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NNSA-IAEC Science and Technology Working Group Area V - Waste Management and Subsurface Science, (Q1 FY2021)

The objective of Topic Area V is to evaluate the feasibility and safety of an intermediate-depth borehole for disposal of IAEC nuclear waste. The IAEC nuclear waste is currently stored in above ground and/or in near-surface facilities that provide short-term radiological worker safety but do not provide long-term, full security and safeguards protection for the nuclear material. Disposal of the IAEC nuclear waste several hundred meters below the surface in a sealed borehole would provide long-term security and safeguards due to its depth underground, as well as long-term radiological safety, due to its isolation in a stable geological formation.

54 ENVIRONMENTAL SCIENCES↗

HPAC Validation against NRC Documentation

This report describes validation of the radiological source terms in the Nuclear Facility Accident (NFAC) module of the Defense Threat Reduction Agency (DTRA)’s Hazard Prediction and Assessment Capability (HPAC) software. The validation will be conducted by comparing the source terms defined in HPAC to published data from references approved by the U. S. Nuclear Regulatory Commission (NRC). Comparisons will be done for both pressurized water reactors (PWRs) and boiling water reactors (BWRs). This comparison includes the magnitude, isotopic composition, and timing of the release fractions over the course of a severe or moderate accident. Calculations for both facility-specific nuclear power plants and for more generic reactor categories are involved. It is shown that the NFAC radiological source terms in HPAC agree well with NRC standards for moderate and severe accidents at PWRs and BWRs.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

TCR Postulated Accident and MHA Dose Assessment

Oak Ridge National Laboratory (ORNL) is engaged in regulatory activities to gain US Department of Energy (DOE) approval to build and operate a small high-temperature gas reactor, the Transformational Challenge Reactor (TCR). ORNL uses advanced manufacturing techniques to produce select reactor components. The TCR is unique in its mission: the reactor’s at-power operating lifetime will be less than one effective full-power day to limit the radiological source term to very low values, thus facilitating approval to operate. The primary regulatory documents governing construction and operation of the facility are NUREG-1537, “Guidelines for Preparing and Reviewing Applications for the Licensing of Non-Power Reactors” and DOE-STD-3009, “Preparation of Nonreactor Nuclear Facility Documented Safety Analysis.” Although this document is not a safety basis document, it provides a conservative indication of the magnitude of onsite and offsite radiological doses for specific scenarios, thus informing future design and regulatory activities. As required by NUREG-1537, scenarios included in this analysis are (1) a worstcase depressurized loss-of-forced-circulation accident, and (2) a maximum hypothetical accident. Details on the analysis of dose consequences with various system configurations are also provided.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Dosimeter Area Monitoring Program (DAMP) Technical Basis Document

This document provides a technical basis for establishing a Dosimetry-based Area Monitoring Program (DAMP) at Lawrence Livermore National Laboratory (LLNL). A DAMP is part of a comprehensive routine monitoring program and provides information about radiation levels inside and outside of Radiologically-Controlled Areas (RCAs). The routine, hand-held radiation survey program driven by the Health Physics Discipline Action Plan (HP-DAP) helps to ensure radiological conditions within RCAs are well-characterized and routinely monitored; however, such surveys are a snapshot in time, whereas area monitoring dosimeters (AMDs) continuously monitor radiation doses in the areas where they are installed. Together, data from the hand-held radiation surveys and the DAMP provides a comprehensive picture of radiation environment at LLNL. A DAMP helps to verify the effectiveness of established engineered and administrative controls while documenting that radiation doses in RCAs are below that which requires individual monitoring. This document establishes the basis for determining which model of dosimeter to use, the exchange frequency, the occupancy factor, monitoring locations, and a method for evaluating AMD results.

61 RADIATION PROTECTION AND DOSIMETRY↗

Comparative Assessment of Data-driven Process Models in Health Information Technology

Process mining for conformance analysis consists of comparing a reference process model against a data-driven process model generated via log files from information technology systems. However, in the absence of a complete reference process model, we found no suggested approaches in the literature to address the need for evaluating process conformance among different healthcare facilities to assess standardization of care. Our goal is to find similarities and dissimilarities in data-driven process models among US Veterans Health Administration (VHA) facilities that can be indicative of patient safety issues. Our hypothesis was that the analysis would not produce statistically significant differences in outcome. We present a unique implementation of conformance analysis in process mining that consists of combining process mining, process mapping and statistical metrics. We illustrate our approach by applying it to the analysis of two clinical radiology order process models generated from healthcare data provided by two similar facilities in the VHA. The comparative assessment showed that about 70% of the orders completed successfully and 30% were not completed due to policy and duplications. Our analysis found a good statistical correlation between both facilities, as the Spearman’s correlation coefficient between facilities for the frequency of cases per total hours was 0.87879, for the frequency of cases by state transition was 0.79702 and for the throughput time per state transition was 0.63582. Additional statistical analyses using the Mann-Whitney U test and the root mean square error both produced values that were not significant. The foregoing approach validated our hypothesis by demonstrating a good statistical correlation of data describing the flow of clinical radiology orders absent a credible reference model. Finding good agreement between both facilities was important in confirming that the clinical orders flow in a similar manner, suggesting standardization of care.

97 MATHEMATICS AND COMPUTING↗

Application of Shift Ex-Core Calculations to a Detailed MSR Model

This report documents the collaborative research conducted between Argonne National Laboratory (ANL) and Oak Ridge National Laboratory (ORNL) on applying the Monte Carlo neutronics code Shift to calculate the radiation dose rates for a detailed molten salt reactor (MSR) model based on the Molten Salt Breeder Reactor (MSBR). In this work scope, the ANL and ORNL teams worked together and applied Shift to calculate the radiological environments of this detailed MSR facility modeled with explicit geometries. The radiological conditions within the MSR facility were modeled for when the reactor is at two different operation modes: normal full power and drained state. The FW-CADIS hybrid method in Shift was applied successfully to calculate the ex-core neutron and gamma dose rates for the MSBR at full power. Dose rate maps showed that in the current MSBR numerical model, potential pathways exist for neutrons and gammas to stream through the 8-foot concrete shield to reach the top of the MSBR reactor cell. Neutron and gamma dose rates within the drain cell were also calculated for the MSBR at the drained state by integrating the source terms obtained from an ORIGEN-S depletion calculation into the Shift simulation. The results indicate that in the drained state, the delayed gammas from the depleted fuel salt are the main contributors to the dose rates, which suggests that a steel liner in the tank model must be added for calculating the dose rates in the drain cell.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

LANL MLU TRUPACT Loading Survey Document

The following SNL document contains requested radiological survey information, as part of the documentation for the MLU shipment being performed by the LANL MLU team. The survey was performed in TA-5, on October 19th, 2021. This survey was for radiological coverage for the disassembly of two TRUPACTs, the assembly and loading of their payloads, and the reassembly of the TRUPACTs.

61 RADIATION PROTECTION AND DOSIMETRY↗

LANL MLU 20 October TRUPACT Loading Survey Document

This SNL document contains requested radiological survey information, as part of the documentation for the MLU shipment performed by the LANL MLU team on October 20th. The survey was performed in TA-5, on October 20th, 2021. This survey was for radiological coverage for the disassembly of two TRUPACTs, the assembly and loading of their payloads, and the reassembly of the TRUPACTs.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Nuclear Emergency Support Team Public Health and Safety [Slides]

RAP is the nation’s premier first-response resource for advising Federal, state, local and tribal decision-makers on steps to take to evaluate and minimize the hazards of a radiological or nuclear incident. RAP support ranges from giving technical information or advice over the telephone to sending highly trained personnel with state-of-the-art equipment to the incident site where team members help identify, characterize and minimize any radiological or nuclear hazards.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Hanford Site Composite Analysis Data Package: Exposure Scenarios and Radionuclide Specific Dose Conversion Factors.

This data package summarizes the exposure assumptions, equations, and methods used to calculate radionuclide-specific unit dose factors and the radiological doses for both groundwater and atmospheric pathways as a part of the revised Hanford Site Composite Analysis. An All-Pathways Representative Person exposure scenario is considered to evaluate exposure via both groundwater and atmospheric transport pathways. The radiological dose assessments for both groundwater and atmospheric pathways are included in the performance assessments for various Waste Management Areas at the Hanford Site. This data package calculates exposure route-specific and total unit dose factors for composite-analysis-specific radionuclides of concern based on the exposure assumptions used in the composite analysis and performance assessments. This data package presents the results and comparison of the radionuclide-specific unit dose factors based on the exposure assumptions used in the revised composite analysis and various performance assessments.

61 RADIATION PROTECTION AND DOSIMETRY↗

International Radiological/Nuclear Training for Emergency Response - Major Public Events Virtual Workshop: Radiation Detection and Emergency Response Equipment (Day 2) [Slides]

The objective of this presentation is to familiarize participants with the different types of radiation detection systems and their practical applications for radiological emergency response. The specific goals are for participants to: (1) Understand the Three Step Process for Radiological Response of (i) Search and/or Survey, (ii) Radioisotope Identification, and (iii) Source Recovery, (2) Recognize the types of radiation detection equipment and their applications, and (3) View examples of common radiation detection instrumentation with operational videos.

61 RADIATION PROTECTION AND DOSIMETRY↗

Naval Reactors Facility Environmental Monitoring Report (CY2020)

This report presents the results of the radiological and non-radiological environmental monitoring programs for 2020 at the Naval Reactors Facility (NRF). Current operations at NRF are in compliance with applicable regulations governing use, emission, and disposal of solid, liquid, and gaseous materials. The results obtained from the environmental monitoring programs verify that releases to the environment from operations at NRF did not have any adverse effect on human health or the environment. Evaluation of the environmental data confirms that the operation of NRF continues to have no adverse effect on the environment or the health and safety of the general public. Furthermore, a conservative assessment of radiation exposure to the general public as a result of NRF operations demonstrated that the maximum potential dose received by any member of the public was well below the most restrictive dose limits prescribed by the US Environmental Protection Agency (EPA), the US Department of Energy (DOE), and the Nuclear Regulatory Commission.

54 ENVIRONMENTAL SCIENCES↗

Naval Reactors Facility Environmental Monitoring Report (CY2019)

This report presents the results of the radiological and non-radiological environmental monitoring programs for 2019 at the Naval Reactors Facility (NRF). Current operations at NRF are in compliance with applicable regulations governing use, emission, and disposal of solid, liquid, and gaseous materials. The results obtained from the environmental monitoring programs verify that releases to the environment from operations at NRF did not have any adverse effect on human health or the environment. Evaluation of the environmental data confirms that the operation of NRF continues to have no adverse effect on the environment or the health and safety of the general public. Furthermore, a conservative assessment of radiation exposure to the general public as a result of NRF operations demonstrated that the maximum potential dose received by any member of the public was well below the most restrictive dose limits prescribed by the US Department of Energy (DOE) and the Nuclear Regulatory Commission.

54 ENVIRONMENTAL SCIENCES↗

Traditional Forensic Examinations on Bulk Special Nuclear Material

The Federal Bureau of Investigation (FBI) Laboratory at Quantico, Virginia is responsible for the forensic examination of radiological evidence and evidence contaminated with radioactive materials. Due to these unique hazards and the necessary specialized safety protocols, the FBI has developed a network of Partner Laboratories (PLs) across the United States of America to support conventional forensic examinations of radiological evidence and evidence contaminated with radioactive materials. In support of this, the FBI Laboratory has established the Hazardous Evidence Analysis Team (HEAT), a group of qualified forensic examiners, scientists, technicians, and photographers who can deploy to laboratories outside of the FBI Laboratory at Quantico, VA to perform conventional forensics on evidence containing/contaminated with hazardous materials. One of the FBI’s PLs, the United States Department of Energy’s Los Alamos National Laboratory (LANL), in Los Alamos, New Mexico, has unique facilities, personnel, and procedures to secure, safely handle, and process significant quantities of special nuclear material (SNM). While LANL’s procedures for working with SNM are well established, working with SNM under evidentiary controls is not. Close cooperation between LANL and FBI HEAT is required due to FBI policies on evidence handling, as well as the challenges associated with the exploitation and preservation of conventional forensics (fingerprints, trace evidence, and photography) on SNM evidence.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Microfluidic Uranium Microspheres Production for TRISO and Advanced Fuel Concepts

The purpose of this project was to expand existing internal gelation sol-gel capabilities at PNNL to explore producing uranium dioxide spheres for potential use as fuel kernels in next generation Tri-isotropic (TRISO) particle fuel. This project expands on previous sol-gel efforts at PNNL by (1) increasing the size regime of sphere production from the micro-fluidic range to the milli-fluidic range, and (2) producing uranium spheres. The approach involved first scaling up the channel size of the fluidic system to the millimeter range, with radiation safety considerations in mind; testing and demonstration on non-radioactive surrogate material, cerium oxide; then transitioning to uranium production and finally optimizing system parameters. Commercially available fluidic chips in the desired size range were could not be found, therefore the project designed and fabricated a T-junction with 1mm channels for droplet production. Because the production process is temperature sensitive, prior efforts have involved performing droplet production in a lab freezer. To reduce radiological waste and footprint, two alternative chilling methods were explored using aluminum thermal beads as a chill bath and a custom aluminum block fit to reagent reservoir sizes. Both were successful in the cerium tests, however the aluminum block design outperformed the thermal bead bath and was further adapted for the radiological test and production run in the Radiochemical Processing Laboratory (RPL). Gelation trials were performed to determine an acceptable range of feed solution parameters for the uranium dioxide gels, characterized by R-values, which is determined by the ratio of uranium nitrate to Hexamethylenetetramine (HMTA)/urea in the feed solution. R-values ranging from 1.6-2 were examined in the gelation trials, with only the 1.8 condition being tested in production. The project was successful in demonstrating a proof of concept design for producing uranium dioxide spheres, however further optimization is needed to dial in production parameters and improve sphere quality and homogeneity.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Radon Survey of Los Alamos National Laboratory Buildings and Los Alamos County Residential Buildings

A radon survey of office spaces was of interest to LANL for several reasons. First, exposure to natural radon in LANL office spaces has been considered to be outside the regulatory reach of the federal regulations and the U.S. Department of Energy (U.S. DOE) orders, and thus has not been studied as extensively as occupational exposure to other radionuclides and is not subject to the same rigorous radiological controls. Second, a general survey of radon concentrations in LANL workspaces was of interest to management to ensure safe environments for workers and is in keeping with the intent of OSHA requirements. Though radon in LANL offices would not be derived from enhanced radioactive sources, radon exposure in general office spaces has the potential to significantly impact worker risk. The purpose of the 2009 radon survey was to measure and document indoor radon levels across a broad spectrum of office-type workspaces and neighboring homes. The measured concentrations were compared against those measured across the United States and across the world. The results were also compared against a wide variety of radiation protection thresholds such as (1) the action levels of 148 Bq m -3 (the U.S. EPA action level for public housing), (2) ≈1,200 Bq m -3 OSHA threshold for office spaces, (3) effective dose threshold of 1 mSv threshold for defining a radiological worker, (4) 50 mSv occupational effective dose limit, and (5) 0.1 mSv and 1 mSv limits for public exposures from the air pathway and all pathways, respectively.

07 ISOTOPE AND RADIATION SOURCES↗

Lawrence Livermore National Laboratory Environmental Report 2021

The purposes of the Lawrence Livermore National Laboratory Environmental Report 2021 are to record Lawrence Livermore National Laboratory’s (LLNL’s) compliance with environmental standards and requirements, describe LLNL’s environmental protection and remediation programs, and present the results of environmental monitoring at the two LLNL sites—the Livermore Site and Site 300. The report is prepared for the U.S. Department of Energy (DOE) by LLNL’s Environmental Functional Area. Submittal of the report satisfies requirements under DOE Order 231.1B, “Environment, Safety and Health Reporting,” and DOE Order 458.1, “Radiation Protection of the Public and Environment.” The report is distributed electronically and is available at https://saer.llnl.gov/, the website for the LLNL annual environmental report. Previous LLNL annual environmental reports beginning with 1994 are also on the website. Some references in the electronic report text are underlined, which indicates that they are clickable links. Clicking on one of these links will open the related document, data workbook, or website. Sampling location maps throughout this report were created using ArcGIS® software by Esri. The report begins with an executive summary, which provides the purpose of the report and an overview of LLNL’s compliance and monitoring results. The first three chapters provide background information: Chapter 1 is an overview of the location, meteorology, and hydrogeology of the two LLNL sites; Chapter 2 is a summary of LLNL’s compliance with environmental regulations; and Chapter 3 is a description of LLNL’s environmental programs with an emphasis on the Environmental Management System including pollution prevention. The majority of the report covers LLNL’s environmental monitoring programs and monitoring data for 2021: effluent and ambient air monitoring and dose assessment (Chapter 4); waters, including wastewater, storm water runoff, surface water, rain, and groundwater (Chapter 5); and terrestrial, including soil, sediment, vegetation, foodstuff, ambient radiation, and special status wildlife and plants (Chapter 6). The remaining two chapters discuss LLNL’s groundwater remediation program (Chapter 7), and quality assurance for the environmental monitoring programs (Chapter 8). Complete monitoring data, which are summarized in the body of the report, are provided in Appendix A. The report uses Système International units, consistent with the federal Metric Conversion Act of 1975 and Executive Order 12770, “Metric Usage in Federal Government Programs” (1991). For ease of comparison to environmental reports issued prior to 1991, dose values and many radiological measurements are given in both metric and U.S. customary units. A conversion table is provided in the glossary. The report is the responsibility of LLNL’s Environmental Functional Area. Monitoring data were obtained through the combined efforts of the Environmental Functional Area; Environmental Restoration Department; Physical and Life Sciences Environmental Monitoring Radiological Laboratory; and the Radiation Protection Functional Area.

54 ENVIRONMENTAL SCIENCES↗

TA-55 building entrusted with more plutonium capability: What does it mean for the mission?

The first floor of the Radiological Laboratory/Utility/Office Building at TA-55, known as RLUOB (roo-lob) or Plutonium Facility-400 (PF-400), will soon become a bustling and dynamic space as employees and programs increase their work scope thanks to the new hazard category 3 designation. On Feb. 7, NNSA gave the final stamp of approval designating RLUOB as a hazard category 3 (HC-3) nuclear facility. RLUOB has been designated as a radiological facility (less than HC-3) since 2013, when the first phase of RLUOB Equipment Installation was completed. HC-3 is a level up in facility hazard category, a major effort to support the national security mission.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗