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At least 379 records · Page 21

A study of the Sabatier-methanation reaction kinetics

The kinetics of the Sabatier methanation reaction, the reduction of carbon dioxide with hydrogen to methane and water, was investigated for 58 percent nickel on kieselguhr catalyst and 20 percent ruthenium on alumina catalyst. Differential rate data from an experimental program were correlated with a power function rate equation both for forward and reverse reactions. The kinetic parameters of activation energy, frequency rate constant and reaction order were determined for the rate equation. The values of these parameters were obtained from an Arrhenius plot of the experimental differential rate data. Also the carbon monoxide side reaction effect was measured and included in the correlation of parameters. The reaction was found to fit the rate equation experimentally within the temperature range 421 K, where the reaction effectively begins, the 800 K where the reaction rate drops and departs from the rate equation form.

Verostko, C. E.↗

Some recent applications of the suction analogy to asymmetric flow situations

A recent extension of the suction analogy for the estimation of vortex loads on asymmetric configurations was reviewed. This includes the asymmetric augmented vortex lift and the forward sweep effect on side edge suction. Application of this extension to a series of skewed wings has resulted in an improved estimating capability for a wide range of asymmetric flow situations. Hence, the suction analogy concept now has more general applicability for subsonic lifting surface analysis.

Luckring, J. M.↗

An application of the suction analog for the analysis of asymmetric flow situations

A recent extension of the suction analogy for estimation of vortex loads on asymmetric configurations is reviewed. This extension includes asymmetric augmented vortex lift and the forward sweep effect on side edge suction. Application of this extension to a series of skewed wings has resulted in an improved estimating capability for a wide range of asymmetric flow situations. Hence, the suction analogy concept now has more general applicability for subsonic lifting surface analysis.

Luckring, J. M.↗

Prediction of the vortex wake for noncircular missiles in supersonic flow

Engineering prediction methods with the capability to calculate induced effects of lee-side separation vorticity associated with circular and noncircular missiles at high angles of attack in supersonic flow are compared. Methods of interest include a discrete vortex cloud technique, concentrated vortex models, and solutions of Euler's equations with specified separation. Comparison of measured and predicted surface pressure distributions and flow field surveys are presented for bodies with circular and elliptic cross sections. Two flow models for computing lee-side vortex-induced effects on control fins in the vicinity of the vortex field are examined, and suggestions regarding the appropriate flow model for specific situations are included.

Mendenhall, M. R.↗

Cooling on the Front of an Air-cooled Engine Cylinder in a Conventional Engine Cowling

Measurements were made of the cooling on the fronts of model cylinders in a conventional cowling for cooling in both the ground and the cruising conditions. The mechanisms of front and rear cooling are essentially different. Cooling on the rear baffled part of the cylinders continually increases with increasing fin width. For the front of the cylinder, an optimum fin width was found to exist beyond which an increase in width reduced the heat transfer. The heat transfer coefficient on the front of the cylinders was larger on the side of the cylinder facing the propeller swirl than on the opposite side. This effect became more pronounced as the fin width was increased. These results are introductory to the study of front cooling and show the general effect of several test parameters.

Brevoort, M J↗

Low-Speed Aerodynamic Characteristics of a Model of a Hypersonic Research Airplane at Angles of Attack up to 90 deg for a Range of Reynolds Numbers

Static force tests have been made at low subsonic speeds for a model of a hypersonic research airplane in the Langley high-speed 7- by 10-foot tunnel to determine the aerodynamic forces and moments up to an angle of attack of 90 deg for a range of Reynolds numbers. The Reynolds numbers, based on the mean aerodynamic chord, ranged from 740,000 to 1,900,000, which correspond to dynamic pressures from 15 to 100 lb/sq ft (Mach numbers from 0.10 to 0.27). The model was tested in the clean configuration with various horizontal-tail settings, horizontal tail off, lower rudder off, fuselage alone, and with various size strakes and slats on the nose of the model. Representative results of the present investigation are presented in plotted form, and a tabulation of all the data obtained is presented in a table. Appreciable effects on side force, yawing moment, and pitching moment are indicated by changes in Reynolds number for angles of attack of 40 to 90 deg.

Bowman, James S., Jr.↗

Apparatus for Measuring Total Emissivity of Small, Low-Emissivity Samples

An apparatus was developed for measuring total emissivity of small, lightweight, low-emissivity samples at low temperatures. The entire apparatus fits inside a small laboratory cryostat. Sample installation and removal are relatively quick, allowing for faster testing. The small chamber surrounding the sample is lined with black-painted aluminum honeycomb, which simplifies data analysis. This results in the sample viewing a very high-emissivity surface on all sides, an effect which would normally require a much larger chamber volume. The sample and chamber temperatures are individually controlled using off-the-shelf PID (proportional integral derivative) controllers, allowing flexibility in the test conditions. The chamber can be controlled at a higher temperature than the sample, allowing a direct absorptivity measurement. The lightweight sample is suspended by its heater and thermometer leads from an isothermal bar external to the chamber. The wires run out of the chamber through small holes in its corners, and the wires do not contact the chamber itself. During a steady-state measurement, the thermometer and bar are individually controlled at the same temperature, so there is zero heat flow through the wires. Thus, all of sample-temperature-control heater power is radiated to the chamber. Double-aluminized Kapton (DAK) emissivity was studied down to 10 K, which was about 25 K colder than any previously reported measurements. This verified a minimum in the emissivity at about 35 K and a rise as the temperature dropped to lower values.

Tuttle, James↗

Scale–Resolving Simulations of a Fundamental Trailing–Edge Cooling Slot Using a Discontinuous–Galerkin Spectral–Element Method

The accurate prediction of turbulent mixing in high-pressure turbines that incorporate various airfoil surface-cooling strategies is becoming increasing critical to the design of modern gas turbine engines where the quest for improved efficiency is driving compressor overall pressure ratios and turbine inlet temperatures to much higher levels than ever before. In the present paper, a recently developed computational capability for accurate and efficient scale–resolving simulations of turbomachinery is extended to study the turbulent mixing mechanism of a simplified abstraction of an airfoil trailing-edge cooling slot - a plane wall jet with finite lip thickness discharging into an ambient flow. The computational capability is based on an entropy– stable, discontinuous–Galerkin approach that extends to arbitrarily high orders of spatial and temporal accuracy. The numerical results show that the present simulations capture the trends observed in the experiments. Discrepancies between the simulations and experiments are believed to be due to differences in the inflow profiles and tunnel side–wall effects. The thick lip configuration leads to a thicker wake and higher unsteadiness in the wall jet compared to the thin lip. A detailed comparison of the turbulent flowfields is presented to highlight differences arising due to lip thickness variations.

Scale Resolving↗

Side-Chain and Ring-Size Effects on Permeability in Artificial Water Channels

Artificial water channels (AWCs) have emerged as a promising framework for stable water permeation, with water transport rates comparable to aquaporins (3.4–40.3 × 10 8 H 2 O/channel/s). In this study, we probe the influence of ring-size and side-chain length on the water permeability observed within a class of AWCs termed ligand-appended pillar[n]arenes (LAPs) that have an adjustable ring-size (m) and side-chain length (n). Through all-atom molecular dynamics simulations, we calculate the permeability of these channels using the collective diffusion model and find their permeabilities. We characterize the mechanistic influence of pillar[n]arene ring-size and side-chain length on the channel water permeability by analyzing the characteristics of the internal permeating water-wire and the surrounding channel structure. We observe that water permeability decreases as a function of increasing ring-size due to increases in hydrophilic contacts between the permeating water-wire and the oxygen groups on the channel wall. Further, we observe an increase in water permeability as a function of side-chain length due to increased partitioning of the channel terminal groups into the hydrophilic blocks of the surrounding bilayer. For the LAP6 channel, with increase in side-chain length, the distance between terminal groups increases and leads to an increase in pore size, thereby enhancing water permeability. In the case of LAP5, as side-chain length increases, the channel displays a compensatory effect between tilt and bend angle due to the flexible side-chains. Such flexibility leads to higher terminal group partitioning in the hydrophilic blocks of the bilayer and extends the permeating water-wire. Furthermore, this increase in water-wire length and hydrophilic block access overcomes the nonmonotonic pore size trend in pillar[5]arene channels.

36 MATERIALS SCIENCE↗

Understanding soil organic carbon dynamics at larger scales

This chapter focuses on the effects of biotic and abiotic factors controlling soil organic carbon dynamics at continental to global scales. On the side of natural effects, it highlights processes that can control carbon inputs, turnover and stabilization in soils. On the side of anthropogenic effects, the chapter focuses on the role of climate change as well as historic and modern land conversion. The chapter also divides anthropogenic effects into direct and indirect disturbances done by humans. Both overarching sections close with a short synthesis.

Doetterl, Sebastian↗

Thin-Film Fracture Behavior for Diketopyrrolopyrrole Semiconducting Polymeric Films

Fracture energy, which quantifies a material’s resistance to the propagation of a pre-existing crack, is a key parameter for ensuring the mechanical reliability of stretchable organic electronic devices. However, most existing methods, such as a four-point bending fracture energy, utilized for measuring the fracture energy of semiconducting polymeric thin films are complicated by substrate effects, making it challenging to isolate the intrinsic behavior of the film from interfacial influences. In this study, we employed a pseudo free-standing pure shear method to systematically investigate the cohesive fracture energy of poly(diketopyrrolopyrrole-terthiophene) P(DPP-T)-based thin films to examine the effects of nanoconfinement, side chain length, degree of crystallinity, and strain rates. This method effectively eliminates substrate interference, enabling a direct assessment of the cohesive fracture energy of P(DPP-T) thin films. We found that thinner films and those with lower molecular weights exhibited significantly reduced fracture energies due to diminished chain entanglements. Additionally, films with shorter side chains displayed notably higher fracture energies, which were attributed to an increase in the degree of crystallinity. Finally, slower strain rates led to higher fracture energies, consistent with an enhanced stress relaxation. These insights offer practical guidelines for designing mechanically robust semiconducting polymers, contributing to the advancement of reliable, durable, flexible, and wearable electronic devices.

Zhang, Song [Univ. of Southern Mississippi, Hattie↗

Study of the Effect of a Closed-End Side Branch on Sinusoidally Perturbed Flow of Liquid in a Line

Classical undamped acoustic-wave theory was used to determine analytical relations among sinusoidal perturbations of pressure and flow at the ends of a hydraulic-transmission line having a closed-end branch of arbitrary length attached at an arbitrary point. Experimental data were obtained for the equilateral case (a branch half as long as the main line connected to the main line at the midpoint) at mean flow speeds of 5 to 10 feet per second. Measured pressure-perturbation ratios agreed closely with analytical predictions. As frequencies for which the branch length was an odd multiple of 1/4 wavelength, waves in the main line were almost completely reflected at the junction point.

TRANSMISSION LINE↗

Mineralized sclerites in the gorgonian coral Leptogorgia chilensis as a natural jamming system

The soft corals (Cnidaria, Octocorallia), a diverse group of colonial marine invertebrates, can reversibly tune their body stiffness in response to external stimuli. This capability is attributed to their dynamic skeletal systems, which consist of thousands of mineralized skeletal elements, called sclerites, embedded within a gel-like matrix that swells/deswells and unjams/jams the sclerites, thus modulating skeletal stiffness. While sclerite morphology is widely used for species identification, its role in the mechanical performance of a soft coral’s skeletal system is largely unknown. Here, we investigated structure-jamming relationships in sclerite-based skeletal architectures using the red gorgonian octocoral Leptogorgia chilensis as a model system. The sclerites of L. chilensis exhibit a shaft-like geometry with two axial branches and two sets of triradiate side branches, which are aligned with the crystallographic symmetry of the constituent magnesium-containing calcite. By combining multiscale three-dimensional (3D) structural characterization, parametric geometrical modeling, 3D printing, mechanical testing, and discrete element simulations, we demonstrate how sclerite geometry achieves a balanced jamming performance in terms of stiffness, weight, strength, and fracture resistance in comparison to alternative geometries parametrically modified from the native sclerites (e.g., changes in the length and number of side branches). Here, we also found that these performance metrics are achieved through the effective interlocking among side and axial branches, which is further enhanced by the fractal-like microscopic spikes on the branch tips. The findings in this natural jamming system offer insights for designing synthetic mechanotunable material architectures for a wide range of applications, from soft robotics to mechanical dampeners.

36 MATERIALS SCIENCE↗

A piloted simulator investigation of side-stick controller/stability and control augmentation system requirements for helicopter visual flight tasks

A piloted simulator experiment was conducted to assess the effects of side-stick controller characteristics and level of stability and control augmentation on handling qualities for several low-altitude control tasks. Visual flight tasks were simulated using four-window computer-generated imagery depicting either a nap-of-the-earth course or a runway with obstacles positioned to provide a slalom course. Both low speed and forward flight control laws were implemented, and a method for automatically switching control modes was developed. Variations in force-deflection characteristics and the number of axes controlled through an integrated side-stick were investigated. With high levels of stability and control augmentation, a four-axis controller with small-deflection in all four axes achieved satisfactory handling qualities for low-speed tasks.

Landis, K. H.↗