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At least 379 records · Page 21

Natural Gas Drilling near the Underground Nuclear Test Site of Rulison, Colorado - 19571

In 1969, the Project Rulison test was conducted in western Colorado using a nuclear device to stimulate natural gas production by fracturing low-permeability, gas-bearing rock. The presence of radionuclides (specifically tritium) in the produced gas persisted above acceptable levels, and the test was abandoned. Advances in hydrofracturing technology over the past 10-15 years have revolutionized the extraction of hydrocarbons from low-permeability formations, leading to a significant increase of drilling in the Rulison area. Drilling activity nearing the Rulison site has raised concerns that remnant radioactivity might be encountered. The site, now under the care of the US Department of Energy (DOE), is protected by a 16-hectare (40 acre) institutional control boundary (Lot 11) that prohibits drilling or extraction of materials below 1830 meters (6000 feet) within the lot boundary. Drilling within 0.8 kilometer (0.5 mile) of the site requires a hearing before the Colorado Oil and Gas Conservation Commission. DOE recommends that gas developers adopt a conservative, staged drilling approach, allowing gas reserves near the Rulison site to be recovered in a manner that minimizes the likelihood of encountering contamination. The staged approach calls for collecting data from wells away from the site before drilling closer. For instance, the wells 1.2 kilometer (0.75 mile) west of the site did not encounter any unexpected geologic conditions and now have 8 years of production without encountering any detonation-related radionuclides. The next set of wells would be 0.8 kilometer (0.5 mile) west of the site. This sequential method drills first at locations with a low probability of encountering contamination and then moves closer. This process protects public safety while allowing the collection of additional data to confirm that contamination has not migrated beyond the 16-hectare (40-acre) institutional control boundary. The staged drilling approach was simulated with a modeling effort that estimates the current extent of contamination and the potential for production-induced contaminant migration to nearby wells. The model incorporates geologic data from nearby wells and was calibrated to production data from both the reentry well production testing (1970-1971) and the wells 1.2 kilometer (0.75 mile) from the site that began producing in 2010. The geologic data include both sand/shale distribution statistics as well as the tendency of hydrofractures to preferentially propagate east and west due to the regional stress field. The model results indicate that it is unlikely that wells near the site would ever encounter site-related radionuclides. (authors)

03 NATURAL GAS↗

Fort Nelson Carbon Capture and Storage Feasibility Study: A Best Practices Manual for Storage in a Deep Carbonate Saline Formation

The Plains CO 2 Reduction (PCOR) Partnership, led by the Energy & Environmental Research Center, and Spectra Energy Transmission (SET) have investigated the feasibility of a carbon capture and storage (CCS) project to mitigate carbon dioxide (CO 2 ) emissions produced by SET's Fort Nelson Gas Plant (FNGP). The PCOR partnership applied geologic characterization; modeling; risk assessment (RA), and monitoring, verification, and accounting (MVA) strategies using an integrated, iterative process to produce superior-quality results during the project feasibility period. The Fort Nelson efforts serve as the basis for a Best Practices Manual (BPM) that offers stakeholders insight and guidance on geological storage of CO 2 in a deep carbonate saline formation.

54 ENVIRONMENTAL SCIENCES↗

Peptide formation in the prebiotic era - Thermal condensation of glycine in fluctuating clay environments

As geologically relevant models of prebiotic environments, systems consisting of clay, water, and amino acids were subjected to cyclic variations in temperature and water content. Fluctuations of both variables produced longer oligopeptides in higher yields than were produced by temperature fluctuations alone. The results suggest that fluctuating environments provided a favorable geological setting in which the rate and extent of chemical evolution would have been determined by the number and frequency of cycles.

Lahav, N.↗

Using Controlled-Source Electromagnetic (CSEM) for CO 2 Storage Monitoring in the North Dakota CarbonSAFE Project

Conference presentation for International Meeting for Applied Geophysics & Energy (IMAGE), September 26 – October 1, 2021, Denver, CO. Geophysical methods are key for characterizing the geologic formations to store CO 2 and monitor the injected CO 2 over time to ensure containment. In the integrated multimeasurement geophysical approach considered for this project, it is expected that the controlled-source electromagnetic (CSEM) method is a strong contributor to mapping the CO 2 movement. A feasibility study of the CSEM method, including 1D and 3D modeling and a field noise test, was conducted to determine its effectiveness in monitoring CO 2 in the Broom Creek and Deadwood Formations. The study results demonstrate that the CSEM method can be used for CO 2 storage monitoring in the study area.

20 FOSSIL-FUELED POWER PLANTS↗

Maximizing oil production from water alternating gas (CO 2 ) injection into residual oil zones: The impact of oil saturation and heterogeneity

Residual oil zones (ROZs) are widespread reservoirs, characterized by oil at residual saturation, either underlying oil fields (brownfield) or lateral (greenfield) to such fields. These reservoirs have the potential to produce volumes of oil sufficiently significant to make appreciable impacts on the US’s oil reserves and associated incidental CO 2 sequestration. The objective of this study is to improve our understanding the impact of heterogeneous and low oil saturations, in brownfield ROZs, on the effectiveness of water alternating gas (WAG) injection strategies. ROZs occur in the Permian Basin and elsewhere, and operators are using CO 2 injection for enhanced oil recovery (EOR) in these zones. The consensus model for the formation of ROZs is that they were formed by the effect of faster regional aquifer flow, acting over millions of years. Both the magnitude of oil saturation and the spatial distribution of oil differ from water-flooded main pay zones (MPZs). To explore the most effective injection strategies, we conducted simulations of CO 2 injection into synthetic geologic reservoirs. These simulations focused on injection into reservoirs subject to either man-made waterflooding or long-term natural waterflooding. By exploring the impact of varying: oil saturation; well patterns; reservoir heterogeneity; and permeability anisotropy, we attempt to quantify the factors that most influence the effectiveness of WAG injection. WAG ratios (the ratio of injected water and CO 2 , in reservoir volumes) of interest are those that either minimize the net CO 2 utilization ratios or maximize oil production rates. In general, the most effective WAG ratios for ROZs, are consistently less than those observed undergoing CO 2 injection in the same geologic reservoir models after traditional (man-made) waterflooding. This work demonstrates that most favorable WAG ratios for oil production in ROZs are different from those in traditional MPZs because of oil saturation differences. Therefore, CO 2 injection into both zones or directly copying WAG injection designs from MPZs to ROZs might not maximize oil production.

04 OIL SHALES AND TAR SANDS↗

Estimate of the Geothermal Energy Resource in the Major Sedimentary Basins in the United States (Presentation)

Because most sedimentary basins have been explored for oil and gas, well logs, temperatures at depth, and reservoir properties such as depth to basement and formation thickness are well known. The availability of this data reduces exploration risk and allows development of geologic exploration models for each basin. This study estimates the magnitude of recoverable geothermal energy from 15 major known U.S. sedimentary basins and ranks these basins relative to their potential. The total available thermal resource for each basin was estimated using the volumetric heat-in-place method originally proposed by (Muffler, 1979). A qualitative recovery factor was determined for each basin based on data on flow volume, hydrothermal recharge, and vertical and horizontal permeability. Total sedimentary thickness maps, stratigraphic columns, cross sections, and temperature gradient information was gathered for each basin from published articles, USGS reports, and state geological survey reports. When published data were insufficient, thermal gradients and reservoir properties were derived from oil and gas well logs obtained on oil and gas commission databases. Basin stratigraphy, structural history, and groundwater circulation patterns were studied in order to develop a model that estimates resource size, temperature distribution, and a probable quantitative recovery factor.

15 GEOTHERMAL ENERGY↗

Measurements and models of reactive transport in geological media

Reactive chemical transport plays a key role in geological media across scales, from pore scale to aquifer scale. Systems can be altered by changes in solution chemistry and a wide variety of chemical transformations, including precipitation/dissolution reactions that cause feedbacks that directly affect the flow and transport regime. The combination of these processes with advective-dispersive-diffusive transport in heterogeneous media leads to a rich spectrum of complex dynamics. The principal challenge in modeling reactive transport is to account for the subtle effects of fluctuations in the flow field and species concentrations; spatial or temporal averaging generally suppresses these effects. Moreover, it is critical to ground model conceptualizations and test model outputs against laboratory experiments and field measurements. This paper emphasizes the integration of these aspects, considering carefully designed and controlled experiments at both laboratory and field scales, in the context of development and solution of reactive transport models based on continuum-scale and particle tracking approaches. We first discuss laboratory experiments and field measurements that define the scope of the phenomena and provide data for model comparison. We continue by surveying models involving advection-dispersion-reaction equation and continuous time random walk formulations. The integration of measurements and models is then examined, considering a series of case studies in different frameworks. We delineate the underlying assumptions, and strengths and weaknesses, of these analyses, and the role of probabilistic effects. Finally, we also show the key importance of quantifying the spreading and mixing of reactive species, recognizing the role of small-scale physical and chemical fluctuations that control the initiation of reactions.

58 GEOSCIENCES↗

Optimizing accuracy of determinations of CO₂ storage capacity and permanence, and designing more efficient storage operations: An example from the Rock Springs Uplift, Wyoming

At a potential injection site on the Rock Springs Uplift in southwest Wyoming, an investigation of confining layers was undertaken to develop and test methodology, identify key data requirements, assess previous injection scenarios relative to detailed confining layer properties, and integrate all findings in order to reduce the uncertainty of CO₂ storage permanence. The assurance of safe and permanent storage of CO₂ at a storage site involves a detailed evaluation of the confining layers. Four suites of field data were recognized as crucial for determining storage permanence relative to the confining layers; seismic, core and petrophysical data from a wellbore, formation fluid samples, and in-situ formation tests. Core and petrophysical data were used to create a vertical heterogenic property model that defined porosity, permeability, displacement pressure, geomechanical strengths, and diagenetic history. These analyses identified four primary confining layers and multiple redundant confining layers. In-situ formation tests were used to evaluate fracture gradients, regional stress fields, baseline microseismic data, step-rate injection tests, and formation perforation responses. Seismic attributes, correlated with the vertical heterogenic property models, were calculated and used to create a 3-D volume model over the entire site. The seismic data provided the vehicle to transform the vertical heterogenic property model into a horizontal heterogenic property model, which allowed for the evaluation of confining layers across the entire study site without risking additional wellbore perforations. Lastly, formation fluids were collected and analyzed for geochemical and isotopic compositions from stacked reservoir systems. These data further tested primary confining layers, by evaluating the evidence of mixing between target reservoirs (mixing would imply an existing breach of primary confining layers). All data were propagated into a dynamic, heterogenic geologic property model used to test various injection scenarios. These tests showed that the study site could retain 25MT of injected CO₂ over an injection lifespan of 50 years. Major findings indicate that active reservoir pressure management through reservoir fluid production (minimum of three production wells) greatly reduces the risk of breaching a confining layer. To address brine production, a well completion and engineering study was incorporated to reduce the risks of scaling and erosion during injection and production. These scenarios suggest that the dolostone within the Mississippian Madison Limestone is the site’s best injection/production target by two orders of magnitude, and that commercial well equipment would meet all performance requirements. This confirms that there are multiple confining layers in southwest Wyoming that are capable of retaining commercial volumes of CO₃, making Wyoming’s Paleozoic reservoirs ideal storage targets for low-risk injection and long-term storage. This study also indicates that column height retention calculations are reduced in a CO₂-brine system relative to a hydrocarbon-brine system, which is an observation that affects all potential CCS sites. Likewise, this study identified the impacts that downhole testing imparts on reservoir fluids, and the likelihood of introducing uncertainty in baseline site assumptions and later modeling.

25 ENERGY STORAGE↗

What would we miss if we characterized the Moon and Mars with just planetary meteorites, remote mapping, and robotic landers?

Exploration of the Moon and planets began with telescopic studies of their surfaces, continued with orbiting spacecraft and robotic landers, and will culminate with manned exploration and sample return. For the Moon and Mars we also have accidental samples provided by impacts on their surfaces, the lunar and martian meteorites. How much would we know about the lunar surface if we only had lunar meteorites, orbital spacecraft, and robotic exploration, and not the Apollo and Luna returned samples? What does this imply for Mars? With martian meteorites and data from Mariner, Viking, and the future Pathfinder missions, how much could we learn about Mars? The basis of most of our detailed knowledge about the Moon is the Apollo samples. They provide ground truth for the remote mapping, timescales for lunar processes, and samples from the lunar interior. The Moon is the foundation of planetary science and the basis for our interpretation of the other planets. Mars is similar to the Moon in that impact and volcanism are the dominant processes, but Mars' surface has also been affected by wind and water, and hence has much more complex surface geology. Future geochemical or mineralogical mapping of Mars' surface should be able to tell us whether the dominant rock types of the ancient southern highlands are basaltic, anorthositic, granitic, or something else, but will not be able to tell us the detailed mineralogy, geochemistry, or age. Without many more martian meteorites or returned samples we will not know the diversity of martian rocks, and therefore will be limited in our ability to model martian geological evolution.

Lindstrom, M. M.↗

The DeepMIP Contribution to PMIP4: Experimental Design for Model Simulations of the EECO, PETM, and pre-PETM (version 1.0)

Past warm periods provide an opportunity to evaluate climate models under extreme forcing scenarios, in particular high ( greater than 800 ppmv) atmospheric CO2 concentrations. Although a post hoc intercomparison of Eocene (approximately 50 Ma) climate model simulations and geological data has been carried out previously, models of past high-CO2 periods have never been evaluated in a consistent framework. Here, we present an experimental design for climate model simulations of three warm periods within the early Eocene and the latest Paleocene (the EECO, PETM, and pre-PETM). Together with the CMIP6 pre-industrial control and abrupt 4(times) CO2 simulations, and additional sensitivity studies, these form the first phase of DeepMIP - the Deep-time Model Intercomparison Project, itself a group within the wider Paleoclimate Modeling Intercomparison Project (PMIP). The experimental design specifies and provides guidance on boundary conditions associated with palaeogeography, greenhouse gases, astronomical configuration, solar constant, land surface processes, and aerosols. Initial conditions, simulation length, and output variables are also specified. Finally, we explain how the geological data sets, which will be used to evaluate the simulations, will be developed.

climate models↗

Hydromechanical Modeling of Fault Rupture in Geologic CO 2 Sequestration: A Comparison of Two Failure Criteria

Abstract The large‐scale implementation of geological carbon sequestration has raised concerns about potential fault activation and induced seismicity, which could compromise storage integrity and pose seismic risks. We theoretically compared two failure criteria, Mohr‐Coulomb (MC) and Modified Cam‐Clay criteria (MCC), to assess fault rupture during CO 2 storage. Both criteria characterize fault behavior in a specific stress regime but differ in reducing the complexity of fault rupture to a few key mechanisms. Using a coupled hydromechanical model, we demonstrate that the choice of a failure criterion and the physics of fault weakening associated with these criteria strongly condition fault response to a given fluid injection. MC mainly relates rupture to friction, while MCC relates rupture to fault poro‐plasticity. Our findings highlight that the selection of a failure criterion, being inherently subjective, can significantly alter the predicted fault behavior during CO 2 storage, thereby impacting the reliability of geomechanical risk assessments.

Cao, M. [Energy Geosciences Division Lawrence Berk↗

Digital cartography of Io

A high resolution controlled mosaic of the hemisphere of Io centered on longitude 310 degrees is produced. Digital cartographic techniques were employed. Approximately 80 Voyager 1 clear and blue filter frames were utilized. This mosaic was merged with low-resolution color images. This dataset is compared to the geologic map of this region. Passage of the Voyager spacecraft through the Io plasma torus during acquisition of the highest resolution images exposed the vidicon detectors to ionized radiation, resulting in dark-current buildup on the vidicon. Because the vidicon is scanned from top to bottom, more charge accumulated toward the bottom of the frames, and the additive error increases from top to bottom as a ramp function. This ramp function was removed by using a model. Photometric normalizations were applied using the Minnaert function. An attempt to use Hapke's photometric function revealed that this function does not adequately describe Io's limb darkening at emission angles greater than 80 degrees. In contrast, the Minnaert function accurately describes the limb darkening up to emission angles of about 89 degrees. The improved set of discrete camera angles derived from this effort will be used in conjunction with the space telemetry pointing history file (the IPPS file), corrected on 4 or 12 second intervals to derive a revised time history for the pointing of the Infrared Interferometric Spectrometer (IRIS). For IRIS observations acquired between camera shutterings, the IPPS file can be corrected by linear interpolation, provided that the spacecraft motions were continuous. Image areas corresponding to the fields of view of IRIS spectra acquired between camera shutterings will be extracted from the mosaic to place the IRIS observations and hotspot models into geologic context.

Mcewen, Alfred S.↗

Machine learning-based inversion for acoustic impedance with large synthetic training data: Workflow and data characterization

Where wells are sparse or training data are difficult to label with high-quality wireline-derived impedance logs, machine learning (ML)-based inversion of acoustic impedance typically depends on small training data sets, leading to biased prediction. We have advanced a novel workflow that applies large synthetic seismic training data to reduce facies-related bias. Using a geologically realistic model as the truth model, we randomly select sparse seed wells to perform sequential Gaussian simulation (SGS) for impedance models of the same geometry and simulate facies variability. We implement random forest regression on 30 features extracted from the synthetic volume. We observe that more seed wells tend to reduce facies-induced bias by sampling more types of facies, resulting in a better prediction. We then focus on the responses of SGS models to facies changes, the number of seed wells necessary for a useful synthetic model, and how much a synthetic model can help ML-based inversion. Here, we observe that the SGS synthetic training model outperforms well-direct training in general. For modeled clastic shore-zone systems in Miocene Gulf of Mexico, two or more seed wells are necessary for a significant reduction of root-mean-square error and outliners, and improvement of facies imaging. In a field-data test, we apply a similar workflow to quantitatively predict acoustic impedance, which is then converted to a sand-volume map at a high-frequency sequence (10–100 m), revealing detailed facies and sandstone patterns. Such results are valuable in many geologic and engineering applications, such as hydrocarbon and CO 2 reservoir prospecting, reserve estimation, simulation, etc.

3D seismic↗

LYNM PE1 Pre-Experiment A Site Characterization Report

Underground chemical explosive experiments such as LYNM PE1 generate large multiphenomenological datasets, require complex site preparation and build out, and utilize cutting edge models and analysis techniques to analyze and simulate the explosion-induced signals. This wide range of outcomes makes it a necessity to thoroughly characterize the testbed in advance of experiments in a way that complements the wide suite of data being generated. Here, we present a broad overview of the site characterization work and data collection that was conducted before Experiment A, which is the first in a series of three PE1 experiments. This work includes, but is not limited to, geologic mapping, physical sample collection, analysis of material properties, geophysical borehole logging, and in-situ measurements. This information was collected by a large, dedicated team and was used to inform site construction, finalize instrumentation placement, generate Geologic Framework Models, feed pre-experiment predictions, and facilitate post-experiment data analysis

58 GEOSCIENCES↗

LYNM PE1 Pre-Experiment A Site Characterization Report

Underground chemical explosive experiments such as LYNM PE1 generate large multi-phenomenological datasets, require complex site preparation and build out, and utilize cutting edge models and analysis techniques to analyze and simulate the explosion-induced signals. This wide range of outcomes makes it a necessity to thoroughly characterize the testbed in advance of experiments in a way that complements the wide suite of data being generated. Here, we present a broad overview of the site characterization work and data collection that was conducted before Experiment A, which is the first in a series of three PE1 experiments. This work includes, but is not limited to, geologic mapping, physical sample collection, analysis of material properties, geophysical borehole logging, and in-situ measurements. This information was collected by a large, dedicated team and was used to inform site construction, finalize instrumentation placement, generate Geologic Framework Models, feed pre-experiment predictions, and facilitate post-experiment data analysis.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Diffusion Dominant Solute Transport Modelling in Fractured Media Under Deep Geological Environment - 12211

Deep geologic disposal of high activity and long-lived radioactive waste is gaining increasing support in many countries, where suitable low permeability geological formation in combination with engineered barriers are used to provide long term waste contaminant and minimise the impacts to the environment and risk to the biosphere. This modelling study examines the solute transport in fractured media under low flow velocities that are relevant to a deep geological environment. In particular, reactive solute transport through fractured media is studied using a 2-D model, that considers advection and diffusion, to explore the coupled effects of kinetic and equilibrium chemical processes. The effects of water velocity in the fracture, matrix porosity and diffusion on solute transport are investigated and discussed. Some illustrative modelled results are presented to demonstrate the use of the model to examine the effects of media degradation on solute transport, under the influences of hydrogeological (diffusion dominant) and microbially mediated chemical processes. The challenges facing the prediction of long term degradation such as cracks evolution, interaction and coalescence are highlighted. The potential of a novel microstructure informed modelling approach to account for these effects is discussed, particularly with respect to investigating multiple phenomena impact on material performance. The GRM code is used to examine the effects of media degradation for a geological waste disposal package, under the combined hydrogeological (diffusion dominant) and chemical effects in low groundwater flow conditions that are typical of deep geological disposal systems. An illustrative reactive transport modelling application demonstrates the use of the code to examine the interplay of kinetic controlled biogeochemical reactive processes with advective and diffusive transport, under the influence of media degradation. The initial model results are encouraging which show the disposal system to evolve in a physically realistic manner. In the example presented the reactive-transport coupling develops chemically reducing zones, which limit the transport of uranium. This illustrates the potential significance of media degradation and chemical effect on the transport of radionuclides which would need to be taken into account when examining the long-term behaviour and containment properties of the geological disposal system. Microstructure-informed modelling and its potential linkage with continuum flow modelling is a subject of ongoing studies. The approach of microstructure-informed modelling is discussed to provide insight and a mechanistic understanding of macroscopic parameters and their evolution. The proposed theoretical and methodological basis for microstructure-informed modelling of porous quasi-brittle media has the potential to develop into an explanatory and predictive tool for deriving mechanism-based, as opposed to phenomenological, evolution laws for macroscopic properties. These concepts in micro-scale modelling are likely to be applicable to the diffusion process, in addition to advective transport illustrated here for porous media. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Mountain biodiversity and ecosystem functions: interplay between geology and contemporary environments

Although biodiversity and ecosystem functions are strongly shaped by contemporary environments, such as climate and local biotic and abiotic attributes, relatively little is known about how they depend on long-term geological processes. Here, along a 3000-m elevational gradient with tectonic faults on the Tibetan Plateau (that is, Galongla Mountain in Medog County, China), we study the joint effects of geological and contemporary environments on biological communities, such as the diversity and community composition of plants and soil bacteria, and ecosystem functions. We find that these biological communities and ecosystem functions generally show consistent elevational breakpoints at 2000–2800 m, which coincide with Indus-Yalu suture zone fault and are similar to the elevational breakpoints of soil bacteria on another mountain range 1000 km away. Mean annual temperature, soil pH and moisture are the primary contemporary determinants of biodiversity and ecosystem functions, which support previous findings. However, compared with the models excluding geological processes, inclusion of geological effects, such as parent rock and weathering, increases 67.9 and 35.9% of the explained variations in plant and bacterial communities, respectively. Such inclusion increases 27.6% of the explained variations in ecosystem functions. The geological processes thus provide additional links to ecosystem properties, which are prominent but show divergent effects on biodiversity and ecosystem functions: parent rock and weathering exert considerable direct effects on biodiversity, whereas indirectly influence ecosystem functions via interactions with biodiversity and contemporary environments. Thus, the integration of geological processes with environmental gradients could enhance our understanding of biodiversity and, ultimately, ecosystem functioning across different climatic zones.

54 ENVIRONMENTAL SCIENCES↗