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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Variations of Mars gravitational field and rotation due to seasonal CO2 exchange

About a quarter of the Martian atmospheric mass is exchanged between the atmosphere and the polar caps in the course of a Martian year: CO2 condenses to form (or add to) the polar caps in winter and sublimes into the atmosphere in summer. This paper studies the effect of this CO2 mass redistribution on Martian rotation and gravitational field. Two mechanisms are examined: (1) the waxing and waning of solid CO2 in the polar caps and (2) the geographical distribution of gaseous CO2 in the atmosphere. In particular, the net peak-to-peak changes in J2 and J3 over a Martian year are both found to be as much as about 6 x 10 to the -9th. A simulation suggests that these changes may be detected by the upcoming Mars Observer under favorable but realistic conditions.

Chao, B. Fong↗
NASA NTRS1990

Atmosphere-biosphere exchange of CO2 and O3 in the Central Amazon Forest

An eddy correlation measurement of O3 deposition and CO2 exchange at a level 10 m above the canopy of the Amazon forest, conducted as part of the NASA/INPE ABLE2b mission during the wet season of 1987, is presented. It was found that the ecosystem exchange of CO2 undergoes a well-defined diurnal variation driven by the input of solar radiation. A curvilinear relationship was found between solar irradiance and uptake of CO2, with net CO2 uptake at a given solar irradiance equal to rates observed over forests in other climate zones. The carbon balance of the system appeared sensitive to cloud cover on the time scale of the experiment, suggesting that global carbon storage might be affected by changes in insolation associated with tropical climate fluctuations. The forest was found to be an efficient sink for O3 during the day, and evidence indicates that the Amazon forests could be a significant sink for global ozone during the nine-month wet period and that deforestation could dramatically alter O3 budgets.

Fan, Song-Miao↗
NASA NTRS1991

Production and uses of liquefied atmosphere (CO2) on Mars

Carbon dioxide is universally accessible on Mars, and can be liquefied and separated from residual atmospheric gases by various compress-refrigeration cycles. Liquid CO2, stored under elevated pressures, can be used as a source of high pressure gas for nighttime power generation at a Martian base powered by solar energy during the daytime. Carbon dioxide can also be used for vehicular power. The extractable energy per unit mass of CO2 can exceed that of commercial lead-acid batteries for operating cycles without heat addition. Improved performance is possible using heat input from the ambient atmosphere or thermochemical agents. A unique vehicular application uses pressurized CO2 as a non-combustion low performance propellant for intermediate distance surface transportation. The thermodynamic properties of CO2 are presented with typical operating cycles for the application classes described above.

Waldron, R. D.↗
NASA NTRS1991

Laboratory studies of the newly discovered infrared band at 4705.2/cm (2.1253 microns) in the spectrum of Io - The tentative identification of CO2

The present evaluation of results from over 120 laboratory experiments relevant to the Trafton et al. (1991) discovery of a 2.1253-micron line in the spectrum of Io demonstrates that this band is produced by neither overtones nor combinations of the fundamental bands of molecules already noted on Io. Since the band's frequency is close to the first overtone of the nu(3) asymmetric stretching mode of CO2, attention is given this molecule's behavior under Io conditions. While pure solid CO2, and CO2 intimately mixed in a matrix of solid SO2 and H2S, generate bands of similar widths, these fall at frequencies lower than the Io band. Attention is given to the possible identification of the Io band with CO2 multimers of 'clusters' on Io.

Sandford, Scott A.↗
NASA NTRS1991

Is CO2 capable to keeping early Mars warm?

One of the goals of NASA's Exobiology Research Program is to determine whether life exists today on Mars (unlikely) or whether it might have existed there at some time in the past (more likely). Speculation about extinct life is driven by the observation of channels on the Martian surface, thought to indicate the past presence of liquid water and, hence, the existence of a warmer climate. Current thinking suggests that such a climate could have been maintained if early Mars had a dense CO2 atmosphere with a surface pressure of 1 to 5 bars. One of the phenomena that Martian climate modelers have not looked at very carefully is the process of CO2 condensation. Reexamination of some of my own calculations indicates that condensation should occur at high altitudes in some high-CO2, Martian atmospheres, particularly those in which the solar constant is set to its initial main sequence value (about 70 percent of present. CO2 condensation should affect the surface temperature in two ways: (1) if it occurs in the convective lower atmosphere, condensation will reduce the magnitude of the greenhouse effect by decreasing the lapse rate; and (2) condensation at any altitude will produce clouds, which can either warm or cool the climate depending on their altitude and optical depth. Preliminary calculations with a 1-D, radiative-convective climate model indicate that the lapse rate change is substantial for low solar luminosity models. Other aspects of this study are discussed.

Kasting, J. F.↗
NASA NTRS1992

CO2 and clathrate as past erosive agents on Mars

The debate on the history of the Martian atmosphere continues without resolution. Much hinges on a satisfactory solution to the problem of what liquid was responsible for the extensive development of canyons, channels, fretted terrain, and similar features. The 1960s and 1970s saw much debate about the roles of various fluids, namely water or brine, liquid CO2, or H2O sources in CO2 clathrate (CC), or magma. The last was discounted long ago, CC is largely ignored, and the most recent look at CO2 was by ourselves, utilizing the phase diagrams for the CO2-H2O system. In this article, we will further investigate this dilemma.

Lambert, R. ST.J.↗
NASA NTRS1992

Coherent CO2 lidar: A superior system for observing clouds?

Lidars have long been used to study various parameters of clouds. NOAA's Wave Propagation Laboratory has operated a coherent CO2 lidar for over a decade, using Doppler to study wind fields and turbulence, atmospheric absorption for Differential Absorption Lidar (DIAL) applications, backscatter to investigate aerosol distributions, and backscatter and extinction measurements on clouds. A system under development for our laboratory promises to overcome the older system's problems of large size, frequency instability, and need for continual operator attention. We are also thoroughly evaluating the capabilities of CO2 lidar for observing clouds, including development of some new techniques. CO2 lidar provides a view of clouds different in many ways from that of lidars at other extinction measurements from clouds. This discussion argues in support of the proposition: coherent CO2 lidar can be a superior lidar system for measuring most cloud properties.

Eberhard, Wynn L.↗
NASA NTRS1992

Mars seasonal CO2 ice lifetimes and the angular dependence of albedo

The albedo of the polar caps on Mars brightens appreciably at high solar zenith angle (Warren et al., J. Geophys. Res., 95, 14717, 1990), an effect not included in prior polar-cap energy-balance models. This decreases absorption of sunlight by the polar cap, hence decreasing sublimation of CO2 ice. Lindner (J. Geophys. Res., 95, 1367, 1990) has shown that the radiative effects of clouds and airborne dust will increase sublimation of CO2 ice over that predicted by prior polar-cap energy-balance models. Furthermore, observations hint that more clouds may exist in the Northern Hemisphere, which Lindner (1990) has shown would sublime CO2 ice more quickly in the north than in the south. I show here that the effects of the solar zenith angle dependence of albedo and the radiative effects of clouds and dust offset each other, but act to extend the lifetime of CO2 ice on the south pole more than on the north pole, possibly explaining the observed hemispherical asymmetry in the residual polar caps without the need of a hemispherical asymmetry in polar-cap albedo required by prior models. Another positive aspect of this solution is that neither the inclusion of the solar zenith angle dependence of albedo nor the radiative effects of clouds and dust should appreciably change prior model agreement with observations of the annual cycle of surface pressure and the recession of the polar caps equatorward of 75 degrees latitude.

Lindner, Bernhard Lee↗
NASA NTRS1991

CO2 condensation and the climate of early Mars

The possibility of the early Mars' greenhouse warming by a dense CO2 atmosphere is presently examined by means of a 1D radiative-convective climate model which differs from earlier ones in considering the effects of CO2 clouds on both the convective lapse rate and the planetary radiation budget. The phenomenon of CO2 condensation, which decreases the lapse rate and thereby reduces the greenhouse effect, increases in importance at low solar luminosities; it may accordingly preclude globally averaged surface temperatures as high as 0 C before about 2 billion years ago in the absence of such other greenhouse gases as CO2 and H2O. Alternative explanations for early Mars warming and channel-formation processes are noted.

Kasting, James F.↗
NASA NTRS1989

Utilization of potatoes for life support systems in space. IV - Effect of CO2 enrichment

To assess the response of potato to elevated carbon dioxide levels in life support farms for space colonies, Norland and Russet Burbank were grown in solid stands in separate controlled environment rooms at two CO2 levels, 365 micromol/mol and 1000 micromol/mol. It is found that potatoes show only marginal growth gains from elevated CO2: tuber dry weight increased by 2 percent for Norland, and 12 percent for Russet Burbank. CO2 assimilation rates of Norland leaves increased by about 24 percent, but assimilation rates of Russet Burbank leaves decreased by about 12 percent. It is concluded that the best productivity obtained in the study (21.9 g tuber dry weight/sq m/day from Norland at 1000 micromol/mol of CO2) indicates that the dietary energy needs of one human in space could be supplied from 34 sq m of potatoes.

Wheeler, Raymond M.↗
NASA NTRS1992

CH4 production via CO2 reduction in a temperate bog - A source of (C-13)-depleted CH4

The paper reports measurements, taken over two annual cycles, of the flux and delta(C-13) of CH4 released from an acidic peat bog located in the foothills of the Cascade Range in Washington state, U.S. Measurements of the rate of aceticlastic methanogenesis and CO2 reduction in peat soil, using (C-14)-labeled acetate and sodium bicarbonate, show that acetate was not an important CH4 precursor and that CO2 reduction could account for all of the CH4 production. The in situ kinetic isotope effect for CO2 reduction, calculated using the delta-(C-13) of soil water CO2 and CH4 flux, was 0.932 +/- 0.007.

Lansdown, J. M.↗
NASA NTRS1992

CO2 laser modeling

The topics covered include the following: (1) CO2 laser kinetics modeling; (2) gas lifetimes in pulsed CO2 lasers; (3) frequency chirp and laser pulse spectral analysis; (4) LAWS A' Design Study; and (5) discharge circuit components for LAWS. The appendices include LAWS Memos, computer modeling of pulsed CO2 lasers for lidar applications, discharge circuit considerations for pulsed CO2 lidars, and presentation made at the Code RC Review.

Johnson, Barry↗
NASA NTRS1992

Micrometeorological measurements of CH4 and CO2 exchange between the atmosphere and subarctic tundra

Eddy correlation flux measurements and concentration profiles of total hydrocarbons (THC) and CO2 were combined to provide a comprehensive record of atmosphere-biosphere exchange for these gases over a 30-day period in July-August 1988 in the Yukon-Kuskokwin River Delta of Alaska. Over 90 percent of net ecosystem exchanges of THC were due to methane. Lakes and wet meadow tundra provided the major sources of methane. The average fluxes from lake, dry tundra, and wet tundra were 11 +/- 3, 29 +/- 3, and 57 +/- 6 mg CH4/sq m/d, respectively. The mean remission rate for the site was 25 mg/sq m/d. Maximum uptake of CO2 by the tundra was 1.4 gC/sq m/d between 1000 and 1500 hrs, and nocturnal respiration averaged 0.73 gC/sq m/d. Net uptake of CO2 was 0.30 gC/sq m/d for the 30 days of measurement; methane flux accounted for 6 percent of CO2 net uptake.

Fan, S. M.↗
NASA NTRS1992

Electrochemical CO2 and O2 separation for crew and plant environments

The study describes a closed ecosystem concept that includes electrochemical CO2 and O2 separators and a moisture condenser/separator for maintaining CO2, O2, and humidity levels in the crew and plant habitats at their respective optimal conditions. The key processes of this concept are aqueous electrolyte-based electrochemical CO2 and O2 separations. The principles and cell characteristics of these electrochemical gas separation processes are described. Also presented are descriptions of test hardware and the test results of the Electrochemical CO2 Separator (ECS) and the Electrochemical O2 Separator (EOS), and the combination of the ECS and the EOS. The test results proved that the ECS and EOS processes for the combined concept are viable.

Lee, M. G.↗
NASA NTRS1993

Experimental constraints on CO2 and H2O in the Martian mantle and primary magmas

We present new data on the stability of hornblende in a Martian mantle composition, on CO2 solubility in iron-rich basaltic magmas, and on the solubility of H2O in an alkalic basaltic magma. These new data are combined with a summary of data from the literature to present a summary of the current state of our estimates of solubilities of H2O and CO2 in probable Martian magmas and the stability of hornblende in a slightly hydrous mantle. The new results suggest that hornblende stability is not sensitive to the Mg/(Mg+Fe) ratio (mg#) of the mantle, that is the results for terrestrial mantle compositions are similar to the more iron-rich Martian composition. Likewise, CO2 solubility in iron-rich tholeiitic basaltic magmas is similar to iron-poor terrestrial compositions. The solubility of H2O has been measured in an alkalic basaltic (basanite) composition for the first time, and it is significantly lower than predicted for models of water solubility in magmas. The lack of mg# dependence observed in hornblende stability and on CO2 solubility that in many cases terrestrial results can be applied to Martian compositions. This conclusion does not apply to other phenomena such as primary magma compositions and major mantle mineral mineralogy.

Holloway, John R.↗
NASA NTRS1993

Far-infrared spectra of CO2 clathrate hydrate frosts

As a product of our interest in remote sensing of planetary ices, frost samples of CO2 clathrate hydrate were grown by depositing water vapor on a cooled surface and pressurizing the resulting water frost with CO2 gas. At pressures above the dissociation pressure of the clathrate, the samples exhibit an absorption peak at 75 cm (sup -1). At pressures below the dissociation pressure, the peak disappears. Since the free CO2 molecule does not have rotational or vibrational absorption in this region, the absorption is attributed to a CO2 rattling mode within a clathrate cage.

Landry, J. C.↗
NASA NTRS1993

Controls on the CO2 seasonal cycle

Surface pressure measurement performed by the Viking landers show substantial variations in pressure on seasonal timescales that are characterized by two local minima and two local maxima. These variations have widely been attributed to the seasonal condensation and sublimation of CO2 in the two polar regions. It has been somewhat of a surprise that the amplitude of the minimum and maximum that is dominated by the CO2 cycle in the north was much weaker than the corresponding amplitude of the south-dominated extrema. Another surprise was that the seasonal pressure cycle during years 2 and 3 of the Viking mission was so similar to that for year 1, despite the occurrence of two global dust storms during year 1 and none during years 2 and 3. An energy balance model that incorporates dynamical factors from general circulation model (GCM) runs in which the atmospheric dust opacity and seasonal date were systematically varied was used to model the observed seasonal pressure variations. The energy balance takes account of the following processes in determining the rates of CO2 condensation and sublimation at each longitudinal and latitudinal grid point: solar radiation, infrared radiation from the atmosphere and surface, subsurface heat conduction, and atmospheric heat advection. Condensation rates are calculated both at the surface and in the atmosphere. In addition, the energy balance model also incorporates information from the GCM runs on seasonal redistribution of surface pressure across the globe. Estimates of surface temperature of the seasonal CO2 caps were used to define the infrared radiative losses from the seasonal polar caps. The seasonal pressure variations measured at the Viking lander sites were closely reproduced.

Pollack, J. B.↗
NASA NTRS1994

Root growth and development in response to CO2 enrichment

A non-destructive technique (minirhizotron observation tubes) was used to assess the effects of CO2 enrichment on root growth and development in experimental plots in a scrub oak-palmetto community at the Kennedy Space Center. Potential effects of CO2 enrichment on plants have a global significance in light of concerns over increasing CO2 concentrations in the Earth's atmosphere. The study at Kennedy Space Center focused on aboveground physiological responses (photosynthetic efficiency and water use efficiency), effects on process rates (litter decomposition and nutrient turnover), and belowground responses of the plants. Belowground dynamics are an exceptionally important component of total plant response but are frequently ignored due to methodological difficulties. Most methods used to examine root growth and development are destructive and, therefore, severely compromise results. Minirhizotrons allow nondestructive observation and quantification of the same soil volume and roots through time. Root length density and root phenology were evaluated for CO2 effects with this nondestructive technique.

Day, Frank P., Jr.↗