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NASA NTRS1987

Copper and nickel partitioning in iron meteorites

Trace element analyses using proton induced X-ray emission and synchrotron X-ray fluorescence have been made on metal and troilite from nine iron meteorites representing five geochemical groups. Nickel and copper distribution coefficients D (troilite/metal) vary by factors of 600 and 20, respectively, correlate positively with kamacite bandwidth and correlate negatively with bulk nickel content. Meteorites with bulk Ni of less than 10 percent have Cu-enriched troilite while those with Ni greater than 10 percent have Cu-depleted troilite. Since magmatic evolution and partial melting will produce Cu-enriched troilite only, the observation of Cu-depleted troilite in Ni-rich meteorites is evidence for subsolidus reequilibration, a process which reduces D(Cu) by transfer of Cu to exsolving metal. Elemental redistribution may have played an important role in establishing the present chemical trends in iron meteorites.

Sutton, S. R.↗

NASA NTRS1988

The distribution and significance of evaporitic weathering products on Antarctic meteorites

This paper examines the occurrence of white evaporitic deposits on Antarctic meteorites from the U.S. collection, as a function of meteorite compositional group and weathering category. Evaporites occur with unusual frequency on carbonaceous chondrites. Almost two-thirds of all evaporite-bearing meteorites belong to weathering categories A, A/B, and B. Where chemical data were available, surficial evaporite deposits could be associated with elemental anomalies in meteorite interiors.

Velbel, Michael Anthony↗

NASA NTRS1988

A comparison of Halley dust with meteorites, interplanetary dust and interstellar grains

The variability of the mineral forming elements in the submicron Halley grains provides a powerful basis for comparison of Halley with the different classes of meteoritic materials that have been studied in the lab. The degree of variability in the Halley samples is larger than that seen in chondrites implying that Halley is more heterogeneous at the submicron scale. A critical distinction is that Halley contains abundant pure Mg silicates at the size scale while the carbon rich meteorites do not. The submicron dispersion composition seen in Halley is dramatically different from the narrowly constrained compositions seen in CI and CM (type 1 and 2) carbonaceous chondrites. These meteorites are carbon rich but are dominated by a hydrated silicate with a very narrow range of Mg/Si ratio. The Halley results are also unlike the composition variations seen in most of interplanetary dust types that are dominated by hydrated materials. The only known class of meteoritic material that appear to closely resemble the Halley data is a class of cosmic dust composed entirely of anhydrous minerals. The composition implies that Halley is dominated by olivine, pyroxene, iron sulfide, glass and amorphous carbonaceous matter.

Brownlee, D. E.↗

NASA NTRS1988

Meteorites on Mars

Four types of meteoritic material should be found on Mars: (1) micrometeorites, many of which will survive atmospheric entry unmelted, which should fall relatively uniformly over the planet's surface, (2) ablation products from larger meteorites which ablate, break up and burn up in the Mars atmosphere, (3) debris from large, crater forming objects, which, by analogy to terrestrial and lunar impact events, will be concentrated in the crater ejecta blankets (except for rare, large events, such as the proposed C-T event on earth, which can distribute debris on a planetary scale), and (4) debris from the early, intense bombardment, which, in many areas of the planet, may now be incorporated into rocks by geologic processes subsequent to the intense bombardment era. To estimate the extent of meteoritic addition to indigenous Martian material, the meteoritic flux on Mars must be known. It is estimated that the overall flux is twice that for the Moon and 1.33 that for Earth. For small particles, whose orbital evolution is dominated by Poynting Robertson drag, the flux at Mars can be estimated from the Earth flux. The smaller Martian gravitational enhancement as well as the decrease in the spatial density of interplanetary dust with increasing heliocentric distance should reduce the flux of small particles at Mars to about 0.33 times the flux at Earth. Because of the smaller planetary cross-section the total infalling mass at Mars is then estimated to be 0.09 time the infalling mass in the micrometeorite size range at Earth.

Flynn, G. J.↗

NASA NTRS1988

Volatile/mobile trace elements in meteoritic, non-lunar basalts: Guides to Martian sample contents

A variety of genetic processes on or in extraterrestrial objects can be examined by study of volatile/mobile trace elements. Doubtless, considerable efforts will be expended on determining these elements in returned Martian samples. The purpose is to estimate levels of such elements expected to be present in returned Martian samples. Some ideas about Martian genesis were already advanced from the volatile/mobile element contents in SNC meteorites, assuming that Mars was their parent body. Even is Mars and the SNC meteorite parent body are identical, compositional ranges for returned Martian samples should exceed those of SNC meteorites. It is expected, therefore, that Martian samples returned from locations other than Polar regions will have indigenous volatile/mobile element contents within howardite-diogenite ranges. Elements with strong lithophile tendences may be more abundant, as they are in many lunar samples. Most of these elements should be at ppb levels except for Co, Ga, Zn, and Rb, which should lie at ppm levels. If Martian volcanism was accompanied by fumarolic emanations, it should be reflected in occasional huge enrichments of mobile trance elements, as in lunar meteorite Y 791197. During collection and transport Earthward, samples must be contained under conditions appropriate to ppb concentrations. Materials must be used that will not cause contamination which occurred during the Apollo program, where indium from seals contaminated many samples.

Lipschutz, M. E.↗

NASA NTRS1988

Overview and classification of meteorites

Before interpreting properties of meteorites in terms of putative processes and conditions in the early solar system, it is necessary to understand just what sort of objects meteorites are. Such understanding begins with classification. In this chapter, the current taxonomy of meteorites is summarized, and it is shown how certain stone meteorites, the chondrites, possess chemical and petrographic features that make them potentially attractive as probes of the early solar system. The prevalence of secondary alteration effects, often capable of perturbing the primitive record even in chondrites, is also emphasized.

Sears, Derek W. G.↗

NASA NTRS1988

Asteroids and meteorites

The hypothesis that most meteorites are asteroid fragments generated by comparatively recent collisions in the asteroid belt runs up against spectrophotometric data indicating that asteroids with the composition of the most abundant meteorite class are either rare or absent in the asteroid belt. An understanding of the origin and evolution of the asteroid belt is essential to an adequate interpretation of meteoritic data; conversely, the detailed early asteroidal history preserved in the meteorites provides evidence otherwise unavailable for the earliest history of any other planetary bodies.

Wetherill, George W.↗

NASA NTRS1988

Irradiation records in meteorites

The approximately 4.6 billion-year history of a meteorite will encompass at least one episode of exposure to such energetic particles as cosmic rays; measurements of such exposure allow determination of how long a meteorite existed as a meter-sized body prior to earth impact. Meteorite exposure to energetic particles before their ejection from a parent body entails that the meteorite reside in the upper several m of that parent regolith. At the periods closest to the 4.6 billion year horizon, early solar system conditions may have been characterized by much gas and dust; irradiation records from this period may prove invaluable in reconstructing its characteristics.

Caffee, M. W.↗

NASA NTRS1989

The carbon chemistry of meteorites: Relationships to comets

The carbonaceous meteorites exhibiting alteration by liquid water bear a strong relationship to comets. Not only is their elemental composition closer to solar in relative abundances than other meteorites, they are water rich; and they contain isotopic compositions among refractory and volatile elements indicative of presolar components. Some of these isotopic anomalies occur in organic compounds and carbonaceous grains signifying the presence of discrete and identifiable carbon components derived from interstellar and circumstellar matter. Insofar as comets and meteorites are ultimately formed from interstellar gas and dust, and comets have been subjected to considerably less aqueous and thermal evolution than carbonaceous meteorites, the interstellar imprint should be much stronger and better preserved in comets.

Chang, S.↗

NASA NTRS1990

Carbon in primitive meteorites

No meteorites are truly primitive, in the sense of being pristine collections of interstellar grains or solar-nebular condensates. Nonetheless, some chrondritic meteorites have been so little altered by secondary processing that they are commonly termed primitive and it is almost a definition of such chondrites that they contain significant quantities of carbon. Most of that carbon is of apparently local, i.e., solar-system, origin but a proportion that ranges from trace, in some cases, to minor, in others, is believed to be exotic, i.e., of circumstellar or interstellar origin, and it is upon such material that researchers focus here. The nature of the meteoritic samples and the techniques used to analyse them are briefly discussed and the observational record is surveyed. Clearly, the study of exotic carbon preserved in meteorites has been informative about sites of nucleosynthesis, processes of nucleation and growth of grains in stellar outflows, grain survival in the interstellar medium, and many other topics of astrophysical significance. Much more work, particularly of an interdisciplinary nature remains to be done, however.

Kerridge, John F.↗

NASA NTRS1990

An assessment of the meteoritic contribution to the Martian soil

The flux of meteoritic material at Mars was assessed and the perturbations to the indigenous soil produced by the addition of meteoritic material to the Martian soil was determined. Using the measured mass influx at earth and the estimates of the Mars/earth flux ratio, the planet-wide mateoritic mass influx on Mars was found to be between 2700 and 59,000 t/yr. Assuming a uniform distribution into a soil with a mean planetary production rate of 1 m/b.y., it is estimated that this mass influx would produce a meteoritic concentration in the Mars soil ranging from 2 to 29 percent by mass. Experimental measurements which a Mars lander spacecraft could make to determine the fraction of meteoritic material in the soils are suggested.

Flynn, George J.↗

NASA NTRS1991

Stable hydrogen and carbon isotope ratios of extractable hydrocarbons in the Murchison meteorite

A fairly fool-proof method to ensure that the compounds isolated from meteorites are truly part of the meteorites and not an artifact introduced by exposure to the terrestrial environment, storage, or handling is presented. The stable carbon and hydrogen isotope ratios in several of the chemical compounds extracted from the Murchison meteorite were measured. The results obtained by studying the amino acids in this meteorite gave very unusual hydrogen and carbon isotope ratios. The technique was extended to the different classes of hydrocarbons and the hydrocarbons were isolated using a variety of separation techniques. The results and methods used in this investigation are described in this two page paper.

Krishnamurthy, R. V.↗

NASA NTRS1991

Midinfrared (2.5-13.5 microns) reflectance spectra of powdered stony meteorites

Asteroid spectral measurements are presently approached via comparisons with reflectance spectra from 60 powdered meteorite samples representing 50 different meteorites. While the powdered meteorites have undergone alteration by exposure to water vapor and by hydrocarbon contamination characterized by absorption bands near 3.45 microns, they retain various other spectral features which render them useful for identification. While these features can be used independently to ascertain mineralogy and meteorite type, the use of the entire spectrum in a digital search library is preferred for successful identification.

Salisbury, John W.↗

NASA NTRS1991

Clay minerals in primitive meteorites and interplanetary dust 1

Many meteorites and interplanetary dust particles (IDPs) with primitive compositions contain significant amounts of phyllosilicate minerals, which are generally interpreted as evidence of protoplanetary aqueous alteration at an early period of the solar system. These meteorites are chondrites (near solar composition) of the carbonaceous and ordinary varieties. The former are subdivided (according to bulk composition and petrology) into CI, CM, CV, CO, CR, and ungrouped classes. IDPs are extraterrestrial particulates, collected in stratosphere, which have chemical compositions indicative of a primitive origin; they are typically distinct from the primitive meteorites. Characterization of phyllosilicates in these materials is a high priority because of the important physico-chemical information they hold. The most common phyllosilicates present in chondritic extraterrestrial materials are serpentine-group minerals, smectites, and micas. We discuss these phyllosilicates and describe the interpretation of their occurrence in meteorites and IDPs and what this indicates about history of their parent bodies, which are probably the hydrous asteroids.

Zolensky, M. E.↗

NASA NTRS1991

Abstracts for the 54th Annual Meeting of the Meteoritical Society

Abstracts of the papers presented at 54th Annual Meeting of the Meteoritic Society are compiled. The following subject areas are covered: Antarctic meteorites; nebula and parent body processing; primary and secondary SNC parent planet processes; enstatite chondrites and aubrites; achondrite stew; refractory inclusions; meteorite exposure ages and sizes; interstellar/meteorite connections; lunar origins, processes and meteorites; craters, cratering and tektites; cretaceous-tertiary impact(s); IDPs (LDEF, stratosphere, Greenland and Antarctica); chondrules; and chondrites.

Source record↗

NASA NTRS1991

Extraterrestrial water of possible Martian origin in SNC meteorites: Constraints from oxygen isotopes

Many lines of evidence suggest that the SNC group of meteorites (Shergotty-Nakhla-Chassigny) are derived from the planet Mars. Because SNC meteorites have water, they may contain information on the origin and fate of water on the planet Mars. The first measurements are presented of delta O-18 and delta O-17 of water extracted from SNC's. The water analyses are displayed with each meteorite designated. The isotopic composition is shown of the SNC waters relative to the SNC whole rocks and the terrestrial line. The O-17 excess is shown of the SNC water as a function of pyrolysis temperature. And delta O-18 values are displayed of the water as a function of pyrolysis temperature for the four SNC meteorites. The analyses are briefly examined.

Karlsson, H. R.↗

NASA NTRS1992

The meteoritic contribution to dust and aerosols in the atmosphere of Mars

The continuous, planet-wide accretion of meteoritic material onto the Earth and Moon has been established by stratospheric sampling on Earth and chemical abundance analysis of the lunar soils. Meteoritic material must contribute in a similar manner to the atmospheres of all the planets and moons of the inner solar system. Although meteorites that survive planetary entry unmelted are the primary contributors, secondary contributions come from: (1) recondensed vapor in meteorite trails; and (2) fragmentation debris from low density meteoroids. These three contributions provide a constant planet-wide source of atmospheric particulates on Mars. In the size range greater than 1 micro-m in diameter micrometeorites which survive atmospheric entry unmelted are the major contributor, accounting for about 8.6 x 10(exp 6) kg/year of material. For particles less than 1 micro-m in diameter the majority of the mass is likely to come from recondensed meteoric vapor, which could account for approx. 2 x 10(exp 6) kg/year.

Flynn, G. J.↗

NASA NTRS1991

A ferroan region of the lunar highlands as recorded in meteorites MAC88104 and MAC88105

MAC88104 and 88105, paired meteorites of noritic anorthosite composition, are examined. Results indicate that these meteorites contain a variety of materials including impact-melt breccias, igneous and metamorphosed bressia clasts, glass clasts and veins, mineral clasts, and extralunar meteoritic debris. Compositions of the bulk meteorite and its components suggest that it came from a region of the moon's crust that was highly aluminous, low in incompatible trace elements, and ferroan in character.

Jolliff, Bradley L.↗