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At least 379 records · Page 21

Phillips CO-oxidation catalyts for long-lived CO2 lasers: Activity and initial characterization studies

Four different catalysts have been developed specifically for use in sealed carbon dioxide lasers. The catalysts have been designed to be low dusting, stable to shock and vibration, have high activity at low temperatures and have long active lifetimes. Measured global CO oxidation rates range from 1.4 to 2.2 cc CO converted per minute per gram of catalyst at ambient temperature. The catalysts also retain substantial activity at temperatures as low as -35 C. The Phillips laser catalysts are prepared in a variety of different shapes to meet the different pressure drop and gas flow profiles present in the many different styles of lasers. Each catalyst has been tested in sealed TEA lasers and has been shown to substantially increase the sealed life of the laser. Activity measurements made on the precious metal catalysts which were prepared with and without activity promoters showed that the promoter materials increase catalyst CO oxidation activity at least an order of magnitude at ambient temperature. Initial studies using H2 and CO chemisorption, X ray diffraction (XRD) and X ray photoelectron spectroscopy (XPS) have shown that the activity promoters do not significantly affect the precious metal crystallite size or the electronic structure around the precious metal. In addition, the formation or lack of formation of solid solutions between the precious metal and promoters has also been shown not to affect the activity of the promoted catalyst.

Kolts, J. H.↗

On-chip spectroscopic sensors with optical fringe suppression

An on-chip spectroscopic sensor includes a tunable diode laser. A laser driver for drives the tunable diode laser. An analyte test cavity receives a chemical sample and exposes the received chemical sample to light from the tunable diode laser. An optical detector detects light emerging from the analyte test cavity as a result of the laser exposure. A spectral analyzer determines a spectrum of the emerging light, matches and removes one or more known optical fringe patterns from the determined spectrum, and determines a composition or concentration of the chemical sample from the optical fringe pattern-removed spectrum.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On-chip spectroscopic sensors with optical fringe suppression

An on-chip spectroscopic sensor includes a tunable diode laser. A laser driver for drives the tunable diode laser. An analyte test cavity receives a chemical sample and exposes the received chemical sample to light from the tunable diode laser. An optical detector detects light emerging from the analyte test cavity as a result of the laser exposure. A spectral analyzer determines a spectrum of the emerging light, matches and removes one or more known optical fringe patterns from the determined spectrum, and determines a composition or concentration of the chemical sample from the optical fringe pattern-removed spectrum.

Green, William↗

Rapid in situ nutrient element distribution in plants and soils using laser-induced breakdown spectroscopy ($\mathrm{LIBS}$)

The aim of this study is to develop and test the applicability of a rapid in situ plant chemistry profiling technique to determine elemental composition of small-volume plant and soil samples obtained from a woody bioenergy crop species, Populus trichocarpa. Expanding the research tools available to characterize the nutrient element correlations among plant tissue types and soil depths is a critical need in the path of understanding productivity and adaptation of plants to variations in external abiotic and biotic factors and developing sustainable perennial bioenergy crops that are co-optimized for biomass valorization aboveground and carbon sequestration belowground. Several plant root, stem, and soil samples were tested using laser-induced breakdown spectroscopy (LIBS) to evaluate the presence and distribution of nutrient elements. Samples were tested as collected and after being dried and cross sectioned to evaluate the effectiveness of using LIBS for in situ analysis on plant samples. The collected LIBS spectra show the elemental peaks were the same in both the as collected and prepared samples for roots and stems. Qualitative amounts of elements such as H, C, N, O, Li, Na, Mg, K, Ca, Fe, Al, and Si were able to be identified rapidly in raw samples. Here in this report we demonstrate suitability of LIBS in obtaining rapid, in situ, elemental distribution in plant and soil samples, utilizing only small sample volumes and minimal sample preparation. This demonstration opens up a new rapid phenotyping avenue necessary to fill the asymmetrical knowledge gaps in belowground performance of plant systems.

59 BASIC BIOLOGICAL SCIENCES↗

Slab-geometry Nd:glass laser performance studies

It is noted that slab-geometry solid-state lasers potentially provide significant performance improvements relative to conventional rod-geometry lasers. Experimental measurements that use an Nd:glass test-bed slab laser are presented. A comparison is made between the results and computer-model predictions of the slab-geometry approach. The computer model calculates and displays the temperature and stress fields in the slab, and on the basis of these predicts birefringence and index-of-refraction distributions. The effect that these distributions have on optical propagation is determined in a polarization-sensitive ray-tracing section of the model. Calculations are also made of stress-induced surface curvature and the resulting focusing effects. The measurements are found to be in good agreement with the computer-model predictions. It is concluded that the slab configuration offers significant laser-performance advantages in comparison with the traditional rod-laser geometry.

Eggleston, J. M.↗

Life test results for an ensemble of CO2 lasers

The effects of cathode material, cathode operating temperature, anode configuration, window materials, and hydrogen additives on laser lifetime are determined. Internally oxidized copper and silber-copper alloy cathodes were tested. The cathode operating temperature was raised in some tubes through the use of thermal insulation. Lasers incorporating thermally insulated silver copper oxide cathodes clearly yielded the longest lifetimes-typically in excess of 22,000 hours. The use of platinum sheet versus platinum pin anodes had no observable effect on laser lifetime. Similarly, the choice of germanium, cadmium telluride, or zinc selenide as the optical window material appears to have no impact on lifetime.

Peruso, C. J.↗

A laser velocimeter system for small radial turbomachinery

The paper describes the design and test of a laser Doppler velocimeter (LDV) to map the velocity fields in small high-speed turbomachinery. This instrument is presently being used as a diagnostic tool for the study of the basic fluid dynamics of the inducer, impeller and the diffuser regions of high-pressure-ratio small centrifugal compressors. The LDV instrumentation has been optimized to permit measurement of instantaneous velocities up to approximately 500 m/s within a rotating impeller. It is shown that LDV can make nondisturbing gas velocity measurements and surmount the difficulties found in applying other types of aerodynamic instrumentation, e.g., hot-wire anemometers, to this measurement problem.

Runstadler, P. W., Jr.↗

Laser-beam power for lunar and space applications

GaAlAs/GaAs heteroface converters were experimentally tested using DIRECT laser irradiation of photovoltaic devices. It is concluded that the two types of converters are promising for converting diode-laser radiation to electricity. Conversion efficiency as high as 45 and 34.2 percent was obtained using GaAS and Si converters of the SSF type, respectively.

Walker, Gilbert H.↗

Laser diagnostics for microgravity droplet studies

An instrument has been designed, built, and tested for performing laser diagnostic measurements of droplet combustion in low-gravity-flight aircraft. Nonintrusive measurements are of particular importance for droplet combustion (the simplest example of non-premixed combustion) and transport in microgravity environments, where physical contact would introduce an unacceptable level of perturbations. The resolution of these diagnostics can also isolate transport to length scales much smaller than the droplet diameter. These techniques can be configured to instantaneously map an entire flow field in two and three dimensions, providing either qualitative or quantitative information on the distribution of a desired scalar or vector quantity. Detailing the gas-phase flow field and position of the flame front can be achieved using planar laser-induced fluorescence (PLIF) of OH or another flame front marker. An alternative approach is to obtain LIF from a diagnostic seed included in the liquid phase fuel; it would be consumed at the flame front. The main advantage to this approach is that it is easier to choose the wavelength of the molecular absorption which coincides with convenient laser wavelengths rather than finding lasers which can be configured to access OH. Our present method uses a nitrogen-pumped dye laser tuned to a sodium absorption and addition of small concentrations of NaCl to the fuel. Particle image velocimetry (PIV) is a laser-based technique which has recently had its practicality greatly enhanced by the development of high-resolution CCD cameras and the increase in speed and capacity of computer systems. With this technique, a seeded flow is illuminated with a double-pulsed laser sheet to generate a double exposure image on a film or CCD camera. Computer analysis of the image is used to determine the particle velocity vectors and, thus, the gas velocity within the plane of the laser sheet. Our current experiment uses PIV for measuring relative droplet gas-phase velocities in a parabolic flight environment. The results show successful application of PLIF relative to luminosity and radical emission near 308 nm. PIV results are less successful due to gas thermal expansion deflecting the seed particles away from the measurement volume. PIV is applicable for measurements in the absence of combustion.

Winter, Michael↗

Designing transonic wind-tunnel test sections for flow diagnostics and laser velocimeter applications

The design, fabrication, and validation of the Basic Aerodynamic Facility (BARF), developed for the direct comparison of three-dimensional laser velocimetry (LV) and hot-wire techniques at transonic speeds, are discussed. To accommodate the installation of the three-dimensional orthogonal LV system in the BARF, the transonic slots were redesigned to house windows, and the test section mounting was redesigned to facilitate LV transversing. Two-dimensional and three-dimensional code validation tests of the LV test section showed uniform mean flow through the test section to sonic speeds, and fluctuating pressure measurements at subsonic speeds which are consistent with facilities with good flow quality.

Jones, G. S.↗

Post-Flight Test Results of Acousto-Optic Modulator Devices Subjected to Space Exposure

The objective of the Materials International Space Station Experiment (MISSE) is to study the performance of novel materials when subjected to the synergistic effects of the harsh space environment for several months. MISSE missions provide an opportunity for developing space qualifiable materials. Several laser and lidar components were sent by NASA Langley Research Center (LaRC) as a part of the MISSE 7 mission. The MISSE 7 module was transported to the international space station (ISS) via STS 129 mission that was launched on Nov 16, 2009. Later, the MISSE 7 module was brought back to the earth via the STS 134 that landed on June 1, 2011. The MISSE 7 module that was subjected to exposure in a space environment for more than one and a half years included fiber laser, solid-state laser gain materials, detectors, and semiconductor laser diode. Performance testing of these components is now progressing. In this paper, the results of performance testing of a laser diode module sent by NASA Langley Research Center on MISSE 7 mission will be discussed. This paper will present the comparison of pre-flight and post-flight performance of two different COTS acousto-optic modulator (AOM) devices. Post-flight measurements indicate that these two devices did not undergo any significant performance degradation.

Prasad, Narasimha S.↗

Mode-locked frequency doubled Nd:YAG laser

The design, fabrication, test, and delivery of two mode-locked, frequency doubled Nd:YAG laser systems are described. Each system was comprised of two units, the laser head and optics on an Invar plate and the electronics control unit in a relay rack chassis panel. Laser number one operated at a repetition rate of 400 MHz and was designed for use in an optical communication system. Laser number two operated at 200 MHz repetition rate and was designed for optical ranging and target signature experiments. Both lasers had a pulse width of 200 ps at the 10% amplitude points at 1.064 micrometer wavelength (150 ps at 0.532 micrometers) with an amplitude stability of + or - 4%. Output power exceeded the design goals.

Brookman, J. S.↗

Recent Accomplishments in Laser-Photovoltaic Wireless Power Transmission

Wireless power transmission can be accomplished over long distances using laser power sources and photovoltaic receivers. Recent research at AMOS has improved our understanding of the use of this technology for practical applications. Research by NASA, Boeing, the University of Alabama-Huntsville, the University of Colorado, Harvey Mudd College, and the Naval Postgraduate School has tested various commercial lasers and photovoltaic receiver configurations. Lasers used in testing have included gaseous argon and krypton, solid-state diodes, and fiber optic sources, at wavelengths ranging from the visible to the near infra-red. A variety of Silicon and Gallium Arsenide photovoltaic have been tested with these sources. Safe operating procedures have been established, and initial tests have been conducted in the open air at AMOS facilities. This research is progressing toward longer distance ground demonstrations of the technology and practical near-term space demonstrations.

Fikes, John C.↗

Laser doppler velocimeter system for subsonic jet mixer nozzle testing at the NASA Lewis Aeroacoustic Propulsion Lab

A laser Doppler velocimeter (LDV) system developed for the Aeroacoustic Propulsion Laboratory (APL) at the NASA Lewis Research Center is described. This system was developed to acquire detailed flow field data which could be used to quantify the effectiveness of internal exhaust gas mixers (IEGM's) and to verify and calibrate computational codes. The LDV was used as an orthogonal, three component system to measure the flow field downstream of the exit of a series of IEGM's and a reference axisymmetric splitter configuration. The LDV system was also used as a one component system to measure the internal axial flow within the nozzle tailpipe downstream of the mixers. These IEGM's were designed for low-bypass ratio turbofan engines. The data were obtained at a simulated low flight speed, high-power operating condition. The optical, seeding, and data acquisition systems of the LDV are described in detail. Sample flow field measurements are provided to illustrate the capabilities of the system at the time of this test, which represented the first use of LDV at the APL. A discussion of planned improvements to the LDV is also included.

Podboy, Gary G.↗

Laser Diode Analysis and Verification (Professional Report)

The goal of this project at Lawrence Livermore National Laboratory (LLNL) was focused on analyzing and verifying laser diodes to ensure that the diodes meet requirements for LLNL mission applications. The different stages of this testing were documented in a process flow map which included location color coding so that each step was clearly defined in scope and location of appropriate testing facility. Data were collected and analyzed and compared to minimum acceptable values to see if requirements were met. The process map documents the initial receipt, inspection, and testing of the laser diodes. Initial inspections started with Keyence Microscope imaging and then moved on to High Potential, Ramp, and Burst Testing. Data from the diode testing were processed through MATLAB and Python codes to verify various metrics such as slope efficiency, threshold current, back irradiance, and beam divergence met requirements. These metrics were then recorded in Excel summary reports. Approximately 95% of the laser diodes passed all tests. Presentations were given to Lawrence Livermore’s internal leadership team, an external partner, and to a Lab-wide audience. The data released for this report was constrained by information protection considerations of LLNL’s national security missions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Cold cathodes for sealed off CO2 lasers

Experimental results of a group of theoretically selected cold cathode materials are presented. These tests indicate Ag-CuO, Cu, and Pt-Cu as three new cold cathode materials for sealed-off CO2 lasers. The power output of a test laser with an Ag-CuO cathode and a gas volume of only 50 cu cm varied from 0.72 W to 1.1 W at 3000 hours and still yields 0.88 W after 8000 hours. Gas discharge tubes with Cu cathodes and a volume of 25 cu cm yield lifetimes in excess of 10,000 hours. Gas analysis results, obtained from a similar tube over a period of 3000 hours, look most promising. A Pt-Cu alloy cathode shows an extremely promising V-I characteristic over a period of 2800 hours.

Hochuli, U. E.↗

Lasers for Surgery and Photodynamic Therapy Final Report CRADA No. TC-0437-93

This proposed project is designed to apply the combined resources and expertise of the Lawrence Livermore National Laboratory (LLNL) and the Wellman Laboratories of Photomedicine (WL) to develop several new diode laser systems for use in photodynamic therapy (PDT) and to develop diode-pumped solid state infrared lasers for surgery. The use oflaser light-activated photosensitive dyes in the treatment and diagnosis of disease is developing rapidly. Current PDT relies on the use of large, expensive, and inefficient argon-ion laser pumped dye lasers as sources. The recent advances in the technology of diode lasers emitted in the 620-700 nm region offers an opportunity to make source technology for PDT more reliable, compact, and efficient. This project will develop visible diode lasers and control system for photodynamic therapy, and infrared diode pumped solid-state lasers for applications to surgery. Testing and evaluation of the laser systems will be performed at WL using cells, tissue in vitro, animal models, and ultimately human subjects in clinical trials. Once clinical testing is complete, commercialization will be pursued through WL ties to the medical laser industry. Several efforts within this proposed program are of interest to a number of other potential ti.NL funding sources. In particular, several of the diode pumped solid-state devices share some commonalty with work being proposed in conjunction with the Beckman Laser Institute and Medical Clinic. A further example is the commonalty with LLNL existing and proposed efforts in coupling high average power diode arrays into fiber optic delivery systems.

42 ENGINEERING↗