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At least 379 records · Page 21

All sources NASA NTRS DOE OSTI

NASA NTRS2001

Genomic instability, bystander effect, cytoplasmic irradiation and other phenomena that may achieve fame without fortune

The possible risk of induced malignancies in astronauts, as a consequence of the radiation environment in space, is a factor of concern for long term missions. Cancer risk estimates for high doses of low LET radiation are available from the epidemiological studies of the A-bomb survivors. Cancer risks at lower doses cannot be detected in epidemiological studies and must be inferred by extrapolation from the high dose risks. The standard setting bodies, such as the ICRP recommend a linear, no-threshold extrapolation of risks from high to low doses, but this is controversial. A study of mechanisms of carcinogenesis may shed some light on the validity of a linear extrapolation. The multi-step nature of carcinogenesis suggests that the role of radiation may be to induce a mutation leading to a mutator phenotype. High energy Fe ions, such as those encountered in space are highly effective in inducing genomic instability. Experiments involving the single particle microbeam have demonstrated a "bystander effect", ie a biological effect in cells not themselves hit, but in close proximity to those that are, as well as the induction of mutations in cells where only the cytoplasm, and not the nucleus, have been traversed by a charged particle. These recent experiments cast doubt on the validity of a simple linear extrapolation, but the data are so far fragmentary and conflicting. More studies are necessary. While mechanistic studies cannot replace epidemiology as a source of quantitative risk estimates, they may shed some light on the shape of the dose response relationship and therefore on the limitations of a linear extrapolation to low doses.

NASA Discipline Radiation Health↗

DOE OSTI2021

Structures of HIV-1 Neutralizing Antibody 10E8 Delineate the Mechanistic Basis of Its Multi-Peak Behavior on Size-Exclusion Chromatography

Antibody 10E8 is capable of effectively neutralizing HIV through its recognition of the membrane-proximal external region (MPER), and a suitably optimized version of 10E8 might have utility in HIV therapy and prophylaxis. However, 10E8 displays a three-peak profile on size-exclusion chromatography (SEC), complicating its manufacture. Here we show cis-trans conformational isomerization of the Tyr-Pro-Pro (YPP) motif in the heavy chain 3rd complementarity-determining region (CDR H3) of antibody 10E8 to be the mechanistic basis of its multipeak behavior. We observed 10E8 to undergo slow conformational isomerization and delineate a mechanistic explanation for effective comodifiers that were able to resolve its SEC heterogeneity and to allow an evaluation of the critical quality attribute of aggregation. We determined crystal structures of single and double alanine mutants of a key di-proline motif and of a light chain variant, revealing alternative conformations of the CDR H3. We also replicated both multi-peak and delayed SEC behavior with MPER-antibodies 4E10 and VRC42, by introducing a Tyr-Pro (YP) motif into their CDR H3s. Our results show how a conformationally dynamic CDR H3 can provide the requisite structural plasticity needed for a highly hydrophobic paratope to recognize its membrane-proximal epitope.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2021

Proximity-induced anisotropic magnetoresistance in magnetized topological insulators.

Topological insulators (TIs) host spin-momentum locked surface states that are inherently susceptible to magnetic proximity modulations, making them promising for nano-electronic, spintronic, and quantum computing applications. While much effort has been devoted to studying (quantum) anomalous Hall effects in magnetic magnetically doped TIs, the inherent magnetoresistance (MR) properties in magnetic proximity-coupled surface states remain largely unexplored. Here, we directly exfoliate Bi 2 Se 3 TI flakes onto a magnetic insulator, yttrium iron garnet, and measure the MR at various temperatures. We experimentally observe an anisotropic magnetoresistance that is consistent with a magnetized surface state. Our results indicate that the TI has magnetic anisotropy out of the sample plane, which opens an energy gap between the surface states. Additionally, by applying a magnetic field along any in-plane orientation, the magnetization of the TI rotates toward the plane and the gap closes. Consequently, we observe a large (similar to 6.5%) MR signal that is attributed to an interplay between coherent rotation of magnetization within a topological insulator and abrupt switching of magnetization in the underlying magnetic insulator.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2024

Emergent Properties from Three-Dimensional Assemblies of (Nano)particles in Confined Spaces

The assembly of (nano)particles into compact hierarchical structures yields emergent properties not found in the individual constituents. The formation of these structures relies on a profound knowledge of the nanoscale interactions between (nano)particles, which are often designed by researchers aided by computational studies. These interactions have an effect when the (nano)particles are brought into close proximity, yet relying only on diffusion to reach these closer distances may be inefficient. Recently, physical confinement has emerged as an efficient methodology to increase the volume fraction of (nano)particles, rapidly accelerating the time scale of assembly. Specifically, the high surface area of droplets of one immiscible fluid into another facilitates the controlled removal of the dispersed phase, resulting in spherical, often ordered, (nano)particle assemblies. In this review, we discuss the design strategies, computational approaches, and assembly methods for (nano)particles in confined spaces and the emergent properties therein, such as trigger-directed assembly, lasing behavior, and structural photonic color. Finally, we provide a brief outlook on the current challenges, both experimental and computational, and farther afield application possibilities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Molecular Design of Functional Polymers for Silica Scale Inhibition

Silica polymerization, which involves the condensation reaction of silicic acid, is a fundamental process with wide-ranging implications in biological systems, material synthesis, and scale formation. The formation of a silica-based scale poses significant technological challenges to energy-efficient operations in various industrial processes, including heat exchangers and water treatment membranes. Despite the common strategy of applying functional polymers for inhibiting silica polymerization, the underlying mechanisms of inhibition remain elusive. In this study, we synthesized a series of nitrogen-containing polymers as silica inhibitors and elucidated the role of their molecular structures in stabilizing silicic acids. Polymers with both charged amine and uncharged amide groups in their backbones exhibit superior inhibition performance, retaining up to 430 ppm of reactive silica intact for 8 h under neutral pH conditions. In contrast, monomers of these amine/amide-containing polymers as well as polymers containing only amine or amide functionalities present insignificant inhibition. Molecular dynamics simulations reveal strong binding between the deprotonated silicic acid and a polymer when the amine groups in the polymer are protonated. Notably, an extended chain conformation of the polymer is crucial to prevent proximity between the interacting monomeric silica species, thereby facilitating effective silica inhibition. Furthermore, the hydrophobic nature of alkyl segments in polymer chains disrupts the hydration shell around the polymer, resulting in enhanced binding with ionized silicic acid precursors compared to monomers. Finally, our findings provide novel mechanistic insights into the stabilization of silicic acids with functional polymers, highlighting the molecular design principles of effective inhibitors for silica polymerization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1972

Calculation of irrotational wind pattern with application to Cleveland topography

Small perturbation theory is applied to compute the deflection of the wind blowing across land that has an irregular topography. As an illustration, the method is applied first to the flow around a single hill of Gaussian profile. Then calculations are made for the irregular topography on the east side of Cleveland where the elevation changes by several hundred feet. It was found that the topography produced small wind deflections that would not be of practical importance in air pollution dispersion studies. The calculations were for a neutrally stable atmosphere. Although they are not investigated here, other factors such as thermal stratification of the atmosphere, diurnal variations, and convection currents resulting from the proximity of Lake Erie and the city heat island effect are expected to be more significant than the influence of topography.

Siegel, R.↗

NASA NTRS1975

Effect of hand-based sensors on manipulator control performance

The effect of hand based sensors (e.g tactile, force, and proximity sensors) on the performance of manipulator control is discussed. A brief overview is presented on various experimental hand based information systems which provide the manipulator controller some nonvisual awareness of the task environment. It is established that differences in manipulator task categories and motion phases require different hand based information systems to cope with control performance requirements.

Bejczy, A. K.↗

NASA NTRS1981

Automatic arc welding of propulsion system tubing in close proximity to sensitive electronic devices

The planned final assembly of the Galileo spacecraft propulsion system tubing, which involves welding in close proximity to sensitive electronics, raised significant concerns about the effects of electromagnetic coupling of weld energy on CMOS and other sensitive integrated circuits. A test program was established to assess the potential of an orbital arc welder and an RF-induction brazing machine to damage sensitive electronic equipment. Test parameters were varied to assess the effectiveness of typical transient suppression practices such as grounding, bonding, and shielding. A technique was developed to calibrate the hazard levels at the victim-circuit location; this technique is described along with the results and conclusions of the test program.

Lumsden, J. M.↗

NASA NTRS1982

Aerodynamic characteristics of a large-scale, twin tilt-nacelle V/STOL model

A subsonic tilt-nacelle V/STOL aircraft configuration is described which is powered by two turbofan engines, mounted on a single carry-through structure that is designed to maintain the thrust axis close to the center of gravity at nacelle incidences of 5-95 deg. Control during V/STOL operation, often from small ship platforms, is achieved by means of a vane assembly that is immersed in each turbofan's exhaust. Wind tunnel test data have been obtained with an 11.2-m wing span model for the vertical-to-horizontal flight transition capability of the concept. It is found that the aircraft can operate over a broad transition corridor, with sufficient maneuver capability about the trim points. The control vane exhibited linear response characteristics over a large deflection range, with little influence from power, angle of attack or ground proximity in hover. The model induced a positive ground effect in hover that increased as wheel height was approached and strake angle increased.

Falarski, M. D.↗

NASA NTRS1989

Demonstrating system for servicing satellites

NASA has initiated a program to demonstrate a Satellite Servicer System prototype in a series of flight tests with the Space Shuttle. When the commitment to an operational system has been demonstrated, it is anticipated that a variety of missions will develop that can productively use the servicing capability. Rendezvous and proximity operations contain key enabling technologies needed for an effective operational system. Guidance, navigation and control hardware and operational techniques must be integrated into the program. Supporting sensor technology may limit or enhance the capability of the system depending on its readiness. Requirements for docking the spacecraft in the system concept development and technology requirements are reviewed. Examples of the initial assessment of technology readiness and applications opportunities are discussed. The degree of autonomy is of particular interest.

Jenkins, Lyle M.↗

NASA NTRS1991

Supersonic quasi-axisymmetric vortex breakdown

An extensive computational study of supersonic quasi-axisymmetric vortex breakdown in a configured circular duct is presented. The unsteady, compressible, full Navier-Stokes (NS) equations are used for the present computational study. The NS equations are solved for quasi-axisymmetric flow using an implicit, upwind, flux-difference splitting, finite-volume scheme. The quasi-axisymmetric solutions are time accurate and are obtained by forcing the components of the flowfield vector to be equal on two axial planes, which are in close proximity of each other. The computational study addresses the effect of the Reynolds number, for laminar flows, on the evolution and persistence of vortex breakdown. The effect of boundary conditions at the duct exit on vortex breakdown is also studied. Finally, the effect of swirl ratio at the duct inlet is investigated.

Kandil, Osama A.↗

NASA NTRS1995

The L1551NE molecular outflow

L1551NE is a very young protostar (class I or perhaps class 0), located very close to L1551NE IRS 5. It is the second brightest far-infrared source in the Taurus molecular cloud complex, but its proximity to the brightest source IRS 5 has prevented effective observations of any molecular outflow. We here present evidence that it does indeed process an outflow, that the optical/infrared reflection nebula is associated with the blueshifted outflow lobe, and that the L1551W outflow does not originate from L1551NE, as has been suggested.

Moriarty-Schieven, G. H.↗

NASA NTRS2013

EDSN: A First Demonstration of a Distributed System of Nanosatellites

Edison Demonstration of SmallSat Networks (EDSN) is the first demonstration of a distributed system of nano-scale satellites to use intersatellite communication while working towards common science and technology goals. This unique mission configuration poses key technological challenges, including multi-satellite deployment, close proximity flight, cross-satellite communications, and simplified and effective operations. Tackling these challenges has required extensive development on EDSNs guidance navigation and control (GNC) and flight software systems. Although use of COTS component is common to the CubeSat community, it is prudent to point out that utilization of these components enables EDSN to accomplish its objectives at relatively low cost ($12M) in comparison to current multi-satellite missions capable of cross-link communications. EDSN is on cost and schedule with flight unit shipment in August 2013. This paper aims to update the community of EDSN's progress since SRR and speaks to the approach EDSN has taken to resolve some of the main issues revolving around a distributed system of nano-scale satellites.

Nanosatellite↗

NASA NTRS2023

Python Based Plume Dynamics Estimation Tool (PyPDET) Rapid Plume Strike Analysis for RPOD Maneuvers in Deep Space Operations

I worked as a NASA Intern during the Summer 2023 term in the DS-00 division under the supervision of my mentor, Dr. Jonathan Pitt. Our goal was to build on our previous work from 2022 to develop a plume strike estimation tool using a prescribed physics methodology and model plume impingement effects while considering the dynamics of a rendezvous, operations, proximity, and docking (RPOD) maneuver. This tool supports previously configured CFD-DSMC calculations by allowing for rapid analysis of initial designs using a low-fidelity source flow model. Engineers can then use the high-fidelity CFD-DSMC tool to consolidate results as they work towards finalizing a design. This year’s project was focused on developing a software application that other engineers would be using in their analysis. Thus, the user’s experience was considered in the development of this application. Proper documentation, testability, and modularity of the codebase was our priority. For example, the project included auto documentation procedures to start building towards a User Manual, while also including dedicated demonstration cases for more explicit communication of functionality. Also, this project included a framework for testing the source code for future developments. Additionally, care was taken to develop the code using an Object-Oriented Programming approach. Thus, allowing for a modular extensibility of functionality in anticipation of future developments. The core work of this project was developing an algorithm that would transform the visiting vehicle and associated thruster data according to the kinematics described in the jet firing history. It would then calculate the estimated plume strikes on two of the target vehicles and write data accordingly into a VTK file. Summer work is to conclude by developing and presenting a PowerPoint slide deck at the intern exit briefing on August 11 th , 2023. Once the model for simple plume strike calculations is developed and tested there are several avenues to explore to continue development of this tool. These are also discussed in this report.

Plume Impingement↗

NASA NTRS1979

A theoretical investigation of ground effects on USB configurations

A formulation predicts the variation of circulation forces and jet reaction forces in ground proximity as a function of ground height. The predicted results agree well with available experimental data. It is shown that the wing-alone theory is not capable of predicting the ground effect for USB configurations.

Lan, C. E.↗

DOE OSTI2022

Nonconventional NMR Spin-Coupling Constants in Oligosaccharide Conformational Modeling: Structural Dependencies Determined from Density Functional Theory Calculations

Nonconventional NMR spin-coupling constants were investigated to determine their potential as conformational constraints in MA’AT modeling of the O-glycosidic linkages of oligosaccharides. Four ( 1 J C1',H1' , 1 J C1',C2' , 2 J C1',H2' , and 2 J C2',H1' ) and eight ( 1 J C4,H4 , 1 J C3,C4 , 1 J C4,C5 , 2 J C3,H4 , 2 J C4,H3 , 2 J C5,H4 , 2 J C4,H5 , and 2 J C3,C5 ) spin-couplings in methyl β-d-galactopyranosyl-(1→4)-β-d-glucopyranoside (methyl β-lactoside) were calculated using density functional theory (DFT) to determine their dependencies on O-glycosidic linkage C–O torsion angles, $\phi$ and ψ, respectively. Long-range 4 J H1',H4 was also examined as a potential conformational constraint of either $\phi$ or ψ. Secondary effects of exocyclic (hydroxyl) C–O bond rotation within or proximal to these coupling pathways were investigated. Based on the findings of methyl β-lactoside, analogous J-couplings were studied in five additional two-bond O-glycosidic linkages [βGlcNAc-(1→4)-βMan, 2-deoxy-βGlc-(1→4)-βGlc, αMan-(1→3)-βMan, αMan-(1→2)-αMan, and βGlcNAc(1→2)-αMan] to determine whether the coupling behaviors observed in methyl β-lactoside were more broadly observed. Of the 13 nonconventional J-couplings studied, 7 exhibit properties that may be useful in future MA’AT modeling of O-glycosidic linkages, none of which involve coupling pathways that include the linkage C–O bonds. The findings also provide new insights into the general effects of exocyclic C–O bond conformation on the magnitude of experimental spin-couplings in saccharides and other hydroxyl-containing molecules.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

Electrical Detection of Single-Domain Néel Vector Reorientation across the Spin–Flop Transition in Cr 2 O 3 Crystals

Electrical transport measurements in heterostructures of antiferromagnetic Cr 2 O 3 bulk crystals and a thin Pt layer exhibit sharp responses as the Néel vector of Cr 2 O 3 undergoes the spin−flop transition. This abrupt change can arise from several distinct mechanisms including magnetostriction, proximity-induced anomalous Hall, spin Hall anomalous Hall, and spin Hall planar Hall effects. While large Pt devices sensing multiple up/ down domains can produce indistinguishable Hall signal jumps due to different initial Néel vector orientations, smaller Pt devices that sense single domains isolate the proximity-induced Hall signals. This allows direct electrical detection of Néel vector reorientation across the spin−flop transition in single-domain regions. Furthermore, the single-domain state can be prepared by magnetic field cooling or magnetoelectric cooling. We demonstrate a method to control and characterize the three-dimensional orientation of single-domain Néel vectors by exploiting Hall measurements and cooling techniques, crucial for future antiferromagnetic spintronic applications.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

NASA NTRS1978

Analytical study of STOL Aircraft in ground effect. Part 2: Nonplanar, nonlinear method applicable to three dimensional jets of finite thickness

The ability of the potential flow analysis (POTFAN) to predict the influence of ground proximity on lift systems is examined. A two dimensional study employing vortex lattice methodology provides confidence that ground effect phenomenon can be predicted using discrete singularity representation. Two dimensional quasi-steady ascent and descent behavior determined provides guidance in interpreting three dimensional results. Steady and quasi-steady ground effect aerodynamic characteristics predicted by POTFAN are presented for several basic unpowered configurations. POTFAN results are compared with experimental data and results of other analytical methods. Modification of POTFAN to incorporate multienergy flow analysis is discussed. General aspects of thick jet models are examined to provide a basic for extending POTFAN's scope to include analysis of propulsive lift interactions.

Shollenberger, C. A.↗