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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Unsteady turbulent shear flow in shock tube discontinuities

A pressure-ruptured shock tube and an arc driven shock tube, have been used to study the evolution of turbulent fluctuations at contact surfaces with N2O4-2NO2 mixtures and at ionizing shock fronts in argon. The study has focused on point density diagnostics derived from crossed light beam correlations and electric probes. Turbulent bursts are found for which dynamical and spectral analyses suggest a particle-like evolution of fluctuation segments with a unique and characteristic frequency, independent of flow history and overall flow conditions.

Johnson, J. A., III↗
NASA NTRS2019

White Papers for the Next Decadal Survey: Thermal Protection Systems and Instrumentation

NASA is anticipated to commission the next Planetary Science Decadal Survey (PSDS) with preparation expected in early calendar year 2020. The new PSDS will outline the priorities of science missions for the decade spanning 2023-2032. For the previous PSDS, the science and technology communities have been invited to submit white papers to the PSDS sub-panels as background information to guide the PSDS recommendations. The National Research Council has previously stated that white papers that represent the opinion of many authors from different institutions carried more significance and weight, and the recommendations from the previous PSDS attempted to reflect more of a consensus opinion. In 2009, a total of 4 white papers were submitted to the PSDS panels regarding thermal protection system (TPS) readiness for missions, as well as one on TPS instrumentation. The TPS readiness papers were co-authored by 90 individuals from many institutions. These white papers surveyed the TPS materials for both forebody and afterbody of a probe and analyzed the suitability of materials for missions to each destination. In addition, each paper outlined the ground testing required and ongoing technology development. Recommendations were provided for further technology development and ground test capability in order to fulfill future missions. Many improvements and changes have occurred in the past 10 years with regard to TPS materials and instrumentation. New materials have been developed and tested, such as the high density material Heat-shield for Extreme Entry Environment Technology (HEEET), and new capabilities for ground testing for high heating and high pressures have been added such as the 3-inch nozzle at the Ames arc jet. NASA has also flown several TPS instrumentation suites, such as MEDLI (Mars Science Laboratory Entry, Descent, and Landing Instrument) and EFT-1 (Exploration Flight Test-1). In order to provide the PSDS sub-panels with the most current information about the state-of-the-art suitability for TPS materials for entry missions, we are beginning to update and draft new white papers. We will present the outline for material to be covered in the white papers, and we invite all IPPW (International Planetary Probe Workshop) attendees to particiate in co-authoring these papers.

Hwang, Helen H.↗
NASA NTRS1981

Auroral kilometric radiation - A theoretical review

Auroral kilometric radiation (AKR) is a high-density radio wave radiation in the frequency band from 50 to 750 kHz, with a peak around 250 kHz, that has been observed emanating from the auroral zone. In connection with its low frequency, the radiation can not penetrate through the ionosphere to earth, so all observations have been made by satellite. The AKR is closely correlated with the occurrence of discrete auroral arcs, which are believed to be generated by intense inverted V electron precipitation bands. A review is presented of several theories which have been proposed to explain the observed AKR. Attention is given to the conversion of electron cyclotron wave to O mode, the coherent amplification of gyroemission by velocity space instabilities, beam-driven electromagnetic instability via low-frequency turbulence, soliton radiation, loss cone instability, nonlinear beating of electrostatic waves, and the beam amplification of electromagnetic wave via coherent EIC density fluctuations.

Grabbe, C. L.↗
DOE OSTI2025

Rapid scalable plasma processing of thin-film Li–La–Zr–O solid-state electrolytes

Solid-state electrolytes, such as lithium lanthanum zirconium oxide (LLZO), show promise as technologies for next-generation high-energy-density batteries, but commercial development has been hindered by a lack of scalable processing methods. Current fabrication methods are costly or require long annealing steps to create dense films. We report an atmospheric pressure blown-arc nitrogen plasma jet process to rapidly form sub-micrometer-thick, dense amorphous LLZO (a-LLZO) films from sol-gel precursors. Films are processed in less than 2 min, an order of magnitude faster than what has previously been reported. We demonstrate 500-nm-thick a-LLZO films processed at 350°C with an ionic conductivity of 2 × 10 −6 S/cm at 30°C and 2 × 10 −3 S/cm at 100°C and a conductance of 19 S at 100°C, the highest conductance of any LLZO phase to date. Here, the films exhibit outstanding smooth surface morphology with low defectivity, advancing atmospheric plasma processing as a scalable processing method for solid-state electrolytes.

25 ENERGY STORAGE↗
DOE OSTI2022

Fluorination Enables Simultaneous Improvements of a Dialkoxybenzene-Based Redoxmer for Nonaqueous Redox Flow Batteries

Redoxmers or redox-active organic materials, arc one critical component for nonaqueous redox flow batteries (RFBs), which hold high promise in enabling the time domain of the grid. While tuning redox potentials of redoxmers is a very effective way to enhance energy densities of NRFBs, those improvements often accompany accelerated kinetics of the charged species, undermining stability and cycling performance. In this paper, a strategy for designing redoxmers with simultaneous improvements in redox potential and stability is proposed. Specifically, the redoxmer 1,4-di-tert-butyl-2,5-bis(2,2,2-trifluoroethoxy)benzene (ANL-C46) is developed by incorporating fluorinated substitutions into the dialkoxybenzene-based platform. Compared to the non-fluorinated analogue, ANL-C46 demonstrates not only an increased (similar to 0.41 V) redox potential but also much enhanced stability (1.6 times) and cyclability (4 times) evidenced by electron paramagnetic resonance kinetic study, H-cell and flow cell cycling. In fact, the cycling performance of ANL-C46 is among the best of high potential (>1.0 V vs Ag/Ag + ) redoxmers ever reported. Density functional theory calculations suggest that while the introduced fluorine substitutions elevate the redox potentials, they also help to depress the decomposition reactions of the charged redoxmers, affording excellent stability. The findings represent an interesting strategy for simultaneously improving energy density and stability, which could further prompt the development of high-performance redoxmers.

25 ENERGY STORAGE↗
DOE OSTI2020

Unipolar arc plasmas on nanostructured tungsten surfaces under perpendicular magnetic field

Abstract Unipolar arcing is an important phenomenon in terms of wall erosion and the subsequent plasma contamination in nuclear fusion devices. In this study, unipolar arc plasmas are experimentally explored under the presence of the external magnetic field perpendicular to a tungsten (W) sample on which a ‘fuzz’ nanostructure surface is formed. It is found that the fuzz layer thickness, d fuzz , plays a dominant role in determining the motion of arc spots, the arc ignition probability, and arc plasma parameters. High-speed imaging reveals that the motion of arc spots becomes more collective, as d fuzz increases. Interestingly, arc spots make a circle while moving outward. With increasing d fuzz , the amount of eroded W atoms increases, as indicated from an observed increase in the total visible emission intensity, while the arc ignition probability is found to drop. The physical mechanisms are discussed, in detail, based on spectroscopic measurements of the electron temperature, obtained from Boltzmann plots of both W I and W II, and the electron density, determined from Stark broadening of W I lines.

Physics↗
NASA NTRS1996

Role of the micro/macro structure of welds in crack nucleation and propagation in aerospace aluminum-lithium alloy

Al-Li alloys offer the benefits of increased strength, elastic modulus and lower densities as compared to conventional aluminum alloys. Martin Marietta Laboratories has developed an Al-Li alloy designated 2195 which is designated for use in the cryogenic tanks of the space shuttle. The Variable Polarity Plasma Arc (VPPA) welding process is currently being used to produce these welds [1]. VPPA welding utilizes high temperature ionized gas (plasma) to transfer heat to the workpiece. An inert gas, such as Helium, is used to shield the active welding zone to prevent contamination of the molten base metal with surrounding reactive atmospheric gases. [1] In the Space Shuttle application, two passes of the arc are used to complete a butt-type weld. The pressure of the plasma stream is increased during the first pass to force the arc entirely through the material, a practice commonly referred to as keyholing. Molten metal forms on either side of the arc and surface tension draws this liquid together as the arc passes. 2319 Al alloy filler material may also be fed into the weld zone during this pass. During the second pass, the plasma stream pressure is reduced such that only partial penetration of the base material is obtained. Al 2319 filler material is added during this pass to yield a uniform, fully filled welded joint. This additional pass also acts to alter the grain structure of the weld zone to yield a higher strength joint.

Talia, George E.↗
NASA NTRSDate not supplied

TPSAS-NF1676L-32577-DND

The ground testing of hypersonic vehicles requires the replication of the flow conditions at high speed and altitude. To produce these flow conditions, stored compressed air is expanded through a convergent-divergent nozzle to produce the required pressures and speed. However, the expansion process also cools the air, and so to match the flight temperatures, some form of heating needs to be employed. Vitiated heating is a common method, where the air is heated by burning fuel in the low speed side of the nozzle, and then oxygen is added to bring the level of O2 up to match that of standard air. The resulting flow no longer has the same composition as standard air, (except for the oxygen level), but rather contains combustion products, often referred to as vitiates as part of the mixture. The presence of these vitiates in the flow effects the wind tunnel test conditions. For example, the specific heat and molecular density are changed, the kinetics of combustion are altered and the flow features in the test article are altered. In this talk, the effects of the vitiates on the testing conditions and on the performance of test articles is described. Specific examples include the effects of molecular density on the flow, how combustion processes are altered by the presence of vitiates and how condensation of vitiates can alter the test conditions. In addition, the effect of the less common vitiates produced by arc-heated tunnels are mentioned, such as NO, non-thermal equilibrium and the presence of copper solids in the flow. Finally some thoughts on how large an effect these vitiates have on the test results are presented.

Andrew T Norris↗
NASA NTRS1981

Global simulation of auroral arcs

Numerical simulation of global formation of auroral arcs is carried out for a three-dimensional coupled ionosphere-magnetosphere system. With the presence of the stationary convection electric field, the field-aligned current driven by the polarization and drift of the ionospheric conductivity enhancement is shown to be responsible for the feedback instability of the shear Alfven wave. The simulation result demonstrates the dynamic process of auroral arc formation, where an ionospheric perturbation nearly resonant with the magnetospheric Alfven wave (toroidal mode) can eventually grow into auroral arcs. Many of the important characteristics of quiet auroral arcs are demonstrated, and it is shown that the overall distribution of auroras depends critically on the stationary state of the auroral oval characterized by the large-scale Birkeland current, the electric field, and the electron density distribution.

Miura, A.↗
NASA NTRS1994

Effect of high-latitude ionospheric convection on Sun-aligned polar caps

A coupled magnetospheric-ionospheric (M-I) magnetohydrodynamic (MHD) model has been used to simulate the formation of Sun-aligned polar cap arcs for a variety of interplanetary magnetic field (IMF) dependent polar cap convection fields. The formation process involves launching an Alfven shear wave from the magnetosphere to the ionosphere where the ionospheric conductance can react self-consistently to changes in the upward currents. We assume that the initial Alfven shear wave is the result of solar wind-magnetosphere interactions. The simulations show how the E region density is affected by the changes in the electron precipitation that are associated with the upward currents. These changes in conductance lead to both a modified Alfven wave reflection at the ionosphere and the generation of secondary Alfven waves in the ionosphere. The ensuing bouncing of the Alfven waves between the ionosphere and magnetosphere is followed until an asymptotic solution is obtained. At the magnetosphere the Alfven waves reflect at a fixed boundary. The coupled M-I Sun-aligned polar cap arc model of Zhu et al.(1993a) is used to carry out the simulations. This study focuses on the dependence of the polar cap arc formation on the background (global) convection pattern. Since the polar cap arcs occur for northward and strong B(sub y) IMF conditions, a variety of background convection patterns can exist when the arcs are present. The study shows that polar cap arcs can be formed for all these convection patterns; however, the arc features are dramatically different for the different patterns. For weak sunward convection a relatively confined single pair of current sheets is associated with the imposed Alfven shear wave structure. However, when the electric field exceeds a threshold, the arc structure intensifies, and the conductance increases as does the local Joule heating rate. These increases are faster than a linear dependence on the background electric field strength. Furthermore, above the threshold, the single current sheet pair splits into multiple current sheet pairs. For the fixed initial ionospheric and magnetospheric conditions used in this study, the separation distance between the current pairs was found to be almost independent of the background electric field strength. For either three-cell or distorted two-cell background convection patterns the arc formation favored the positive B(sub y) case in the northern hemisphere.

Sojka, J. J.↗
NASA NTRS1993

A new giant luminous arc gravitational lens associated with a z = 0.62 galaxy cluster, and the environments of distant radio galaxies

In the course of a survey investigating the cluster environments of distant 3CR radio galaxies, I have identified a previously unknown 'giant luminous arc' gravitational lens. The lensing cluster is associated with the radio galaxy 3C 220.1 at z = 0.62 and is the most distant cluster now known to produce such arcs. I present imaging and spectroscopic observations of the cluster and the arc, and discuss the implications for the cluster mass. At z greater than 0.6 the cluster velocity dispersions implied by such giant arcs may provide an interesting constraint on theories of large scale structure formation. The parent investigation in which this arc was identified concerns galaxy clusters and radio galaxy environments at 0.35 less than z less than 0.8. At the present epoch, powerful FR 2 radio galaxies tend to be found in environments of poor or average galaxy density. In contrast, at the higher redshifts investigated here, richer group and cluster environments are common. I present additional data on other clusters from this survey, and discuss its extension to z greater than 1 through a program of near-infrared and optical imaging.

Dickinson, Mark↗
NASA NTRS1998

The Anatomy of the Perseus Spiral Arm: 12 CO and IRAS Imaging Observations of the W3-W4-W5 Cloud Complex

Panoramic images of 12CO J = 1-0 and thermal dust emissions from the W3-W4-W5 region of the outer Galaxy are presented. These data and recently published H I 21 cm line emission images provide an approximate 1' resolution perspective to the dynamics and thermal energy content of the interstellar gas and dust components contained within a 9 deg. arc of the Perseus spiral arm. We tabulate the molecular properties of 1560 clouds identified as closed surfaces within the l-b-v CO data cube at a threshold of 0.9 K T* (sub R). Relative surface densities of the molecular (28:1) and atomic (2.5:1) gas components determined within the arm and interarm velocity intervals demonstrate that the gas component that enters the spiral arm is predominantly atomic. Molecular clouds must necessarily condense from the compressed atomic material that enters the spiral arm and are likely short lived within the interarm regions. From the distribution of centroid velocities of clouds, we determine a random cloud-to-cloud velocity dispersion of 4 km s (exp. -1) over the width of the spiral arm but find no clear evidence within the molecular gas for streaming motions induced by the spiral potential. The far-infrared images are analyzed with the CO J = 1-0 and H I 21 cm line emission. The enhanced UV (Ultraviolet) radiation field from members of the Cas OB6 association and embedded newborn stars provide a significant source of heating to the extended dust component within the Perseus arm relative to the quiescent cirrus regions. Much of the measured far-infrared flux (69% at 60 micrometers and 47% at 100 micrometers) originates from regions associated with star formation rather than the extended, infrared cirrus component.

Heyer, Mark H.↗
NASA NTRS1975

Large space telescope control moment gyro test program

The underlying theory and design of test instrumentation and computer techniques used to determine the power spectral density (PSD) of the third generation gyro are described in detail. Acceptance test results on the completed instrument are presented as well as composite PSD plots. The measured RMS noise over the frequency band 0.0025 - 10 Hz was 0.012 arc seconds. Results obtained at Martin Company indicate an RMS noise of 0.009 arc seconds (0.05 - 10 Hz). The results obtained showed the TGG performance was close to the proposed LST requirements but that additional development work would be needed to reduce the TGG noise to within more desirable limits.

Salamin, E.↗
NASA NTRS1984

Type II bursts, shock waves, and coronal transients - The event of 1980 June 29, 0233 UT

The metric Type-II solar burst event of June 29, 1980, is characterized on the basis of spatially resolved radioheliograph observations obtained at Culgoora, Australia, and visible-light observations obtained with the coronograph/polarimeter of the SMM satellite. The data are presented in images, diagrams, and graphs and discussed in detail. The Type-II emission is found to arise in the dense moving material behind the transient loops, which have sky-plane width 0.5 solar radius and line-of-sight depth 0.1-0.4 solar radius. A faint arc observed moving ahead of the transient loops at about 900 km/sec and not associated with the Type-II burst is attributed to a shock front, and the compression ratio and Alfven Mach number of the enhanced-density region are estimated as n2/n1 = 1.3-3 and M(A) = 1.2-3. The ambient material at 3 solar radii is determined to have Alfven speed 250-625 km/sec and magnetic-field strength 50-120 mG. The total mass of the event is calculated as 700 Tg; the total magnetic energy of the loops is (1.5-15) x 10 to the 29th ergs.

Gary, D. E.↗
NASA NTRS1984

O(+) charge exchange in the polar wind

O(+) density and flux profiles are calculated for a steady state polar wind flow of O(+) ions and electrons along geomagnetic field lines in the polar cap. Profiles are computed both with and without allowance for accidentally resonant charge exchange (ARCE) between O(+) and H. It is found that ARCE acts to reduce the limiting O(+) escape flux by less than 30 percent for typical atmospheric conditions and by only a factor of about 3.5 for atmospheres with low exospheric temperatures. Allowing for ARCE, the limiting O(+) escape flux is of the order of 5 x 10 to the 8th to 9th/cu cm/s, depending on the atmospheric conditions. This indicates that, contrary to previous predictions, there is no O(+) charge exchange barrier and it is therefore not necessary to have an acceleration mechanism at low altitudes in order to have an appreciable O(+) escape flux.

Barakat, A. R.↗
NASA NTRS1998

The Anatomy of the Perseus Spiral ARM: (sup 12)CO and IRAS Imaging Observations of the W3-W4-W5 Cloud Complex

Panoramic images of (sup l2)CO J = 1-0 and thermal dust emissions from the W3-W4-W5 region of the outer Galaxy are presented. These data and recently published H (sub I) 21 cm line emission images provide an approx. 1 min resolution perspective to the dynamics and thermal energy content of the interstellar gas and dust components contained within a 9 deg arc of the Perseus spiral arm. We tabulate the molecular properties of 1560 clouds identified as closed surfaces within the l-b-v CO data cube at a threshold of 0.9 K T(sup *)(sub R). Relative surface densities of the molecular (28:1) and atomic (2.5: 1) gas components determined within the arm and interarm velocity intervals demonstrate that the gas component that enters the spiral arm is predominantly atomic. Molecular clouds must necessarily condense from the compressed atomic material that enters the spiral arm and are likely short lived within the interarm regions. From the distribution of centroid velocities of clouds, we determine a random cloud-to-cloud velocity dispersion of 4 km/s over the width of the spiral arm but find no clear evidence within the molecular gas for streaming motions induced by the spiral potential. The far-infrared images are analyzed with the CO J = 1-0 and H (sub I) 21 cm line emission. The enhanced UV radiation field from members of the Cas OB6 association and embedded newborn stars provide a significant source of heating to the extended dust component within the Perseus arm relative to the quiescent cirrus regions. Much of the measured far-infrared flux (69% at 60 microns and 47% at 100 microns) originates from regions associated with star formation rather than the extended, infrared cirrus component.

Heyer, Mark H.↗
NASA NTRS2003

Processing and Properties of HfB2 Based Materials

Contents include the following: Modified hot pressing schedule has significantly improved UHTC billet processing: density and microstructure uniformity have improved. 2 in. dia. x 2 in. tall UHTC billets have been successfully hot pressed: scaled up billets have slightly higher density gradients axially than 1 in. billets. Hot press schedule has not been optimized for scaled up billets. Strengths and strength distributions are improving with experience: need to evaluate strength uniformity in the center of the billets. CTE or ARC materials compares favorably with heritage materials. Thermal conductivity of ARC materials considerably different than that of heritage materials.

Johnson, Sylvia M.↗
NASA NTRS1986

A compact density condensation around L1551-IRS 5: 2.7mm continuum observations with 4" resolution

The dark cloud L1551 contains the best known examples of bipolar molecular outflow. Such outflows are assumed to be driven by winds from young stars embedded in a cloud but the mechanism for collimation of the outflows is still in doubt, though it has been much debated. Among the possibilities put forth to date are intrinsically anisotropic stellar winds, isotropic stellar winds collimated by interstellar toroidal shaped clouds on the order of 10(17) cm in size, or circumstellar disks of order 10(15) cm in size. Because the outflow in L1551 as revealed by the Very Large Array (VLA) cm continuum observations is collimated even at the arc second level it seems as though the stellar wind powering the outflow must either be initially anisotropic or be collimated by something very close to the star, such as a circumstellar disk. We have observed L1551 in the continuum at 2.7 mm with the OVRO millimeter-wave interferometer in the winter of 1983-4 and again, more extensively, in 1985-6. The resulting map shows for the first time direct evidence for a density condensation capable of collimating an initially isotropic flow from IRS 5. This map made from data taken in 1985-6 with projected baselines up to 100 m in length (37k lambda). It has been cleaned and reconstructed with a 4'' gaussian beam. It shows a nearly unresolved source with a suggestion of extension at the 3'' level (assuming a gaussian source shape). The integrated flux density in this map is 170 mJy. A composite spectrum of L1551 is presented which shows that the flux at 2.7 mm is due to the thermal radiation from dust that is also seen at shorter wavelengths. Very little of it can be due to the continuation of the nearly flat cm wavelength spectrum which is assumed to be from thermal bremsstrahlung radiation. The map and spectrum provide strong constraints on the size, temperature, and optical depth of the density condensation surrounding IRS 5.

Keene, J.↗