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At least 379 records · Page 21

An In Situ , Automated High-Explosives Aging Method Utilizing Two-Dimensional Gas Chromatography–Mass Spectrometry

Understanding chemical changes that occur in high explosives as they age is of great importance to the safe employment and storage of these compounds. Traditional methods of aging high explosives even under accelerated aging conditions are time intensive with durations on the order of months to years. The nature of traditional aging analyses reduces each sample to a snapshot data point often separated widely in time, requiring many assumptions as to how the degradation products develop. Further complicating matters, several analytical techniques are typically employed for each sample analysis in order to ascertain an entire picture of the decomposition pathways. To address these shortcomings with existing methods, a new method of accelerated aging of high explosives utilizing comprehensive two-dimensional gas chromatography coupled to high-resolution mass spectrometry (GC × GC-HRMS) was developed using 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) as a model compound for method development. This in situ automated method reduces the time scale of aging to a matter of hours using the inlet of the GC × GC as the aging vessel. GC × GC in combination with HRMS allowed for the collection of both evolved gases and other decomposition products produced during the entire aging process in real time with HRMS providing far greater certainty in identification of explosives aging products. Additionally, this method allowed for a higher throughput of samples with greatly simplified sample preparation. Chemometric analysis of the GC × GC-HRMS data set via the alteration analysis (ALA) enabled discovery of statistically significant chemical changes providing insight into the variation of decomposition pathways with varying aging temperatures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Discriminating Underground Nuclear Explosions Leading To Late-Time Radionuclide Gas Seeps

Utilizing historical data from the U.S. nuclear test program and freely available barometric pressure data, we performed an analytical barometric-pumping efficiency analysis to determine factors resulting in late-time radionuclide gas seeps from underground nuclear explosions. In this work, we considered 16 underground nuclear explosions with similar geology and test setup, of which five resulted in the measurement of late-time radionuclide gas concentrations at the ground surface. Additionally, the factors we considered include barometric frequency and amplitude, depth of burial, air-filled porosity, intact-rock permeability, fracture aperture, and fracture spacing. The analysis indicates that the best discriminators of late-time radionuclide gas seeps for these explosions are barometric frequency and amplitude and air-filled porosity. While geologic information on fracture aperture and spacing is not available for these explosions, the sensitivity of barometric-pumping efficiency to fracture aperture indicates that it would likely also be a good discriminator.

58 GEOSCIENCES↗

Global Nuclear Explosion Discrimination Using a Convolutional Neural Network

Using P-wave seismograms, we trained a seismic source classifier using a Convolutional Neural Network. We trained for three classes: earthquake P-wave, underground nuclear explosion (UNE) P-wave, and noise. With the current absence of nuclear testing by countries that have signed the Comprehensive Test Ban Treaty, high quality seismic data from UNEs is limited. Even with limited training data, our model can accurately characterize most events recorded at regional and teleseismic distances, finding over 95% signals in the validation set. We applied the model on holdout datasets of the North Korean test explosions to evaluate the performance on unique region and station-source pairs, with promising results. Additionally, we tested on the Source Physics Experiment events to investigate the potential for chemical explosions to act as a surrogate for nuclear explosions. We anticipate that machine-learning models like our classifier system can have broad application for other seismic signals including volcanic and non-volcanic tremor, anomalous earthquakes, ice-quakes or landslide-quakes.

58 GEOSCIENCES↗

Predicting multiphase flow and tracer transport for an underground chemical explosive test

Detecting radionuclide gas seepage from clandestine underground nuclear tests is central to nonproliferation explosion monitoring research. Yet, early-time (<6 day) gas transport driven by the explosive pressure wave remains poorly constrained due to scarcity of field data. We simulate multi-phase gas transport in the vadose zone using pre-shot data from a recent chemical explosion in P-Tunnel at the Nevada National Security Site, USA. Despite using a simplified 2D-radial model, predictions of tracer arrival matched observations within one order-of-magnitude. Our results show how transient blast forcing rapidly mobilizes gases from the cavity into surrounding rock – critical for optimizing sensor placement and test planning. This unique integration of field data and modeling represents a significant improvement in our ability to predict gas migration from underground explosions. More broadly, it offers insights into the coupled dynamics of pressure waves and contaminant transport in the vadose zone, with implications for monitoring and hazard assessment.

54 ENVIRONMENTAL SCIENCES↗

Improving the {sup 33}S(p,{gamma}){sup 34}Cl Reaction Rate for Models of Classical Nova Explosions

Reduced uncertainty in the thermonuclear rate of the {sup 33}S(p,{gamma}){sup 34}Cl reaction would help to improve our understanding of nucleosynthesis in classical nova explosions. At present, models are generally in concordance with observations that nuclei up to roughly the calcium region may be produced in these explosive phenomena; better knowledge of this rate would help with the quantitative interpretation of nova observations over the S-Ca mass region, and contribute towards the firm establishment of a nucleosynthetic endpoint. As well, models find that the ejecta of nova explosions on massive oxygen-neon white dwarfs may contain as much as 150 times the solar abundance of {sup 33}S. This characteristic isotopic signature of a nova explosion could possibly be observed through the analysis of microscopic grains formed in the environment surrounding a nova and later embedded within primitive meteorites. An improved {sup 33}S(p,{gamma}){sup 34}Cl rate (the principal destruction mechanism for {sup 33}S in novae) would help to ensure a robust model prediction for the amount of {sup 33}S that may be produced. Finally, constraining this rate could confirm or rule out the decay of an isomeric state of {sup 34}Cl(E{sub x} = 146 keV, t{sub 1/2} = 32 m) as a source for observable gamma-rays from novae. We have performed several complementary experiments dedicated to improving our knowledge of the {sup 33}S(p,{gamma}){sup 34}Cl rate, using both indirect methods (measurement of the {sup 34}S({sup 3}He,t){sup 34}Cl and {sup 33}S({sup 3}He,d){sup 34}Cl reactions with the Munich Q3D spectrograph) and direct methods (in normal kinematics at CENPA, University of Washington, and in inverse kinematics with the DRAGON recoil mass separator at TRIUMF). Our results will be used with nova models to facilitate comparisons of model predictions with present and future nova observables.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

In situ investigation of explosive crystallization in a-Ge: Experimental determination of the interface response function using dynamic transmission electron microscopy

The crystallization of amorphous semiconductors is a strongly exothermic process. Once initiated the release of latent heat can be sufficient to drive a self-sustaining crystallization front through the material in a manner that has been described as explosive. Here, we perform a quantitative in situ study of explosive crystallization in amorphous germanium using dynamic transmission electron microscopy. Direct observations of the speed of the explosive crystallization front as it evolves along a laser-imprinted temperature gradient are used to experimentally determine the complete interface response function (i.e., the temperature-dependent front propagation speed) for this process, which reaches a peak of 16 m/s. Fitting to the Frenkel-Wilson kinetic law demonstrates that the diffusivity of the material locally/immediately in advance of the explosive crystallization front is inconsistent with those of a liquid phase. This result suggests a modification to the liquid-mediated mechanism commonly used to describe this process that replaces the phase change at the leading amorphous-liquid interface with a change in bonding character (from covalent to metallic) occurring in the hot amorphous material.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Tracing explosive in solvent using quantum cascade laser with pulsed electric discharge system

We demonstrated highly sensitive detection of explosive dissolved in solvent with a portable spectroscopy system (Q-MACS) by tracing the explosive byproduct, N{sub 2}O, in combination with a pulsed electric discharge system for safe explosive decomposition. Using Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), the gas was monitored and analyzed by Q-MACS and the presence of the dissolved explosive clearly detected. While HMX presence could be identified directly in the air above the solutions even without plasma, much better results were achieved under the decomposition. The experiment results give an estimated detection limit of 10 ppb, which corresponds to a 15 pg of HMX.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Experimental investigation on the energy deposition and expansion rate under the electrical explosion of aluminum wire in vacuum

Experimental investigations on the electrical explosion of aluminum wire using negative polarity current in vacuum are presented. Current pulses with rise rates of 40 A/ns, 80 A/ns, and 120 A/ns are generated for investigating the influence of current rise rate on energy deposition. Experimental results show a significant increase of energy deposition into the wire before the voltage breakdown with the increase of current rise rate. The influence of wire dimension on energy deposition is investigated as well. Decreasing the wire length allows more energy to be deposited into the wire. The energy deposition of a 0.5 cm-long wire explosion is ∼2.5 times higher than the energy deposition of a 2 cm-long wire explosion. The dependence of the energy deposition on wire diameter demonstrates a maximum energy deposition of 2.7 eV/atom with a diameter of ∼18 μm. Substantial increase in energy deposition is observed in the electrical explosion of aluminum wire with polyimide coating. A laser probe is applied to construct the shadowgraphy, schlieren, and interferometry diagnostics. The morphology and expansion trajectory of exploding products are analyzed based on the shadowgram. The interference phase shift is reconstructed from the interferogram. Parallel dual wires are exploded to estimate the expansion velocity of the plasma shell.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

X-ray radiography of the overheating instability in underwater electrical explosions of wires

We introduce the measurements of the development of striation like instabilities during the electrical driven explosions of wires in a water bath. In vacuum based wire explosion experiments, such instabilities have long been known. Yet, in spite of intense research into the explosion of wires in liquids, the development of these instabilities has either not been observed or has been assumed to play a minor role in the parameters of the exploding wire due to the tamping of the wire's explosion. Using synchrotron based multiframe radiography, we have seen the development of platelike density structures along an exploding copper wire. Our measurements were compared to a 2D magnetohydrodynamics simulation, showing similar striation formation. These observed instabilities could affect the measurements of the conductivity of the wire material in the gas-plasma state—an important parameter in the warm dense matter community. The striations could also act as a seed for other instabilities later in time if the wire is in a dense flow of material or experiences a shock from an adjacent wire—as it would do in experiments with arrays of wires.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Scaled experiments on cavity confined explosions in limestone and poly(methyl methacrylate)

A scaled experiment comprising a laser-driven explosion in a cavity is used to characterize the coupling of mechanical energy into the surrounding solid material. Experiments are performed using poly(methyl methacrylate) and dry Salem limestone as the explosion containment blocks materials, in which are milled scaled spherical cavities of various dimensions. Measurements of the coupled shock, taken with fiber optic probes at the cavity wall, show the critical radius where wall deformation transitions from plastic to elastic deformation. These measurements also provide a diagnostic of the air blast, which is validated against GEODYN simulation code. The measurement of the coupled shock amplitude taken farther from the wall in the linear region indicates increased coupling efficiency in small cavities over the range of scaled cavity radii from 6 to 20 m/kt 1/3 , a phenomenon not previously observed in experiments. A comparison of results taken in this experiment with a parallel experiment using high explosive (HE) as the source shows that coupled shocks generated with HE are characteristically different with much larger amplitude than those produced by a high energy density laser-driven source with the same yield. This experimental technique potentially provides a rapid and cost-effective method to analyze the consequences of a full-scale, low yield, buried explosion.

58 GEOSCIENCES↗

A NEW MULTI-DIMENSIONAL GENERAL RELATIVISTIC NEUTRINO HYDRODYNAMICS CODE FOR CORE-COLLAPSE SUPERNOVAE. II. RELATIVISTIC EXPLOSION MODELS OF CORE-COLLAPSE SUPERNOVAE

We present the first two-dimensional general relativistic (GR) simulations of stellar core collapse and explosion with the COCONUT hydrodynamics code in combination with the VERTEX solver for energy-dependent, three-flavor neutrino transport, using the extended conformal flatness condition for approximating the space-time metric and a ray-by-ray-plus ansatz to tackle the multi-dimensionality of the transport. For both of the investigated 11.2 and 15 M{sub Sun} progenitors we obtain successful, though seemingly marginal, neutrino-driven supernova explosions. This outcome and the time evolution of the models basically agree with results previously obtained with the PROMETHEUS hydro solver including an approximative treatment of relativistic effects by a modified Newtonian potential. However, GR models exhibit subtle differences in the neutrinospheric conditions compared with Newtonian and pseudo-Newtonian simulations. These differences lead to significantly higher luminosities and mean energies of the radiated electron neutrinos and antineutrinos and therefore to larger energy-deposition rates and heating efficiencies in the gain layer with favorable consequences for strong nonradial mass motions and ultimately for an explosion. Moreover, energy transfer to the stellar medium around the neutrinospheres through nucleon recoil in scattering reactions of heavy-lepton neutrinos also enhances the mentioned effects. Together with previous pseudo-Newtonian models, the presented relativistic calculations suggest that the treatment of gravity and energy-exchanging neutrino interactions can make differences of even 50%-100% in some quantities and is likely to contribute to a finally successful explosion mechanism on no minor level than hydrodynamical differences between different dimensions.

79 ASTRONOMY AND ASTROPHYSICS↗

AN INVESTIGATION INTO THE CHARACTER OF PRE-EXPLOSION CORE-COLLAPSE SUPERNOVA SHOCK MOTION

We investigate the structure of the stalled supernova shock in both two and three dimensions (2D and 3D, respectively) and explore the differences in the effects of neutrino heating and the standing accretion shock instability (SASI). We find that early on the amplitude of the dipolar mode of the shock is factors of {approx}2-3 smaller in 3D than in 2D. However, later in both 3D and 2D, the monopole and dipole modes start to grow until explosion. Whereas in 2D, the (l, m) = (1, 0) mode changes sign quasi-periodically, producing the 'up-and-down' motion always seen in modern 2D simulations, in 3D this almost never happens. Rather, in 3D when the dipolar mode starts to grow, it grows in magnitude and wanders stochastically in direction until settling before explosion to a particular patch of solid angle. Furthermore, in 2D, we find that the amplitude of the dipolar shock deformation separates into two classes. For the first, identified with the SASI and for a wide range of 'low' neutrino luminosities, this amplitude remains small and roughly constant. For the other, identified with higher luminosities and neutrino-driven convection, the dipolar amplitude grows sharply. Importantly, it is only for this higher luminosity class that we see neutrino-driven explosions within {approx}1 s of bounce. Moreover, for the 'low' luminosity runs (including zero), the power spectra of these dipolar oscillations peak in the 30-50 Hz range associated with advection timescales, while for the high-luminosity runs the power spectra at lower frequencies are significantly more prominent. We associate this enhanced power at lower frequencies with slower convective effects and the secular growth of the dipolar shock amplitude. Though our study involves a simplified, parameterized approach, on the basis of it we hypothesize that neutrino-driven buoyant convection should almost always dominate the SASI when the supernova explosion is neutrino-driven.

79 ASTRONOMY AND ASTROPHYSICS↗

NEW TWO-DIMENSIONAL MODELS OF SUPERNOVA EXPLOSIONS BY THE NEUTRINO-HEATING MECHANISM: EVIDENCE FOR DIFFERENT INSTABILITY REGIMES IN COLLAPSING STELLAR CORES

The neutrino-driven explosion mechanism for core-collapse supernovae in its modern flavor relies on the additional support of hydrodynamical instabilities in achieving shock revival. Two possible candidates, convection and the so-called standing accretion shock instability (SASI), have been proposed for this role. In this paper, we discuss new successful simulations of supernova explosions that shed light on the relative importance of these two instabilities. While convection has so far been observed to grow first in self-consistent hydrodynamical models with multi-group neutrino transport, we here present the first such simulation in which the SASI grows faster while the development of convection is initially inhibited. We illustrate the features of this SASI-dominated regime using an explosion model of a 27 M{sub Sun} progenitor, which is contrasted with a convectively dominated model of an 8.1 M{sub Sun} progenitor with subsolar metallicity, whose early post-bounce behavior is more in line with previous 11.2 M{sub Sun} and 15 M{sub Sun} explosion models. We analyze the conditions discriminating between the two different regimes, showing that a high mass-accretion rate and a short advection timescale are conducive for strong SASI activity. We also briefly discuss some important factors for capturing the SASI-driven regime, such as general relativity, the progenitor structure, a nuclear equation of state leading to a compact proto-neutron star, and the neutrino treatment. Finally, we evaluate possible implications of our findings for two-dimensional and three-dimensional supernova simulations.

79 ASTRONOMY AND ASTROPHYSICS↗

Constraints on explosive silicon burning in core-collapse supernovae from measured Ni/Fe ratios

Measurements of explosive nucleosynthesis yields in core-collapse supernovae provide tests for explosion models. We investigate constraints on explosive conditions derivable from measured amounts of nickel and iron after radioactive decays using nucleosynthesis networks with parameterized thermodynamic trajectories. The Ni/Fe ratio is for most regimes dominated by the production ratio of {sup 58}Ni/({sup 54}Fe + {sup 56}Ni), which tends to grow with higher neutron excess and with higher entropy. For SN 2012ec, a supernova (SN) that produced a Ni/Fe ratio of 3.4 ± 1.2 times solar, we find that burning of a fuel with neutron excess η≈6×10{sup −3} is required. Unless the progenitor metallicity is over five times solar, the only layer in the progenitor with such a neutron excess is the silicon shell. SNe producing large amounts of stable nickel thus suggest that this deep-lying layer can be, at least partially, ejected in the explosion. We find that common spherically symmetric models of M{sub ZAMS}≲13 M{sub ⊙} stars exploding with a delay time of less than one second (M{sub cut}<1.5 M{sub ⊙}) are able to achieve such silicon-shell ejection. SNe that produce solar or subsolar Ni/Fe ratios, such as SN 1987A, must instead have burnt and ejected only oxygen-shell material, which allows a lower limit to the mass cut to be set. Finally, we find that the extreme Ni/Fe value of 60–75 times solar derived for the Crab cannot be reproduced by any realistic entropy burning outside the iron core, and neutrino-neutronization obtained in electron capture models remains the only viable explanation.

79 ASTRONOMY AND ASTROPHYSICS↗

CONSTRAINING EXPLOSION TYPE OF YOUNG SUPERNOVA REMNANTS USING 24 {mu}m EMISSION MORPHOLOGY

Determination of the explosion type of supernova remnants (SNRs) can be challenging, as SNRs are hundreds to thousands of years old and supernovae are classified based on spectral properties days after explosion. Previous studies of thermal X-ray emission from Milky Way and Large Magellanic Cloud SNRs have shown that Type Ia and core-collapse (CC) SNRs have statistically different symmetries, and thus these sources can be typed based on their X-ray morphologies. In this Letter, we extend the same technique, a multipole expansion technique using power ratios, to infrared (IR) images of SNRs to test whether they can be typed using the symmetry of their warm dust emission as well. We analyzed archival Spitzer Space Telescope Multiband Imaging Photometer 24 {mu}m observations of the previously used X-ray sample, and we find that the two classes of SNRs separate according to their IR morphologies. The Type Ia SNRs are statistically more circular and mirror symmetric than the CC SNRs, likely due to the different circumstellar environments and explosion geometries of the progenitors. Broadly, our work indicates that the IR emission retains information of the explosive origins of the SNR and offers a new method to type SNRs based on IR morphology.

79 ASTRONOMY AND ASTROPHYSICS↗

On various mechanisms of shear wave generation from underground chemical explosions in hard rocks

Significant shear waves observed during underground explosions can make them look similar to natural earthquakes. In the near field, they can be caused by the source geometry and emplacement conditions, heterogeneous and anisotropic properties of the rock mass, relaxation of a non-uniform in situ stress around the source after the departure of the shock wave as well as by activation of nearby faults. Here, the stress relaxation mechanism is important at depth when the difference in main principal stresses becomes significant. Another mechanism of shear motion generation is due to explosive gas flow from the source cavity into the cracks initiated by the shock wave and joints connected to the cavity. Also, the shock wave from the explosion can cause weakening of the rock either due to permanent damage or shock-induced liquefaction at saturated joints. Numerical modelling of underground chemical explosions in hard rock at various confinement stresses has been conducted to compare various mechanisms of shear wave generation and their seismic characteristics with that of a simple fault rupture process observed during an earthquake.

58 GEOSCIENCES↗

Characteristics of infrasound signals from North Korean underground nuclear explosions on 2016 January 6 and September 9

This study investigates infrasound signals from North Korean underground nuclear explosions on 2016 January 6 at 01:30:01 UTC (UNEJ16) and on 2016 September 9 at 00:30:01 UTC (UNES16). Infrasound observations from eight, seismo-acoustic arrays at distances of 300–600 km from the explosions and aligned approximately east–west across South Korea are used in the analysis. Progressive multichannel correlation was used followed by analyst review to identify the infrasound arrivals with estimates of azimuth, phase velocity, celerity, F-statistic, signal-to-noise ratio, correlation and signal duration. These observations are compared with model predictions of travel path, ray turning height and relative amplitudes, using Ground-to-Space atmospheric specifications at the time of each explosion. Stratospheric conditions at the time of the UNEJ16 are favourable to the Korean arrays when all arrays detected infrasound signals, while the few detections for UNES16 are consistent with unfavourable stratospheric winds and reduced amplitude thermospheric arrivals. Infrasound locations of the explosions were estimated using the Bayesian Infrasonic Source Location method (BISL), with wind-corrected backazimuth estimates based on the ray tracing calculations. Adding wind corrections to BISL resulted in infrasound locations up to 50 per cent closer to the seismic epicentre over uncorrected locations. The UNES16 infrasound location estimate using atmospheric corrections had larger differences (~67 km difference from seismic location) than the UNEJ16 location (~11 km difference from seismic location) as a result of the reduced number of observations and poor azimuth coverage for UNES16. Based on stratospheric phases recorded at six arrays and the empirical yield-scaling relations, wind corrected amplitudes from UNEJ16 lead to equivalent infrasound source energy estimates between 0.9 and 16.1 tons of TNT detonated in the atmosphere with an average of 6.4 tons and a standard deviation of 4.6 tons.

58 GEOSCIENCES↗

Constraining Type Ia supernova explosions and early flux excesses with the Zwicky Transient Factory

In the new era of time-domain surveys, Type Ia supernovae are being caught sooner after explosion, which has exposed significant variation in their early light curves. Two driving factors for early-time evolution are the distribution of 56 Ni in the ejecta and the presence of flux excesses of various causes. We perform an analysis of the largest young SN Ia sample to date. We compare 115 SN Ia light curves from the Zwicky Transient Facility to the turtls model grid containing light curves of Chandrasekhar mass explosions with a range of 56 Ni masses, 56 Ni distributions, and explosion energies. We find that the majority of our observed light curves are well reproduced by Chandrasekhar mass explosion models with a preference for highly extended 56 Ni distributions. We identify six SNe Ia with an early-time flux excess in our gr-band data (four ‘blue’ and two ‘red’ flux excesses). We find an intrinsic rate of 18 ± 11 percent of early flux excesses in SNe Ia at z < 0.07, based on three detected flux excesses out of 30 (10 percent) observed SNe Ia with a simulated efficiency of 57 percent. This is comparable to rates of flux excesses in the literature but also accounts for detection efficiencies. Two of these events are mostly consistent with circumstellar material interaction, while the other four have longer lifetimes in agreement with companion interaction and 56 Ni-clump models. We find a higher frequency of flux excesses in 91T/99aa-like events (44 ± 13 percent).

79 ASTRONOMY AND ASTROPHYSICS↗