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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Synthesis and Characterization of Magnesium Vanadates as Potential Magnesium‐Ion Cathode Materials through an Ab Initio Guided Carbothermal Reduction Approach**

Abstract Many technologically relevant materials for advanced energy storage and catalysis feature reduced transition‐metal (TM) oxides that are often nontrivial to prepare because of the need to control the reducing nature of the atmosphere in which they are synthesized. Herein, we show that an ab initio predictive synthesis strategy can be used to produce multi‐gram‐scale products of various MgV x O y ‐type phases (δ‐MgV 2 O 5 , spinel MgV 2 O 4 , and MgVO 3 ) containing V 3+ or V 4+ relevant for Mg‐ion battery cathodes. Characterization of these phases using 25 Mg solid‐state NMR spectroscopy illustrates the potential of 25 Mg NMR for studying reversible magnesiation and local charge distributions. Rotor‐assisted population transfer (RAPT) is used as a much‐needed signal‐to‐noise enhancement technique. The ab initio guided synthesis method is seen as a step forward towards a predictive synthesis strategy for targeting specific complex TM oxides with variable oxidation states of technological importance.

Lee, Jeongjae↗
DOE OSTI2021

Synthesis and Characterization of Magnesium Vanadates as Potential Magnesium-Ion Cathode Materials through an Ab Initio Guided Carbothermal Reduction Approach**

Many technologically relevant materials for advanced energy storage and catalysis feature reduced transition-metal (TM) oxides that are often nontrivial to prepare because of the need to control the reducing nature of the atmosphere in which they are synthesized. In this report, we show that an ab initio predictive synthesis strategy can be used to produce multi-gram-scale products of various MgV x O y -type phases (δ-MgV 2 O 5 , spinel MgV 2 O 4 , and MgVO 3 ) containing V 3+ or V 4+ relevant for Mg-ion battery cathodes. Characterization of these phases using 25 Mg solid-state NMR spectroscopy illustrates the potential of 25 Mg NMR for studying reversible magnesiation and local charge distributions. Rotor-assisted population transfer (RAPT) is used as a much-needed signal-to-noise enhancement technique. The ab initio guided synthesis method is seen as a step forward towards a predictive synthesis strategy for targeting specific complex TM oxides with variable oxidation states of technological importance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Self‐Assembly Methods Induce Different Individual‐Polymer‐Block Solvation Responses

An understanding of block-specific responses to stimuli in self-assembled copolymers is essential for the effective design of responsive materials. Here, materials formed from different post-reaction processing methods of the same ROMP block copolymer exhibit different block-specific solvent responses, as characterized in situ by fluorescence lifetime imaging microscopy (FLIM). FLIM data were acquired by tagging the polar or nonpolar block separately with a covalently incorporated viscosity-sensitive fluorescent molecular rotor to measure the changing tightness or looseness of assembly upon changes in solvent composition. Rapid precipitation from an insoluble solvent to form a film results in tighter assembly and less difference in tightness/looseness between the two blocks. Further, it interrupts individual block-solvent response behavior. Both results indicate an apparent disruption of the core–shell assembly. This model from FLIM is further supported by differential scanning calorimetry (DSC) and small-angle X-ray scattering (SAXS) data from isolated solids, which show tighter long-range interactions and more long-range order in these kinetically trapped states. Here, the experiments develop FLIM as a method for pinpointing stimuli-responsive behaviors from different processing methods to individual blocks. Together these outcomes provide a future handle for tailoring solvent-triggered assembly/disassembly behavior.

López, Pía A. [University of California, Irvine, C↗
DOE OSTI2022

Bond Length Alternation and Internal Dynamics in Model Aromatic Substituents of Lignin

In this report broadband microwave spectra were recorded over the 2-18 GHz frequency range for a series of four model aromatic components of lignin; namely, guaiacol (ortho-methoxy phenol, G), syringol (2,6-dimethoxy phenol, S), 4-methyl guaiacol (MG), and 4-vinyl guaiacol (VG), under jet-cooled conditions in the gas phase. Using a combination of 13 C isotopic data and electronic structure calculations, distortions of the phenyl ring by the substituents on the ring are identified. In all four molecules, the r C(1)-C(6) bond between the two substituted C-atoms lengthens, leading to clear bond alternation that reflects an increase in the phenyl ring resonance structure with double bonds at r C(1)-C(2) , r C(3)-C(4) and r C(5)-C(6) . Syringol, with its symmetric methoxy substituents, possesses a microwave spectrum with tunneling doublets in the a-type transitions associated with H-atom tunneling. These splittings were fit to determine a barrier to hindered rotation of the OH group of 1975 cm -1 , a value nearly 50% greater than that in phenol, due to the presence of the intramolecular OH…OCH 3 H-bonds at the two equivalent planar geometries. In 4-methyl guaiacol, methyl rotor splittings are observed and used to confirm and refine an earlier measurement of the three-fold barrier V 3 = 67 cm -1 . Finally, 4-vinyl guaiacol shows transitions due to two conformers differing in the relative orientations of the vinyl and OH groups.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

New vortex‐lift and tangential‐force models for HAWT aerodynamic load prediction

Abstract Horizontal axis wind turbines (HAWTs) experience three‐dimensional rotational and unsteady aerodynamic phenomena at the rotor blades sections. These highly unsteady three‐dimensional effects have a dramatic impact on the aerodynamic load distributions on the blades, in particular, when they occur at high angles of attack due to stall delay and dynamic stall. Unfortunately, there is no complete understanding of the flow physics yet at these unsteady 3D flow conditions, and hence, the existing published theoretical models are often incapable of modelling the impact on the turbine response realistically. The purpose of this paper is to provide an insight on the combined influence of the stall delay and dynamic stall on the blade load history of wind turbines in controlled and uncontrolled conditions. New dynamic stall vortex and nonlinear tangential force coefficient modules, which integrally take into account the three dimensional rotational effect, are also proposed in this paper. This module along with the unsteady influence of turbulent wind speed and tower shadow is implemented in a blade element momentum (BEM) model to estimate the aerodynamic loads on a rotating blade more accurately. This work presents an important step to help modelling the combined influence of the stall delay and dynamic stall on the load history of the rotating wind turbine blades which is vital to have lighter turbine blades and improved wind turbine design systems.

Elgammi, Moutaz↗
DOE OSTI2020

Assessing the blockage effect of wind turbines and wind farms using an analytical vortex model

Wind farm blockage effects are currently neglected in the prediction of wind farm energy yield, typically leading to an overestimation of the production. This work presents a novel method to assess wind farm production, while accounting for blockage effects. We apply a vortex model, based on a cylindrical wake, to assess induction effects. We present variations of the model to account for finite wake length, finite tip-speed ratios, and the proximity to the ground. The results are applied to single rotors in aligned and yawed conditions and to different wind farm layouts. We provide far-field approximations for faster estimates of the velocity field. Further, this article includes a new methodology to couple the induction model to engineering wake models, such as the ones present in the FLOw Redirection and Induction in Steady State (FLORIS). We compare the results to actuator disk simulations for various operating conditions of a single turbine and different wind farm layouts. We found that the mean relative error of the model in the induction zone is typically around 0.2% compared with actuator disk simulations. The computational time of the velocity field using the analytical vortex model is three orders of magnitude less than the one obtained with the actuator disk simulation.

17 WIND ENERGY↗
DOE OSTI2021

Numerical investigation of wind turbine wakes under high thrust coefficient

Abstract We study wind turbine wakes of rotors operating at high thrust coefficients ( C T > 24/25) using large‐eddy simulations with a rotating actuator disk model. Wind turbine wakes at high thrust coefficients are different from wakes at low thrust coefficients. Wakes behave differently at high thrust, with increased turbulence and faster recovery. Lower induction in the wake is achieved because wakes in high‐thrust conditions recover much faster than in normal operating conditions. This enhanced recovery is possible thanks to the turbulence generated in the near wake. We explore the mechanism behind this behavior and propose a simple model to reproduce it. We also propose a Gaussian fit for the wakes under high‐thrust conditions and use it use it to initialize an Ainslie type model within the FAST.Farm framework.

FAST.Farm↗
DOE OSTI2022

Expert perspectives on the wind plant of the future

Abstract Wind power technology has changed rapidly in recent years. Technology innovation, evolving power markets, and competing land and ocean uses continue to influence the design and operation of wind turbines and plants. Anticipating these trends and their impact on future facilities can inform commercial strategies and research priorities. Drawing from a recent survey of 140 of the world's foremost wind experts, we identify expectations of future wind plant design in 2035, both for onshore and offshore wind. Experts anticipate continued growth in turbine size, to 5.5 (onshore) and 17 MW (offshore), with plants located in increasingly less favorable wind and siting regimes. They expect plant sizes of 1,100 MW for fixed‐bottom and 600 MW for floating offshore wind. Experts forecast enhanced grid‐system value from wind through significant to widespread use of larger rotors, hybrid projects with batteries and hydrogen production, and more. To explain experts' perspectives on future plant design and operation, we identify five mechanisms: economies of unit, plant, and resource scale; grid‐system value economies; and production efficiencies. We characterize learning effects as a moderating influence on the strength of these mechanisms. In combination, experts predict that these design choices support levelized cost of energy reductions of 27% (onshore) and 17%–35% (floating and fixed‐bottom offshore) by 2035 compared to today, while enhancing wind energy's grid service offerings. Our findings provide a much‐needed benchmark for representing future wind technologies in power sector models and address a critical research gap by explaining the economics behind wind energy design choices.

17 WIND ENERGY↗
DOE OSTI2022

Design space exploration and decision‐making for a segmented ultralight morphing 50‐MW wind turbine

Abstract Wind turbine design encompasses many different aspects including aerodynamic, structural, electrical, and control system design. To achieve optimal plant performance, a system design approach is utilized in which the performance of the whole wind turbine is evaluated and quantified during operational scenarios with subsystem interactions. In this paper, the design for a Segmented Ultralight Morphing Rotor (SUMR) 50‐MW wind turbine is presented utilizing levelized cost of energy (LCOE) for design choices, with additional quantification of simulated performance shortcomings at the 50‐MW scale. The multi‐disciplinary design process results in a final ultra‐scale turbine configuration that outperforms other existing offshore wind farms regarding the LCOE.

Kianbakht, Sepideh↗
DOE OSTI2023

Aero‐servo‐elastic co‐optimization of large wind turbine blades with distributed aerodynamic control devices

Abstract This work introduces automated wind turbine optimization techniques based on full aero‐servo‐elastic models and investigates the potential of trailing edge flaps to reduce the levelized cost of energy (LCOE) of wind turbines. The Wind Energy with Integrated Servo‐control (WEIS) framework is improved to conduct the presented research. Novel methods for the generic implementation and tuning of trailing edge flap devices and their controller are also introduced. Primary flap and controller parameters are optimized to demonstrate potential maximum blade tip deflection reductions of 21 % . Concurrent design optimization (i.e., co‐design) of a novel segmented wind turbine blade with trailing edge flaps and its controller is then conducted to demonstrate blade cost savings of 5 % . Additionally, rotor diameter co‐design optimization is demonstrated to reduce the LCOE by 1.3 % without significant load increases to the tower. These results demonstrate the efficacy of control co‐design optimization using trailing edge flaps, and the entirety of this work provides a foundation for numerous control co‐design‐oriented studies for distributed aerodynamic control devices.

17 WIND ENERGY↗
DOE OSTI2023

Advanced wind turbine control development using field test analysis for generator overspeed mitigation

Abstract Turbulent and gusty wind conditions can cause generator overspeed peaks to exceed a threshold that then lead to wind turbine shutdowns, which then decrease the energy production of the wind turbines. We derive so‐called “gust measures” that predict when generator overspeed peaks may occur. These gust measures are then used to develop advanced controllers to mitigate generator overspeed peaks so that wind turbines can operate more robustly in difficult wind conditions without exceeding generator overspeed thresholds that would lead to turbine shutdown events. The advanced controllers are demonstrated in nonlinear aeroelastic simulations using the open‐source wind turbine simulation tool OpenFAST. To increase the realism of the simulations, they are run using field‐replicated wind conditions and a wind turbine model based on data from an experimental field campaign on a downscaled demonstrator of a novel extreme‐scale, two‐bladed, downwind rotor design.

17 WIND ENERGY↗
DOE OSTI2023

Intracycle RPM control for vertical axis wind turbines

The wind energy market is currently dominated by horizontal axis wind turbines (HAWTs); however, vertical axis wind turbines (VAWTs) are emerging as a design alternative, especially for deep-water offshore siting due to their low center of gravity, ease of access to drivetrain components, and overall simplicity. Due to the absence of a pitch mechanism in large-scale Darrieus VAWTs, stall control has often been used to manage power and loads. Introducing a pitching mechanism in H-type VAWTs has been studied, but this diminishes the mechanical simplicity advantage, and the use of a pitching mechanism in a large-scale Darrieus-type VAWT is not practical. This work examines an innovative, alternative method to control the rotor dynamics of a large-scale 5 MW VAWT to maximize power while constraining loads without introducing any new or complex mechanical elements. This control strategy is termed intracycle revolution per minute (RPM) control, where the rotational speed of the turbine is allowed to vary in an optimal fashion with the azimuthal location of blades as opposed to typical constant RPM operation. An optimization framework is formulated for an open-loop optimal control problem and solved to maximize power subject to constraints on aerodynamic design loads. Results are presented to demonstrate the benefits and the performance limits of intracycle RPM control for large-scale 5 MW Darrieus VAWTs, namely, (1) power production (quantified in terms of AEP) that can be increased subject to baseline load limits and (2) opportunities to significantly increase AEP or decrease loads via intracycle RPM control that are examined for both two-bladed and three-bladed VAWTs.

17 WIND ENERGY↗
DOE OSTI2024

Advanced multimaterial shape optimization methods as applied to advanced manufacturing of wind turbine generators

Abstract Currently, many utility‐scale wind turbine generator original equipment manufacturers are dependent on imported rare earth permanent magnets, which are susceptible to market risks from cost instability. To lower the production costs of these generators and stay competitive in the market, several small wind manufacturers are pursuing continuous improvements to both generator design and manufacturing. However, traditional design and manufacturing methods have yielded marginal improvements in wind power performance. This work presents novel methods to redesign a baseline 15‐kW wind turbine generator with reduced rare‐earth permanent magnets by leveraging cutting‐edge three‐dimensional (3D) printed polymer‐bonded permanent magnets and steel. Symmetric, asymmetric, and multimaterial‐magnet parametrization methods are introduced for shape optimization. We extend the symmetric and asymmetric methods to the back iron in the stator to further investigate the impact and opportunities for performance improvements with lesser active materials. We employ a design‐of‐experiments approach with parametric computer‐aided design for shape generation and evaluate different designs by magneto‐thermal modeling and finite‐element analysis. We use adaptive sampling technique to identify better performing designs with lesser magnet mass, higher efficiency, and lower cogging torque when compared with the baseline generator. Asymmetric pole designs resulted in a magnet mass in the range of 4.77–5.37 kg, which was 27%–35% lighter than the baseline generator, suggesting that a new design freedom exists that can be enabled by advanced manufacturing, such as 3D printing. Shaping the back iron in the stator resulted in material savings in electrical steel of up to 14.62 kg, which was 20% lighter than the baseline stator. We conducted a structural analysis to evaluate an optimized asymmetric rotor design from the point of view of mechanical integrity and air‐gap stiffness. The magnetically optimal shape profile was shown as having a positive impact on the radial stiffness, and an optimal solution was discovered to reduce the structural mass by nearly 30 kg, which was 29% lighter than the baseline.

17 WIND ENERGY↗
DOE OSTI2024

A Green's Function Wind Turbine Induction Model That Incorporates Complex Inflow Conditions

ABSTRACT In this work, we develop a new analytical turbine induction model that can incorporate complex inflow conditions including cases where the wind velocity and temperature profiles can vary as functions of height. This induction model is derived from the linearized Navier–Stokes and leads to a second‐order ODE that can be solved using a Green's function formulation. The corresponding Green's function for several configurations are found including the infinite domain, semi‐infinite domain with ground plane, and a power law velocity inflow profile. The results of this approach are then compared with simulations of the turbine induction field using the AMR‐Wind CFD solver with a uniformly loaded actuator disk model. These comparisons show that the Green's function approach captures the centerline blockage, three‐dimensional blockage flow field, and streamwise velocity slow down, with very good agreement for lower thrust conditions and at larger distances away from rotor disk. The effects of shear on the turbine blockage were also compared using a power law inflow profile, and we show that this approach matches the CFD predictions for the cases considered.

17 WIND ENERGY↗
DOE OSTI2021

Acoustic Exposure to Turbine Operation Quantifies Risk to Bats at Commercial Wind Energy Facilities

ABSTRACT Turbine‐related bat mortality at commercial wind energy facilities may threaten populations of migratory tree‐roosting bat species in North America. Industry stakeholders and regulatory agencies alike are investigating strategies to reduce risk of population‐level consequences as the wind energy industry grows. Bats collide with turbines only when turbine rotors are spinning and curtailing turbine operation at low wind speeds can effectively reduce bat fatality rates. Nonetheless, few quantitative data exist to determine appropriate threshold wind speeds below which turbine operations should be curtailed. Carcass monitoring is labor‐intensive and does not provide information on factors linked to bat fatality rates on any scale finer than nightly. We tested whether acoustic bat data recorded at turbine nacelles could provide a more precise and sensitive measure of fatality risk to bats by analyzing acoustics, weather, turbine operation, and carcass data collected at 2 commercial wind energy facilities in West Virginia over 7 years. Each wind facility implemented several distinct curtailment treatments during our study, allowing us to compare fatality rates and acoustic bat activity across multiple operational strategies. We found that bat passes exposed to turbine operation explained close to 80% of the variation in carcass‐based estimates of bat fatality rates and accounted for significant variation in raw carcass counts per turbine and probability of finding bat carcasses during individual turbine searches. Conversely, bat activity occurring when turbines were not operating had little or no relationship to fatality rates. We also found that patterns in bat activity exposure could be predicted accurately among turbines and years. Our results demonstrate that measuring exposure of acoustic bat activity provides a quantitative basis for designing, evaluating, and adaptively managing curtailment strategies. This is an important advance towards using curtailment to reduce bat fatality rates strategically while allowing for increased generation of renewable energy. © 2021 The Authors. Wildlife Society Bulletin published by Wiley Periodicals LLC on behalf of The Wildlife Society.

17 WIND ENERGY↗
DOE OSTI2022

Wind Shear and Wind Veer Effects on Wind Turbines

This chapter highlights key contributions to the scientific literature on the sources of wind shear and wind veer in the atmospheric boundary layer, observations of shear and veer, and the effects of shear and veer on wind turbine power production, wind turbine wake evolution, and wind turbine loads. As wind turbines have grown larger, they encounter deeper and more complicated regions of the atmosphere. Over this height, profiles of wind speed shear and wind direction veer play a quantifiable role. Changes in the wind speed and wind direction across the vertical extent of a wind turbine rotor disk modify the inflow vector on the blades of the turbine, thereby affecting the magnitude and orientation of the lift and drag forces of the blade's airfoil. These changes can affect the power production and loads on large modern turbines, as well as the evolution of the wake that could affect a downwind turbine.

atmospheric stability↗
DOE OSTI2021

Considerations for testing full-scale wind turbine nacelles with hardware-in-the-loop

In this paper, pole placement control techniques are utilized to compensate for variations in the torsional dynamics resulting from the different boundary conditions experienced by a wind turbine nacelle when mounted on a test bench. Simulation case studies are used to understand the baseline torsional characteristics of the nacelle coupled to the test bench versus that coupled to the rotor. It was found that the frequency shifts by up to 200% and 400% for the first and second torsional modes, respectively. The feasibility of utilizing pole placement technique to match the torsional characteristics of the turbine on the test bench is investigated using PI and PID controllers. Here, the performance of the tuned controller is then verified under two test scenarios: Low Voltage Ride Through (LVRT), and a highly dynamic turbulent wind input. It is demonstrated that tuning the test bench speed controller can effectively shift the poles of the closed-loop system to match the desired first and second modes of the full turbine and replicate transient field events on the test bench.

17 WIND ENERGY↗