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At least 379 records · Page 21

Bio-markers and the search for extinct life on Mars

In order to predict what biomarkers could be used on Mars, several biomarkers, or key signatures, of extinct life on earth are identified. Some of these biomarkers which may be applicable to Mars include reduced carbon and nitrogen compounds, CO3(2-), SO4(2-), NO3(-), Mg, Mn, Fe, and the isotopic ratios of C, N, and S. It is suggested that a fully equipped Mars rover might be able to perform analyses to measure most of these biomarkers while on the Martian surface.

Schwartz, D. E.↗

Cosmogenic helium and volatile-rich fluid in Sierra Leone alluvial diamonds

Noble gas measurements were carried out on two identical splits of a finely powdered harshly acid-washed sample derived from fragments of a single alluvial diamond from Sierra Leone, with essentially identical results obtained for both splits. Isotopic ratios for Ar, Kr, and Xe were found to be atmospheric. Their elemental abundances were high relative to published data, owing to the effect of shock implantation in the crushing step, as was verified in a supplementary experiment. No Ne was detected above the blank level. The He-3 was exceptionally abundant, while He-4 was exceptionally depleted, possibly due to the acid wash. The He-3/He-4 ratio was anomalously high at an R/Ra value of 246 + or - 16. The results support the hypothesis that the He-3 excess in diamonds is cosmogenic.

Mcconville, P.↗

Oxygen and hydrogen isotope geochemistry of zeolites

Oxygen and hydrogen isotope ratios for natural samples of the zeolites analcime, chabazite, clinoptilolite, laumontite, mordenite, and natrolite have been obtained. The zeolite samples were classified into sedimentary, hydrothermal, and igneous groups. The ratios for each species of zeolite are reported. The results are used to discuss the origin of channel water, the role of zeolites in water-rock interaction, and the possibility that a calibrated zeolite could be used as a low-temperature geothermometer.

Karlsson, Haraldur R.↗

Instellar Gas Experiment (IGE): Testing interstellar gas particles to provide information on the processes of nucleosynthesis in the big bang stars and supernova

The Interstellar Gas Experiment (IGE) is designed to collect particles of the interstellar gas - a wind of interstellar media particles moving in the vicinity of the solar system. These particles will be returned to earth where the isotopic ratios of the noble gases among these particles will be measured. IGE was designed and programmed to expose 7 sets of six copper-beryllium metallic collecting foils to the flux of neutral interstellar gas particles which penetrate the heliosphere to the vicinity of the earth's orbit. These particles are trapped in the collecting foils and will be returned to earth for mass-spectrographic analysis when Long Duration Exposure Facility (LDEF) on which IGE was launched, is recovered.

Lind, Don↗

The Interstellar Gas Experiment (IGE)

The Interstellar Gas Experiment (IGE) exposed thin metallic foils in order to collect neutral particles from the interstellar gas. These particles were entrapped in the foils along with precipitating magnetospheric and ambient atmospheric particles. Seven of these foils collected particles arriving from seven different directions as seen from the spacecraft for the entire duration of the Long Duration Exposure Facility (LDEF) mission. The authors' mass spectroscopy analysis of the noble gas component of these interstellar particles detected isotopes of helium and neon. These preliminary measurements suggest that the various isotopes are occurring in approximately the expected amounts and that their distribution in direction of arrival is close to what models predict. The analysis to subtract the background fluxes of magnetospheric and atmospheric particles is still in progress. The hope of this experiment is to investigate the noble gas isotopic ratios of this interstellar sample of matter which originated outside the solar system.

Lind, Don↗

The Olton, Texas, H chondrite regolith breccia - Paired with Dimmitt

The Olton ordinary chondrites (two stones found in 1948) are H group, solar wind-bearing regolith breccias. The proximity of the recovery site to the Dimmitt strewnfield, and the similarity in texture, composition, noble gas contents and isotopic ratios to Dimmitt indicate that Olton is paired with Dimmitt.

Keil, Klaus↗

Helium and neon isotopes in stratospheric particles

He and Ne isotope ratios were determined for 16 interplanetary dust particles (IDPs) collected in the stratosphere. The observed He concentration varied greatly from particle to particle, with the highest values approaching those found for lunar surface fines and some gas-rich meteorites. The average Ne-20/Ne-22 ratio was 12.0 + or - 0.5. The data suggest that the observed IDPs could have entered the atmosphere at relatively low velocities, and hence may be primarily of asteroidal rather than cometary origin.

Nier, A. O.↗

Isotopic analysis of cometary organic matter

Carbon isotope ratios have been measured for CN in the coma of Comet Halley and for several CHON particles emitted by Halley. Of these, only the CHON-particle data may be reasonably related to organic matter in the cometary nucleus, but the true range of (C-13)/(C-12) values in those particles is quite uncertain. The D/H ratio in H2O in the Halley coma resembles that in Titan/Uranus.

Kerridge, John F.↗

Identification and characterization of extraterrestrial non-chondritic interplanetary dust

Interplanetary dust particles (IDPs) are among the most pristine and primitive extraterrestrial materials available for direct study. Most of the stratospheric particles selected for study from the JSC Curatorial Collection were chondritic in composition (major element abundances within a factor of two of chondritic meteorites) because this composition virtually ensures that the particle is from an extraterrestrial source. It is likely that some of the most interesting classes of IDP's have not been recognized simply because they are not chondritic or do not fit established criteria for extraterrestrial origin. Indeed, mass spectroscopy data from the Giotto Flyby of comet Halley indicate that a substantial fraction of the dust is in the submicron size range and that a majority of these particles contain C, H, O, and/or N as major elements. The preponderance of CHON particles in the coma of Halley implies that similar particles may exist in the JSC stratospheric dust collection. However, the JSC collection also contains a variety of stratospheric contaminants from terrestrial sources which have these same characteristics. Because established criteria for extraterrestrial origin may not apply to such particles in individual cases, and integrated approach is required in which a variety of analysis techniques are applied to the same particle. Non-chondritic IDP's, like their chondritic counterparts, can be used to elucidate pre- and early solar system processes and conditions. The study of non-chondritic IDP's may additionally yield unique information which bears on the nature of cometary bodies and the processing of carbonaceous and other low atomic number materials. A suite of complementary techniques, including Low Voltage Scanning Electron Microscopy (LVSEM), Energy-Dispersive X-ray Microanalysis (EDX), Secondary Ion Mass Spectrometry (SIMS) isotope-ratio imaging and Analytical Electron Microscopy (AEM), were utilized to accomplish the following two objectives: (1) to develop criteria for the unequivocal identification of extraterrestrial non-chondritic IDP's; and (2) to infer IDP parent body, solar nebula, and pre-solar conditions through the study of phases, textures, and components contained within non-chondritic IDP's. The general approach taken is designed to maximize the total information obtained from each particle. Techniques will be applied in order from least destructive to most destructive.

Blake, D. F.↗

Galileo Probe Mass Spectrometer experiment

The chemical and isotopic composition of the Jupiter atmosphere's constituents, including their vertical variations, will be measured by the Galileo Probe Mass Spectrometer instrument through in situ sampling; batch sampling will also be undertaken for noble gas composition and isotopic ratio determinations. The instrument's gas-sampling system is connected to a quadrupole mass analyzer for molecular weight analysis. Threshold values are lowered through sample enrichment by a factor of 100-500 for stable hydrocarbons and by a factor of 10 for noble gases. The instrument follows a sampling sequence of 8192 steps, at a rate of 2 steps/sec.

Niemann, H. B.↗

Pre- and main-sequence evolution of solar activity

The magnetic activity on single solarlike stars declines with stellar age. This has important consequences for the influence of the sun on the early solar system. What is meant by stellar activity, and how it is measured, is reviewed. Stellar activity on the premain-sequence phase of evolution is discussed; the classical T Tauri stars do not exhibit solarlike activity, while the naked T Tauri stars do. The emission surface fluxes of the naked T Tauri stars are similar to those of the youngest main-sequence G stars. The best representation for solarlike stars is a decay proportional to exp(A x t exp 0.5), where A is a function of line excitation temperature. From these decay laws, one can determine the interdependences of the activity, age, and rotation periods. The fluxes of ionizing photons at the earth early in its history are discussed; there was sufficient fluence to account for the observed isotopic ratios of the noble gases.

Walter, Frederick M.↗

The Interstellar Gas Experiment: Analysis in progress

The Interstellar Gas Experiment (IGE) exposed thin metallic foils aboard the LDEF spacecraft in low Earth orbit in order to collect neutral interstellar particles which penetrate the solar system due to their motion relative to the sun. By mechanical penetration these atoms were imbedded in the collecting foils along with precipitating magnetospheric ions and, possibly, with ambient atmospheric atoms. During the entire LDEF mission, seven of these foils collected particles arriving from seven different directions as seen from the spacecraft. After the foils were returned to Earth, a mass spectrometric analysis of the noble gas component of the trapped particles was begun. The isotopes of He-3, He-4, Ne-20, and Ne-22 were detected. We have given a first account of the experiment. In order to infer the isotopic ratios in the interstellar medium from the concentrations found in the foils, several lines of investigation had to be initiated. The flux of ambient atmospheric noble gas atoms moving toward the foils due to the orbital motion of LDEF was estimated by detailed calculations. Any of these particles which evaded the baffles in the IGE collector could be entrapped in the foils as a background flux. However, the calculations have shown that this flux is negligible, which was the intent of the experiment hardware design. This conclusion is supported by the measurements. However, both the concentration of trapped helium and its impact energy indicate that the flux of magnetospheric ions which was captured was larger than had been expected. In fact, it appears that the magnetospheric particles constitute the largest fraction of the particles in the foils. Since little is known about this particle flux, their presence in the IGE foils appears fortunate. The analysis of these particles provides information about their isotropic composition and average flux.

Buehler, F.↗

On the weathering of Martian igneous rocks

Besides the young crystallization age, one of the first arguments for the martian origin of shergottite, nakhlite, and chassignite (SNC) meteorites came from the chemical similarity of the meteorite Shergotty and the martian soil as measured by Viking XRF analyses. In the meantime, the discovery of trapped rare gas and nitrogen components with element and isotope ratios closely matching the highly characteristic ratios of the Mars atmosphere in the shock glasses of shergottite EETA79001 was further striking evidence that the SNC's are martian surface rocks. The martian soil composition as derived from the Viking mission, with its extremely high S and Cl concentrations, was interpreted as weathering products of mafic igneous rocks. The low SiO2 content and the low abundance of K and other trace elements in the martian soils point to a mafic crust with a considerably smaller degree of fractionation compared to the terrestrial crust. However, the chemical evolution of the martian regolith and soil in respect to surface reaction with the planetary atmosphere or hydrosphere is poorly understood. A critical point in this respect is that the geochemical evidence as derived from the SNC meteorites suggests that Mars is a very dry planet that should have lost almost all its initially large water inventory during its accretion.

Dreibus, G.↗

Comets in the post-Halley era. Vols. 1 & 2

The present volume on comets in the post-Halley era discusses observing techniques and intepretation, laboratory studies and simulations, the origin and evolution of comets, the cometary nucleus and coma, cometary dust, and plasmas and fields. Attention is given to IR techniques for comet observations, UV spectroscopy of cometary comae, radio interferometric imaging of comets, and irradiation effects on comets and cometary debris. Topics addressed include laboratory simulation of cometary structures, chemical theories on the origin of comets, biological implications of organic compounds in comets, the dynamic history of the Oort cloud, and physical aspects of the evolution of cometary debris. Also discussed are possible mechanisms of cometary outbursts, isotopic ratios in comets, the hydrogen clouds of comets, and physical and optical properties of cometary dust.

Newburn, R. L., Jr.↗

Post-eruptive alteration of silicic ignimbrites and lavas, Gran Canaria, Canary Islands - Strontium, neodymium, lead, and oxygen isotopic evidence

The isotopic composition of lavas from oceanic islands provides important information about the composition and evolution of the earth's mantle. Isotopic analyses of Miocene comenditic, pantelleritic, and trachyphonolitic ignimbrites and lavas from the Canary islands were performed. Results provide evidence for posteruptive mobility of Rb and Sr during low temperature postemplacement interaction with circulating ground water. Calculated Sr isotope ratios define a magmatic trend in the stratigraph section. 87Sr/86Sr ratios in hydrated vitrophyte and devitrified matrix separates indicate significant posteruptive interaction with meteoric water starting soon after deposition. This process extends patchily through the entire pyroclastic flow and may be ongoing. 87Sr/86Sr ratios determined by whole rock analysis of silicic rocks from oceanic islands are suspect and should not be incorporated into mantle tracer studies. Anorthoclase phenocrysts are resistant to these processes and may produce useful data.

Cousens, Brian L.↗

Osmium isotopes in Ivory Coast tektites: Confirmation of a meteoritic component and rhenium depletion

The sensitive negative thermal ionization mass spectrometry method was used for the measurement of concentrations and isotopic ratios of osmium and rhenium in four Ivory Coast tektites. These tektites have crustal major and trace element composition, as well as large negative epsilon(sub Nd)(-20) and positive epsilon(sub Sr)(+260 to +300) which are characteristic for old continental crust. Os concentrations ranging from 0.09 to 0.30 ppb were found, clearly much higher than average crustal values, Os-187/Os-186 ratios of about 1.2-1.7, and low Re-187/Os-186 ratios. These results show unambiguously the existence of a meteoritic component (on the order of 0.06%) in the Ivory Coast tektites. Low Re abundances are the result of fractionation of Re during the impact.

Koeberl, Christian↗

CO2 production by impact in carbonates? An ATEM and stable isotope (C,O) study

Carbonates may have been a common target for large impacts on the Earth and possible related CO2 outgassing would have important consequences for the composition of the atmosphere. To estimate volatile release during such impacts, isotopic ratios (C-13/C-12 and O-18/O-16) were determined on highly shocked carbonate samples in combination with SEM and analytical transmission electron microscopy (ATEM) investigations. The study was performed on both naturally and experimentally shocked rocks, i.e. 50-60 GPa shocked limestone-dolomite fragments from the Haughton impact crater (Canada), and carbonates shocked in shock recovery experiments. For the experiments, unshocked carbonates consisting of mixture of dolomite and calcite from the Haughton area were used. Naturally shocked samples were collected in the polymict breccia near the center of the Haughton crater.

Martinez, I.↗

Workshop on Early Mars: How Warm and How Wet?, part 1

This volume contains papers that have been accepted for presentation at the Workshop on Early Mars: How Warm and How Wet?, 26-28 Jul. 1993, in Breckenridge, CO. The following topics are covered: the Martian water cycle; Martian paleoclimatology; CO2/CH4 atmosphere on early Mars; Noachian hydrology; early Martian environment; Martian weathering; nitrogen isotope ratios; CO2 evolution on Mars; and climate change.

Squyres, S.↗