Quenching and radiation rates of CO /a super 3 pi/
Carbon monoxide in metastable state, considering quenching and radiative lifetime
Lawrence, G. M.↗
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Quenching of vibrationally excited hydroxyl /v = 9/ with oxygen.
In the experiment discussed molecular oxygen was allowed to mix with atomic hydrogen and ozone at the entrance to a 3-m flow tube. A rate equation for the decay of the vibrationally excited hydroxyl is derived, taking into consideration the reaction with ozone, radiative decay, wall quenching, and interaction with molecular oxygen. It is pointed out that molecular oxygen might be important as a quencher for the hydroxyl airglow in the upper atmosphere in spite of negative results obtained in fast-flow experiments conducted in the laboratory.-
Worley, S. D.↗
Lifetime and quenching of CO /a super 3 pi/ produced by recombination of CO2 ions in a helium afterglow.
Demonstration that rapid dissociative recombination of CO2(+) in a flowing, helium afterglow is an efficient source of CO in the a super 3 pi metastable state. Ions produced by mixing CO2 with He(2 super 3 S) recombine to produce a CO metastable afterglow with a number density as great as 10 to the 9th per sq cm. Monitoring of the (a super 3 pi-X super 1 sigma) Cameron transition in CO was used to study the lifetime and quenching of CO (a super 3 pi) by CO2, N2, NO, and He. Recombination of CO2(+) also produces CO in the d super 3 delta and a' super 3 sigma states.
Wauchop, T. S.↗
Properties of splat-quenched 7075 aluminum type alloys
The 7075 alloy belonging to the Al-Zn-Mg-Cu system, prepared by powder metallurgy techniques, was used in a study of alloys prepared from splat-quenched foils consolidated into bar material by hot extrusion. Ni and Fe were included in one alloy specimen, producing a fine dispersion of FeAl3 type particles which added to the strength of the aged alloy but did not coarsen upon heat treatment. Fine oxide films showing up on air-splatted foils induce finely dispersed oxide stringers (if the foils are not hot-worked subsequently) which in turn promote axial cracking (but longitudinal tensile strength is not seriously impaired). Splatting in a protective atmosphere, or thermomechanical processing, is recommended to compensate for this.
Durand, J. P. H. A.↗
What quenches the helium shell flashes
An analysis is conducted of a typical stellar helium shell flash cycle. A sequence of 12 flashes for a population I star is considered. The changes taking place at a constant mass layer in the helium-burning shell are studied as the flash develops. A highly simplified mathematical description is presented, taking into account the three necessary conditions for the occurrence of the flash and the pressure-density and temperature-density relationships. Quantities which are helpful in explaining what triggers the flash are found to be useful in explaining what quenches the flash.
Sackmann, I.-J.↗
Photodissociation of CO2 and quenching of metastables
Investigations in four different areas were carried out to further our understanding of the chemistry of the atmospheres of Mars and Venus. CO2 photodissociation quantum yields were determined in the 1300-1500 A spectral region by measuring both CO and oxygen atoms. The O(1S) quantum yield was determined for CO2 photodissociation in the 1060-1175 A spectral region. The measurement resolves the differences between two earlier experiments, and demonstrates that the O(1S) yield is unity throughout most of the measured region. The pathways for the quenching of O(1S) by N2O, CO2, H2O and NO were investigated and the source of the Venus nightglow, detected by Venera 9 and 10, was investigated. What appears to be a new O2 band system, was detected although the identity of the transition is not yet evident.
Slanger, T. G.↗
The OI/1S/ state - Its quenching by O2 and formation by the dissociative recombination of vibrationally excited O2/+/ ions
The rate coefficient for the quenching of metastable O(1S) atoms by O2 was measured as a function of temperature from 250 to 550 K. The resulting Arrhenius expression correlates well with previous laboratory work. It is suggested that the much larger value of the rate coefficient inferred from an analysis of artificial auroral experiment, Precede, may be explained by overestimation of the contribution of O(1S) production from O2(+) dissociative recombination. The possibility that O(1S) atoms are produced only by the dissociative recombination of vibrationally excited O2(+) ions is examined; such excited ions would not exist in the Precede experiment because of the rapid cooling of the ions by resonant charge transfer processes.
Zipf, E. C.↗
Quenching of O+/2D/ by electrons in the thermosphere
Satellite measurements of relevant ionospheric parameters were used to determine the rate coefficient for quenching of O+(2D) by electrons as a function of temperature. The results agree with the theoretically determined rate coefficient to within statistical uncertainties. The study provides confirmation of the absolute magnitude of the rate coefficient given by theoretical calculation at these temperatures, but it also indicates a somewhat steeper dependence on electron temperature than that predicted by theory.
Torr, M. R.↗
Transient stress intensity factors for edge and corner cracks in quench-test specimens
The transient temperature and stress fields in a quenched rectangular bar were computed and used to determine the stress intensity factors for midside and corner-edge cracks. The stress intensity factors, KI, are presented as a function of time, flaw size, and aspect ratio. The variations of KI along the crack edge are given and the self-limiting growth of the crack depth is discussed in relation to the nonlimited surface growth.
Emery, A. F.↗
Atmospheric quenching of vibrationally excited O2/1 Delta/
The paper presents photolysis absorption spectroscopy experimental results which show rapid vibrational quenching of O2(1 Delta, v not less than 1) molecular oxygen fragments in an atmospheric environment. The reactions of this species were determined by flash photolysis of ozone in the Hartley band combined with absorption spectroscopic detection of O2(1 Delta v equals 0) fragments and resonance fluorescence detection of O(3P). It was shown that rapid vibrational deactivation occurs under atmospheric conditions; in addition, an upper limit was determined for the photolytic channel of the O(1D) + O3 yields O2(1 Sigma) reaction.
Klais, O.↗
Radiative lifetimes and quenching rate coefficients for directly excited rotational levels of OH/A 2Sigma +, v-prime = 0/
A narrow-bandwidth pulsed dye laser was used to excite OH X 2Pi i radicals to the A 2Sigma(+) state by pumping in the (0, 0) vibrational band around 308 nm. The radiative lifetimes of specific (K-prime, J-prime) rotational levels in v-prime = 0 were measured at low pressures (not greater than 1 mtorr), which yielded a mean lifetime of 0.71 + or - 0.009 microsec (2 sigma). Electronic quenching rate constants for N2, O2, H2O, and H2 were measured for a range of initially excited rotational levels. A strong dependence of this rate constant on the initially excited rotational level was found for N2, and less markedly for O2, with the rate constant tending to increase for the lowest rotational levels K-prime not greater than 3. The implications of these results for the laser-induced fluorescence detection of atmospheric OH are discussed.
Mcdermid, I. S.↗
Quenching Alloys in Containerless Processing
Magnetic levitation and gas quenching combined in proposed method to melt and rapidly solidify alloys without contacting container walls. Method used to develop new carbides for drill bits, high-ductility structured steel and new high-strength superplastic alloys.
Oran, W. A.↗
Quenched-in defects in flashlamp-annealed silicon
Deep levels introduced in boron-doped silicon by heat-pulse annealing with a tungsten-halogen flashlamp are investigated using deep-level transient spectroscopy. Two majority-carrier trapping levels in the band gap, at Ev + 0.32 eV and at Ev + 0.45 eV, are observed. These results are compared to those obtained by furnace-quenching and laser-annealing studies. Both the position in the gap and the annealing kinetics of the hole trap at Ev + 0.45 eV suggest that this center is due to an interstitial iron impurity in the lattice. The deep levels are not consistently observed in all flashlamp-annealed Si crystals utilized.
Borenstein, J. T.↗
Rate constants for the quenching of metastable O2 (1Sigma g +) molecules
The O2 (1Sigma g +) rates for CO2, H2, N2, Cl2, CO, O3, and 2,3 DMB-2 are determined by monitoring the 762-nm emission in a fast-flow-discharge chemiluminescence detection system (Leu, 1984; Leu and Smith, 1981). The results are presented in tables and graphs and briefly characterized. The rate constants (in cu cm/s x 10 to the -16th) are 4600 + or - 500 for CO2, 7000 + or - 300 for H2, 17 + or - 1 for N2, 4.5 + or - 0.8 for Cl2, 45 + or - 5 for CO, 220,000 + or - 30,000 for O3, and 6000 + or - 100 for 2,3 DMB-2. The temperature dependence of the CO2 and O3 quenching reactions at 245-362 K is found to be negligible.
Kwang, Y. C.↗
Growth process of gamma'-particles in a liquid-quenched Ni-15 at percent Al alloy
The growth of gamma-prime particles in a supersaturated Ni-15 at% Al alloy prepared by the liquid-quench method was studied using a magnetic mass balance, transmission electron microscopy, and field ion microscopy. Three stages in the precipitation and growth of these particles are demonstrated. In the first phase, the gamma-prime phase was produced by nucleation of spinodal decomposition of the alloy. In the second stage, spherical gamma-prime particles were arranged at random in the matrix with the size independent of aging time. Then, the Al concentration in the matrix decreased with the -1/3 power of the aging time. These results suggest that the degree of ordering increases with aging time. In the third stage, the particles were coarsened with aging time. They were arranged in the matrix (100) zone and were cubic, with the cube face lying on (100). The interfacial free energy was 28.4 mJ/sq m at 873 K and 22.4 mJ/sq m at 973 K.
Tachikake, A.↗
Ultraviolet and infrared observations of stars with 'quenched' chromospheres and the nature of mass loss
Previous observational evidence implies that the presence of Ca II emission, a chromospheric indicator, is correlated with the gas/dust ratio in the envelopes of red giant and supergiant stars. An attempt is made to determine whether this correlation can be generalized to all chromospheric activity indicators and the gas/dust ratio. New ultraviolet observations address the strength of UV emission features and the fraction of the total chromospheric flux emitted in various lines. Evidence is found that chromospheres are not completely quenched in the presence of dust, but that significant alteration of relative radiative loss patterns may occur. These observations are interpreted in terms of an instability that converts warm, chromospheric gas into near-surface dust grains and cool gas capable of supporting molecular masing. This supports the dust-driven mass loss scenario for red giant winds.
Stencel, R. E.↗
Dissociative excitation of the N(+)(5S) state by electron impact on N2 - Excitation function and quenching
Metastable N(+)(5S) ions were produced in the laboratory by dissociative excitation of N2 with energetic electrons. The resulting radiative decay of the N(+)(5S) state was observed with sufficient resolution to completely resolve the doublet from the nearby N2 molecular radiation. The excitation function was measured from threshold to 500 eV. The cross section peaks at a high electron energy and also exhibits a high threshold energy both of which are typical of dissociative excitation-ionization processes. This finding complicates the explanation of electron impact on N2 as the mechanism for the source of the 2145 A 'auroral mystery feature' by further increasing the required peak cross section. It is suggested that the apparent N(+)(5S) quenching in auroras may be an artifact due to the softening of the electron energy spectrum in the auroral E region.
Erdman, P. W.↗
Quenching and disruption of lunar KREEP lava flows by impacts
The results of a reexamination of petrography of the Apollo 15 KREEP basalts are reported. Several of the basalts contain yellow residual glasses which cross-cut the crystallized phases; some show more extreme disruption. The features of the glasses appear to be compatible only with impact disruption, ejection, and quenching from actively crystallizing flows, indicating a high impact flux immediately after the impact that formed the Imbrium basin. No other example of impacts into active lava flows is known in the solar system.
Ryder, Graham↗