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At least 361 records · Page 20

Numerical Investigation of the characteristics of pressurized biomass-oxy-combustion

As a second generation of oxy-fuel combustion technologies, pressurized oxy-combustion has a potential to improve the process efficiency and economy. With the modern decarbonization needs, biomass combustion is considered to be nearly CO2 neutral, and thus co-firing biomass with coal in an oxy-combustion process can achieve a negative CO2 balance. The size of the biomass fuel particles is a key parameter in an entrained flow combustor because large biomass particles, exceeding some threshold size, may only partially be burnt due to the restrictions on the heat transport, thereby diminishing the combustion efficiency. While such a threshold particle size has been scrutinized at an atmospheric pressure, the present study extends the analysis to elevated pressures. Specifically, two scenarios were set up, for experimental-scale and full-scale pressurized oxy-combustors, with the threshold sizes of biomass particles appearing 0.5 mm and 5 mm, respectively, without temperature gradient in biomass particles. With temperature gradient, the parametric study included the particles in the range from 0.15 mm to 5 mm. It is shown that the thermal-thin model is applicable to spherical biomass particles not exceeding 0.15 mm. The impact of the heating rate on biomass particle devolatilization was also investigated and the biomass devolatilization could happen in less than 1 second; the same amount of heat energy could induce different volatile release rates.

Li, Lei↗

Thermal-Mechanical Stability of Single Crystal Oxide Refractive Concentrators for High-Temperature Solar Thermal Propulsion

Single crystal oxides such as yttria-stabilized zirconia (Y2O3-ZrO2), yttrium aluminum garnet (Y3Al5O12, or YAG), magnesium oxide (MgO) and sapphire (Al2O3) are candidate refractive secondary concentrator materials for high temperature solar propulsion applications. However, thermo-mechanical reliability of these components in severe thermal environments during the space mission sun/shade transition is of great concern. Simulated mission tests are important for evaluating these candidate oxide materials under a variety of transient and steady-state heat flux conditions, and thus provide vital information for the component design. In this paper, a controlled heat flux thermal shock test approach is established for the single crystal oxide materials using a 3.0 kW continuous wave CO2 laser, with a wavelength 10.6 micron. Thermal fracture behavior and failure mechanisms of these oxide materials are investigated and critical temperature gradients are determined under various temperature and heating conditions. The test results show that single crystal sapphire is able to sustain the highest temperature gradient and heating-cooling rate, and thus exhibit the best thermal shock resistance, as compared to the yttria-stabilized zirconia, yttrium aluminum garnet, and magnesium oxide.

Zhu, Dongming↗

Thermal-Mechanical Stability of Single Crystal Oxide Refractive Concentrators for High-Temperature Solar Thermal Propulsion

Single crystal oxides such as yttria-stabilized zirconia (Y2O3-ZrO2), yttrium aluminum garnet (Y3Al5O12, or YAG), magnesium oxide (MgO) and sapphire (Al2O3) are candidate refractive secondary concentrator materials for high temperature solar propulsion applications. However, thermo-mechanical reliability of these components in severe thermal environments during the space mission sun/shade transition is of great concern. Simulated mission tests are important for evaluating these candidate oxide materials under a variety of transient and steady-state heat flux conditions, and thus provide vital information for the component design. In this paper, a controlled heat flux thermal shock test approach is established for the single crystal oxide materials using a 3.0 kW continuous wave CO2 laser, with a wavelength 10.6 micron. Thermal fracture behavior and failure mechanisms of these oxide materials are investigated and critical temperature gradients are determined under various temperature and heating conditions. The test results show that single crystal sapphire is able to sustain the highest temperature gradient and heating-cooling rate, and thus exhibit the best thermal shock resistance, as compared to the yttria-stabilized zirconia, yttrium aluminum garnet and magnesium oxide.

Zhu, Dongming↗

Modeling fuel assembly distortion in light water reactors using BISON

Individual fuel rods in a light water reactor fuel assembly (FA) often have different power profiles that result in a spatial temperature gradient in the FA. This temperature gradient causes some rods to elongate more than others which could in turn distort the entire FA. Such FA distortion has been known to cause operational difficulties with refueling and with the insertion of control rods [1]. Numerical modeling of FA distortion due to differential elongation of fuel rods requires: (i) modeling the thermal elongation as well as the creep and irradiation induced elongation of the fuel rods, and (ii) modeling the bending response of the FA due to the differential elongation of the fuel rods. Past studies on this topic have been focused on the mechanical deformation of the FA with simplistic modeling of fuel rod elongation. In this paper, a simulation approach is presented that directly couples 2D axisymmetric fuel performance models of the individual fuel rods in a FA with structural beam models of the fuel rods in a FA using the Bison code [2]. This allows all of the mechanisms internal to the fuel rod leading to cladding elongation to be accounted for in the FA distortion model. To demonstrate this capability, the bowing of a simplified and idealized 6x6 FA (Fig. 1a), modeled using beam elements, is analyzed under different spatially varying power profiles. For this study, the guide tubes are rigidly connected to the spacer grid. Also, the fuel rods are rigidly connected to the spacer grid in all directions except the vertical direction (Y) along which slipping can occur between the fuel rods and spacer grids, depending on the friction coefficient between them. Coupling the thermo-mechanical response of individual fuel rods to the global mechanical behavior of the FA can shed light on the mechanisms that cause distortion of the FA and potential solutions to address this issue.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Linear multispecies gyrokinetic flux tube benchmarks in shaped tokamak plasmas

Verification is the fundamental step that any turbulence simulation code has to be submitted in order to assess the proper implementation of the underlying equations. We have carried out a cross comparison of three flux tube gyrokinetic codes, GENE [F. Jenko et al., Phys. Plasmas 7, 1904 (2000)], GKW [A. G. Peeters et al., Comput. Phys. Commun. 180, 2650 (2009)], and GS2 [W. Dorland et al., Phys. Rev. Lett. 85, 5579 (2000)], focusing our attention on the effect of realistic geometries described by a series of MHD equilibria with increasing shaping complexity. To simplify the effort, the benchmark has been limited to the electrostatic collisionless linear behaviour of the system. A fully gyrokinetic model has been used to describe the dynamics of both ions and electrons. Several tests have been carried out looking at linear stability at ion and electron scales, where for the assumed profiles Ion Temperature Gradient (ITG)/Trapped Electron Modes and Electron Temperature Gradient modes are unstable. The capability of the codes to handle a non-zero ballooning angle has been successfully benchmarked in the ITG regime. Finally, the standard Rosenbluth-Hinton test has been successfully carried out looking at the effect of shaping on Zonal Flows (ZFs) and Geodesic Acoustic Modes (GAMs). Inter-code comparison as well as validation of simulation results against analytical estimates has been accomplished. All the performed tests confirm that plasma elongation strongly stabilizes plasma instabilities as well as leads to a strong increase in ZF residual and GAM damping.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Dynamic and Thermal Turbulent Time Scale Modelling for Homogeneous Shear Flows

A new turbulence model, based upon dynamic and thermal turbulent time scale transport equations, is developed and applied to homogeneous shear flows with constant velocity and temperature gradients. The new model comprises transport equations for k, the turbulent kinetic energy; tau, the dynamic time scale; k(sub theta), the fluctuating temperature variance; and tau(sub theta), the thermal time scale. It offers conceptually parallel modeling of the dynamic and thermal turbulence at the two equation level, and eliminates the customary prescription of an empirical turbulent Prandtl number, Pr(sub t), thus permitting a more generalized prediction capability for turbulent heat transfer in complex flows and geometries. The new model also incorporates constitutive relations, based upon invariant theory, that allow the effects of nonequilibrium to modify the primary coefficients for the turbulent shear stress and heat flux. Predictions of the new model, along with those from two other similar models, are compared with experimental data for decaying homogeneous dynamic and thermal turbulence, homogeneous turbulence with constant temperature gradient, and homogeneous turbulence with constant temperature gradient and constant velocity gradient. The new model offers improvement in agreement with the data for most cases considered in this work, although it was no better than the other models for several cases where all the models performed poorly.

Schwab, John R.↗

The role of ETG modes in JET–ILW pedestals with varying levels of power and fuelling

Abstract We present the results of GENE gyrokinetic calculations based on a series of JET–ITER-like-wall (ILW) type I ELMy H-mode discharges operating with similar experimental inputs but at different levels of power and gas fuelling. We show that turbulence due to electron-temperature-gradient (ETGs) modes produces a significant amount of heat flux in four JET–ILW discharges, and, when combined with neoclassical simulations, is able to reproduce the experimental heat flux for the two low gas pulses. The simulations plausibly reproduce the high-gas heat fluxes as well, although power balance analysis is complicated by short ELM cycles. By independently varying the normalised temperature gradients ( ω T e ) and normalised density gradients ( ω n e ) around their experimental values, we demonstrate that it is the ratio of these two quantities η e = ω T e / ω n e that determines the location of the peak in the ETG growth rate and heat flux spectra. The heat flux increases rapidly as η e increases above the experimental point, suggesting that ETGs limit the temperature gradient in these pulses. When quantities are normalised using the minor radius, only increases in ω T e produce appreciable increases in the ETG growth rates, as well as the largest increases in turbulent heat flux which follow scalings similar to that of critical balance theory. However, when the heat flux is normalised to the electron gyro-Bohm heat flux using the temperature gradient scale length L T e , it follows a linear trend in correspondence with previous work by different authors.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

On the applicability of probabilistic analyses to assess the structural reliability of materials and components for solid-oxide fuel cells

The applicability of probabilistic analyses to assess the structural reliability of materials and components for solid-oxide fuel cells (SOFC) is investigated by measuring the failure rate of Ni-YSZ when subjected to a temperature gradient and comparing it with that predicted using the Ceramics Analysis and Reliability Evaluation of Structures (CARES) code. The use of a temperature gradient to induce stresses was chosen because temperature gradients resulting from gas flow patterns generate stresses during SOFC operation that are the likely to control the structural reliability of cell components The magnitude of the predicted failure rate was found to be comparable to that determined experimentally, which suggests that such probabilistic analyses are appropriate for predicting the structural reliability of materials and components for SOFCs. Considerations for performing more comprehensive studies are discussed.

Lara-Curzio, Edgar↗

The Effect of Bismuth on the Structural Perfection and the Luminescent Properties of Thin-Film Elastically Stressed Al{sub x}In{sub y}Ga{sub 1–x–y}Bi{sub z}Sb{sub 1–z}/GaSb Heterostructures

The effect of bismuth on the structural perfection and the luminescent properties of Al{sub x}In{sub y}Ga{sub 1–x–y}Bi{sub z}Sb{sub 1–z}/GaSb heterostructures has been studied. The optimal parameters of the process of zone recrystallization with temperature gradient at which epitaxial AlInGaBiSb layers have the minimum roughness and high structural perfection have been revealed: temperature gradient 1 ≤ G ≤ 30 K/cm, the liquid zone thickness 60 ≤ l ≤ 100 μm, the temperature range 773 K ≤ T ≤ 873 K, and bismuth concentration 0.3–0.4 mol fraction.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

West Flank Coso FORGE: 3D Temperature Model

x,y,z data of the 3D temperature model for the West Flank Coso FORGE site. Model grid spacing is 250m. The temperature model for the Coso geothermal field used over 100 geothermal production sized wells and intermediate-depth temperature holes. At the near surface of this model, two boundary temperatures were assumed: (1) areas with surface manifestations, including fumaroles along the northeast striking normal faults and northwest striking dextral faults with the hydrothermal field, a temperature of ~104 deg C was applied to datum at +1066 meters above sea level elevation, and (2) a near-surface temperature at about 10 meters depth, of 20 deg C was applied below the diurnal and annual conductive temperature perturbations. These assumptions were based on heat flow studies conducted at the CVF and for the Mojave Desert. On the edges of the hydrothermal system, a 73 deg C/km temperature gradient contour was established using conductive gradient data from shallow and intermediate-depth temperature holes. This contour was continued to all elevation datums between the 20 deg C surface and -1520 meters below mean sea level. Because the West Flank is outside of the geothermal field footprint, during Phase 1, the three wells inside the FORGE site were incorporated into the preexisting temperature model. To ensure a complete model was built based on all the available data sets, measured bottom-hole temperature gradients in certain wells were downward extrapolated to the next deepest elevation datum (or a maximum of about 25% of the well depth where conductive gradients are evident in the lower portions of the wells). After assuring that the margins of the geothermal field were going to be adequately modelled, the data was contoured using the Kriging method algorithm. Although the extrapolated temperatures and boundary conditions are not rigorous, the calculated temperatures are anticipated to be within ~6 deg C (20 deg F), or one contour interval, of the observed data within the Coso geothermal field. Based on a lack of temperature data west of 74-2TCH, the edges of this model still seem to have an effect on West Flank modeled temperatures.

15 GEOTHERMAL ENERGY↗

SU-E-J-273: Skin Temperature Recovery Rate as a Potential Predictor for Radiation-Induced Skin Reactions

Purpose: To assess the potential of dynamic infrared imaging to evaluate early skin reactions during radiation therapy in cancer patients. Methods: Thermal images were captured by our home-built system consisting of two flash lamps and an infrared (IR) camera. The surface temperature of the skin was first raised by ∼ 6 °C from ∼1 ms short flashes; the camera then captured a series of IR images for 10 seconds. For each image series, a basal temperature was recorded for 0.5 seconds before flash was triggered. The temperature gradients (ε) were calculated between a reference point (immediately after the flash) and at a time point of 2sec, 4sec and 9sec after that. A 1.0 cm region of interest (ROI) on the skin was drawn; the mean and standard deviations of the ROIs were calculated. The standard ε values for normal human skins were evaluated by imaging 3 healthy subjects with different skin colors. All of them were imaged on 3 separate days for consistency checks. Results: The temperature gradient, which is the temperature recovery rate, depends on the thermal properties of underlying tissue, i.e. thermal conductivity. The average ε for three volunteers averaged over 3 measurements were 0.64±0.1, 0.72±0.2 and 0.80±0.3 at 2sec, 4sec and 9sec respectively. The standard deviations were within 1.5%–3.2%. One of the volunteers had a prior small skin burn on the left wrist and the ε values for the burned site were around 9% (at 4sec) and 13% (at 9sec) lower than that from the nearby normal skin. Conclusion: The temperature gradients from the healthy subjects were reproducible within 1.5%–3.2 % and that from a burned skin showed a significant difference (9%–13%) from the normal skin. We have an IRB approved protocol to image head and neck patients scheduled for radiation therapy.

60 APPLIED LIFE SCIENCES↗

Inward particle transport at high collisionality in the Experimental Advanced Superconducting Tokamak

We have made the first drift wave study of particle transport in the Experimental Advanced Superconducting Tokamak (Wan et al., Nucl. Fusion 49, 104011 (2009)). The results reveal that collisions make the particle flux more inward in the high collisionality regime. This can be traced back to effects that are quadratic in the collision frequency. The particle pinch is due to electron trapping which is not very efficient in the high collisionality regime so the approach to equilibrium is slow. We have included also the electron temperature gradient (ETG) mode to give the right electron temperature gradient, since the Trapped Electron Mode (TE mode) is weak in this regime. However, at the ETG mode number ions are Boltzmann distributed so the ETG mode does not give particle transport.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The Thermal Response of a Packed Bed Thermal Energy Storage System upon Saturated Steam Injection Using Distributed Temperature Sensing

The effectiveness of a thermal energy storage (TES) system is typically characterized with the help of thermal stratification or temperature gradients along the direction of heat injection, which is typically the flow direction of heat transfer fluid. The steepness of temperature gradients are a direct indicator of the effectiveness or efficiency of the heat storage or dispatch process. The temperature gradient evolution along the packed bed of ceramic particles upon saturated steam injection is presented in this work. Distributed temperature sensing based on optical frequency domain reflectometry was deployed in a packed bed of ceramic particles to capture the thermal front evolution in the axial direction. The physical processes accompanying steam injection in packed beds are complex due to phase change, transitioning two-phase flow, and changes in condensate accumulation. Therefore, the variation of thermal response of the TES system for various steam injection flow rates was experimentally studied using a high-resolution distributed temperature sensing system in a chemically inert alumina particle-packed bed. Distinct zones of different heat transfer modes were observed during the steam injection experiments. A distinct conduction zone, evident from diffuse thermal fronts, was observed at low flow rates, and these thermal gradients became sharper as the flow rate increased. The diffuse thermal fronts in the heat storage media suggest a low exergy efficiency of the TES system, as energy losses started initiating before a significant fraction of the bed was saturated with steam.

25 ENERGY STORAGE↗

A molecular dynamics simulation study of thermal conductivity anisotropy in β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX)

Molecular dynamics (MD) simulations were used to predict the thermal conductivity of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β-HMX) along directions normal to the (011), (110), and (010) crystal planes. These directions were selected based on the measured morphological importance of the corresponding crystal surfaces. A reverse non-equilibrium MD approach was used wherein a constant heat flux is imposed along a prescribed direction and the resulting steady-state temperature gradient determined. The coefficient of thermal conductivity λ is the quotient of heat flux and temperature gradient (i.e. Fourier's law). Finite-size effects and sensitivity to imposed heat flux were investigated. The results reveal a modest dependence of the conductivity on crystal orientation, significant finite-size effects, and low sensitivity to imposed flux so long as the Fourier's law analysis is limited to the spatial interval in the simulation cell for which the temperature gradient is constant. Infinite-length thermal conductivities were estimated by linear regression of λ -1 (L) versus reciprocal cell length L -1 for each direction. The predicted values are systematically larger, but within a factor of two, than most published experimental determinations, the latter of which were obtained for pressed-powder or composite samples rather than oriented single crystals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Thermal generation of spin current in epitaxial CoFe 2 O 4 thin films

The longitudinal spin Seebeck effect (LSSE) has been investigated in high-quality epitaxial CoFe 2 O 4 (CFO) thin films. The thermally excited spin currents in the CFO films are electrically detected in adjacent Pt layers due to the inverse spin Hall effect (ISHE). The LSSE signal exhibits a linear increase with increasing temperature gradient, yielding a LSSE coefficient of –100 nV/K at room temperature. The temperature dependence of the LSSE is investigated from room temperature down to 30 K, showing a significant reduction at low temperatures, revealing that the total amount of thermally generated magnons decreases. Moreover, we demonstrate that the spin Seebeck effect is an effective tool to study the magnetic anisotropy induced by epitaxial strain, especially in ultrathin films with low magnetic moments.

36 MATERIALS SCIENCE↗

Sensitivity study of hydrogen Soret transport in yttrium Hydride-Based nuclear fuel

Yttrium hydride is an excellent solid neutron moderator material for high temperature nuclear reactor applications due to its high hydrogen density and exceptional hydride stability at high temperatures. Despite these attractive characteristics, the details of how hydrogen behaves within yttrium hydride while temperature gradients exist are still not well understood. The evolution of the hydrogen composition profile resulting from a temperature gradient requires knowledge of hydrogen’s heat of transport, a critical parameter that has not yet been measured for this material. In this work, we perform hydride redistribution, hydrogen dissociation, and hydrogen leakage calculations while varying the Soret heat of transport of hydrogen in yttrium hydride to elucidate the sensitivity of hydride stability under temperature gradients to this parameter. This study analyzes hydride stability of a hypothetical uranium-yttrium hydride nuclear fuel design during operation of a high temperature liquid metal-cooled nuclear reactor. Assuming U-YH x could be fabricated in a physically stabilized manner, this fuel system can likely maintain hydride stability while operating at very high power densities and temperatures. We find that even though the hydrogen dissociation pressure in the gas gap does vary by several percent as the heat of transport temperature parameter is varied, the hydrogen content in the U-YH x fuel meat is relatively insensitive to this parameter over the course of a high burnup fuel cycle; this is due to yttrium hydride’s excellent hydrogen retention under the high temperature conditions considered here. Here, this suggests that hydride stability analyses are insensitive to the value of the Soret heat of transport in U-YH x under steady state liquid metal-cooled reactor conditions. However, the susceptibility to internal gas overpressurization-induced stress-rupture of the cladding during a high temperature transient is more sensitive to this parameter due to the non-linear dependence of hydrogen gas dissociation pressure vs. composition and temperature.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Simulation-Aided Design and Interpretation of Results of Microgravity-Based Solidification Experiments

The preparation and interpretation of microgravity experiments conducted on the International Space Station (ISS) can be challenging because of the remote location of the equipment. Although a “ground unit” is typically available on Earth, it is not located in the laboratory of the principal investigator. Furthermore, test experiments in the ground unit cannot fully duplicate heat transfer conditions of the weightless environment, and thus be a reliable reference for experiment design. Under such conditions, numerical simulations are a valuable tool both for preparing the experiments and interpreting the results obtained under terrestrial and micro-gravity conditions. In this work, we developed a detailed 3D model of the “SUBSA” furnace located at the ISS, and demonstrate its use in our present investigation which includes melt growth and vapor growth of InI crystals on the ISS. In 2002, the SUBSA furnace was designed and built for the growth of InSb crystals in the Microgravity Science Glovebox (MSG) at the ISS. The SUBSA furnace features a transparent section without heating elements, where the axial temperature gradient is high. In our present investigation, we have used the same furnace to grow four InI crystals from the melt, and two InI crystals from the vapor phase (2018-2021). InI crystals have ~20 times lower thermal conductivity than InSb crystals. As a result, during melt growth, the InI crystals were exposed to extremely high temperature gradients. To reduce the axial temperature gradient, we added external jackets made from high thermal conductivity material to the growth ampoules. The SUBSA furnace could not be modeled as asymmetric because of its rectangular shape and right-angled transparent section, which contains a convoluted geometry. The rectangular shape of the transparent section further complicates modelling of radiative heat transfer, which dominates in the zone. At present, numerical simulations are being conducted to resolve an apparent discrepancy between the readings of the 5 thermocouples located in the SUBSA furnace, and the observed position of the solid and molten material. The 3D simulation will be presented, along with the calibration and growth experiment results conducted in microgravity and in the SUBSA ground unit. The developed model should be useful for upcoming microgravity investigations planned to be conducted in the SUBSA facility.

V Riabov↗