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DOE OSTI2026

Accelerating ion transport by dynamic asymmetry of alternating polymer electrolytes

Polymer based electrolytes allow the absence of volatile components in batteries thus increasing their safety. Yet, they exhibit drawbacks based on their low conductivity. We have used an alternating polymer consisting of dimethyl siloxane (DMS) and ethylene glycol (EG) blocks to circumvent known disadvantages of the usually used polyethylene glycol (PEG). Incorporating dimethyl siloxane lowers the glass-transition temperature and thus reduces the segmental relaxation time, by dynamic asymmetry or internal plasticization of the constituting polymer blocks. The alternating structure ensures miscibility of the different components and hinders crystallization. Furthermore, the pure polymer, P(DMS 3 -alt-EG 4 ), shows a segmental relaxation time well in the range needed for polymer electrolytes. Mixtures of LiClO 4 and P(DMS 3 -alt-EG 4 ) show a drastically reduced temperature dependence of their DC conductivity in comparison to PEG based systems, resulting in an increase by two orders of magnitude at T = 5 °C and even three to four orders of magnitude at T = 0 °C. Addition of coordinating (acetonitrile) or non-coordinating (toluene) solvent increases conductivity either via additional plasticization or by weakening the Li-binding yet looking at the dynamics at low concentrations of additional solvent the mobility of the polymer is reduced. In conclusion, the solvent addition leads only at higher solvent concentration to a reduction in relaxation time.

Jakobi, Bruno [Louisiana State Univ., Baton Rouge,↗

DOE OSTI2024

High-Temperature Superconductivity in La 3 Ni 2 O 7

Motivated by the recent discovery of high-temperature superconductivity in bilayer La 3 Ni 2 O 7 under pressure, we study its electronic properties and superconductivity due to strong electron correlation. Using the inversion symmetry, we decouple the low-energy electronic structure into block-diagonal symmetric and antisymmetric sectors. It is found that the antisymmetric sector can be reduced to a one-band system near half filling, while the symmetric bands occupied by about two electrons are heavily overdoped individually. Using the strong coupling mean field theory, we obtain strong superconducting pairing withB 1g symmetry in the antisymmetric sector. We propose that due to the spin-orbital exchange coupling between the two sectors,B 1g pairing is induced in the symmetric bands, which in turn boosts the pairing gap in the antisymmetric band and enhances the high-temperature superconductivity with a congruent d-wave symmetry in pressurized La 3 Ni 2 O 7 .

Physics↗

NASA NTRS1972

Analysis of large-scale Martian topography variations. I - Data preparation from earth-based radar, earth-based CO2 spectroscopy, and Mariners 6 and 7 CO2 spectroscopy.

Using direct radar ranging of surface heights on Mars and spectrophotometric observations of absorptions produced by carbon dioxide molecules in the Martian atmosphere, data have been obtained on Martian topographical variations at spatial resolutions ranging from about 100 to 1000 km. These data have been studied and analyzed. As a result, a surface height contour map has been produced which clearly reveals a structural complex of blocks and basins whose distribution enhances the magnitude of low-degree surface harmonics. It is emphasized that Mars possesses unexpectedly pronounced topography which can have important geophysical consequences.

Wells, R. A.↗

NASA NTRS1978

Dynamics of the quiescent solar corona

An analytical model for the quiescent inhomogeneous solar corona is developed on the basis of the hypothesis that looplike structures are the basic coronal building blocks. By assuming that quiescent loop structures observed in X-rays are in hydrostatic equilibrium, it is demonstrated that such loops must have their temperature maximum located near their apex and that substantial nonradiative energy deposition must occur along most of their length. The calculations yield a unique relation among loop temperature, pressure, and size, which fits the X-ray observations of quiescent structures well and is consistent with the initial assumption of hydrostatic equilibrium. The results suggest that the coronal loops visible in X-rays represent a relatively steady-state equilibrium of the confined plasmas and that fluctuations in such quantities as the local heating rate can lead to dynamically unstable states in which the loop plasma does not attain a temperature sufficient for X-ray emission. A parameterization of various proposed coronal heating theories is also developed within the context of the analytical model.

Rosner, R.↗

NASA NTRS1977

Space Fabrication Demonstration System

Progress on fabrication facility (beam builder) support structure control, clamp/weld block, and welding and truss cut off is discussed. The brace attachment design was changed and the design of the weld mechanism was modified which achieved the following system benefits: (1) simplified weld electrode life; (2) reduced weld power requirements; and (3) simplified brace attachment mechanisms. Static and fatigue characteristics of spot welded 2024T3 aluminum joints are evaluated.

Source record↗

NASA NTRS1984

Topography of the shield volcano, Olympus Mons on Mars

Olympus Mons, one of the largest known shield volcanoes in the solar system, covers an area of more than 3.2 x 10 to the 5th sq km and has a diameter of more than 600 km, excluding its vast aureole deposits. The structure is five times larger than the largest shield volcano on the earth. It is situated on the north-west flank of the Tharsis volcanic region, a broad topographic rise on the Martian surface. The volcano has three physical subdivisions: the summit caldera, the terraced upper flanks, and the lower flanks, which terminate in a scarp 2-10 km high that nearly surrounds the structure. A large block of images of the Tharsis region, including Olympus Mons, was obtained by the Viking mission. A topographic map of Olympus Mons is presented here, which has been compiled using various combinations of stereo pairs of these images, together with stereoscopic perspective views generated by image processing techniques.

Wu, S. S. C.↗

NASA NTRS1994

Automatic computation of Euler-marching and subsonic grids for wing-fuselage configurations

Algebraic procedures are described for the automatic generation of structured, single-block flow computation grids for relatively simple configurations (wing, fuselage, and fin). For supersonic flows, a quasi two-dimensional grid for Euler-marching codes is developed, and some sample results in graphical form are included. A type of grid for subsonic flow calculation is also described. The techniques are algebraic and are based on a generalization of the method of transfinite interpolation.

Barger, Raymond L.↗

NASA NTRS1995

A 3DGRAPE/AL: The Ames/Langley technology upgrade

This paper describes a new three-dimensional structured multiple-block volume grid generator called 3DGRAPE/AL. It is a significantly improved version of the previously-released and widely-distributed program 3DGRAPE, with many of the improvements taken from the grid-generator program 3DMAGGS. It generates volume grids by iteratively solving the Poisson Equations in three-dimensions. The right-hand-side terms are designed so that user-specified grid cell heights and user-specified grid cell skewness near boundary surfaces result automatically, with little user intervention. Versatility was a high priority in this code's development, and as a result it can generate grids in almost any three-dimensional physical domain. Improvements include added kinds of forcing functions, improved control of cell skewness, improved initial conditions, convergence acceleration, the ability to take as input the output from GRIDGEN, and a simple but powerful graphical user interface (GUI).

Sorenson, Reese L.↗

NASA NTRS1992

Aerodynamic simulation on massively parallel systems

This paper briefly addresses the computational requirements for the analysis of complete configurations of aircraft and spacecraft currently under design to be used for advanced transportation in commercial applications as well as in space flight. The discussion clearly shows that massively parallel systems are the only alternative which is both cost effective and on the other hand can provide the necessary TeraFlops, needed to satisfy the narrow design margins of modern vehicles. It is assumed that the solution of the governing physical equations, i.e., the Navier-Stokes equations which may be complemented by chemistry and turbulence models, is done on multiblock grids. This technique is situated between the fully structured approach of classical boundary fitted grids and the fully unstructured tetrahedra grids. A fully structured grid best represents the flow physics, while the unstructured grid gives best geometrical flexibility. The multiblock grid employed is structured within a block, but completely unstructured on the block level. While a completely unstructured grid is not straightforward to parallelize, the above mentioned multiblock grid is inherently parallel, in particular for multiple instruction multiple datastream (MIMD) machines. In this paper guidelines are provided for setting up or modifying an existing sequential code so that a direct parallelization on a massively parallel system is possible. Results are presented for three parallel systems, namely the Intel hypercube, the Ncube hypercube, and the FPS 500 system. Some preliminary results for an 8K CM2 machine will also be mentioned. The code run is the two dimensional grid generation module of Grid, which is a general two dimensional and three dimensional grid generation code for complex geometries. A system of nonlinear Poisson equations is solved. This code is also a good testcase for complex fluid dynamics codes, since the same datastructures are used. All systems provided good speedups, but message passing MIMD systems seem to be best suited for large miltiblock applications.

Haeuser, Jochem↗

NASA NTRS1995

3DGRAPE/AL User's Manual

This document is a users' manual for a new three-dimensional structured multiple-block volume g generator called 3DGRAPE/AL. It is a significantly improved version of the previously-released a widely-distributed programs 3DGRAPE and 3DMAGGS. It generates volume grids by iteratively solving the Poisson Equations in three-dimensions. The right-hand-side terms are designed so that user-specific; grid cell heights and user-specified grid cell skewness near boundary surfaces result automatically, with little user intervention. The code is written in Fortran-77, and can be installed with or without a simple graphical user interface which allows the user to watch as the grid is generated. An introduction describing the improvements over the antecedent 3DGRAPE code is presented first. Then follows a chapter on the basic grid generator program itself, and comments on installing it. The input is then described in detail. After that is a description of the Graphical User Interface. Five example cases are shown next, with plots of the results. Following that is a chapter on two input filters which allow use of input data generated elsewhere. Last is a treatment of the theory embodied in the code.

Sorenson, Reese L.↗

NASA NTRS1998

An Investigation into the Elementary Temporal Structure of Solar Flare Hard X-Ray Bursts Using BATSE

The research performed under this contract is part of an on-going investigation to explore the finest time-resolution hard X-ray data available on solar flares. Since 1991, the Burst and Transient Source Experiment (BATSE) aboard the Compton Gamma Ray Observatory has provided almost continual monitoring of the Sun in the hard X-ray and gamma-ray region of the spectrum. BATSE provides for the first time a temporal resolution in the data comparable to the timescales on which flare particle energization occurs. Under this contract, we have employed an important but under-utilized BATSE data type, the Time-To-Spill (TTS) data, to address the question of how fine a temporal structure exists in flare hard X-ray emission. By establishing the extent to which "energy release fragments," or characteristic (recurrent) time structures, are building blocks of flare emission, it is possible to place constraints on particle acceleration theories. We have utilized a spectral estimation technique, known as Lomb's normalized periodogram, to overcome the challenge of computing the power spectra of the unevenly sampled TTS data. By comparing the flare's power spectra to the expected power arising from Poisson noise, we obtain measurements of the smallest, statistically significant timescales present in the data. We have found, in an initial sample of 100 flares, that the smallest statistically significant timescales detected in a single flare are: 89 ms (30 May 1991 11:26:06) in channel 0, 117 ms (17 May 1991 09:03:20) in channel 1, 167 ms (31 May 1991 16:53:12) in channel 2, and 1.55 s (06 June 1991 01:02:08) in channel 3. We have also found some evidence for the existence of preferred timescales, however, the significance of this finding awaits a larger sample of flares.

Newton , Elizabeth↗

NASA NTRS1998

An Investigation into the Elementary Temporal Structure of Solar Flare Hard X-Ray Bursts Using BATSE

Newton, Elizabeth↗

NASA NTRS1999

Investigation of Near Shannon Limit Coding Schemes

Turbo codes can deliver performance that is very close to the Shannon limit. This report investigates algorithms for convolutional turbo codes and block turbo codes. Both coding schemes can achieve performance near Shannon limit. The performance of the schemes is obtained using computer simulations. There are three sections in this report. First section is the introduction. The fundamental knowledge about coding, block coding and convolutional coding is discussed. In the second section, the basic concepts of convolutional turbo codes are introduced and the performance of turbo codes, especially high rate turbo codes, is provided from the simulation results. After introducing all the parameters that help turbo codes achieve such a good performance, it is concluded that output weight distribution should be the main consideration in designing turbo codes. Based on the output weight distribution, the performance bounds for turbo codes are given. Then, the relationships between the output weight distribution and the factors like generator polynomial, interleaver and puncturing pattern are examined. The criterion for the best selection of system components is provided. The puncturing pattern algorithm is discussed in detail. Different puncturing patterns are compared for each high rate. For most of the high rate codes, the puncturing pattern does not show any significant effect on the code performance if pseudo - random interleaver is used in the system. For some special rate codes with poor performance, an alternative puncturing algorithm is designed which restores their performance close to the Shannon limit. Finally, in section three, for iterative decoding of block codes, the method of building trellis for block codes, the structure of the iterative decoding system and the calculation of extrinsic values are discussed.

Kwatra, S. C.↗

NASA NTRS2002

Heat Transfer in a Complex Trailing Edge Passage for a High Pressure Turbine Blade: Simulation Results - Part 2:

A combined experimental and numerical study to investigate the heat transfer distribution in a complex blade trailing edge passage was conducted. The geometry consists of a two pass serpentine passage with taper toward the trailing edge, as well as from hub to tip. The upflow channel has an average aspect ratio of roughly 14:1, while the exit passage aspect ratio is about 5:1. The upflow channel is split in an interrupted way and is smooth on the trailing edge side of the split and turbulated on the other side. A turning vane is placed near the tip of the upflow channel. Reynolds numbers in the range of 31,000 to 61,000, based on inlet conditions, were simulated numerically. The simulation was performed using the Glenn-HT code, a full three-dimensional Navier-Stokes solver using the Wilcox k-omega turbulence model. A structured multi-block grid is used with approximately 4.5 million cells and average y+ values on the order of unity. Pressure and heat transfer distributions are presented with comparison to the experimental data. While there are some regions with discrepancies, in general the agreement is very good for both pressure and heat transfer.

Rigby, David L.↗

NASA NTRS2003

An Immunized Aircraft Maneuver Selection System

The objective of this project, as stated in the original proposal, was to develop an immunized aircraft maneuver selection (IAMS) system. The IAMS system was to be composed of computational and informational building blocks that resemble structures in natural immune systems. The ultimate goal of the project was to develop a software package that could be flight tested on aircraft models. This report describes the work performed in the first year of what was to have been a two year project. This report also describes efforts that would have been made in the final year to have completed the project, had it been continued for the final year. After introductory material is provided in Section 2, the end-of-year-one status of the effort is discussed in Section 3. The remainder of the report provides an accounting of first year efforts. Section 4 provides background information on natural immune systems while Section 5 describes a generic ar&itecture developed for use in the IAMS. Section 6 describes the application of the architecture to a system identification problem. Finally, Section 7 describes steps necessary for completing the project.

Karr, Charles L.↗

NASA NTRS2009

F-16XL Geometry and Grids

The objective of the Cranked-Arrow Wing Aerodynamics Project International (CAWAPI) was to allow a comprehensive validation of Computational Fluid Dynamics methods against the CAWAP flight database. A major part of this work involved the generation of high-quality computational grids. Prior to the grid generation an IGES file containing the air-tight geometry of the F-16XL aircraft was generated by a cooperation of some of the CAWAPI partners. Based on this geometry description both structured and unstructured grids have been generated. The baseline structured (multi-block) grid (and a family of derived grids) has been generated by the National Aerospace Laboratory (NLR). The baseline all-tetrahedral and hybrid unstructured grids were generated at the NASA Langley Research Center and the U.S. Air Force Academy, respectively. To provide more geometrical resolution, additional unstructured grids were generated at EADS-MAS, the UTSimCenter, and Boeing Phantom Works. All the grids generated within the framework of CAWAPI will be discussed.

Boelens, Okko J.↗

NASA NTRS2010

An Overview of Thermal Distortion Modeling, Analysis, and Model Validation for the JWST ISIM Structure

This paper describes thermal distortion modeling, analysis, and model validation activities completed in support of the design and qualification of the JWST ISIM Structure. An overview of the building blocks approach utilized to develop the structural design and modeling capabilities to meet thermal distortion performance requirements will be provided. This effort culminated in a cryogenic (35 K) distortion test of the flight ISIM Structure hardware, the Cryoset Test that both verified the thermal distortion performance and provided data for validation of the structural models. An overview of the modeling, analysis, and model validation development effort will be discussed, and the results of the Cryoset Test and the subsequent model validation will be described.

Johnston, John↗

NASA NTRS2009

Orbiter Payload Bay Bucket Hoist Mishap...An Accident We Should Never Forget

This slide presentation reviews the accident that occurred in 1985 when a bay bucket hoist fell from its stowed position. This accident damaged the orbiter, injured a technician, and delayed the launch. The accident was investigated, and the cause of the accident was determined to be the practice of two-blocking. Two-blocking is the result of hoisting beyond the intended safe upper limit of hook travel to the point of solid contact between the load block and the upper block or hoist/trolley structure. The usual result is immediate failure of the wire rope, due to the ropes being cut by the grooves of the drum or sheaves. The design of the hoist, the inspection, and the operator training were all in part responsible for this failure.

Lytle, Bradford P.↗