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At least 379 records · Page 21

Uncovering the binding nature of thiocyanate in contact ion pairs with lithium ions

Ion pair formation is a fundamental molecular process that occurs in a wide variety of systems, including electrolytes, biological systems, and materials. In solution, the thiocyanate (SCN–) anion interacts with cations to form contact ion pairs (CIPs). Due to its ambidentate nature, thiocyanate can bind through either its sulfur or nitrogen atoms, depending on the solvent. This study focuses on the binding nature of thiocyanate with lithium ions as a function of the solvents using FTIR, 2D infrared spectroscopy (2DIR) spectroscopies, and theoretical calculations. The study reveals that the SCN– binding mode (S or N end) in CIPs can be identified through 2DIR spectroscopy but not by linear IR spectroscopy. Linear IR spectroscopy shows that the CN stretch frequencies are too close to one another to separate N- and S-bound CIPs. Moreover, the IR spectrum shows that the S–C stretch presents different frequencies for the salt in different solvents, but it is related to the anion speciation rather than to its binding mode. A similar trend is observed for the anion bend. 2DIR spectra show different dynamics for N-bound and S-bound thiocyanate. In particular, the frequency–frequency correlation function (FFCF) dynamics extracted from the 2DIR spectra have a single picosecond exponential decay for N-bound thiocyanate and a biexponential decay for S-bound thiocyanate, consistent with the binding mode of the anion. Lastly, it is also observed that the binding mode also affects the line shape parameters, probably due to the different molecular mechanisms of the FFCF for N- and S-bound CIPs.

25 ENERGY STORAGE↗

Theory-based scaling laws of near and far scrape-off layer widths in single-null L-mode discharges

Abstract Theory-based scaling laws of the near and far scrape-off layer (SOL) widths are analytically derived for L-mode diverted tokamak discharges by using a two-fluid model. The near SOL pressure and density decay lengths are obtained by leveraging a balance among the power source, perpendicular turbulent transport across the separatrix, and parallel losses at the vessel wall, while the far SOL pressure and density decay lengths are derived by using a model of intermittent transport mediated by filaments. The analytical estimates of the pressure decay length in the near SOL is then compared to the results of three-dimensional, flux-driven, global, two-fluid turbulence simulations of L-mode diverted tokamak plasmas, and validated against experimental measurements taken from an experimental multi-machine database of divertor heat flux profiles, showing in both cases a very good agreement. Analogously, the theoretical scaling law for the pressure decay length in the far SOL is compared to simulation results and to experimental measurements in TCV L-mode discharges, pointing out the need of a large multi-machine database for the far SOL decay lengths.

Physics↗

Universal lower bound on the axion decay constant from free streaming effects

We show that enhancement of the axion relic abundance compared to the standard misalignment contribution generically leads to the production of nonzero momentum axion modes, resulting in warm dark matter behavior and enhanced isocurvature perturbations. It leads to universal constraints on the axion parameter space that are independent of detailed model assumptions and cosmological history. For models enhancing relic abundance with gradient axion modes, observations of the Lyman-$α$ forest impose a lower bound on the axion decay constant, $f_a \gtrsim 10^{15} {\rm GeV}\,(10^{-18}{\rm eV}/m_a)$, from the free-streaming effect. For models relying on the delay of coherent axion oscillations, we obtain a slightly weaker bound, $f_a \gtrsim 10^{14} {\rm GeV}\,(10^{-18}{\rm eV}/m_a)$. We make relatively conservative choices to establish these universal bounds but also provide scaling parameters that can be calibrated for stronger constraints in concrete models and updated as observations improve.

Harigaya, Keisuke [Chicago U., EFI; Tokyo U., IPMU↗

Revisiting AVHRR Tropospheric Aerosol Trends Using Principal Component Analysis

The advanced very high resolution radiometer (AVHRR) satellite instruments provide a nearly 25 year continuous record of global aerosol properties over the ocean. It offers valuable insights into the long-term change in global aerosol loading. However, the AVHRR data record is heavily influenced by two volcanic eruptions, El Chichon on March 1982 and Mount Pinatubo on June 1991. The gradual decay of volcanic aerosols may last years after the eruption, which potentially masks the estimation of aerosol trends in the lower troposphere, especially those of anthropogenic origin. In this study, we show that a principal component analysis approach effectively captures the bulk of the spatial and temporal variability of volcanic aerosols into a single mode. The spatial pattern and time series of this mode provide a good match to the global distribution and decay of volcanic aerosols. We further reconstruct the data set by removing the volcanic aerosol component and reestimate the global and regional aerosol trends. Globally, the reconstructed data set reveals an increase of aerosol optical depth from 1985 to 1990 and decreasing trend from 1994 to 2006. Regionally, in the 1980s, positive trends are observed over the North Atlantic and North Arabian Sea, while negative tendencies are present off the West African coast and North Pacific. During the 1994 to 2006 period, the Gulf of Mexico, North Atlantic close to Europe, and North Africa exhibit negative trends, while the coastal regions of East and South Asia, the Sahel region, and South America show positive trends.

volcanoes↗

Topological prethermal strong zero modes on superconducting processors

Abstract Symmetry-protected topological phases 1–4 cannot be described by any local order parameter and are beyond the conventional symmetry-breaking model 5 . They are characterized by topological boundary modes that remain stable under symmetry respecting perturbations 1–4,6–8 . In clean, gapped systems without disorder, the stability of these edge modes is restricted to the zero-temperature manifold; at finite temperatures, interactions with mobile thermal excitations lead to their decay 9–11 . Here we report the observation of a distinct type of topological edge mode 12–14 , which is protected by emergent symmetries and persists across the entire spectrum, in an array of 100 programmable superconducting qubits. Through digital quantum simulation of a one-dimensional disorder-free stabilizer Hamiltonian, we observe robust long-lived topological edge modes over up to 30 cycles for a wide range of initial states. We show that the interaction between these edge modes and bulk excitations can be suppressed by dimerizing the stabilizer strength, leading to an emergent U(1) × U(1) symmetry in the prethermal regime of the system. Furthermore, we exploit these topological edge modes as logical qubits and prepare a logical Bell state, which exhibits persistent coherence, despite the system being disorder-free and at finite temperature. Our results establish a viable digital simulation approach 15–18 to experimentally study topological matter at finite temperature and demonstrate a potential route to construct long-lived, robust boundary qubits in disorder-free systems.

Science & Technology - Other Topics↗

Analysis of ProSEDS Test of Bare-Tether Collection

NASA's tether experiment ProSEDS will be placed in orbit on board a Delta-II rocket to test bare-tether electron collection, deorbiting of the rocket second stage, and the system dynamic stability. ProSEDS performance will vary because ambient conditions change along the orbit and tether-circuit bulk elements at the cathodic end follow the step-by-step sequence for the current cycles of operating modes (open-circuit, shunt and resistor modes for primary cycles; shunt and battery modes for secondary cycles). In this work we discuss expected ProSEDS values of the ratio L,/L*, which jointly with cathodic bulk elements determines bias and current tether profiles; L, is tether length, and L* (changing with tether temperature and ionospheric plasma density and magnetic field) is a characteristic length gauging ohmic versus baretether collection impedances. We discuss how to test bare-tether electron collection during primary cycles, using probe measurements of plasma density, measurements of cathodic current in resistor and shunt modes, and an estimate of tether temperature based on ProSEDS orbital position at the particular cycle concerned. We discuss how a temperature misestimate might occasionally affect the test of bare-tether collection, and how introducing the battery mode in some primary cycles, for an additional current measurement, could obviate the need of a temperature estimate. We also show how to test bare-tether collection by estimating orbit-decay rate from measurements of cathodic current for the shunt and battery modes of secondary cycles.

Sanmartin, J. R.↗

Scattering by whistler-mode waves during a quiet period perturbed by substorm activity

We study the dynamics of radiation belt electrons during a 10-day quiet period perturbed by substorm activity and preceding a high-speed stream (HSS), aiming at a global description of the radiation belts in L-shell, L in [2, 6], and energy [0.1, 10] MeV. We combine Van Allen Probes observations and Fokker-Planck numerical simulations of pitch-angle diffusion. The Fokker-Planck model uses event-driven pitch angle diffusion coefficients from whistler-mode waves, built from the wave properties and the ambient plasma density measurements from the Van Allen Probes. We first find this event has some similar characteristics to regular quiet times previously studied; a widely extended plasmasphere within which we observe strong and varying whistler-mode waves. These ambient conditions lead to strong pitch-angle scattering, which contributes to the creation of a wide slot region as well as a significant decay of the outer radiation belts, which are observed and qualitatively well simulated. In addition, we find the substorm activity causes short duration (within ± 4h) decay of the plasma density and a lowering amplitude of the whistler-mode waves within the plasmasphere, both causing opposite effects in terms of pitch angle diffusion. This leads to a diminution of pitch-angle diffusion at the time of the main substorm activity. Conversely, whistler-mode waves become enhanced in the time periods between the substorm injections. All effects cumulated, we find an enhancement of pitch angle diffusion by whistler-mode waves above L~4.7 during the 10-day period. This directly relates to the combination of quietness and substorm activity which allows pitch angle diffusing of up to 1 MeV electrons in the outer belt. Relativistic electrons of 1–2 MeV remain trapped in the outer belt, from L~4.7 to L~5.2, forming, in both the observations and the simulations, a distinct pocket of remnant electrons.

79 ASTRONOMY AND ASTROPHYSICS↗

Comparison of experimental rotor damping data-reduction techniques

The ability of existing data reduction techniques to determine frequency and damping from transient time-history records was evaluated. Analog data records representative of small-scale helicopter aeroelastic stability tests were analyzed. The data records were selected to provide information on the accuracy of reduced frequency and decay coefficients as a function of modal damping level, modal frequency, number of modes present in the time history record, proximity to other modes with different frequencies, steady offset in time history, and signal-to-noise ratio. The study utilized the results from each of the major U.S. helicopter manufacturers, the U.S. Army Aeroflightdynamics Directorate, and NASA Ames Research Center using their inhouse data reduction and analysis techniques. Consequently, the accuracy of different data analysis techniques and the manner in which they were implemented were also evaluated. It was found that modal frequencies can be accurately determined even in the presence of significant random and periodic noise. Identified decay coefficients do, however, show considerable variation, particularly for highly damped modes. The manner in which the data are reduced and the role of the data analyst was shown to be important. Although several different damping determination methods were used, no clear trends were evident for the observed differences between the individual analysis techniques. It is concluded that the data reduction of modal-damping characteristics from transient time histories results in a range of damping values.

Warmbrodt, William↗

On the behavior of hydromagnetic surface waves

The behavior of velocity, magnetic field, and pressure perturbations about a continuously varying interface in pressure equilibrium is investigated in detail within ideal incompressible magnetohydrodynamics. A specific initial value problem is solved in quadrature for a thin interface and compared with the solution for a discontinuous interface. The unattenuated surface wave about a discontinuous interface is replaced at a thin interface by a collective surface disturbance which decays, with the associated energy density flowing into local oscillations within the interface. At long times the envelope of the local oscillations is concentrated within a small fraction of the thin interface (gradients within the envelope increase linearly with time, eventually resulting in a breakdown of the linearized ideal theory). Thus, the derived decay rate of the surface disturbance gives a mode-conversion rate rather than a heating rate. In applications to the propagation and dissipation of surface waves in the solar corona, this rate cannot in general be interpreted as a coronal heating rate.

Lee, M. A.↗

Modeling the turbulent kinetic energy equation for compressible, homogeneous turbulence

The turbulent kinetic energy transport equation, which is the basis of turbulence models, is investigated for homogeneous, compressible turbulence using direct numerical simulations performed at CTR. It is shown that the partition between dilatational and solenoidal modes is very sensitive to initial conditions for isotropic decaying turbulence but not for sheared flows. The importance of the dilatational dissipation and of the pressure-dilatation term is evidenced from simulations and a transport equation is proposed to evaluate the pressure-dilatation term evolution. This transport equation seems to work well for sheared flows but does not account for initial condition sensitivity in isotropic decay. An improved model is proposed.

Aupoix, B.↗

Observation of intense wave bursts at very low altitudes within the Venus nightside ionosphere

Intense ELF (100 Hz) bursts were detected by the Pioneer Venus (PV) Orbiter plasma wave instrument during the final operations of the spacecraft prior to atmospheric entry. These bursts were detected at approx. 130 km altitude around 0400 local time. The wave activity lasted for several tens of seconds. Furthermore the bursts were not symmetric about periapsis, unlike instrument noise caused by neutral impacts on the spacecraft. The bursts had a vertical attenuation scale height of the order 1 km, consistent with that expected for whistler-mode waves propagating through a collisional ionosphere. Since the decay of the signals appears to be due to attenuation, the source must persist for several tens of seconds. The wave bursts could therefore be the signature of electromagnetic radiation entering the bottomside ionosphere from several distant sources, as would be expected if lightning were a relatively persistent phenomenon within the Venus atmosphere.

Strangeway, R. J.↗

Observation of Intense Wave Bursts at Very Low Altitudes Within the Venus Nightside Ionosphere

Intense ELF (100 Hz) bursts were detected by the Pioneer Venus Orbiter plasma wave instrument during the final operations of the spacecraft prior to atmospheric entry. These bursts were detected at approx. 130 km altitude around 0400 local time. The wave activity lasted for several tens of seconds. Furthermore the bursts were not symmetric about periapsis, unlike instrument noise caused by neutral impacts on the spacecraft. The bursts had a vertical attenuation scale height of the order 1 km, consistent with that expected for whistler-mode waves propagating through a collisional ionosphere. Since the decay of the signals appears to be due to attenuation, the source must persist for several tens of seconds. The wave bursts could therefore be the signature of electromagnetic radiation entering the bottomside ionosphere from several distant sources, as would be expected if lightning were a relatively persistent phenomenon within the Venus atmosphere.

Strangeway, R. J.↗

The temperature and density structures of an X-ray flare during the decay phase

The X-ray flare of 9 August 1973 was characterized by a spatially small kernel structure which persisted throughout its duration. The decay phase of this flare was observed in the objective grating mode of the X-ray telescope aboard the Skylab. Data analysis was carried out by scanning the images with a microdensitometer, converting the density arrays to energy using laboratory film calibration data and taking cross sections of the energy images. The 9 August flare shows two distinct periods in its decay phase, involving both cooling and material loss. The objective grating observations reveal that the two phenomena are separated in time. During the earlier phase of the flare decay, the distribution of emission measure as a function of temperature is changing, the high temperature component of the distribution being depleted relative to the cooler body of plasma. As the decay continues, the emission measure distribution stabilizes and the flux diminishes as the amount of material at X-ray emitting temperatures decreases.

Silk, J. K.↗

Measurement of branching fractions and search for CP violation in $D^0 → π^+π^-η, D^0 → K^+K^-η$, and $D^0 → Φη$ at Belle

We measure the branching fractions and CP asymmetries for the singly Cabibbo-suppressed decays $D^0 → π^+π^-η, D^0 → K^+K^-η$, and $D^0 → Φη$, using 980 fb -1 of data from the Belle experiment at the KEKB e + e - collider. We obtain $$\mathcal{B}(D^0 → π^+π^-η = \mathrm{[1.22 ± 0.02 (stat) ± 0.02(syst) ± 0.03}(\mathcal{B}_{\mathrm{ref}})] \mathrm{x 10^{-3}}$$ $$\mathcal{B}(D^0 → K^+K^-η = \mathrm{[1.80^{+0.07}_{-0.06}(stat) ± 0.04 (syst) ± 0.05}(\mathcal{B}_{\mathrm{ref}})] \mathrm{x 10^{-4}}$$ $$\mathcal{B}(D^0 → Φη = \mathrm{[1.84 ± 0.09 (stat) ± 0.0 (syst) ± 0.05}(\mathcal{B}_{\mathrm{ref}})] \mathrm{x 10^{-4}}$$ where the third uncertainty ($\mathcal{B}_{\mathrm{ref}}$) is from the uncertainty in the branching fraction of the reference mode $D^0 → K^-π^+η$. The color-suppressed decay $D^0 → Φη$ is observed for the first time, with very high significance. The results for the CP asymmetries are $$A_{CP} (D^0 → π^+π^-η) = \mathrm{[0.9 ± 1.2 (stat) ± 0.5 (syst)]}\%$$ $$A_{CP} (D^0 → K^+K^-η) = \mathrm{[-1.4 ± 3.3 (stat) ± 1.1 (syst)]}\%$$ $$A_{CP} (D^0 → Φη) = \mathrm{[-1.9 ± 4.4 (stat) ± 0.6 (syst)]}\%$$ The results for $D^0 → π^+π^-η$ are a significant improvement over previous results. The branching fraction and A CP results for $D^0 → K^+K^-η$, and the ACP result for $D^0 → Φη$, are the first such measurements. No evidence for CP violation is found in any of these decays.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

169 Tm ( n , γ ) cross section and statistical decay properties from measurements at the DANCE facility

Background: Radiative neutron capture on thulium, which is a monoisotopic element, plays a role in different applications such as nuclear astrophysics or nuclear burning environments. Considerable discrepancies—reaching 20%—exist between evaluations in the unresolved-resonance region. Furthermore, experimental data on statistical 𝛾 decay in odd-odd rare-earth nuclei is scarce. There are still open questions about the systematics of the so-called scissors mode in the 𝑀⁢1 photon strength function, especially in odd-odd nuclei. Purpose: This work is focused on two main topics—deriving experimental 169 Tm ⁢(𝑛,𝛾) cross section and studying statistical 𝛾 decay of 170 Tm, in particular properties of the scissors mode. Methods: The capture experiments to obtain experimental cross section were performed at the Los Alamos Neutron Science Center using the time-of-flight technique and employing the Detector for Advanced Neutron Capture Experiments. Measured coincident 𝛾-ray spectra were also compared with statistical simulations using the dicebox code to test different models of level density and photon strength functions. Results: The capture cross section was determined from 1.8 eV to 0.97 MeV, the broadest neutron-energy range ever measured for this isotope. Several new resonances have been observed. The statistical 𝛾 decay of 170 Tm cannot be reproduced without a scissors mode resonance centered at ≈ 3.3MeV. Conclusions: The measured cross section in the unresolved-resonance region is generally lower than the latest evaluations. The derived 169 Tm 𝑠-process abundance is expected to increase by a factor of 1.26, while the changes of the abundances of elements heavier than 169 Tm are in the order of 0.2%. The scissors mode properties in 170 Tm are similar to those deduced in previous analyses of neighboring nuclei 168 Er and 166 Ho .

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Nonlinear forcing of planetary scale waves by amplifying unstable baroclinic eddies generated in the troposphere

The present investigation is mainly concerned with isolating the effects of wave-wave coupling on the growth of planetary-scale baroclinic modes of zonal wavenumber 1-3. It is shown that a global distribution of amplifying intermediate-scale baroclinic modes can cause rapid growth of planetary-scale modes. The growth rates of the planetary modes are found to be comparable to the growth rates of the most unstable baroclinic modes during the first 5-10 days. Thereafter the planetary waves continue to grow (albeit at a slower rate and not necessarily monotonically), and do not exhibit a decay phase as pronounced as that which is characteristic of the intermediate-scale modes.

Young, R. E.↗

Physics of the Inverted Harmonic Oscillator: From the lowest Landau level to event horizons

In this work, we present the inverted harmonic oscillator (IHO) Hamiltonian as a paradigm to understand the quantum mechanics of scattering and time-decay in a diverse set of physical systems. As one of the generators of area preserving transformations, the IHO Hamiltonian can be studied as a dilatation generator, squeeze generator, a Lorentz boost generator, or a scattering potential. In establishing these different forms, we demonstrate the physics of the IHO that underlies phenomena as disparate as the Hawking–Unruh effect and scattering in the lowest Landau level (LLL) in quantum Hall systems. We derive the emergence of the IHO Hamiltonian in the LLL in a gauge invariant way and show its exact parallels with the Rindler Hamiltonian that describes quantum mechanics near event horizons. This approach of studying distinct physical systems with symmetries described by isomorphic Lie algebras through the emergent IHO Hamiltonian enables us to reinterpret geometric response in the lowest Landau level in terms of relativistic effects such as Wigner rotation. Further, the analytic scattering matrix of the IHO points to the existence of quasinormal modes (QNMs) in the spectrum, which have quantized time-decay rates. We present a way to access these QNMs through wave packet scattering, thus proposing a novel effect in quantum Hall point contact geometries that parallels those found in black holes.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗