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All sourcesNASA NTRSDOE OSTI
NASA NTRS2005

Cosmic Infrared Background and Early Galaxy Evolution

The cosmic infrared background (CIB) reflects the sum total of galactic luminosities integrated over the entire age of the universe. From its measurement the red-shifted starlight and dust-absorbed and re-radiated starlight of the CIB can be used to determine (or constrain) the rates of star formation and metal production as a function of time and deduce information about objects at epochs currently inaccessible to telescopic studies. This review discusses the state of current CIB measurements and the (mostly space-based) instruments with which these measurements have been made, the obstacles (the various foreground emissions) and the physics behind the CIB and its structure. Theoretical discussion of the CIB levels can now be normalized to the standard cosmological model narrowing down theoretical uncertainties. We review the information behind and theoretical modeling of both the mean (isotropic) levels of the CIB and their fluctuations. The CIB is divided into three broad bands: near-IR (NIR), mid-IR (MIR) and far-IR (FIR). For each of the bands we review the main contributors to the CIB flux and the epochs at which the bulk of the flux originates. We also discuss the data on the various quantities relevant for correct interpretation of the CIB levels: the star-formation history, the present-day luminosity function measurements, resolving the various galaxy contributors to the CIB, etc. The integrated light of all galaxies in the deepest NIR galaxy counts to date fails to match the observed mean level of the CIB, probably indicating a significant high-redshift contribution to the CIB. Additionally, Population III stars should have left a strong and measurable signature via their contribution to the CIB anisotropies for a wide range of their formation scenarios, and measuring the excess CIB anisotropies coming from high z would provide direct information on the epoch of the first stars.

Kashlinsky, Alexander↗
NASA NTRS2015

MISR Calibration Issues in High-Contrast Scenes, and Empirical Corrections

We diagnose the potential causes for the Multi-angle Imaging SpectroRadiometer's (MISR) persistent high aerosol optical depth (AOD) bias at low AOD with the aid of coincident MODerate-resolution Imaging Spectroradiometer (MODIS) imagery from NASA's Terra satellite. Internal reflections within the MISR instrument are responsible for a large portion of the high AOD bias in high-contrast scenes, which are especially common as broken-cloud situations over ocean. Discrepancies between MODIS and MISR nadir-viewing near-infrared (NIR) images are used to optimize nine parameters, along with a background reflectance modulation term (that was modeled separately), to represent the observed features. Independent, surface-based AOD measurements from the AErosol RObotic NETwork (AERONET) and the Marine Aerosol Network (MAN) are compared with MISR Research Algorithm (RA) AOD retrievals for 1118 coincidences to validate the corrections when applied to the nadir and off-nadir cameras. Additionally, the calibration coefficients for the red and NIR channels used for MISR over-water aerosol retrievals were reassessed with the RA to be consistent on a camera-by-camera basis. With these corrections, plus the baseline RA corrections applied (except enhanced cloud screening), the median AOD bias in the mid-visible (green) band decreases from 0.010 to 0.002, the RMSE decreases by approx. 10%, and the slope and correlation of the MISR vs. sun photometer Ångström Exponent improves. For AOD558 nm < 0.10 and with additional cloud screening, the median bias for the RA-retrieved AOD in the green band decreases from 0.011 to 0.003, compared to ~ 0.023 for the Standard Algorithm (SA). RMSE decreases by ~ 20% compared to the baseline (uncorrected) RA and by 17-53% compared to the SA. After all corrections and cloud screening are implemented, for AOD558 nm < 0.10, which includes about half the validation data, 68% absolute AOD errors for the RA have dropped to < 0.02 (approx. 0.018).

MISR↗
NASA NTRS2000

Landsat-7 ETM+ On-Orbit Radiometric Calibration

As of July, 2000 the Enhanced Thematic Mapper Plus (ETM+) sensor on Landsat-7 has been operating on-orbit for about 15 months. The ETM+ images the Earth in has eight spectral bands in the visible, near-infrared (IR), short wavelength infrared (SWIR), and thermal portions of the spectrum. Three on-board calibration systems are available for the reflective bands: (1) the Internal Calibrator (IC), (2) the Partial Aperture Solar Calibrator (PASC), and (3) the Full Aperture Solar Calibrator (FASC). The Internal Calibrator also provides the thermal band calibration. Several investigators on the Landsat science team are also regularly performing vicarious calibrations. The internal calibrator, which during much of the pre-launch testing and early on-orbit check out period, showed up to 15% variability with time, has since stabilized as the instrument has assumed a regular schedule of operations and is now typically showing only a few percent variation with time, mostly associated with warm-up. The PASC has been the most variable of the sources: the response to the PASC has increased by as much as 50% is some bands and is oscillating with time, perhaps due to contamination. The FASC has been the most stable of the sources: mid scan response to the FASC diffuser have varied from -4%/yr for band 4 (0.83 microns) to -2%/yr for band 1 (0.49 microns) to +1%/yr for band 7 (2.2 microns). These decreases in response in bands 1-4 would have been about half as large if measured on the right (west) side of the panel and about twice as large if measured on the left side of the panel. The current interpretation is that the FASC diffuser panel is changing non-uniformly in its reflectance characteristics. Vicarious ground measurements have generally been consistent with the pre-launch measurements of the instrument responsivity and have not shown evidence of a change in responsivity with time. The FASC, IC, and vicarious results suggest the instrument has not changed by more than two percent in responsivity since launch and that the absolute calibration is good to the advertised five percent.

Markham, Brian L.↗
NASA NTRS1992

An IDL-based analysis package for COBE and other skycube-formatted astronomical data

UIMAGE is a data analysis package written in IDL for the Cosmic Background Explorer (COBE) project. COBE has extraordinarily stringent accuracy requirements: 1 percent mid-infrared absolute photometry, 0.01 percent submillimeter absolute spectrometry, and 0.0001 percent submillimeter relative photometry. Thus, many of the transformations and image enhancements common to analysis of large data sets must be done with special care. UIMAGE is unusual in this sense in that it performs as many of its operations as possible on the data in its native format and projection, which in the case of COBE is the quadrilateralized sphereical cube ('skycube'). That is, after reprojecting the data, e.g., onto an Aitoff map, the user who performs an operation such as taking a crosscut or extracting data from a pixel is transparently acting upon the skycube data from which the projection was made, thereby preserving the accuracy of the result. Current plans call for formatting external data bases such as CO maps into the skycube format with a high-accuracy transformation, thereby allowing Guest Investigators to use UIMAGE for direct comparison of the COBE maps with those at other wavelengths from other instruments. It is completely menu-driven so that its use requires no knowledge of IDL. Its functionality includes I/O from the COBE archives, FITS files, and IDL save sets as well as standard analysis operations such as smoothing, reprojection, zooming, statistics of areas, spectral analysis, etc. One of UIMAGE's more advanced and attractive features is its terminal independence. Most of the operations (e.g., menu-item selection or pixel selection) that are driven by the mouse on an X-windows terminal are also available using arrow keys and keyboard entry (e.g., pixel coordinates) on VT200 and Tektronix-class terminals. Even limited grey scales of images are available this way. Obviously, image processing is very limited on this type of terminal, but it is nonetheless surprising how much analysis can be done on that medium. Such flexibility has the virtue of expanding the user community to those who must work remotely on non-image terminals, e.g., via modem.

Ewing, J. A.↗
NASA NTRSDate not supplied

The PCM is Dead! Long Live O-PCM!

The ability to reconfigure the optical behavior of a device enables free-space applications ranging from imaging to sensing and signal control. Such optical devices can be compacted via meta-surfaces, patterned structures with feature sizes below the incident wavelength. Leveraging geometry in addition to material properties and CMOS fabrication techniques has allowed meta-surfaces for lenses, holograms, beam steerers and more. To incorporate multiple optical functions into one device, various methods of device control have been implemented, such as stretching of flexible substrates, tuning the refractive index of the comprising meta-atoms via the electro-optic or the thermo-optic effects, phase transition materials such as VO2 and more. Chalcogenide glasses used as optical phase change materials, such as Ge¬2Sb2Te5 (GST), have gained increased traction in the optics community for potential use in the near infrared (NIR) and mid infrared (MIR) bands, including the telecom bands. Various chalcogenides such as Sb2Se3, Sb2S3, Ge2Sb¬2Se5 and Ge2Sb2Se4Te (GSST) have been investigated due to their broad NIR or MIR transparency window and large changes in refractive index. In their amorphous phase, these materials usually display a lower refractive index and low absorption when compared to their crystalline state which display a higher refractive index and typically larger extinction coefficients. The amorphous-crystalline reversible switching can be done via fast melt-quenching thermal processes triggered by laser or electrical impulses, relying on a substrate as a heat sink. The potential of PCMs in photonic devices can be limited by intrinsic material limitations as well as by device fabrication issues. To explore the cyclability of GSST, a PCM with large refractive index contrast and on-chip electrothermal switching on a silicon-on-insulator platform has been done to analyze potential failure mechanisms from both a material and device perspective. A brief outline of the instrumentation and phase change contrast analysis is provided. Dewetting of the PCM, delamination of and damage in the PECVD SiNx protective layer, elemental migration in the PCM and optical contrast decay have been observed in cycled GSST devices. Guidelines for device performance improvement are proposed, and an improved design with larger endurance is shown in progress.

reconfigurable photonics↗
DOE OSTI2025

Changing-look Active Galactic Nuclei from the Dark Energy Spectroscopic Instrument. II. Statistical Properties from the First Data Release

We present the identification of changing-look active galactic nuclei (CL-AGNs) from the Dark Energy Spectroscopic Instrument First Data Release and Sloan Digital Sky Survey Data Release 16 at z ≤ 0.9. To confirm the CL-AGNs, we utilize spectral flux calibration assessment via an [O III ]-based calibration, pseudophotometry examination, and visual inspection. This rigorous selection process allows us to compile a statistical catalog of 561 CL-AGNs, encompassing 527 Hβ, 149 Hα, and 129 Mg II CL behaviors. In this sample, we find (1) a 283:278 ratio of turn-on to turn-off CL-AGNs. (2) The median Eddington ratio for CL-AGNs in the dim state is approximately λ Edd ∼ 0.01. (3) A strong correlation between the change in the luminosity of the broad emission lines (BELs) and variation in the continuum luminosity, with Mg II and Hβ displaying similar responses during CL phases. (4) The Baldwin–Phillips–Terlevich diagram for CL-AGNs shows no statistical difference from the general AGN catalog. (5) Five CL-AGNs are associated with asymmetrical mid-infrared flares, possibly linked to tidal disruption events. Given the large CL-AGN sample and the stochastic sampling of spectra, we propose that some CL phenomena are inherently due to typical AGN variability during low accretion rates, particularly for CL phenomenon only occurring on one BEL. Finally, we introduce a monotonically dimming CL phase for objects characterized by a gradual decline over decades in the light curve and the complete disappearance of entire BELs in faint spectra, indicative of a real transition in the accretion disk.

accretion↗
DOE OSTI2025

Changing-look Active Galactic Nuclei from the Dark Energy Spectroscopic Instrument. II. Statistical Properties from the First Data Release

We present the identification of changing-look active galactic nuclei (CL-AGNs) from the Dark Energy Spectroscopic Instrument First Data Release and Sloan Digital Sky Survey Data Release 16 at z≤ 0.9. To confirm the CL-AGNs, we utilize spectral flux calibration assessment via an [O iii]-based calibration, pseudophotometry examination, and visual inspection. This rigorous selection process allows us to compile a statistical catalog of 561 CL-AGNs, encompassing 527 Hβ, 149 Hα, and 129 Mg ii CL behaviors. In this sample, we find (1) a 283:278 ratio of turn-on to turn-off CL-AGNs. (2) The median Eddington ratio for CL-AGNs in the dim state is approximately λ$_{Edd}$ ∼ 0.01. (3) A strong correlation between the change in the luminosity of the broad emission lines (BELs) and variation in the continuum luminosity, with Mg ii and Hβ displaying similar responses during CL phases. (4) The Baldwin–Phillips–Terlevich diagram for CL-AGNs shows no statistical difference from the general AGN catalog. (5) Five CL-AGNs are associated with asymmetrical mid-infrared flares, possibly linked to tidal disruption events. Given the large CL-AGN sample and the stochastic sampling of spectra, we propose that some CL phenomena are inherently due to typical AGN variability during low accretion rates, particularly for CL phenomenon only occurring on one BEL. Finally, we introduce a monotonically dimming CL phase for objects characterized by a gradual decline over decades in the light curve and the complete disappearance of entire BELs in faint spectra, indicative of a real transition in the accretion disk.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2007

High-Resolution N-Band Observations of the Nova RS Ophiuchi with the Keck Interferometer Nuller

We report new observations of the nova RS Ophiuchi (RS Oph) using the Keck Interferometer Nulling Instrument, approximately 3.8 days following the most recent outburst that occurred on 2006 February 12. The Keck Interferometer Nuller (KIN) operates in K-band from 8 to 12.5 pm in a nulling mode, which means that the central broad-band interference fringe is a dark fringe - with an angular width of 25 mas at mid band - rather than the bright fringe used ill a conventional optical interferometer. In this mode the stellar light itself is suppressed by the destructive fringe, effectively enhancing the contrast of the circumstellar material located near the star. By subsequently shifting the neighboring bright fringe onto the center of the source brightness distribution and integrating, a second spatial regime dominated by light from the central portion of the source is almost simultaneously sampled. The nulling technique is the sparse aperture equivalent of the conventional corongraphic technique used in filled aperture telescopes. By fitting the unique KIK inner and outer spatial regime data, we have obtained an angular size of the mid-infrared continuum of 6.2, 4.0. or 5.4 mas for a disk profile, gaussian profile (fwhm), and shell profile respectively. The data show evidence of enhanced neutral atomic hydrogen emission located in the inner spatial regime relative to the outer regime. There is also evidence of a 9.7 micron silicate feature seen outside of this region. Importantly, we see spectral lines excited by the nova flash in the outer region before the blast wave reaches these regions. These lines are from neutral, weakly excited atoms which support the following interpretation. We discuss the present results in terms of a unifying model of the system that includes an increase in density in the plane of the orbit of the two stars created by a spiral shock wave caused by the motion of the stars through the cool wind of the red giant star. These data show the power and potential of the nulling technique which has been developed for the detection of Earth-like planets around nearby stars for the Terrestrial Planet Finder Mission and Darwin missions.

Barry, R. K.↗
DOE OSTI2023

49 W carrier-envelope-phase-stable few-cycle 2.1 µm OPCPA at 10 kHz

We demonstrate a mid-infrared optical parametric chirped pulse amplifier (OPCPA), delivering 2.1 µm center wavelength pulses with 20 fs duration and 4.9 mJ energy at 10 kHz repetition rate. This self-seeded system is based on a kW-class Yb:YAG thin-disk amplifier driving a CEP stable short-wavelength-infrared (SWIR) generation and three consecutive OPCPA stages. Our SWIR source achieves an average power of 49 W, while still maintaining excellent phase and average power stability with sub-100 mrad carrier-envelope-phase-noise and 0.8% average power fluctuations. These parameters enable the OPCPA setup to drive attosecond pump probe spectroscopy experiments with photon energies in the water window.

47 OTHER INSTRUMENTATION↗
DOE OSTI2023

Intersubband Transitions in Lead Halide Perovskite-Based Quantum Wells for Mid-Infrared Detectors

Due to their excellent optical and electrical properties as well as versatile growth and fabrication processes, lead halide perovskites have been widely considered as promising candidates for green energy and applications related to optoelectronics. Here, we investigate their potential applications at infrared wavelengths by modeling the intersubband transitions in perovskite-based quantum well systems. Both single-well and double-well structures are studied, and their energy levels as well as the corresponding wave functions and intersubband transition energies are calculated by solving the one-dimensional Schrödinger equations. Via adjustment of the quantum well and barrier thicknesses, the intersubband transition energies can be tuned to cover a broad infrared wavelength range. We also find that the lead halide perovskite-based quantum wells possess high absorption coefficients. In conclusion, the widely tunable transition energies and high absorption coefficients of the perovskite-based quantum well systems, combined with their unique material and electrical properties, may enable an alternative material system for infrared photodetector applications.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS2004

Preliminary Parallaxes of 40 L and T Dwarfs from the US Naval Observatory Infrared Astronometry Program

We present preliminary trigonometric parallaxes and proper motions for 22 L dwarfs and 18 T dwarfs measured using the ASTROCAM infrared imager on the US naval Observatory (USNO) 1.55 m Strand Astrometric Reflector. The results presented here are based on observations obtained between 2000 September and 2002 November; about half of the objects have an observational time baseline of t 1:3 yr and half t 2:0 yr. Despite these short time baselines, the astrometric quality is sufficient to produce significant new results, especially for the nearer T dwarfs. Seven objects are in common with the USNO optical CCD parallax program for quality control and seven in common with the European Southern Observatory 3.5 m New Technology Telescope parallax program. We compare astrometric quality with both of these programs. Relative to absolute parallax corrections are made by employing Two Micron All Sky Survey and/or Sloan Digital Sky Survey photometry for reference-frame stars. We combine USNO infrared and optical parallaxes with the best available California Institute of Technology (CIT) system photometry to determine MJ , MH, and MK values for 37 L dwarfs between spectral types L0 and L8 and 19 T dwarfs between spectral types T0.5 and T8 and present selected absolute magnitude versus spectral type and color diagrams, based on these results. Luminosities and temperatures are estimated for these objects. Of special interest are the distances of several objects that are at or near the L-T dwarf boundary so that this important transition can be better understood. The previously reported early to mid T dwarf luminosity excess is clearly confirmed and found to be present at J, H, and K. The large number of objects that populate this luminosity-excess region indicate that it cannot be due entirely to selection effects. The T dwarf sequence is extended to MJ 16:9 by 2MASS J041519 0935, which, at d 5:74 pc, is found to be the lluminous LOG (L=L )pa

L DWARFS↗
DOE OSTI2024

Developing a robust sensor for infrared imaging bolometers

A new type of large area sensor for infrared imaging bolometers has been developed. It replaces the thin and fragile free-standing metal foils, which typically have been used, with a multi-layer coated sapphire (or diamond) substrate. Sapphire is transparent to mid-infrared wavelengths, is robust against transients, and can be thick enough to even be the vacuum window. The primary radiation absorber is still a thin deposited metal layer, but now it is partially insulated from the supporting sapphire substrate by a black (carbon-based) layer, which also acts as a blackbody remitter. Test results indicate 6× more noise equivalent power density (estimated NEPD = 23 W/m 2 at 5 ms camera exposure time, foil temperature decay time 60 ms) for a 2 μm gold-coated sapphire disk compared to estimated NEP = 4 W/m 2 at 1.8 ms exposure time, with foil decay time 420 ms, for a nominal 2.5 μm thick platinum-free-standing foil.

47 OTHER INSTRUMENTATION↗
NASA NTRS2010

Recent Advances in Laboratory Infrared Spectroscopy of Polycyclic Aromatic Hydrocarbons: PAHs in the Far Infrared

Over 25 years of observations and laboratory work have shown that the mid-IR spectra of a majority of astronomical sources are dominated by emission features near 3.3, 6.2, 7.7, and 11.2 microns, which originate in free polycyclic aromatic hydrocarbon (PAH) molecules. PAHs dominate the mid-IR emission from many galactic and extragalactic objects. As such, this material tracks a wide variety of astronomical processes, making this spectrum a powerful probe of the cosmos Apart from bands in the mid-IR, PAHs have bands spanning the Far-IR (FIR) and emission from these FIR features should be present in astronomical sources showing the Mid-IR PAH bands. However, with one exception, the FIR spectral characteristics are known only for a few neutral small PAHs trapped in salt pellets or oils at room temperature, data which is not relevant to astrophysics. Furthermore, since most emitting PAHs responsible for the mid-IR astronomical features are ionized, the absence of any experimental or theoretical PAH ion FIR spectra will make it impossible to correctly interpret the FIR data from these objects. In view of the upcoming Herschel space telescope mission and SOFIA's FIR airborne instrumentation, which will pioneer the FIR region, it is now urgent to obtain PAH FIR spectra. This talk will present an overview recent advances in the laboratory spectroscopy of PAHs, Highlighting the FIR spectroscopy along with some quantum calculations.

Mattioda, Andrew L.↗
NASA NTRS2015

IceCube: CubeSat 883-GHz Radiometry for Future Ice Cloud Remote Sensing

Ice clouds play a key role in the Earth's radiation budget, mostly through their strong regulation of infrared radiation exchange. Accurate observations of global cloud ice and its distribution have been a challenge from space, and require good instrument sensitivities to both cloud mass and microphysical properties. Despite great advances from recent spaceborne radar and passive sensors, uncertainty of current ice water path (IWP) measurements is still not better than a factor of 2. Submillimeter (submm) wave remote sensing offers great potential for improving cloud ice measurements, with simultaneous retrievals of cloud ice and its microphysical properties. The IceCube project is to enable this cloud ice remote sensing capability in future missions, by raising 874-GHz receiver technology TRL from 5 to 7 in a spaceflight demonstration on 3-U CubeSat in a low Earth orbit (LEO) environment. The NASAs Goddard Space Flight Center (GSFC) is partnering with Virginia Diodes Inc (VDI) on the 874-GHz receiver through its Vector Network Analyzer (VNA) extender module product line, to develop an instrument with precision of 0.2 K over 1-second integration and accuracy of 2.0 K or better. IceCube is scheduled to launch to and subsequent release from the International Space Station (ISS) in mid-2016 for nominal operation of 28 plus days. We will present the updated design of the payload and spacecraft systems, as well as the operation concept. We will also show the simulated 874-GHz radiances from the ISS orbits and cloud scattering signals as expected for the IceCube cloud radiometer.

cloud ice remote sensing↗
NASA NTRS1994

Increase of carbonyl fluoride (COF2) in the stratosphere and its contribution to the 1992 budget of inorganic fluorine in the upper stratosphere

Volume mixing ratio profiles of COF2 have been derived through most of the stratosphere between 30 deg N and 54 deg S from series of 0.01-/cm resolution infrared solar spectra recorded in the occultation mode by the atmospheric trace molecule spectroscopy (ATMOS) instrument during the ATLAS 1 space shuttle mission of March-April 1992. When compared with similar results obtained from the ATMOS/Spacelab 3 mission of April-May 1985, the cumulative increase in the burden of COF2 in the middle and upper stratosphere was found to be 67% for that 7-year time interval. By combining a subset of these COF2 results with upper stratospheric concentrations of HF also derived from the ATMOS observations, it was further found that the budget of inorganic fluorine above 35 km altitude increased by (60 +/- 10)% over the 1985-1992 time interval, which corresponds to an average exponential rate of increase of (6.7 +/- 1/1)%/yr, or a linear rate of increase reference to 1985 of (8.5 +/- 1.3)%/yr at the 1 sigma confidence level. The total inorganic F atom volume mixing ratio found in the upper stratosphere for 1985 and 1992 and the increase during this perid mirror the rise in man-made fluorine-bearing compounds at the ground during the early to mid 1980s. This demonstrates the negligible impact of natural sources of fluorine, in particular volcanic activity, on the observed change in F in the upper stratosphere. Implications of the present findings and comparison with model results are discussed.

Zander, R.↗
NASA NTRS1994

Increase of carbonyl fluoride (COF2) in the stratosphere and its contribution to the 1992 budget of inorganic fluorine in the upper stratosphere

Volume mixing ratio profiles of COF2 have been derived through most of the stratosphere between 30 deg N and 54 deg S from series of 0.01-cm(exp -1) resolution infrared solar spectra recorded in the occultation mode by the atmospheric trace molecule spectroscopy (ATMOS) instrument during the ATLAS 1 space shuttle mission of March-April 1992. When compared with similar results obtained from the ATMOS/Spacelab 3 mission of April-May 1985, the cumulative increase in the burden of COF2 in the middle and upper stratosphere was found to be 67% for that 7-year time interval. By combining a subset of these COF2 results with upper stratospheric concentrations of HF also derived from the ATMOS observations, it was further found that the budget of inorganic fluorine above 35 km altitude increased by (60 +/- 10) % over the 1985-1992 time interval, which corresponds to an average exponential rate of increase of(6.7 +/- 1.1) % /yr , or a linear rate of increase referenced to 1985 of (8.5 +/- 1.3) % /yr at the 1(sigma) confidence level. The total inorganic F atom volume mixing ratio found in the upper stratosphere for 1985 and 1992 and the increase during this period mirror the rise in man-made fluorine-bearing compounds at the ground during the early to mid 1980s. This demonstrates the negligible impact of natural sources of fluorine, in particular volcanic activity, on the observed change of F in the upper stratosphere. Implications of the present findings and comparison with model results are discussed.

Zander, R.↗
DOE OSTI2022

In-situ investigation of the vibrational properties of H 2 O CO 2 -bearing and dry K-rich basaltic glasses at high pressure by mid infrared spectroscopy

Here, the vibrational properties of CO 2 –H 2 O-bearing and dry synthetic K-rich basaltic glasses were investigated at room temperature and pressures between 0.0001–5.5 GPa using the diamond anvil cell combined with in situ reflectance and transmittance Fourier Transform infrared micro-spectroscopy. The absorption coefficient a(v) calculated from the Kramers-Kronig relation shows that glasses are dominated by the Q 2 aluminosilicate unit followed by Q 1 , Q 3 . The variation in Q n concentration upon compression suggests that glasses undergo polymerization from ambient pressure to 2 GPa followed by less marked structural changes up to 4 GPa, above which the structure is further polymerized. Once decompressed, glasses retained a polymerized structure. Our results show that 1.03 wt% CO 2 -1.42 wt% H 2 O in a glass with 3.10 wt% K 2 O and 46.77 wt% SiO 2 prevent the formation of fully polymerized connections when cold-compressed. Our results can be used to explain the effect of volatiles and alkali on the rheology of natural basaltic magmas.

36 MATERIALS SCIENCE↗
NASA NTRS1998

Validation of POLDER/ADEOS data using a ground-based lidar network: Preliminary results for semi-transparent and cirrus clouds

At mid and tropical latitudes, cirrus clouds are present more than 50% of the time in satellites observations. Due to their large spatial and temporal coverage, and associated low temperatures, cirrus clouds have a major influence on the Earth-Ocean-Atmosphere energy balance through their effects on the incoming solar radiation and outgoing infrared radiation. At present the impact of cirrus clouds on climate is well recognized but remains to be asserted more precisely, for their optical and radiative properties are not very well known. In order to understand the effects of cirrus clouds on climate, their optical and radiative characteristics of these clouds need to be determined accurately at different scales in different locations i.e. latitude. Lidars are well suited to observe cirrus clouds, they can detect very thin and semi-transparent layers, and retrieve the clouds geometrical properties i.e. altitude and multilayers, as well as radiative properties i.e. optical depth, backscattering phase functions of ice crystals. Moreover the linear depolarization ratio can give information on the ice crystal shape. In addition, the data collected with an airborne version of POLDER (POLarization and Directionality of Earth Reflectances) instrument have shown that bidirectional polarized measurements can provide information on cirrus cloud microphysical properties (crystal shapes, preferred orientation in space). The spaceborne version of POLDER-1 has been flown on ADEOS-1 platform during 8 months (October 96 - June 97), and the next POLDER-2 instrument will be launched in 2000 on ADEOS-2. The POLDER-1 cloud inversion algorithms are currently under validation. For cirrus clouds, a validation based on comparisons between cloud properties retrieved from POLDER-1 data and cloud properties inferred from a ground-based lidar network is currently under consideration. We present the first results of the validation.

Chepfer, H.↗