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Demonstration of Electrolyzer Operation at a Nuclear Plant to Allow for Dynamic Participation in an Organized Electricity Market and In-House Hydrogen Supply

This document details the execution of Cooperative Agreement DE-EE0008849, “demonstration of electrolyzer operation at a nuclear plant to allow for dynamic participation in an organized electricity market and in-house hydrogen supply” during the performance period of 10/1/2019 – 9/30/2024. The project was funded by the U.S. Department of Energy’s Office of Energy Efficiency and Renewable Energy (EERE). Constellation Energy Generation, LLC (formerly Exelon Generation Company, LLC) is the prime recipient of the award. Other members of the project team are INL, NREL, ANL and Nel Hydrogen. The main project objective was to demonstrate an end-to-end integrated grid-scale carbon-free H 2 production, storage and utilization pilot plant at a nuclear generating facility. The project also aimed to evaluate market opportunities and regulatory requirements related to the participation of integrated hydrogen production and nuclear plant facilities in organized power markets, by demonstrating dynamic control and operation of the electrolyzer and assessing the economics of dynamic participation combined with the revenue streams from hydrogen production. On March 7th , 2023 Constellation started hydrogen production at it’s Nine Mile Point Nuclear Plant in Oswego, New York. The PEM electrolyzer operating at Nine Mile Point uses 1.25 megawatt of nuclear electricity to produce 560 kilograms of clean hydrogen per day, more than enough to meet the plant’s operational hydrogen use. It will also help set the stage for possible large-scale deployments at other clean energy centers in Constellation’s fleet that would couple clean hydrogen production with storage and other on-site uses. Employing the lessons learned from the 1.25 MW demonstration-scale, nuclear-powered clean hydrogen production facility at Nine Mile Point, Constellation was a major participant in the MachH2 hydrogen hub recently selected for up to $\$$1 billion by the Department of Energy (DOE) as part of the bipartisan Infrastructure Investment and Jobs Act. Constellation will use a portion of the hub funding to build the world’s largest nuclear-powered clean hydrogen production facility at its LaSalle Clean Energy Center in Illinois. The project was featured in a number of news articles and press releases and received 2 awards. At the 2023 DOE HFTO’s Annual Merit Review meeting, the P.I. Dr. Uuganbayar Otgonbaatar and project manager Robert Beaumont were recognized for “outstanding achievements in the development and demonstration of a first-of-a-kind clean hydrogen production facility, powered by carbon-free nuclear energy, at the Nine Mile Point Nuclear Station in Oswego, New York.” The project was also awarded 2023 Nuclear Energy Institute’s Top Innovative Practice award.

08 HYDROGEN

Beam Performance of the Positron Transport Line for CEBAF Positron Upgrade

The Low Energy Recirculator Facility (LERF) at Jefferson Lab, formerly operated for the Free-Electron Laser program, has been proposed as the injector complex for the planned 12 GeV CEBAF positron upgrade (Ce+BAF), with an additional pathway to support a potential 22 GeV CEBAF electron upgrade. In this configuration, LERF would generate and pre-accelerate positrons to 123 MeV, matching the present injection energy into the North Linac. Due to the relatively large emittance expected from the positron source, a comprehensive acceptance study has been performed from LERF through the CEBAF recirculating linacs and beam transport lines to the experimental halls. The objective is to establish the positron phase-space acceptance and provide design feedback to the positron production and capture systems. Furthermore, given CEBAF’s capability to deliver highly polarized beams, spin-tracking simulations have been carried out including magnet imperfections, alignment errors, and synchrotron-radiation–induced energy spread. Particular attention is given to the evolution of the spin tune and the corresponding depolarization mechanisms along the beam delivery path, especially for providing longitudinal polarization at the experimental halls. These results inform injector design choices and assess the overall feasibility of delivering high-polarization positron beams in CEBAF.

Ogur, S. [Thomas Jefferson National Accelerator Fa

Indoor Air Quality (IAQ) Monitoring for Space Farming Institute [Slides]

Through the U.S. Department of Energy's Energy to Communities (E2C) program, NREL, other national laboratory experts, and select organizations provide Expert Match - free, short-term technical assistance to address near-term energy challenges and questions. Expert Match is for community stakeholders who have decision-making power or influence in their community but need access to additional energy expertise to inform key upcoming decisions. This Expert Match request supported the Space Farming Institute, a nonprofit organization located in Anchorage, AK, with an indoor air quality analysis. The NREL team analyzed indoor air quality data provided by the Space Farming Institute, which experts at PNNL used to design an indoor bioreactor to grow Ulva algae for indoor air quality mitigation purposes.

29 ENERGY PLANNING, POLICY, AND ECONOMY

Optimizing Fleet Operations With Telematics [Slides]

Through the U.S. Department of Energy's Energy to Communities (E2C) program, NLR, other national laboratory experts, and select organizations provide Expert Match - free, short-term technical assistance to address near-term energy challenges and questions. Expert Match is for community stakeholders who have decision-making power or influence in their community but need access to additional energy expertise to inform key upcoming decisions. This Expert Match request supported Prince William County, VA with information about fleet charging and telematics.

29 ENERGY PLANNING, POLICY, AND ECONOMY

Energy to Communities Program Short Introduction: Evaluation of Enhanced Geothermal System for Cornell District Heating [Slides]

Through the U.S. Department of Energy's Energy to Communities (E2C) program, NLR, other national laboratory experts, and select organizations provide Expert Match - free, short-term technical assistance to address near-term energy challenges and questions. Expert Match is for community stakeholders who have decision-making power or influence in their community but need access to additional energy expertise to inform key upcoming decisions. This Expert Match request supported Cornell University (Itaca, NY) community efforts in developing Enhanced Geothermal System (EGS) reservoir performance, by simulating fracture flow to estimate pressure drop, flow distribution, and heat extraction efficiency in fractured rock. Thermal drawdown modeling was used to assess long-term resource sustainability, while system optimization studies refined key parameters such as well configuration and flow rate to improve overall reservoir efficiency.

15 GEOTHERMAL ENERGY

Mobility Hubs: Workforce Landscape Assessment, Development Opportunities, and Local Transportation Planning

Through the U.S. Department of Energy's Energy to Communities (E2C) program, NLR, other national laboratory experts, and select organizations provide Expert Match - free, short-term technical assistance to address near-term energy challenges and questions. Expert Match is for community stakeholders who have decision-making power or influence in their community but need access to additional energy expertise to inform key upcoming decisions. This Expert Match request supported Equticity in Chicago, IL with an analysis workforce development considerations and opportunities and is intended to support decision-making on micromobility initiatives.

33 ADVANCED PROPULSION SYSTEMS

Techno-Economic Analysis of Distributed Energy Generation in Crow Creek, Alaska

Through the U.S. Department of Energy's Energy to Communities (E2C) program, NLR, other national laboratory experts, and select organizations provide Expert Match - free, short-term technical assistance to address near-term energy challenges and questions. Expert Match is for community stakeholders who have decision-making power or influence in their community but need access to additional energy expertise to inform key upcoming decisions. This Expert Match request supported Crow Creek in Girdwood, AK with a feasibility analysis for a microgrid to provide year-round power across the community.

24 POWER TRANSMISSION AND DISTRIBUTION

Excited electronic states of Na 2 and K 2 : The potential for long-lived “reservoir” states leading to collision induced population inversions

Potential energy curves (PECs) for the spin-free (ΛS) and spin–orbit (Ω) states associated with the four lowest-lying dissociation channels of Na 2 and K 2 were calculated at the SA-CASSCF/SO-CASPT2/aug-cc-pwCVQZ-DK level. The PECs of Na 2 were consistent with the experimental data and with the FS-CCSD (2,0) calculations, reproducing the double-well and the “shelf” character for some of the potentials of the excited states. For K 2 , the PECs behaved in a similar way and the spectroscopic parameters for the ground and the excited states are in good agreement with the available experimental values. The dissociation energy of K 2 was predicted to be D e = 4454 cm −1 , within an agreement of 5 cm −1 with the experiments. For Na 2 , D e = 5789 cm −1 compared to the experimental value of 6022 cm −1 . The inclusion of spin–orbit coupling effects resulted in avoided crossings, which affect the PECs. Spin–orbit changes the predicted curves for some excited Ω states arising from ΛS states that overlap each other, affecting their associated vibrational frequencies and bond distances. Here, the current studies of the low-lying states in K 2 reveal a similar structure to those of Na 2 , which suggests the accessibility of long-lived energy storing reservoir states and possible population inversions in K 2 following prior experimental work on the reaction of halogen atoms with Na 3 to produce excited states of Na 2 .

Ab-initio methods

Plasma-wakefield accelerator simultaneously boosts electron beam energy and brightness

High-energy particle colliders and X-ray free-electron lasers demand electron beams with qualities currently achieved only in kilometer-scale radio-frequency accelerators. Plasma accelerators promise a compact alternative but have faced challenges in delivering the needed beam quality at relevant energies. Here, we demonstrate that a plasma-wakefield accelerator operating in the nonlinear regime acts as a transformer to simultaneously boost the energy and brightness of an electron bunch injected from the plasma. Using a 10-GeV drive bunch and a three-stage meter-scale plasma source, we generated electron bunches exceeding 20 GeV with sub-percent energy spread, 2 mm·mrad normalized emittance, and multi-kA peak current. A significant number of drive-bunch electrons lost over 90% of their energy, a prerequisite for high energy-conversion efficiency. This demonstration of an energy transformer ratio exceeding two and a brightness enhancement over an order of magnitude opens a path towards cost-effective accelerators for future colliders and light sources.

experimental particle physics

Development of an Energy-Efficient and High-Productivity Ammonia Recovery and Removal Process Using Resin-Wafer Electrodeionization

As efforts to develop various energy resources, ammonia energy is emerging as a promising carbon-free fuel alternative. Recovering high-concentration ammonia and ammonium from wastewater potentially offers significant environmental and economic benefits. However, research on recovery technologies for industries such as semiconductors remains limited. This study develops an efficient, energy-saving ammonia recovery technology using Resin Wafer Electrodeionization (RW-EDI), specifically for the semiconductor industry. RW-EDI shows promise for recovering ammonia from high-concentration wastewater. By optimizing parameters, such as voltage and initial concentration, a balance between productivity and energy consumption is achieved. Results indicate that ammonium and fluoride ion transport kinetics are similar, with minimal competition and selectivity values between 0.95 and 1.08. As the initial ammonia/ammonium concentration increases from 500 to 8000 ppm, reaction rate constants and the overall mass transfer coefficient decrease. Increasing the voltage can enhance mass transfer and eliminate barriers. Ion transport primarily occurs in the RW solid phase, accounting for 93.89% of the total current. Additionally, RW-EDI shows superior specific energy consumption within a concentration range of 500 ppm to 8000 ppm, outperforming technologies like electrodialysis by reducing specific energy consumption from 8−15 kWh/kg-NH 4 + to 1.2−2.5 kWh/kg-NH 4 + . This study highlights RW-EDI’s potential for ammonia recovery, providing valuable insights for future applications in wastewater treatment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Nonperturbative Lorentz violation and field quantization

Regimes of Lorentz-violating effective field theories are studied in which departures from Lorentz symmetry are nonperturbative. Within a free toy theory exhibiting Lorentz breakdown involving an operator of mass dimension three, it is shown that conventional methods suffice to achieve field quantization and Fock-space construction. However, the absence of an observer-invariant energy-positivity condition requires physical input beyond the free theory for the unambiguous identification of a ground state. An investigation of the role of thermodynamics in this context is instigated.

Ground state

National Energy Water Treatment & Speciation (NEWTS): A Water & Critical Mineral Database and Dashboard

The scarcity of water resources, the need for beneficial water reuse, and the challenges of wastewater treatment are becoming increasingly pressing in economic, social, and environmental domains. Addressing these concerns requires effective treatment strategies to manage wastewater streams and tackle environmental and economic issues. Furthermore, the recovery of critical minerals from the waste streams associated with energy production holds the promise of offsetting treatment costs and securing local sources of valuable minerals. However, relevant data on these waste streams are dispersed and challenging to locate. The process of ingesting such data into modeling software often involves multiple steps, requiring data restructuring to meet software-input requirements. The non-standardized reporting of water data makes data aggregation and reformatting a time-consuming process. Additionally, essential attributes necessary for modeling water treatment and mineral scale formation are frequently missing. Moreover, data gaps vary depending on the region of interest. Consequently, there is a pressing need for high-quality energy-water composition data that can be easily imported into water chemistry modeling software. To address this need, the National Energy Technology Laboratory has created the National Energy Water Treatment and Speciation (NEWTS) Database and Dashboard—a free online tool catering to community leaders and water researchers. NEWTS facilitates a comprehensive understanding of the composition of energy-related wastewater streams in the United States. The datasets provide detailed concentrations and speciation of major and minor aqueous compounds in energy-related wastewater streams, including power plant leachate, acid mine drainage, brackish water, and oil and gas produced water across the United States. Many of the aqueous species are critical minerals (Li, REEs) in high demand to modernize the world’s energy infrastructure. Many of the datasets also contain volumetric flow-rates needed to model the treatment and reuse scenarios in advanced aqueous chemistry software programs. The NEWTS Database and Dashboard offer public access to hitherto challenging-to-access datasets, presented in a standardized format that is tailored for easy input into aqueous chemistry modeling software. By performing the work needed to transform dispersed, disparate data sources into unified, model-ready datasets, NEWTS serves as an essential resource in advancing water treatment research and sustainable water resource management.

produced water management

Nanoscale Free-Electron Lasing (Final Technical Report)

Optical control of electron dynamics and energy structure can be leveraged for tailoring classical and quantum light sources. Previous work was primarily limited to Transmission Electron Microscopes (TEMs). Our work under this program sought to enable full time and energy control of electrons in SEMs for exploring the physics of attosecond electron dynamics and light generation at the nanoscale. The motivation behind this work was to understand these fundamental processes important to free-electron lasing at the nanoscale using sub-relativistic electrons.

42 ENGINEERING

Carbon-conserving bioproduction of malate in an E. coli -based cell-free system

Formate, a biologically accessible form of CO 2 , has attracted interest as a renewable feedstock for bioproduction. However, approaches are needed to investigate efficient routes for biological formate assimilation due to its toxicity and limited utilization by microorganisms. Cell-free systems hold promise due to their potential for efficient use of carbon and energy sources and compatibility with diverse feedstocks. However, bioproduction using purified cell-free systems is limited by costly enzyme purification, whereas lysate-based systems must overcome loss of flux to background reactions in the cell extract. Here, we engineer an E. coli-based system for an eight-enzyme pathway from DNA and incorporate strategies to regenerate cofactors and minimize loss of flux through background reactions. We produce the industrial di-acid malate from glycine, bicarbonate, and formate by engineering the carbon-conserving reductive TCA and formate assimilation pathways. We show that in situ regeneration of NADH drives metabolic flux towards malate, improving titer by 15-fold. Background reactions can also be reduced 6-fold by diluting the lysate following expression and introducing chemical inhibitors of competing reactions. Together, these results establish a carbon-conserving, lysate-based cell-free platform for malate production, producing 64 μM malate after 8 h. This system conserves 43 % of carbon otherwise lost as CO 2 through the TCA cycle and incorporates 0.13 mol CO 2 equivalents/mol glycine fed. Finally, techno-economic analysis of cell-free malate production from formate revealed that the high cost of lysate is a key challenge to the economic feasibility of the process, even assuming efficient cofactor recycling. This work demonstrates the capabilities of cell-free expression systems for both the prototyping of carbon-conserving pathways and the sustainable bioproduction of platform chemicals.

60 APPLIED LIFE SCIENCES

Single-Shot Reconstruction of Electron Beam Longitudinal Phase Space in a Laser Wakefield Accelerator

We report on a single-shot longitudinal phase-space reconstruction diagnostic for electron beams in a laser wakefield accelerator via the experimental observation of distinct periodic modulations in the angularly resolved spectra. Such modulated angular spectra arise as a result of the direct interaction between the ultrarelativistic electron beam and the laser driver in the presence of the wakefield. A constrained theoretical model for the coupled oscillator, assisted by a genetic algorithm, can recreate the experimental electron spectra and, thus, fully reconstructs the longitudinal phase-space distribution of the electron beam with a temporal resolution of approximately 1.3 fs. In particular, it reveals the slice energy spread of the electron beam, which is important to measure for applications such as x-ray free electron lasers. In our experiment, the root-mean-square energy spread retrieved is bounded at 9.9 MeV, corresponding to a 0.9%–3.0% relative spread, despite the overall GeV energy beam having approximately 100% relative energy spread.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

ERAD: A Graph-Based Tool for Energy Resilience Analysis of Electric Distribution Systems

Understanding the impact of extreme events on people's ability to access energy is crucial for designing resilient energy systems. In the event of a disaster, damage to the electric system and related infrastructure (e.g., downed power lines, flooded equipment, hacked communication systems, damaged roads, etc.) can impact people's access to critical services, including not just electricity but also shelter, food, healthcare, and more. There is a key need to understand such impacts better and evaluate options to improve energy resilience. The Energy Resilience Analysis for Electric Distribution Systems (ERAD) tool is a free and open-source software package designed to help researchers and decision-makers analyze and improve energy system resilience.

24 POWER TRANSMISSION AND DISTRIBUTION

Preliminary Assessment of Renewable Energy Options at the Sravasti Abbey [Slides]

Through the U.S. Department of Energy's Energy to Communities (E2C) program, NREL, other national laboratory experts, and select organizations provide Expert Match - free, short-term technical assistance to address near-term clean energy challenges and questions. Expert Match is for community stakeholders who have decision-making power or influence in their community but need access to additional clean energy expertise to inform key upcoming decisions. This Expert Match request supported the Sravasti Abbey in Washington a preliminary assessment of distributed energy technology financial feasibility for their site. The outcome consists of low estimated savings from these technologies due to their already low energy consumption.

29 ENERGY PLANNING, POLICY, AND ECONOMY

Locally Confined Polysulfide-Reactive Electrolytes for Shuttle-Free Sodium–Sulfur Batteries

Sodium-sulfur batteries promise high-energy-density and sustainable electrochemical energy storage but suffer from uncontrolled polysulfides dissolution and high sodium reactivity. These challenges fundamentally originate from poor electrolyte-electrode compatibility. Current electrolyte research inadequately addresses the trade-off between minimal polysulfides solvation and stabilizing sodium interfaces. Here, we present a locally-confined polysulfide-reactive electrolyte strategy that mediates the polysulfide dissolution dynamics and sodium stability by leveraging an electrophilic solvating species with a localized high-concentration electrolyte. This design enables shuttle-free cell operation by synergistically restricting the global solvating power of the electrolyte through intermolecular interactions and locally scavenging sparingly dissolved polysulfides via electrolyte electrophilicity. The precisely confined surface reaction facilitates a protective cathode-electrolyte interface, realizing a quasi-solid-state sulfur conversion in our liquid ether-based electrolyte, which crucially avoids crossover-induced catastrophic sodium-metal degradation. The proposed electrolyte demonstrates long-term cycling of high-mass-loading sulfur cathodes (> 3 mg S cm −2 with commercial carbon host and 70 wt% sulfur content), which afford 710 mA h g −1 over 400 cycles in coin cells and steady pouch cell operation over 180 cycles. Furthermore, this work establishes a scalable electrolyte design protocol that regulates the reaction chemistry of highly reactive electrodes, offering a pathway toward sustainable renewable energy storage.

25 ENERGY STORAGE