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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Solvent-Free Preparation of High Energy, Binder-Free Electrodes Enabled by Dry Compressible Holey Graphene

Graphene is an atomically thick sheet consisting of a graphitic carbon network with excellent mechanical strength, electrical and thermal conductivity, and chemical stability. Holey graphene, a structural derivative of graphene, has an array of through-the-thickness holes across the lateral surface of the nanosheet. The presence of these holes has minimal detrimental effect on the graphene properties and leads to enhanced performance in applications such as electronics, sensors, and energy storage. For example, these holes allow more facile cross-plane ion and gas transport than intact graphene, making holey graphene an ideal electrode material for electrochemical energy storage. This presentation will focus on the ability of holey graphene to be compression molded into robust articles or architectures under solvent-free conditions without the need for potentially parasitic binders. The unique dry compressibility of holey graphene has enabled facile fabrication of high mass loading electrodes with both high density and high porosity, which have found use in supercapacitors and various high-energy battery systems such as lithium-oxygen, lithium-sulfur, and lithium-selenium batteries.

Yi Lin↗
NASA NTRS1998

Electrolytes for Low Temperature Lithium-Ion Cells

Lithium-ion rechargeable batteries have been demonstrated to have high energy density, high voltage, and excellent cycle life which make this technology more attractive than competing systems such as Ni-Cd and Ni-H2.

Lithium-Ion↗
NASA NTRS2019

The Global Fire Atlas of Individual Fire Size, Duration, Speed and Direction

Natural and human-ignited fires affect all major biomes, altering ecosystem structure, biogeochemical cycles and atmospheric composition. Satellite observations provide global data on spatiotemporal patterns of biomass burning and evidence for the rapid changes in global fire activity in response to land management and climate. Satellite imagery also provides detailed information on the daily or sub-daily position of fires that can be used to understand the dynamics of individual fires. The Global Fire Atlas is a new global dataset that tracks the dynamics of individual fires to determine the timing and location of ignitions, fire size and duration, and daily expansion, fire line length, speed, and direction of spread. Here, we present the underlying methodology and Global Fire Atlas results for 2003–2016 derived from daily moderate-resolution (500 m) Collection 6 MCD64A1 burned-area data. The algorithm identified 13.3 million individual fires over the study period, and estimated fire perimeters were in good agreement with independent data for the continental United States. A small number of large fires dominated sparsely populated arid and boreal ecosystems, while burned area in agricultural and other human-dominated landscapes was driven by high ignition densities that resulted in numerous smaller fires. Long-duration fires in boreal regions and natural landscapes in the humid tropics suggest that fire season length exerts a strong control on fire size and total burned area in these areas. In arid ecosystems with low fuel densities, high fire spread rates resulted in large, short-duration fires that quickly consumed available fuels. Importantly, multiday fires contributed the majority of burned area in all biomass burning regions. A first analysis of the largest, longest and fastest fires that occurred around the world revealed coherent regional patterns of extreme fires driven by large-scale climate forcing. Global Fire Atlas data are publicly available through http://www.globalfiredata.org (last access: 9 August 2018) and https://doi.org/10.3334/ORNLDAAC/1642, and individual fire information and summary data products provide new information for benchmarking fire models within ecosystem and Earth system models, understanding vegetation–fire feedbacks, improving global emissions estimates, and characterizing the changing role of fire in the Earth system.

global fire atlas↗
NASA NTRS1970

High energy density electrochemical cell

Primary cell has an anode of lithium, a cathode containing dihaloisocyanuric acid, and a nonaqueous electrolyte comprised of a solution of lithium perchlorate in methyl formate. It produces an energy density of 213 watt hrs/lb and can achieve a high current density.

Byrne, J. J.↗
NASA NTRS1996

High energy density micro-fiber based nickel electrode for aerospace batteries

The nickel electrode is the specific energy limiting component in battery systems such as nickel-hydrogen, nickel-metal hydride and nickel-zinc. Lightweight, high energy density nickel electrodes have been developed which deliver in excess of 180 mAh/g at the one-hour discharge rate. These electrodes are based on a highly porous, nickel micro-fiber (less than 10 micron diameter) substrate, electrochemically impregnated with nickel-hydroxide active material. Electrodes are being tested both as a flooded half-cell and in full nickel-hydrogen and nickel-metal hydride cells. The electrode technology developed is applicable to commercial nickel-based batteries for applications such as electric vehicles, cellular telephones and laptop computers and for low-cost, high energy density military and aerospace applications.

Francisco, Jennifer↗
NASA NTRS2008

Constitutive Soil Properties for Unwashed Sand and Kennedy Space Center

Accurate soil models are required for numerical simulations of land landings for the Orion Crew Exploration Vehicle. This report provides constitutive material models for one soil, unwashed sand, from NASA Langley's gantry drop test facility and three soils from Kennedy Space Center (KSC). The four soil models are based on mechanical and compressive behavior observed during geotechnical laboratory testing of remolded soil samples. The test specimens were reconstituted to measured in situ density and moisture content. Tests included: triaxial compression, hydrostatic compression, and uniaxial strain. A fit to the triaxial test results defines the strength envelope. Hydrostatic and uniaxial tests define the compressibility. The constitutive properties are presented in the format of LS-DYNA Material Model 5: Soil and Foam. However, the laboratory test data provided can be used to construct other material models. The four soil models are intended to be specific to the soil conditions discussed in the report. The unwashed sand model represents clayey sand at high density. The KSC models represent three distinct coastal sand conditions: low density dry sand, high density in-situ moisture sand, and high density flooded sand. It is possible to approximate other sands with these models, but the results would be unverified without geotechnical tests to confirm similar soil behavior.

Thomas, Michael A.↗
NASA NTRS2002

An Accurate Quartic Force Field, Fundamental Frequencies, and Binding Energy for the High Energy Density Material T(d)N4

The CCSD(T) method has been used to compute a highly accurate quartic force field and fundamental frequencies for all N-14 and N-15 isotopomers of the high energy density material T(sub d)N(sub 4). The computed fundamental frequencies show beyond doubt that the bands observed in a matrix isolation experiment by Radziszewski and coworkers are not due to different isotopomers of T(sub d)N(sub 4). The most sophisticated thermochemical calculations to date yield a N(sub 4) -> 2N(sub 2) heat of reaction of 182.22 +/- 0.5 kcal/mol at 0 K (180.64 +/- 0.5 at 298 K). It is hoped that the data reported herein will aid in the ultimate detection of T(sub d)N(sub 4).

Lee, Timothy J.↗
NASA NTRS1989

High power density dc/dc converter: Component selection and design

Further work pertaining to design considerations for the new high power, high frequency dc/dc converters is discussed. The goal of the project is the development of high power, high power density dc/dc converters at power levels in the multi-kilowatt to megawatt range for aerospace applications. The prototype converter is rated for 50 kW at a switching frequency of 50 kHz, with an input voltage of 200 Vdc and an output of 2000 Vdc. The overall power density must be in the vicinity of 0.2 to 0.3 kg/kW.

Divan, Deepakraj M.↗
NASA NTRS2008

A Cryogenic High-Power-Density Bearingless Motor for Future Electric Propulsion

The NASA Glenn Research Center (GRC) is developing a high-power-density switched-reluctance cryogenic motor for all-electric and pollution-free flight. However, cryogenic operation at higher rotational speeds markedly shortens the life of mechanical rolling element bearings. Thus, to demonstrate the practical feasibility of using this motor for future flights, a non-contact rotor-bearing system is a crucial technology to circumvent poor bearing life that ordinarily accompanies cryogenic operation. In this paper, a bearingless motor control technology for a 12-8 (12 poles in the stator and 8 poles in the rotor) switched-reluctance motor operating in liquid nitrogen (boiling point, 77 K (-196 C or -321 F)) was presented. We pushed previous disciplinary limits of electromagnetic controller technique by extending the state-of-the-art bearingless motor operating at liquid nitrogen for high-specific-power applications. The motor was levitated even in its nonlinear region of magnetic saturation, which is believed to be a world first for the motor type. Also we used only motoring coils to generate motoring torque and levitation force, which is an important feature for developing a high specific power motor.

Choi, Benjamin↗
NASA NTRS1991

Friction and wear of plasma-deposited amorphous hydrogenated films on silicon nitride

An investigation was conducted to examine the friction and wear behavior of amorphous hydrogenated carbon (a-C:H) films in sliding contact with silicon nitride pins in both dry nitrogen and humid air environments. Amorphous hydrogenated carbon films approximately 0.06 micron thick were deposited on silicon nitride flat substrates by using the 30 kHz ac glow discharge of a planar plasma reactor. The results indicate that an increase in plasma deposition power gives an increase in film density and hardness. The high-density a-C:H films deposited behaved tribologically much like bulk diamond. In the dry nitrogen environment, a tribochemical reaction produced a substance, probably a hydrocarbon-rich layer, that decreased the coefficient of friction. In the humid air environment, tribochemical interactions drastically reduced the wear life of a-C:H films and water vapor greatly increased the friction. Even in humid air, effective lubrication is possible with vacuum-annealed a-C:H films. The vacuum-annealed high-density a-C:H film formed an outermost superficial graphitic layer, which behaved like graphite, on the bulk a-C:H film. Like graphite, the annealed a-C:H film with the superficial graphitic layer showed low friction when adsorbed water vapor was present.

Miyoshi, Kazuhisa↗
NASA NTRS1993

An experimental investigation of fatigue damage in aluminum 2024-T3 alloys

Aluminum alloys are finding increasing use in the aerospace and automobile industries due to their attractive low density-high modulus and low density-high strength characteristics. Unfortunately, cyclic stress-strain deformation alters the microstructure of the material. These structural changes can lead to fatigue damage and ultimately service failure. Therefore, in order to assess the integrity of the alloy, a correlation between fatigue damage and a measurable microstructural property is needed. Aluminum 2024-T3, a commonly used commercial alloy, contains many grains (individual crystals) of various orientations. The sizes and orientations of these grains are known to affect the strength, hardness, and magnetic permeability of polycrystalline alloys and metals; therefore, perhaps a relationship between a grain property and the fatigue state can be established. Tension-compression cycling in aluminum alloys can also induce changes in their dislocation densities. These changes can be studied from measurements of the electrical resistivities of the materials. Consequently, the goals of this investigation were: to study the grain orientation of aluminum 2024-T3 and to seek a correlation between the grain orientation and the fatigue state of the material; and to measure the electrical resistivities of fatigued samples of aluminum 2024-T3 and to interpret the findings.

Ferguson, Milton W.↗
NASA NTRS2001

Theoretical Studies of Possible Synthetic Routes for the High Energy Density Material Td N4: Excited Electronic States

Vertical electronic excitation energies for single states have been computed for the high energy density material (HEDM) Td N4 in order to assess possible synthetic routes that originate from excited electronic states of N2 molecules. Several ab initio theoretical approaches have been used, including complete active space self-consistent field (CASSCF), state averaged CASSCF (SA-CASSCF), singles configuration interaction (CIS), CIS with second-order and third-order correlation corrections [CIS(D)) and CIS(3)], and linear response singles and doubles coupled-cluster (LRCCSD), which is the highest level of theory employed. Standard double zeta polarized (DZP) and triple zeta double polarized (TZ2P) one-particle basis sets were used. The CASSCF calculations are found to overestimate the excitation energies, while the SA-CASSCF approach rectifies this error to some extent, but not completely. The accuracy of the CIS calculations varied depending on the particular state, while the CIS(D), CIS(3), and LRCCSD results are in generally good agreement. Based on the LRCCSD calculations, the lowest six excited singlet states are 9.35(l(sup)T1), 10.01(l(sup)T2), 10.04(1(sup)A2), 10.07(1(sup)E), 10.12(2(sup)T1), and 10.42(2(sup)T2) eV above the ground state, respectively. Comparison of these excited state energies with the energies of possible excited states of N2+N2 fragments, leads us to propose that the most likely synthetic route for Td N4 involving this mechanism arises from combination of two bound quintet states of N2.

Lee, Timothy J.↗
NASA NTRS1994

Nondestructive evaluation of fatigue damage in aluminum 2024 by x-ray diffraction

Aluminum alloys are widely used in the automobile and aerospace industries. This is due to their attractive low density-high modulus and low density-high strength characteristics. Unfortunately, cyclic stress-strain deformations alter the microstructure of aluminum alloys when they are placed into service. These structural changes can lead to fatigue damage and ultimately service failure. Since x-ray diffraction analysis is known to be a sensitive nondestructive indicator of structural changes due to deformations, this technique is being used to evaluate changes in the microstructure of cycled aluminum 2024 commercial alloys. Line shapes, widths, and positions in an x-ray diffraction pattern depend on microstructural properties such as grain size, grain orientation, residual stress, microstrain, etc. Changes in the microstructure due to fatigue will appear as changes in the diffraction pattern. One parameter used to characterize a reflection in a diffraction pattern is the full width at half maximum (FWHM). Preliminary x-ray diffraction results on cycled Al 2024 indicate that the (111) and (222) reflections of the matrix phase do not show any variations in the FWHM due to an increase in the fatigue cycles. However, the FWHM of the (200) and (400) reflections of the same phase unexpectedly showed a dramatic decrease. These results can be interpreted as due to the relaxation of some initial nonuniform residual stresses in the matrix phase lattice. Further work is in progress to evaluate the FWHM of the second phase of the cycled alloys.

Ferguson, Milton W.↗