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At least 379 records · Page 21

Nuclear magnetic resonance of Al-27 in topaz, Al2SiO4/F, OH/2.

The Al-27 nuclear quadrupolar coupling constant and asymmetry parameter (eta) in topaz have been determined to be 1.67 (plus or minus 0.03) MHz and 0.38 plus or minus 0.05, respectively. These values and the orientations of the principal axes are consistent with the Fe(3+) paramagnetic resonance data and with the symmetry of the AlO4F2 octahedron.

Tsang, T.↗

Solid-phase epitaxial growth of Si mesas from Al metallization.

Using scanning electron microscopy, Si epitaxial growth from solution in solid Al onto crystal Si substrates was studied. Growth in reentrant corners of the substrate was found to be favored over growth onto a flat surface. These preferred locations for growth appear to be the result of a force not present in conventional crystal growth from fluid media, namely, the nonuniform stress field present in solids.

Sankur, H.↗

Relation between surface slip topography and stress corrosion cracking in Ti-8 wt % Al

The deformation behavior of Ti-8 wt % Al has been investigated in an inert environment (air), and an aggressive environment (salt water). Details of surface slip geometry were examined by high resolution surface replicas at various stages of deformation in both environments. Specimens aged to contain a fine dispersion of Ti3Al precipitates failed by subcritical crack growth in salt water, whereas specimens in the single phase condition showed no effects of environment on the yield or fracture characteristics. The Ti3Al precipitates produce little change in strength level or slip character compared to the single phase alloy, and there is no evidence of any effects of environment on the character of surface slip. Rather, the presence of trenches along slip bands on the surface of aged specimens suggest that the specific effect of the Ti3Al precipitates is to render the surface slip steps chemically active relative to the surrounding matrix by slip induced dissolution of the particles.

Boyd, J. D.↗

Ejecta from large craters on the moon - Comments on the geometric model of McGetchin et al

Amendments to a quantitative scheme developed by T. R. McGetchin et al. (1973) for predicting the distribution of ejecta from lunar basins yield substantially thicker estimates of ejecta, deposited at the basin rim-crest and at varying ranges beyond, than does the original model. Estimates of the total volume of material ejected from a basin, illustrated by Imbrium, also are much greater. Because many uncertainties affect any geometric model developed primarily from terrestrial analogs of lunar craters, predictions of ejecta thickness and volume on the moon may range within at least an order of magnitude. These problems are exemplified by the variability of T, thickness of ejecta at the rim-crest of terrestrial experimental craters. The proportion of T to crater rim-height depends critically upon scaled depth-of-burst and whether the explosive is nuclear or chemical.

Pike, R. J.↗

Spectrum of Al VII in the vuv

The spectrum of Al VII is re-examined in the vuv. A laser-produced plasma is used as a light source. Twenty-four newly classified lines are reported. No new energy levels have been determined.

Valero, F. P. J.↗

Auger spectroscopy of HCl interaction with Al at low pressures

The purpose of the present study was to determine some adsorption characteristics of HCl with partially clean polycrystalline Al by Auger electron spectroscopy. The adsorption was found to exhibit a Freundlich-type behavior pattern in which the number of molecules adsorbed varied with HCl pressure linearly on a log-log plot. Assuming that the adsorption behaves according to the Clausius-Clapeyron equation, the isosteric heat of adsorption increases with coverage at low pressures, appearing to approach a constant value of 4-5 kcal/mole.

Lassiter, W. S.↗

Proton and deuteron double differential cross sections at angles from 10 deg to 60 deg from Be, C, Al, Fe, Cu, Ge, W, and Pb under 558-MeV-proton irradiation

The double differential cross sections for the production of protons and deuterons from targets of Be, C, Al, Fe, Cu, Ge, W, and Pb were obtained at laboratory angles of scatter of 10, 20, 30, 40, 50, and 60 degrees for 558-MeV incident protons. The position of the quasi-elastic peak, discernible in the cross sections up to approximately 40 degrees, corresponded closely to the theoretical predictions for proton-proton elastic scattering at 558 MeV. The mean ratio of deuteron to proton energy-integrated cross sections was 0.056 + or - 0.008. The dependence of energy-integrated cross sections for both protons and deuterons on target mass number A varied from A to the 1/3 power at 10 degrees to A to the 2/3 power above approximately 30 degrees. The ratio of energy-integrated deuteron cross sections for quasielastic processes to that for reactions yielding a deuteron-pi-meson pair was approximately 10 percent.

Beck, S. M.↗

Precipitation of silicon from splat-cooled Al-Si alloys

Splat cooled Al-Si solid solutions with 1 to 11 at.% Si were prepared and their precipitation kinetics were studied by transmission electron microscopy. The time required for appearance of particles visible at a magnification of 35,000 times was determined at temperatures between 248 K and 573 K. The resulting Arrhenius plots yielded activation energies ranging from 55 to 40 plus or minus 2kJ/mol over the composition range. Precipitate densities were higher and denuded zones of 100 to 150 nm were narrower than in comparable solid quenched samples. The activation energies are explained in terms of excess point defect concentrations.

Matyja, H.↗

The influence of growth rate and temperature on high cycle fatigue of Al-Al3Ni

High-cycle fatigue tests have been conducted on specimens of an Al-Al3Ni eutectic alloy, unidirectionally solidified at selected rates from 0.000139 to 0.3 cm/sec. Tests were conducted in air at 298, 458 and 683 K. Room temperature fatigue lives were independent of growth rate at low solidification rates but were markedly improved in samples grown at 0.3 cm/sec. Materials grown at 0.00833 cm/sec exhibited fatigue lives similar to those of the lower growth rates, despite gross misalignment due to cellular growth. The dependence of fatigue life on growth rate at elevated temperatures appears to be due primarily to differences in cyclic creep rates as a result of varying interfiber spacings. Crack initiation and propagation mechanisms were established by metallographic and fractographic examination. Dislocation substructure-fiber interactions were studied by transmission electron microscopy.

Maurer, G. E.↗