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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Interlaminar improvement of carbon fiber/epoxy composites via fluorine‐containing high‐epoxy‐value sizing agent

Abstract To improve the interfacial bonding effect of carbon fibers (CFs) and epoxy resins, we prepared a fluorine‐containing high‐epoxy‐value sizing agent (named TS) in this article. It is an emulsion with a more uniform particle size distribution and higher stability better than a commercial Takemoto sizing agent. In addition, sulfonic acid groups can improve the hydrophilicity of the TS, and the presence of epoxy groups enhances the wettability between CFs and the matrix. The properties of the sizing agents were examined by Fourier transform infrared spectroscopy, dynamic light scattering, and thermogravimetric analysis. The sized CFs were evaluated by scanning electron microscopy, x‐ray photoelectron spectroscopy, monofilament tensile test, and dynamic contact angle. Afterward, CF/epoxy composites were prepared, and their fracture morphology and interlaminar shear strength (ILSS) were examined. Results indicated that the TS sizing significantly increased the content of activated carbon on the surface of the CFs and improved the bonding effect between the fiber and the matrix. After TS was sized, the ILSS increased from 49.64 to 58.74 MPa, 18.34% higher than unsized CF/epoxy composites, showing the prominent interfacial reinforcement better than commercial Takemoto.

Qiu, Zhijie↗
DOE OSTI2020

Green synthesis and characterization of nontoxic L-methionine capped silver and gold nanoparticles

The simple green method for synthesis of stable L-Methionine (L-Met) capped silver (Ag@LM NPs) and gold (Au@LM NPs) nanoparticles (NPs) without adding any additional reduction agent or stabilizer was developed. Colloidal dispersions were characterized by UV–Vis spectrophotometry. The size and spherical shape of NPs were evaluated by transmission electron microscopy. Their surface covering was confirmed by atomic force microscopy, Fourier transform infrared spectroscopy, dynamic light scattering, and zeta potential measurements. Density functional theory calculations pointed that the preferential adsorption mode of L-Met on both Ag and Au surfaces was a vertical binding geometry via –NH2 group, while horizontal binding mode via [sbnd]S[sbnd] and –NH2 groups is also possible. The genotoxicity (evaluated by the micronucleus assay) of NPs, as well as their effects on some oxidative stress parameters (catalase activity, malondialdehyde level), were assessed in vitro using human peripheral blood cells as a model system. The influence of NPs on the morphology of lymphocyte cells studied using atomic force microscopy revealed that the membrane of cells remained unaffected after the treatment with NPs. When considering the effects of NPs on catalase activity and malondialdehyde level, neither particle type promoted oxidative stress. However, the treatment of lymphocytes with Ag@LM NPs induced a concentration-dependent enhancement of the micronuclei incidence and suppression of the cell proliferation while Au@LM NPs promoted cell proliferation, with no significant effects on micronuclei formation. The Ag@LM NPs were more prone to induce DNA damage than Au@LM NPs, which makes the latter type more suitable for further studies in nano-medicine. © 2019.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2025

Floquet–Bloch manipulation of the Dirac gap in a topological antiferromagnet

Floquet–Bloch manipulation, achieved by driving a material periodically with a laser pulse, is a method that enables the engineering of electronic and magnetic phases in solids by effectively modifying the structure of their electronic bands. However, the application of Floquet–Bloch manipulation in topological magnetic systems, particularly those with inherent disorder, remains largely unexplored. Here, in this study, we realize Floquet–Bloch manipulation of the Dirac surface-state mass of the topological antiferromagnet MnBi 2 Te 4 . Using time- and angle-resolved photoemission spectroscopy, we show that opposite helicities of mid-infrared circularly polarized light result in substantially different Dirac mass gaps in the antiferromagnetic phase, despite the equilibrium Dirac cone being massless. We explain our findings in terms of a Dirac fermion with a random mass. Our results underscore Floquet–Bloch manipulation as a powerful tool for controlling topology, even in the presence of disorder, and for uncovering properties of materials that may elude conventional probes.

42 ENGINEERING↗
DOE OSTI2022

A theoretical investigation of the hydrolysis of uranium hexafluoride: the initiation mechanism and vibrational spectroscopy

Depleted uranium hexafluoride (UF 6 ), a stockpiled byproduct of the nuclear fuel cycle, reacts readily with atmospheric humidity, but the mechanism is poorly understood. Here we compare several potential initiation steps at a consistent level of theory, generating underlying structures and vibrational modes using hybrid density functional theory (DFT) and computing relative energies of stationary points with double-hybrid (DH) DFT. A benchmark comparison is performed to assess the quality of DH-DFT data using reference energy differences obtained using a complete-basis-limit coupled-cluster (CC) composite method. The associated large-basis CC computations were enabled by a new general-purpose pseudopotential capability implemented as part of this work. Dispersion-corrected parameter-free DH-DFT methods, namely PBE0-DH-D3(BJ) and PBE-QIDH-D3(BJ), provided mean unsigned errors within chemical accuracy (1 kcal mol -1 ) for a set of barrier heights corresponding to the most energetically favorable initiation steps. The hydrolysis mechanism is found to proceed via intermolecular hydrogen transfer within van der Waals complexes involving UF 6 , UF 5 OH, and UOF 4 , in agreement with previous studies, followed by the formation of a previously unappreciated dihydroxide intermediate, UF 4 (OH) 2 . The dihydroxide is predicted to form under both kinetic and thermodynamic control, and, unlike the alternate pathway leading to the UO 2 F 2 monomer, its reaction energy is exothermic, in agreement with observation. Finally, harmonic and anharmonic vibrational simulations are performed to reinterpret literature infrared spectroscopy in light of this newly identified species.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Orbitally selective resonant photodoping to enhance superconductivity

Signatures of superconductivity at elevated temperatures above T c in high-temperature superconductors have been observed near 1/8 hole doping for photoexcitation with infrared or optical light polarized either in the CuO 2 plane or along the c axis. While the use of in-plane polarization has been effective for incident energies aligned to specific phonons, c-axis laser excitation in a broad range between 5 μm and 400 nm was found to affect the superconducting dynamics in striped La 1.88 5Ba 0.115 CuO 4 , with a maximum enhancement in the 1/ω dependence to the conductivity observed at 800 nm. This broad energy range, specifically 800 nm, is not resonant with any phonon modes, yet induced electronic excitations appear to be connected to superconductivity at energy scales well above the typical gap energies in the cuprates. A critical question is, What can be responsible for such an effect at 800 nm? Using time-dependent exact diagonalization, we demonstrate that the holes in the CuO 2 plane can be photoexcited into the charge reservoir layers at resonant wavelengths within a multiband Hubbard model. This orbitally selective photoinduced charge transfer effectively changes the in-plane doping level, which can lead to an enhancement of T c near the 1/8 anomaly.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Chemically tuned intermediate band states in atomically thin Cu x GeSe/SnS quantum material for photovoltaic applications

A new generation of quantum material derived from intercalating zerovalent atoms such as Cu into the intrinsic van der Waals gap at the interface of atomically thin two-dimensional GeSe/SnS heterostructure is designed, and their optoelectronic features are explored for next-generation photovoltaic applications. Advanced ab initio modeling reveals that many-body effects induce intermediate band (IB) states, with subband gaps (~0.78 and 1.26 electron volts) ideal for next-generation solar devices, which promise efficiency greater than the Shockley-Queisser limit of ~32%. The charge carriers across the heterojunction are both energetically and spontaneously spatially confined, reducing nonradiative recombination and boosting quantum efficiency. Using this IB material in a solar cell prototype enhances absorption and carrier generation in the near-infrared to visible light range. Tuning the active layer’s thickness increases optical activity at wavelengths greater than 600 nm, achieving ~190% external quantum efficiency over a broad solar wavelength range, underscoring its potential in advanced photovoltaic technology.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Machine Learning Enabled Sensor Fusion for In-Situ Defect Detection in Laser Powder Bed Fusion

Laser Powder Bed Fusion (L-PBF) Additive Manufacturing (AM) is among the metal 3D printing technologies most broadly adopted by the manufacturing industry. The current industry qualification paradigm for critical-application L-PBF parts relies heavily on expensive non-destructive inspection techniques such as X-Ray Computed Tomography (XCT), which significantly limits the use-cases of L-PBF. In situ monitoring of the process promises a less expensive alternative to ex situ testing, but existing sensor technologies and data analysis techniques struggle to detect sub-surface flaws (e.g., porosity and cracking) on production-scale L-PBF printers. RTX Technologies Research Center (RTRC) has licensed ORNL’s Peregrine software package – a printer- and camera-agnostic data analytics tool designed specifically for detecting process anomalies using in situ data collected during powder bed printing. The goal of this project was to feed temporally rich, multi-modal sensor data, including visible light, integrated near infrared (NIR), and spatially mapped co-axial melt pool thermal emission data into Peregrine to enable detection of subsurface flaws. XCT data was used as ground truth training data to allow Peregrine’s deep learning algorithms to recognize anomalies in these complex data streams in both test artifacts and industrially relevant geometries. Completion of this program has seen the successful implementation of multi-modal, multi-layer sensor data footprints for training of machine learning models in Peregrine. Flaws detected in XCT data have been successfully detected directly from this in situ data footprint, and initial analyses of the in situ probability-of-detection has been conducted, showing performance levels commensurate with traditional non-destructive evaluation (NDE) methods. The in situ monitoring methodology was then applied to an industrially relevant component that was using post-build NDE, highlighting the utility of the proposed method for hard-to-inspect AM components. As a direct result of this program, two journal manuscripts [1], [2] have been published in Additive Manufacturing, with additional manuscripts planned following program completion.

36 MATERIALS SCIENCE↗
NASA NTRS1966

Lunar thermal environment

Quantitative data on photometric, luminescence, light polarization, color, infrared temperature, and microwave temperature properties of moon

THERMAL ENVIRONMENT↗
NASA NTRS1973

Investigation of laser dynamics, modulation and control by means of intra-cavity time varying perturbation

Work continued on a number of projects aimed at the generation of tunable visible, infrared, and ultraviolet light; and on the control of this light by means of novel mode-locking and modulation techniques. Progress is summarized for the following projects: (1) the transient modelocking of the Nd:YAG laser and application of short optical pulses; (2) studies of the sodium-xenon excimer laser; (3) development of techniques for vacuum ultraviolet holography; and (4) studies of multiple photon pumped xenon and argon excimer lasers.

Harris, S. E.↗
NASA NTRS1975

Investigation of laser dynamics, modulation and control by means of intra-cavity time varying perturbation

The generation of tunable visible, infrared, and ultraviolet light is examined, along with the control of this light by means of novel mode-locking and modulation techniques. Transient mode-locking of the Nd:YAG laser and generation of short tunable pulses in the visible and the alkali metal inert gas excimer laser systems were investigated. Techniques for frequency conversion of high power and high energy laser radiation are discussed, along with high average power blue and UV laser light sources.

Harris, S. E.↗
NASA NTRS1974

Very high resolution radiometer

A primary sensor used in environmental and earth-resource observation, the Very High Resolution Radiometer (VHRR) was designed for use on the ITOS D series spacecraft. The VHRR provides a 0.47 mile resolution made possible with a mercury-cadmium-telluride detector cooled to approximately 105 K by a passive radiator cooler. The components of this system are described. The optical subsystem of the VHRR consists of a scanning mirror, a Dall-Kirkham telescope, a dichroic beam splitter, relay lenses, spectral filters, and an IR detector. Signal electronics amplify and condition the signals from the infrared and visible light detector. Sync generator electronics provides the necessary time signals. Scan-drive electronics is used for commutation of the motor winding, velocity, and phase control. A table lists the performance parameters of the VHRR.

Aronson, A. I.↗
NASA NTRS1980

Studies of laser and laser devices

The generation of tunable, infrared, and ultraviolet light, and the control of this light by mode-locking and modulation techniques are discussed. Particular emphasis is given to energy storage and extraction using atomic levels, the development of a tunable narrowband vacuum ultraviolet light source, and to the generation and applications of ultrashort optical pulses.

Harris, S. E.↗
NASA NTRS1989

Progress of research on water vapor lidar

Research is summarized on applications of stimulated Raman scattering (SRS) of laser light into near infrared wavelengths suitable for atmospheric monitoring. Issues addressed are conversion efficiency, spectral purity, optimization of operating conditions, and amplification techniques. A Raman cell was developed and built for the laboratory program, and is now available to NASA-Langley, either as a design or as a completed cell for laboratory or flight applications. The Raman cell has been approved for flight in NASA's DC-8 aircraft. The self-seeding SRS technique developed here is suggested as an essential improvement for tunable near-IR DIAL applications at wavelengths of order 1 micrometer or greater.

Wilkerson, Thomas D.↗
NASA NTRS1991

Theory of CW lidar aerosol backscatter measurements and development of a 2.1 microns solid-state pulsed laser radar for aerosol backscatter profiling

The performance and calibration of a focused, continuous wave, coherent detection CO2 lidar operated for the measurement of atmospheric backscatter coefficient, B(m), was examined. This instrument functions by transmitting infrared (10 micron) light into the atmosphere and collecting the light which is scattered in the rearward direction. Two distinct modes of operation were considered. In volume mode, the scattered light energy from many aerosols is detected simultaneously, whereas in the single particle mode (SPM), the scattered light energy from a single aerosol is detected. The analysis considered possible sources of error for each of these two cases, and also considered the conditions where each technique would have superior performance. The analysis showed that, within reasonable assumptions, the value of B(m) could be accurately measured by either the VM or the SPM method. The understanding of the theory developed during the analysis was also applied to a pulsed CO2 lidar. Preliminary results of field testing of a solid state 2 micron lidar using a CW oscillator is included.

Kavaya, Michael J.↗
NASA NTRS1993

Velocity resolved spectroscopy of molecular hydrogen emission in NGC6240

NGC6240 is a member of the class of luminous galaxies which emit a significant fraction of their total light in the infrared. Based on its highly disturbed morphology, Fosbury and Wall (1979) suggested that the system may be a merger of two gas rich galaxies. It has two nuclei separated by 2 arcsec which are visible in the near infrared and at radio wavelengths and CO observations show that the galaxy contains a large mass of molecular gas. Unusually strong H2 emission lines dominate the near infrared spectrum of this galaxy. The galaxy emits approximately 4x10(exp 7) solar luminosity in the 2.12 micron v = 1 to 0 S(1) line alone, an order of magnitude more than other merging or starburst galaxies. To provide a better understanding of the physical processes responsible for the H2 emission from NGC6240 we have begun a program to obtain high spectral resolution observations using the echelle in CGS4 on the UKIRT. Preliminary data which were obtained in February 1991 are presented here. It is intended to obtain further observations with twice the spatial and spectral resolution in June of this year.

Wright, G. S.↗
NASA NTRS1993

Probing the optical depth of spiral galaxies using multi-waveband observations

The questions of the optical depth and extinction of galaxies obviously have far-reaching implications; from determining the true stellar content and baryonic mass of galaxies to the origin of the major component of their far infrared radiation. We have investigated whether the reddening of stars can be used to determine the amount and extent of obscuring dust. We find that the amount of reddening is very sensitive to the assumed geometry. The usually assumed case of a screen of dust between the observer and the star produces, for a given optical depth, the maximum amount of reddening. However, for external galaxies such a geometry is clearly wrong. More realistic geometries where the dust and stars are uniformly mixed (a 'slab') or where the dust is sandwiched by unobscured stars (a 'sandwich') produce significantly less reddening. For the slab geometry of the reddening rises to a maximum value as the optical depth is increased, and for a sandwich geometry the reddening will actually decrease as the optical depth becomes larger. The reddening vectors produced by these realistic geometries are compared to multi-waveband observations of individual regions of a sample of eight galaxies. We find evidence for significant optical depths in the central regions of some of these galaxies, but optical depths of less than unity at approx. 2 scale lengths from the centers. The optical depths derived are in good agreement with other tests such as the measured hydrogen column densities and the far infrared to blue light ratios. However, whereas these two latter approaches are insensitive to the relative distributions of the stars and the dust, the amount of reddening seen in these eight galaxies suggests that the dust to stellar scale height ratio xi is greater than or equal to 0.5. We find typical blue band extinctions of A(sub B) = 0.75-1.0, a factor of 3-4 higher than the RC2 value.

Evans, Rhodri↗
NASA NTRS1993

All solid-state high power visible laser

The overall objective of this Phase 2 effort was to develop and deliver to NASA a high repetition rate laser-diode-pumped solid-state pulsed laser system with output in the green portion of the spectrum. The laser is for use in data communications, and high efficiency, short pulses, and low timing jitter are important features. A short-pulse 1 micron laser oscillator, a new multi-pass amplifier to boost the infrared power, and a frequency doubler to take the amplified infrared pulsed laser light into the green. This produced 1.5 W of light in the visible at a pulse repetition rate of 20 kHz in the laboratory. The pulses have a full-width at half maximum of near 1 ns. The results of this program are being commercialized.

Grossman, William M.↗