 nm of 77% are achieved with the spin-coated and photonic-cured composite flexible TCE films.

14 SOLAR ENERGY↗
DOE OSTI2020

Residue Specific Characterization of Electrostatics, Conformational Heterogeneity, and Dynamics of Electron Transfer Proteins with Linear and Nonlinear Infrared Spectroscopy. Final Report

The goal of this research project was to further our understanding of biological electron transfer through the development and application of new methods for studying proteins and their complexes with high spatial and temporal detail. The approach was based on incorporation of reporter bonds with distinct vibrational frequencies at specific locations in proteins and their characterization through the interaction of the bonds with pulses of infrared light. The project focused on the proteins plastocyanin (Pc) and cytochrome (cyt) f, two electron transfer partners in photosynthesis. The first thrust of the project was the incorporation of carbon deuterium bonds as non-perturbative probes at a ligand to the copper ion of Pc and their use to detect changes in the bonding due to the number of electrons at the metal and how the bonding changes upon association with cyt f. Toward developing more advanced approaches to characterize proteins, we incorporated a stronger reporter, the cyano group of cyanophenylalanine, at several locations in Pc and measured the frequency dynamics in the absence and presence of cyt f. The acquired data improved the current model for the protein complex. Notably, the data indicated that the majority of the population is involved in a loosely bound complex, providing insight into the nature of the ensembles formed by electron transfer protein complexes that is not available via other approaches. In addition to learning about the protein complex, we made strides toward developing and improving the new experimental approach to study highly dynamic behaviors of proteins.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Technical Guidance on Use of the Netzsch LFA 447 Nanoflash for Measurement of Ceramic-Metallic (Cermet) Pellet Specimen

The Netzsch LFA 447 Nanoflash Instrument uses the laser flash method to measure thermal diffusivity of a material. Thermal conductivity can be determined if specific heat and density are known for that material. The 238 Pu Supply Program is interested in re-establishing the capability to determine thermal diffusivity and thermal conductivity of various 237Np Al/cermet samples during heating. The bottom side of a plane parallel sample is heated by an energy pulse from a light source (in this case a xenon lamp). An infrared (IR) detector is on the top side of the sample which detects the time dependent temperature rise of the sample due to the energy input from the xenon lamp. The LFA 447 Nanoflash is user-friendly, simple to operate, and has minor sample preparation which will allow technicians to be trained easily on its use. When using the multi-property measurement option, the LFA 447 Nanoflash can determine both thermal diffusivity and specific heat which means only density is needed to identify the thermal conductivity of a sample. This equipment is recognized for being highly accurate and having fast test times, replacing steady-state methods which have proven to be difficult and much slower.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1971

High resolution portable holocamera

High resolution portable hologram recording camera with pulsed ruby laser light source and rechargeable storage batteries as self contained power supply

Close, D. H.↗
NASA NTRS1976

Ruby laser induced emission from NO2

Two different types of emission from excited NO2 were observed using pulsed ruby laser light at 6943 A. The first type of fluorescence was seen in the near IR and results from the single photon excitation of NO2 from the ground 2-A1 state. By observing the emission as a function of time an unexpected behavior was observed in the near IR and could be explained by a consecutive deactivation mechanism, wherein a secondary species is preferentially detected. A second type of emission recently observed in the blue spectral region is weaker and is due to a multiphoton process. The intensity of the blue emission is a function of the cube of the laser intensity at low pressures and approaches the square at high pressures. This variation is attributed to simultaneous deactivation of the excited NO2 intermediate by collision (square) and by anti-Stokes Raman scattering off of the excited NO2 (cube).

Hakala, D. F.↗
NASA NTRS1982

Measurement potential of laser speckle velocimetry

Laser speckle velocimetry, the measurement of fluid velocity by measuring the translation of speckle pattern or individual particles that are moving with the fluid, is described. The measurement is accomplished by illuminating the fluid with consecutive pulses of Laser Light and recording the images of the particles or the speckles on a double exposed photographic plate. The plate contains flow information throughout the image plane so that a single double exposure may provide data at hundreds or thousands of points in the illuminated region of the fluid. Conventional interrogation of the specklegram involves illuminating the plate to form Young's fringes, whose spacing is inversely proportional to the speckle separation. Subsequently the fringes are digitized and analyzed in a computer to determine their frequency and orientation, yielding the velocity magnitude and orientation. The Young's fringe technique is equivalent to performing a 2-D spatial correlation of the double exposed specklegram intensity pattern, and this observation suggests that correlation should be considered as an alternative processing method. The principle of the correlation technique is examined.

Adrian, R. J.↗
NASA NTRS1986

Quantitative determination of engine water ingestion

This paper describes a novel non-intrusive optical technique for determination of liquid mass flux in a droplet laden airstream. The technique was developed for quantitative determination of engine water ingestion resulting from heavy rain or wheel spray. Independent measurements of the liquid water content (LWC) of the droplet laden aircraft and of the droplet velocities were made at the simulated nacelle inlet plane for the liquid mass flux determination. The liquid water content was measured by illuminating and photographing the droplets contained within a thin slice of the flow field by means of a sheet of light from a pulsed YAG laser. A fluorescent dye introduced in the water greatly improved the droplet image definition. The droplet velocities were determined from double exposed photographs of the moving droplet field. The technique was initially applied to a steady spray generated in a wind tunnel. It was found that although the spray was initially steady, the aerodynamic breakup process was inherently unsteady. This resulted in a wide variation of the instantaneous liquid water content of the droplet laden airstream. The standard deviation of ten separate LWC measurements was 31 percent of the average. However, the liquid mass flux calculated from the average LWC and droplet velocities came within 10 percent of the known water ingestion rate.

Parikh, P.↗
NASA NTRS1986

Quantitative determination of engine water ingestion

A nonintrusive optical technique is described for determination of liquid mass flux in a droplet laden airstream. The techniques were developed for quantitative determination of engine water ingestion resulting from heavy rain or wheel spray. Independent measurements of the liquid water content (LWC) of the droplet laden airstream and of the droplet velocities were made at the stimulated nacelle inlet plane for the liquid mass flux determination. The LWC was measured by illuminating and photographing the droplets contained within a thin slice of the flow field by means of a sheet of light from a pulsed laser. A fluorescent dye introduced in the water enchanced the droplet image definition. The droplet velocities were determined from double exposed photographs of the moving droplet field. The technique was initially applied to a steady spray generated in a wind tunnel. It was found that although the spray was initially steady, the aerodynamic breakup process was inherently unsteady. This resulted in a wide variation of the instantaneous LWC of the droplet laden airstream. The standard deviation of ten separate LWC measurements was 31% of the average. However, the liquid mass flux calculated from the average LWC and droplet velocities came within 10% of the known water ingestion rate.

Parikh, P.↗
NASA NTRS1987

A method of atmospheric density measurements during Shuttle entry using UV laser Rayleigh scattering

A detailed study is described of the performance capabilities and the hardware requirements for a method in which ambient density is measured along the Space Shuttle flight path using on-board optical instrumentation. The technique relies on Rayleigh scattering of light from a pulsed, ultraviolet, ArF excimer laser operating at a wavelength of 193 nm. The method is shown to be capable of providing direct measurements of ambient density with an uncertainty of less than 1 percent and with a spatial resolution of 1 km, over an altitude range from 50 to 90 km. In addition, extensions of this concept are discussed that allow measurements of the shock wave location and the density profile within the shock layer. Two approaches are identified that appear to be feasible, in which the same laser system is used for the extended measurements as that required for the ambient density measurements.

Mckenzie, Robert L.↗
NASA NTRS1988

A method of atmospheric density measurements during space shuttle entry using ultraviolet-laser Rayleigh scattering

An analytical study and its experimental verification are described which show the performance capabilities and the hardware requirements of a method for measuring atmospheric density along the Space Shuttle flightpath during entry. Using onboard instrumentation, the technique relies on Rayleigh scattering of light from a pulsed ArF excimer laser operating at a wavelength of 193 nm. The method is shown to be capable of providing density measurements with an uncertainty of less than 1 percent and with a spatial resolution along the flightpath of 1 km, over an altitude range from 50 to 90 km. Experimental verification of the signal linearity and the expected signal-to-noise ratios is demonstrated in a simulation facility at conditions that duplicate the signal levels of the flight environment.

Mckenzie, Robert L.↗
NASA NTRS1989

Closed-Loop Motor-Speed Control

Electronic motor-speed control circuit designed to operate in electrically noisy environment. Includes optoelectronic pick-up device, placed inside motor housing to provide speed feedback signal. Automatically maintains speed motor at commanded value. Measures speed of motor in terms of frequency of pulses of infrared light chopped by fan blades of motor. Difference between measured and commanded speeds serves as control signal for external amplifier driving motor. Major advantage of circuit is low cost.

Smith, Matthew A.↗
NASA NTRS1990

Optically excited states in positronium

Optical excitation are reported of the 1 3S-2 3P transition in positronium, and a second excitation from n=2 to higher n states. The experiment used light from two pulsed dye lasers. Changes in the positronium annihilation rate during and after the laser pulse were used to deduce the excited state populations. The n=2 level was found to be saturable and excitable to a substantial fraction of n=2 positronium to higher levels. Preliminary spectroscopic measurements were performed on n=14 and n=15 positronium.

Howell, R. H.↗
NASA NTRS1990

Novel laser gain and time-resolved FTIR studies of photochemistry

Several techniques are discussed which can be used to explore laboratory photochemical processes and kinetics relevant to planetary atmospheres; these include time-resolved laser gain-versus-absorption spectroscopy and time-resolved Fourier transform infrared (FTIR) emission studies. The laser gain-versus-absorption method employed tunable diode and F-center lasers to determine the yields of excited photofragments and their kinetics. The time-resolved FTIR technique synchronizes the sweep of a commercial FTIR with a pulsed source of light to obtain emission spectra of novel transient species in the infrared. These methods are presently being employed to investigate molecular photodissociation, the yields of excited states of fragments, their subsequent reaction kinetics, Doppler velocity distributions, and velocity-changing collisions of translationally fast atoms. Such techniques may be employed in future investigations of planetary atmospheres, for example to study polycyclic aromatic hydrocarbons related to cometary emissions, to analyze acetylene decomposition products and reactions, and to determine spectral features in the near infrared and infrared wavelength regions for planetary molecules and clusters.

Leone, Stephen R.↗
NASA NTRS1996

CCD Detects Two Images In Quick Succession

Prototype special-purpose charge-coupled device (CCD) designed to detect two 1,024 x 1,024-pixel images in rapid succession. Readout performed slowly to minimize noise. CCD operated in synchronism with pulsed laser, stroboscope, or other pulsed source of light to form pairs of images of rapidly moving objects.

Janesick, James R.↗
NASA NTRS1994

Numerical Simulations of Light Bullets, Using the Full Vector, Time Dependent, Nonlinear Maxwell Equations

This paper will present results in computational nonlinear optics. An algorithm will be described that solves the full vector nonlinear Maxwell's equations exactly without the approximations that are currently made. Present methods solve a reduced scalar wave equation, namely the nonlinear Schrodinger equation, and neglect the optical carrier. Also, results will be shown of calculations of 2-D electromagnetic nonlinear waves computed by directly integrating in time the nonlinear vector Maxwell's equations. The results will include simulations of 'light bullet' like pulses. Here diffraction and dispersion will be counteracted by nonlinear effects. The time integration efficiently implements linear and nonlinear convolutions for the electric polarization, and can take into account such quantum effects as Kerr and Raman interactions. The present approach is robust and should permit modeling 2-D and 3-D optical soliton propagation, scattering, and switching directly from the full-vector Maxwell's equations.

Goorjian, Peter M.↗
NASA NTRS1995

Numerical Simulations of Light Bullets, Using The Full Vector, Time Dependent, Nonlinear Maxwell Equations

This paper will present results in computational nonlinear optics. An algorithm will be described that solves the full vector nonlinear Maxwell's equations exactly without the approximations that we currently made. Present methods solve a reduced scalar wave equation, namely the nonlinear Schrodinger equation, and neglect the optical carrier. Also, results will be shown of calculations of 2-D electromagnetic nonlinear waves computed by directly integrating in time the nonlinear vector Maxwell's equations. The results will include simulations of 'light bullet' like pulses. Here diffraction and dispersion will be counteracted by nonlinear effects. The time integration efficiently implements linear and nonlinear convolutions for the electric polarization, and can take into account such quantum effects as Karr and Raman interactions. The present approach is robust and should permit modeling 2-D and 3-D optical soliton propagation, scattering, and switching directly from the full-vector Maxwell's equations.

Goorjian, Peter M.↗