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At least 379 records · Page 21

Elemental composition and size distribution of particulates in Cleveland, Ohio

Measurements have been made of the elemental particle size distribution at five contrasting urban environments with different source-type distributions in Cleveland, Ohio. Air quality conditions ranged from normal to air pollution alert levels. A parallel network of high-volume cascade impactors (5-stage) were used for simultaneous sampling on glass fiber surfaces for mass determinations and on Whatman-41 surfaces for elemental analysis by neutron activation for 25 elements. The elemental data are assessed in terms of distribution functions and interrelationships and are compared between locations as a function of resultant wind direction in an attempt to relate the findings to sources.

Leibecki, H. F.↗

The solar occultation technique for remote sensing of particulates in the earth's atmosphere. I - The inversion of horizon radiances from space

The aerosol scattering coefficient as a function of height can be recovered from a direct inversion of the single-scattering horizon radiance provided the sun is above the horizon and an independent measurement of extinction as a function of height is made. Aerosol detection is effected by means of spacecraft measurements of the horizon radiance made during periods of spacecraft twilight. A solar occultation technique which allows the twilight measurements to be made when the sun is still above the horizon greatly reduces the complexity of the inversion problem. The second part of the paper reports on the use of a coronograph aboard Skylab to photograph the horizon just before spacecraft twilight in order to monitor the aerosol component above the tropopause. The coronograph picture, centered on 26.5 degrees E longitude and 63.0 degrees S latitude, shows that the aerosol layer peaks at a height of 48 plus or minus 1 km.

Schuerman, D. W.↗

Photographic coronagraph, Skylab particulate experiment T025

A photographic coronagraph, built to monitor Skylab's extravehicular contamination, is described. This versatile instrument was used to observe the earth's vertical aerosol distribution and Comet Kohoutek (1973f) near perihelion. Although originally designed for deployment from the solar airlock, the instrument was modified for EVA operation when the airlock was rendered unusable. The results of the observations made in four EVA's were almost completely ruined by the failure of a Skylab operational camera used with the coronagraph. Nevertheless, an aerosol layer at 48 km was discovered in the southern hemisphere from the few useful photographs.

Giovane, F.↗

Biogenic lipids in particulates from the lower atmosphere over the eastern Atlantic

The occurrence, isolation, and characterization of terrigenous lipids in aeolian dusts from the eastern Atlantic are discussed. It is pointed out that such lipids have also been found in aeolian dust from other oceanic areas. A description is presented of the collection and extraction of samples. The dust samples were extracted with two aliquots of toluene and methanol (3:1) for lipid analysis. The extracts were concentrated on a rotary evaporator. General aeolian dust collection data and sample descriptions are presented in a table. The origin of the samples is discussed.

Simoneit, B. R. T.↗

Measurement of wavelength-dependent extinction to distinguish between absorbing and nonabsorbing aerosol particulates

Measurements of spectral transmission factors in smoky optical transmission paths reveal a difference between wavelength exponents of the extinction cross section of high absorption capacity and those of low absorption capacity. A theoretical explanation of this behavior is presented. In certain cases, it is possible to obtain data on the absorption index of aerosol particles in the optical path by measuring the spectral decadic extinction coefficient at, at least, two wavelengths. In this manner it is possible, for instance, to distinguish smoke containing soot from water vapor.

Portscht, R.↗

Apparatus for handling micron size range particulate material

An apparatus for handling, transporting, or size classifying comminuted material was described in detail. Electrostatic acceleration techniques for classifying particles as to size in the particle range from 0.1 to about 100 microns diameter were employed.

Friichtenicht, J. F.↗

Surfactant-assisted liquefaction of particulate carbonaceous substances

A slurry of carbonaceous particles such as coal containing an oil soluble polar substituted oleophilic surfactant, suitably an amine substituted long chain hydrocarbon, is liquefied at high temperature and high hydrogen presence. The pressure of surfactant results in an increase in yield and the conversion product contains a higher proportion of light and heavy oils and less asphaltene than products from other liquefaction processes.

Hsu, G. C.↗

Decomposition of nitrous oxide and chloromethanes absorbed on particulate matter

The effect of pressure on the heterogeneous thermal and pyrolytic decomposition of nitrous oxides adsorbed on sand was studied. Results indicate that N20 adsorbed on certain sand surfaces can be decomposed by photons which nitrous oxide cannot absorb in the gas phase. There is also a thermal heterogeneous decomposition of nitrous oxide which also produces nitrogen. The photolysis of CC14, CFC13, CF2C12 adsorbed on fused quartz and on different types of sand was also investigated. There was no thermal heterogeneous reaction with any of these chloromethanes. Apparently the larger bond energy of approximately 74 kcal for the C-C1 bond compared to approximately 40 kcal for the N-O bond in N2O makes the thermal reaction inoperative for the chloromethanes.

Rebbert, R. E.↗

Biocontamination and particulate detection system

A method for determining the characteristics and amount of microscopic contaminants lodged on a photographed surface is disclosed. An image enhanced full color photographic negative and print are taken of the contaminated surface. Three black and white prints are developed subsequently from red, green and blue separation filter overlays of the color negative. Both the color and three monochromatic prints are then scanned to extract in digital form a profile of any contaminant possibly existing on the surface. The resulting profiles are electronically analyzed and compared with data already stored relating to known contaminants.

Jacobs, J. M.↗

An estimate of particulates in the vicinity of a Shuttle orbiter due to meteoroid impact

An estimate of the magnitude of released particles in the vicinity of a a Shuttle (STS) Orbiter due to meteoroid impact has been completed. A calculation of the number of particles existing as surface contamination and released by such impacts has been performed. In addition, two estimates of the creation of new particles due to meteoroid cratering (backsplash) have been obtained. In each case, the total number of particles per day as a function of size without regard to velocity, as a function of velocity without regard to size, and as a joint distribution in size and velocity has been calculated.

Barengoltz, J.↗

Monitoring of particulate contamination and background brightness from IECM based instrumentation

Of particular concern to the astronomical community is the effect of Shuttle Transportation System induced contamination in the form of individual particles and general background on astronomical experiments. In an effort to investigate this problem, two camera/photometers in the Induced Environment Contamination Monitor (IECM) will be used to determine the size and velocity distribution of contaminant particles, their origin, and the extent of sunlit background brightness resulting from spacecraft contamination. The cameras will operate synchronously as a stereo pair to make continuous photographic measurements throughout the missions.

Clifton, K. S.↗

Measurement of particulates

The size distributions of particles in the exhaust plumes from the Titan rockets launched in August and September 1977 were determined from in situ measurements made from a small sampling aircraft that flew through the plumes. Two different sampling instruments were employed, a quartz crystal microbalance (QCM) cascade impactor and a forward scattering spectrometer probe (FSSP). The QCM measured the nonvolatile component of the aerosols in the plume covering an aerodynamic size ranging from 0.05 to 25 micrometers diameter. The FSSP, flown outside the aircraft under the nose section, measured both the liquid droplets and the solid particles over a size range from 0.5 to 7.5 micrometers in diameter. The particles were counted and classified into 15 size intervals. The presence of a large number of liquid droplets in the exhaust clouds is discussed and data are plotted for each launch and compared.

Woods, D.↗

Polar nephelometer for atmospheric particulate studies

A polar nephelometer for use in studying atmospheric aerosols was developed. The nephelometer detects molecular scatter from air and measures scattering from very clean air using pure molecular scattering for calibration. A compact system using a folded light path with an air cooled argon laser for the light source was designed. A small, sensitive detector unit permits easy angular rotation for changing the scattering angle. A narrow detector field of view of + or - 1/4 degree of scattering along with a single wavelength of incident light is used to minimize uncertainties in the scattering theory. The system is automated for data acquisition of the scattering matrix elements over an angular range from 2 degrees to 178 degrees of scattering. Both laser output and detector sensitivity are monitored to normalize the measured light scattering.

Hansen, M. Z.↗

Characterization of the exhaust particulates in the ground cloud and high-altitude plume of large solid-propellant booster rockets

The report is concerned with the characterization of Al2O3 particles in the atmosphere. These particles comprise one of the major combustion products of the rocket propellant employed in the Space Shuttle boosters. A ground cloud and stratospheric plume are considered. It is concluded that the typical residence times in the atmosphere are much longer than earlier estimates have indicated.

Strand, L. D.↗

Mechanical properties of Al-mica particulate composite material

Cast aluminum alloy mica particle composites of varying mica content were tested in tension, compression, and impact. With 2.2 percent mica (size range 40-120 microns) the tensile and compression strengths of aluminum alloy decreased by 56 and 22 percent, respectively. The corresponding decreases in percent elongation and percent reduction are 49 and 39 percent. Previous work shows that despite this decrease in strength the composite with 2.5 percent mica and having an UTS of 15 kg/sq mm and compression strength of 28 kg/sq mm performs well as a bearing material under severe running conditions. The differences in strength characteristics of cast aluminum-mica particle composites between tension and compression suggests that, as in cast iron, expansion of voids at the matrix particle interface may be the guiding mechanism of the deformation. SEM studies show that on the tensile fractured specimen surface, there are large voids at the particle matrix interface.

Nath, D.↗