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Identification and Evaluation for Fueling of NRIC DOME Reactors Report

The National Reactor Innovation Center (NRIC) has designed a testbed for advanced microreactor experiments that enables and encourages technology developers to bring advanced designs closer to commercial availability. The test bed, Demonstration of Microreactor Experiments (DOME), will be used to facilitate much of the operation experimentation process of the each advanced microreactor including fueling and operational power experiments. This report identifies and evaluates the options for initial fueling the microreactors in DOME. This report also discusses the optional locations that were considered for the initial fueling of microreactor; namely the Transient Reactor Test (TREAT) reactor building, and an unspecified temporary location. But various logistical and construction issues essentially eliminated these other options from further consideration. A brief discussion in this report outlines potential equipment and protocol associated with fueling in DOME.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Status of Mock-up and Integration for Ultrasonic Deformation Sensor for TREAT Experiments

Fuel deformation (both axial and radial) information provides insights into fuel performance and failure limits. Traditionally, fuel deformation has been quantified using post-irradiation examinations due to the lack of an appropriate sensor for monitoring deformation in situ. Recent developments in sensor and instrumentation design have led to the use of linear variable differential transducers (LVDT) for monitoring axial strain in fuel during irradiation. Size and operational constraints limit the use of LVDT sensors for radial deformation monitoring, and alternatives are needed. One possible alternative to LVDT sensors is an ultrasonic sensor. Ultrasonic sensors monitor the interaction of high-frequency stress waves with the test object. The resulting response may be analyzed to determine the properties of the material, including stress, strain, microstructure, presence of defects, and the elastic constants. While ultrasonic measurements have been successfully applied for monitoring strain in a number of applications, their use for in-core measurements has been limited. Largely, the limitations are due to the challenges associated with designing sensors that can operate under typical in-core conditions. This report documents progress to date toward planning, construction, and testing of a mock-up test capsule/facility to be used for in-lab testing of ultrasonic displacement sensor designs and toward integration of the sensor into prototypic TREAT experiment designs.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Materials and Fuels Complex Five-Year Mission Strategy (FY21- FY25)

The Idaho National Laboratory (INL), through its designated mission of advancing innovative nuclear energy solutions, is actively engaged in the research, development, demonstration and deployment of advanced nuclear technology, as well as in fostering private-public partnership for technology development. Key to the success of INL’s mission is the Materials and Fuels Complex (MFC), the only complex in the U.S. that hosts a world-class assemblage of facilities, capabilities and instruments for handling, testing, and characterizing radioactive materials. Driven by its mission/vision of “Engineering and Experiments that Drive the World’s Nuclear Energy Future,” MFC is at the center of INL’s – and indeed the Department of Energy’s – advanced nuclear technology development initiatives, providing essential capabilities such as engineering-scale high-assay low-enriched uranium (HALEU) fuel production, reactor demonstration facilities, post-irradiation examination, and transient irradiation testing. Furthermore, MFC provides an ideal environment for test beds that are utilized for research, development and demonstration (RD&D) activities on used fuel treatment, nuclear non-proliferation, forensics, and nuclear power sources used for space exploration missions conducted by the National Aeronautics and Space Administration (NASA).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Materials and Fuels Complex (FY2021-2025 Five-Year Mission Strategy)

The Idaho National Laboratory (INL), through its designated mission of advancing innovative nuclear energy solutions, is actively engaged in the research, development, demonstration and deployment of advanced nuclear technology, as well as in fostering private-public partnership for technology development. Key to the success of INL’s mission is the Materials and Fuels Complex (MFC), the only complex in the U.S. that hosts a world-class assemblage of facilities, capabilities and instruments for handling, testing, and characterizing radioactive materials. Driven by its mission/vision of “Engineering and Experiments that Drive the World’s Nuclear Energy Future,” MFC is at the center of INL’s – and indeed the Department of Energy’s – advanced nuclear technology development initiatives, providing essential capabilities such as engineering-scale high-assay low-enriched uranium (HALEU) fuel production, reactor demonstration facilities, post-irradiation examination, and transient irradiation testing. Furthermore, MFC provides an ideal environment for test beds that are utilized for research, development and demonstration (RD&D) activities on used fuel treatment, nuclear non-proliferation, forensics, and nuclear power sources used for space exploration missions conducted by the National Aeronautics and Space Administration (NASA).

99 GENERAL AND MISCELLANEOUS↗

RIA Testing Program for ATF

Presentation on the RIA Testing Program for ATFs at TREAT for the 11th Annual EPRI/DOE/INL Joint Workshop on Accident Tolerant Fuel

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Materials and Fuels Complex FY-22 – FY-26 Five-Year Mission Strategy

The Idaho National Laboratory (INL), through its designated mission of advancing innovative nuclear energy solutions, is actively engaged in the research, development, demonstration and deployment of advanced nuclear technology. Key to the success of INL’s mission is the Materials and Fuels Complex (MFC), the only complex in the U.S. that hosts a world-class assemblage of facilities, capabilities and instruments for handling, testing, and characterizing nuclear fuel and radioactive materials. Driven by its mission/vision of “Engineering and Experiments that Drive the World’s Nuclear Energy Future,” MFC is at the center of INL’s – and indeed the Department of Energy’s – advanced nuclear technology development initiatives, providing essential capabilities such as research-scale high-assay low-enriched uranium (HALEU) fuel production, reactor demonstration facilities, post-irradiation examination, and transient irradiation testing. Furthermore, MFC provides an ideal environment for test beds that are utilized for research, development and demonstration (RD&D) activities on used fuel treatment, nuclear non-proliferation, forensics, and nuclear power sources used for space exploration missions conducted by the National Aeronautics and Space Administration (NASA).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Enhanced geometric capabilities for the transient analysis code T-ReX and its application to simulating TREAT experiments

Here, advances in computational architecture have prompted a resurgence in the simulation of reactor transients from first principles. Most codes are unable to simulate transient events with complex models, and require numerous approximations. The code T-ReX (Transient-Reactor eXperiment simulator), an extensive update to TDKENO, has been developed as a transient analysis tool with few geometric limitations and minimal theoretical approximations. T-ReX achieves this by employing the Improved Quasi-Static (IQS) method to solve the time dependent Boltzmann transport equation with explicit representation of delayed neutrons. The primary change in T-ReX relative to TDKENO is the incorporation of a modified version of the Monte Carlo code KENO-VI to calculate the flux shape and model the geometry of a problem. Using KENO-VI to model systems allows exact representation of the geometry. The changes to T-ReX are verified by comparison of solutions to computational benchmark problems found with a previous version of TDKENO that made use of KENO V.a, and several other codes with time-dependent capabilities. In addition, a three-dimensional model of the Transient Reactor Test Facility (TREAT) core at the Idaho National Laboratory (INL) is constructed with KENO-VI, and used to validate T ReX. T-ReX produces results that agree with benchmark problems, and are in better agreement with TREAT experimental data than TDKENO.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Design Requirements for Ultrasonic Deformation Sensor for TREAT Experiments

Ultrasonic measurements of deformation can provide nondestructive measurements of dimensional changes rapidly (within tens to hundreds of microseconds). Further these methods are sensitive to both microstructural changes due to damage (from thermal, mechanical, and irradiation environments) and gross structural changes (such as swelling). As a result, ultrasonic methods have been applied to address needs in the nondestructive evaluation of structural components in nuclear power plants (including fuel cladding) during periodic pre-service and in-service inspection inspections. Ultrasonic measurements have been successfully used for nondestructive materials characterization, including nondestructive evaluation (NDE) of degradation and damage, microstructure characterization, and process control. Ultrasonic NDE is a critical element of the nuclear power industry’s in-service inspection program for maintaining the integrity of the pressure boundary, and is being actively investigated for post-irradiation examination of fuels. Ultrasonic measurements, typically performed at 10 MHz or higher, performed post irradiation show that fuel microstructural parameters, such as porosity and grain size, can be correlated to ultrasonic velocity. Ultrasonic methods historically have seen limited applicability to environments with high temperatures and irradiation. Though some environmental factors (such as temperature) affect the measurement (sound speed, for instance), the limitation is primarily due to the probes themselves. Most commonly, lead-zirconate-titanate (PZT) is used as the piezoelectric sensor material for ultrasonic nondestructive measurements. PZT is limited in its applicability at elevated temperatures (approximately above 300C). However, recent tests (through DOE-NE’s NEET-ASI program) have identified a number of alternatives that can operate at elevated temperatures (in excess of 400C) and can survive irradiation. Certain grades of PZT have also been demonstrated for use in imaging under-sodium in sodium fast reactors.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Expansion of the Fast Neutron Hodoscope at TREAT to Support Fuel Safety Experiments

In 2024 the Fuel Motion Monitoring System (FMMS), or Hodoscope, at the Transient Reactor Test Facility, is being expanded from 96 viewing channels to 192 viewing channels, effectively doubling the FMMS field of view. Here, this increase in capability will allow the FMMS to support larger scale fuel tests, encompassing height-of-core test devices, test devices with multi-pin fuel assemblies, and test devices with recirculating coolant flow. Work supporting the expansion included refurbishing 96 additional proton recoil scintillator (PRS) detectors, doubling the data acquisition system (DAS) installed architecture, improving time synchronization in the DAS, and new research to measure the PRS detector energy-dependent, fast-neutron detection efficiency. In addition, laboratory activities have produced an improved benchtop testing capability for assessing the DAS, time synchronization, and external start triggering, along with an updated capability to scan PRS detectors to develop a preliminary flat-field normalization prior to deployment to TREAT.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

High-Fluence Active Irradiation and Combined Effects Testing of Sapphire Optical Fiber Distributed Temperature Sensors

The goal of this work was to investigate the in-core performance of sapphire optical fiber temperature sensors and to develop clad sapphire optical fibers for in-core instrumentation. We fabricated clad sapphire optical fibers and evaluated the distributed sensing performance of these sensors via optical backscatter reflectometry under high fluence and combined radiation and temperature effects. A series of irradiations was completed to evaluate the effect of irradiation on sapphire optical fiber temperature sensors and to determine the operational limits of these sensors. (1) Objective 1: Fabricate sapphire optical fiber sensors. (2) Objective 2: Evaluate the clad sapphire fiber to verify single-mode behavior and determine and characterize the light modes supported by optical fibers. (3) Objective 3: Characterize the in-core temperature sensing of sapphire optical fiber, as well as the combined temperature and irradiation effects. (4) Objective 4: Evaluate the lifetime and performance of the sensor under irradiation to high neutron fluence. Objectives 1, 2, and 3 were completed during the first 2 years of the project. Due to the Covid pandemic, Objective 4, a high-fluence irradiation performed at the Massachusetts Institute of Technology Research Reactor (MITR), was delayed, as partner facilities were subject to mandatory shutdowns and required a 1 year, no-cost extension. This irradiation was eventually completed on December 12, 2022. This work indicates that sapphire optical fiber sensors may be a solution for ultra-high-temperature applications in which traditional silica optical fibers are prone to fail. Sapphire sensors are potentially suitable for experiments featuring temperatures above 700°C for long periods of time, or for any length of time above 1000°C. Experiments featuring a low total fluence, such as irradiations conducted in the Transient Reactor Test (TREAT) facility, also represent good applications for sapphire optical sensors. Additional work is required to characterize the sapphire fiber cladding performance, which falls outside the scope of this project, as well as the effects of high temperatures on the response of the fiber. A comprehensive material study is recommended as future work to evaluate the attenuation in sapphire under irradiation, and how that attenuation changes with irradiation temperature. The drift and attenuation in the fiber at temperatures of up to 1600°C and a total fluence of up to 2.9 x 10 17 n/cm 2 was minimal, and the fibers returned to baseline after being heated to 1600°C under irradiation. This is promising for the future use of sapphire optical fibers in advanced reactors.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Synthesis and characterization of g-C{sub 3}N{sub 4}/Cu{sub 2}O composite catalyst with enhanced photocatalytic activity under visible light irradiation

The prepared g-C{sub 3}N{sub 4}/Cu{sub 2}O composite exhibited the enhanced photocatalytic activity under visible-light irradiation due to the stronger ability in separation of electron–hole pairs, which was proven by the transient photocurrent measurement. - Highlights: • The coupled Cu{sub 2}O with g-C{sub 3}N{sub 4} of narrow-band-gap semiconductor has been designed. • g-C{sub 3}N{sub 4}/Cu{sub 2}O is prepared via an alcohol-aqueous based on chemical precipitation method. • g-C{sub 3}N{sub 4}/Cu{sub 2}O exhibits the enhanced photocatalytic activity under visible-light. • The enhanced photocatalytic activity is proven by the transient photocurrent test. • A mechanism for the visible-light-driven photocatalysis of g-C{sub 3}N{sub 4}/Cu{sub 2}O is revealed. - Abstract: To overcome the drawback of low photocatalytic efficiency brought by electron–hole pairs recombination and narrow photo-response range, a novel g-C{sub 3}N{sub 4}/Cu{sub 2}O composite photocatalyst was designed and prepared successfully. Compared with bare Cu{sub 2}O and g-C{sub 3}N{sub 4}, the g-C{sub 3}N{sub 4}/Cu{sub 2}O composite exhibited significantly enhanced photocatalytic activity for acid orange-II (AO-II) degradation under visible light irradiation. Based on energy band positions, the mechanism of enhanced visible-light photocatalytic activity was proposed.

36 MATERIALS SCIENCE↗

ATRC Neutron Detector Testing Quick Look Report

As part of the Advanced Test Reactor (ATR) National Scientific User Facility (NSUF) program, a joint Idaho State University (ISU) / French Alternative Energies and Atomic Energy Commission (CEA) / Idaho National Laboratory (INL) project was initiated in FY-10 to investigate the feasibility of using neutron sensors to provide online measurements of the neutron flux and fission reaction rate in the ATR Critical Facility (ATRC). A second objective was to provide initial neutron spectrum and flux distribution information for physics modeling and code validation using neutron activation based techniques in ATRC as well as ATR during depressurized operations. Detailed activation spectrometry measurements were made in the flux traps and in selected fuel elements, along with standard fission rate distribution measurements at selected core locations. These measurements provide additional calibration data for the real-time sensors of interest as well as provide benchmark neutronics data that will be useful for the ATR Life Extension Program (LEP) Computational Methods and V&V Upgrade project. As part of this effort, techniques developed by Prof. George Imel will be applied by Idaho State University (ISU) for assessing the performance of various flux detectors to develop detailed procedures for initial and follow-on calibrations of these sensors. In addition to comparing data obtained from each type of detector, calculations will be performed to assess the performance of and reduce uncertainties in flux detection sensors and compare data obtained from these sensors with existing integral methods employed at the ATRC. The neutron detectors required for this project were provided to team participants at no cost. Activation detectors (foils and wires) from an existing, well-characterized INL inventory were employed. Furthermore, as part of an on-going ATR NSUF international cooperation, the CEA sent INL three miniature fission chambers (one for detecting fast flux and two for detecting thermal flux) with associated electronics for assessment. In addition, Prof. Imel, ISU, has access to an inventory of Self-Powered Neutron Detectors (SPNDs) with a range of response times as well as Back-to-Back (BTB) fission chambers from prior research he conducted at the Transient REActor Test Facility (TREAT) facility and Neutron RADiography (NRAD) reactors. Finally, SPNDs from the National Atomic Energy Commission of Argentina (CNEA) were provided in connection with the INL effort to upgrade ATR computational methods and V&V protocols that are underway as part of the ATR LEP. Work during fiscal year 2010 (FY10) focussed on design and construction of Experiment Guide Tubes (EGTs) for positioning the flux detectors in the ATRC N-16 locations as well as obtaining ATRC staff concurrence for the detector evaluations. Initial evaluations with CEA researchers were also started in FY10 but were cut short due to reactor reliability issues. Reactor availability issues caused experimental work to be delayed during FY11/12. In FY13, work resumed; and evaluations were completed. The objective of this "Quick Look" report is to summarize experimental activities performed from April 4, 2013 through May 16, 2013.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Parametric Study of the Adjoint Flux Calculation for TDKENO

TDKENO is a time-dependent transport code designed to simulate reactor transients. One application is to study experiments performed at the Transient Reactor Test Facility (TREAT) at the Idaho National Laboratory (INL). TDKENO solves the time-dependent, three-dimensional Boltzmann transport equation with explicit representation of delayed neutrons. Instead of directly integrating this equation, the Improved Quasi Static (IQS) method is employed. This involves factoring the neutron flux into two components - a rapidly varying (in time) amplitude equation and a slowly varying shape equation. These are solved separately on different time scales. The shape equation is solved using the Monte Carlo transport code KENO, from Oak Ridge National Laboratory's SCALE code package. Using the Monte Carlo method to solve the shape equation is computationally intensive, but the operation is only performed when needed - namely when the reactor system is undergoing a significant change. The amplitude equation is solved deterministically. This operation contains the time dependence and can be calculated relatively quickly, resulting in computational savings. TDKENO begins by solving the adjoint form of the transport equation for use as a weighting function. It uses this adjoint flux for multiple aspects of the simulation, including the calculation of all of the point kinetics parameters . The flux shape is found by solving a modified form of the transport equation in 'forward' mode. This paper examines the effect the adjoint weighting function has on the solution. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Fuel – clad chemical interaction evaluation of the TREAT reactor conceptual low-enriched-uranium fuel element

The Transient Reactor Test (TREAT) facility resides at the Materials and Fuels Complex (MFC) at Idaho National Laboratory (INL). The TREAT reactor is currently undergoing design and engineering studies for its conversion from a high enriched uranium (HEU) to a low-enriched uranium (LEU) core. The conceptual design of the LEU fuel element identified two main design differences compared with the HEU fuel element; namely, it will contain four times more fissionable material in its graphite matrix and distinct nuclear-grade Zirconium alloy, as Zircaloy-3 was used in the HEU fuel assembly and is not commercially available currently. These design changes may impact the magnitude of chemical interaction between fuel and cladding materials during physical contact under expected TREAT operation conditions and, therefore, was evaluated through a combination of experimental testing and thermodynamic modeling in order to determine implications for the fuel assembly. In this study, two potential cladding material types, Zircaloy-4 or Zr-1Nb alloys, were evaluated, and it was found for both material types that the extent of interaction and specific chemical reactions are minimal and no detrimental effect on the overall cladding properties is observed. Here, the resulting interaction layer of 3-6 µm was measured after a 2-week exposure at 820°C. The thermodynamic analysis was extended to temperatures beyond the TREAT reactor operation and accident conditions in order to give some insight that may be of interest for other reactor systems as the High Temperature Gas Reactors (operation above 1,000°C) and for Nuclear Reactor Severe Accident phenomenology study where the UO 2 fuel could reach temperatures over 2,800°C and melt.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Experimental results of conductive inserts to reduce nuclear fuel temperature during nuclear volumetric heating

Advanced fuel designs that incorporate thinner fuel UO2 pellets interspaced by high thermal conductivity inserts have been proposed, with the primary goals of reducing peak centerline temperatures and temperature gradients across fuel pellets and enhancing heat transfer from the fuel to the coolant. An initial series of experiments has been performed on this design, including laboratory experiments and a series of experiments using the Idaho National Laboratory (INL) Transient Reactor Test (TREAT) Facility, the latter of which compared thermal gradient driven fracture of standard pellet designs with that in the proposed advanced fuel design. Although reducing fracture is not the primary objective of the new fuel design, the lower thermal gradients are expected to reduce fracture, so it can serve as an indicator of the thermal behavior of this fuel in the reactor. The in-reactor tests were conducted at multiple linear heat generation rates and confirm the expected result that fracture in both the standard and advanced fuel pellets occurs during the first ramp to power in standard light-water reactor conditions. Post-irradiation examination of the experiment material was performed and included quantification of the extent of fracture in the fuel pellets. It was found that the advanced-design pellets reduce the extent of fracture in a statistically significant way. This confirms the expected behavior predicted by two-dimensional axisymmetric models of this experiment. Here in this study is an important first experimental confirmation of the efficacy of the proposed inserts for achieving their desired effect on the thermal behavior of the fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Geant4 evaluation of the Hornyak button and two candidate detectors for the TREAT hodoscope

The performance of traditional Hornyak buttons and two proposed variants for fast-neutron hodoscope applications was evaluated using Geant4. The Hornyak button is a ZnS(Ag)-based device previously deployed at the Idaho National Laboratory's TRansient REActor Test Facility (better known as TREAT) for monitoring fast neutrons emitted during pulsing of fissile fuel samples. Past use of these devices relied on pulse-shape discrimination to reduce the significant levels of background Cherenkov radiation. Proposed are two simple designs that reduce the overall light guide mass (here, polymethyl methacrylate or PMMA), employ silicon photomultipliers (SiPMs), and can be operated using pulse-height discrimination alone to eliminate background noise to acceptable levels. Geant4 was first used to model a traditional Hornyak button, and for assumed, hodoscope-like conditions, an intrinsic efficiency of 0.35% for mono-directional fission neutrons was predicted. The predicted efficiency is in reasonably good agreement with experimental data from the literature and, hence, served to validate the physics models and approximations employed. Geant4 models were then developed to optimize the materials and geometries of two alternatives to the Hornyak button, one based on a homogeneous mixture of ZnS(Ag) and PMMA, and one based on alternating layers of ZnS(Ag) and PMMA oriented perpendicular to the incident neutron beam. For the same radiation environment, optimized, 5-cm long (along the beam path) devices of the homogeneous and layered designs were predicted to have efficiencies of approximately 1.3% and 3.3%, respectively. For longer devices, i.e., lengths larger than 25 cm, these efficiencies were shown to peak at approximately 2.2% and 5.9%, respectively. Furthermore, both designs were shown to discriminate Cherenkov noise intrinsically by using an appropriate pulse-height discriminator level, i.e., pulse-shape discrimination is not needed for these devices.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗