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NASA NTRS2014

Mercury's Weather-Beaten Surface: Understanding Mercury in the Context of Lunar and Asteroidal Space Weathering Studies

Mercury's regolith, derived from the crustal bedrock, has been altered by a set of space weathering processes. Before we can interpret crustal composition, it is necessary to understand the nature of these surface alterations. The processes that space weather the surface are the same as those that form Mercury's exosphere (micrometeoroid flux and solar wind interactions) and are moderated by the local space environment and the presence of a global magnetic field. To comprehend how space weathering acts on Mercury's regolith, an understanding is needed of how contributing processes act as an interactive system. As no direct information (e.g., from returned samples) is available about how the system of space weathering affects Mercury's regolith, we use as a basis for comparison the current understanding of these same processes on lunar and asteroidal regoliths as well as laboratory simulations. These comparisons suggest that Mercury's regolith is overturned more frequently (though the characteristic surface time for a grain is unknown even relative to the lunar case), more than an order of magnitude more melt and vapor per unit time and unit area is produced by impact processes than on the Moon (creating a higher glass content via grain coatings and agglutinates), the degree of surface irradiation is comparable to or greater than that on the Moon, and photon irradiation is up to an order of magnitude greater (creating amorphous grain rims, chemically reducing the upper layers of grains to produce nanometer scale particles of metallic iron, and depleting surface grains in volatile elements and alkali metals). The processes that chemically reduce the surface and produce nanometer-scale particles on Mercury are suggested to be more effective than similar processes on the Moon. Estimated abundances of nanometer-scale particles can account for Mercury's dark surface relative to that of the Moon without requiring macroscopic grains of opaque minerals. The presence of nanometer-scale particles may also account for Mercury's relatively featureless visible-near-infrared reflectance spectra. Characteristics of material returned from asteroid 25143 Itokawa demonstrate that this nanometer-scale material need not be pure iron, raising the possibility that the nanometer-scale material on Mercury may have a composition different from iron metal [such as (Fe,Mg)S]. The expected depletion of volatiles and particularly alkali metals from solar-wind interaction processes are inconsistent with the detection of sodium, potassium, and sulfur within the regolith. One plausible explanation invokes a larger fine fraction (grain size less than 45 micron) and more radiation-damaged grains than in the lunar surface material to create a regolith that is a more efficient reservoir for these volatiles. By this view the volatile elements detected are present not only within the grain structures, but also as adsorbates within the regolith and deposits on the surfaces of the regolith grains. The comparisons with findings from the Moon and asteroids provide a basis for predicting how compositional modifications induced by space weathering have affected Mercury's surface composition.

Weathering↗
NASA NTRS1975

Shock-wave-induced turbulent boundary-layer separation at hypersonic speeds

An experiment is described that tests and guides computations of the interaction of a shock wave with a turbulent boundary layer. Numerical solutions of the time-averaged Navier-Stokes equations for the entire flow field employing algebraic eddy viscosity and turbulent Prandtl number models for shear stress and heat flux are presented and used to illustrate the dependence of the computations on the particulars of the turbulence models. To guide modifications in the models, the mean flow profiles and surface measurements of pressure, shear, and heat flux are analyzed critically. The results show that the models of eddy viscosity require substantial modifications in the interaction region. Improved solutions employing the experimentally modified models are presented.

Horstman, C. C.↗
NASA NTRS1992

Polyethylene Glycol Propionaldehydes

New class of compounds derived from polyethylene glycol (PEG's) namely, PEG-propionaldehydes, offers two important advantages over other classes of PEG aldehyde derivatives: compounds exhibit selective chemical reactivity toward amino groups and are stable in aqueous environment. PEG's and derivatives used to couple variety of other molecules, such as, to tether protein molecules to surfaces. Biotechnical and biomedical applications include partitioning of two phases in aqueous media; immobilization of such proteins as enzymes, antibodies, and antigens; modification of drugs; and preparation of protein-rejecting surfaces. In addition, surfaces coated with PEG's and derivatives used to control wetting and electroosmosis. Another potential application, coupling to aminated surfaces.

Harris, Joe M.↗
NASA NTRS1986

Experimental evidence for modifying the current physical model for ice accretion on aircraft surfaces

Closeup movies, still photographs, and other experimental data suggest that the current physical model for ice accretion needs significant modification. At aircraft airspeeds there was no flow of liquid over the surface of the ice after a short initial flow, even at barely subfreezing temperatures. Instead, there were very large stationary drops on the ice surface that lose water from their bottoms by freezing and replenish their liquid by catching the microscopic cloud droplets. This observation disagrees with the existing physical model, which assumes there is a thin liquid film continuously flowing over the ice surface. With no such flow, the freezing-fraction concept of the model fails when a mass balance is performed on the surface water. Rime ice does, as the model predicts, form when the air temperature is low enough to cause the cloud droplets to freeze almost immediately on impact. However, the characteristic shapes of horn-glaze ice or rime ice are primarily caused by the ice shape affecting the airflow locally and consequently the droplet catch and the resulting ice shape. Ice roughness greatly increases the heat transfer coefficient, stops the movement of drops along the surface, and may also affect the airflow initially and thereby the droplet catch. At high subreezing temperatures the initial flow and shedding of surface drops have a large effect on the ice shape. At the incipient freezing limit, no ice forms.

Olsen, W.↗
NASA NTRS1976

The evolution of the clear air convective layer revealed by surface-based remote sensors

Results are reported for simultaneous observations of the growth and decay of the clear-air convective mixing layer near a coastline, which were made with an FM-CW radar, a high-power narrow-beam S-band radar, and an acoustic echo sounder. The main purpose of this study was to determine the relationship between the rise rate of the convective depth and the lapse rate of temperature, particularly in the morning hours. The results indicate that the three remote sensors can provide excellent mutually supporting data on the convective depth. It is found that this depth is well behaved during the day and that its rise rate varies roughly linearly with the inverse square root of the temperature lapse rate during the morning. The data suggest that some models concerning the rise rate require modification, since these models imply that the surface heat flux would have to be unreasonably large to produce the observed relationship.

Noonkester, V. R.↗
NASA NTRS1994

Improvements to TOVS retrievals over sea ice and applications to estimating Arctic energy fluxes

Modeling studies suggest that polar regions play a major role in modulating the Earth's climate and that they may be more sensitive than lower latitudes to climate change. Until recently, however, data from meteorological stations poleward of 70 degs have been sparse, and consequently, our understanding of air-sea-ice interaction processes is relatively poor. Satellite-borne sensors now offer a promising opportunity to observe polar regions and ultimately to improve parameterizations of energy transfer processes in climate models. This study focuses on the application of the TIROS-N operational vertical sounder (TOVS) to sea-ice-covered regions in the nonmelt season. TOVS radiances are processed with the improved initialization inversion ('3I') algorithm, providng estimates of layer-average temperature and moisture, cloud conditions, and surface characteristics at a horizontal resolution of approximately 100 km x 100 km. Although TOVS has flown continuously on polar-orbiting satellites since 1978, its potential has not been realized in high latitudes because the quality of retrievals is often significantly lower over sea ice and snow than over the surfaces. The recent availability of three Arctic data sets has provided an opportunity to validate TOVS retrievals: the first from the Coordinated Eastern Arctic Experiment (CEAREX) in winter 1988/1989, the second from the LeadEx field program in spring 1992, and the third from Russian drifting ice stations. Comparisons with these data reveal deficiencies in TOVS retrievals over sea ice during the cold season; e.g., ice surface temperature is often 5 to 15 K too warm, microwave emissivity is approximately 15% too low at large view angles, clear/cloudy scenes are sometimes misidentified, and low-level inversions are often not captured. In this study, methods to reduce these errors are investigated. Improvements to the ice surface temperature retrieval have reduced rms errors from approximately 7 K to 3 K; correction of microwaves (50 GHz) brightness temperatures for view angle dependence now allows the surface type (open water versus sea ice) to be determined; modifications to the clear/cloud tests have improved cloud detection over sea ice, especially where it is inhomogeneous; and improved surface temperature estimates have resulted in more successful diagnoses of low-level stratification. Applications of improved retrievals to studies of the Arctic energy budget are encouraging. Preliminary calculations of air-ice stress vectors, 10-m wind speed, and horizontal advection of heat and moisture are presented.

Francis, Jennifer A.↗
NASA NTRS1985

The Deep Structure of Lunar Basins: Clues to the Understanding of Basin Formation and Modification

Basin excavation has played a major role in shaping the surface and subsurface of the Moon. Though photogeologic observations provide estimates for the present volumes of lunar impact basins and their ejecta deposits, there is not sufficient information to describe completely either the geometry of the basins at the time of impact or their modification with time. Determination of the structure of the crust and upper mantle beneath large basins can provide important insight into the thermal and mechanical processes associated with basin formation and modification as well as the differences in these processes as functions of basin age and size. Using observed gravity and topography together with the seismically determined crustal thickness of the central nearside, a model for the structure of the crust and upper mantle of the nearside of the Moon is presented. With this model the deep structure of the largest lunar basins are compared. The implications for the processes of basin formation and modification at different stages in lunar history are explored.

Bratt, S. R.↗
NASA NTRS1979

Automated Array Assembly, Phase 2

The solar cell module process development activities in the areas of surface preparation are presented. The process step development was carried out on texture etching including the evolution of a conceptual process model for the texturing process; plasma etching; and diffusion studies that focused on doped polymer diffusion sources. Cell processing was carried out to test process steps and a simplified diode solar cell process was developed. Cell processing was also run to fabricate square cells to populate sample minimodules. Module fabrication featured the demonstration of a porcelainized steel glass structure that should exceed the 20 year life goal of the low cost silicon array program. High efficiency cell development was carried out in the development of the tandem junction cell and a modification of the TJC called the front surface field cell. Cell efficiencies in excess of 16 percent at AM1 have been attained with only modest fill factors. The transistor-like model was proposed that fits the cell performance and provides a guideline for future improvements in cell performance.

Carbajal, B. G.↗
NASA NTRS1986

Aircraft control surface failure detection and isolation using the OSGLR test

The performance of the orthogonal series generalized likelihood ratio (OSGLR) test in detecting and isolating commercial aircraft control surface and actuator failures is evaluated. A modification to incorporate age-weighting which significantly reduces the sensitivity of the algorithm to modeling errors is presented. The steady-state implementation of the algorithm based on a single linear model valid for a cruise flight condition is tested using a nonlinear aircraft simulation. A number of off-nominal no-failure flight conditions including maneuvers, nonzero flap deflections, different turbulence levels and steady winds were tested. Based on the no-failure decision functions produced by off-nominal flight conditions, the failure detection and isolation performance at the nominal flight condition was determined. The extension of the algorithm to a wider flight envelope by scheduling on dynamic pressure and flap deflection is examined. Based on this testing, the OSGLR algorithm should be capable of detecting control surface failures that would affect the safe operation of a commercial aircraft. Isolation may be difficult if there are several surfaces which produce similar effects on the aircraft. Extending the algorithm over the entire operating envelope of a commercial aircraft appears feasible.

Bonnice, W. F.↗
NASA NTRS1991

The role of nonuniform internal heating in Triton's energy budget

Triton's large heliocentric distance and high albedo, combined with its unusually large silicate mass fraction, make internal heating more important in its energy budget than in that of any other icy satellite. Brown et al. have recently estimated that the average radiogenic heat flux (which is probably between 3.3 and 6.6 mW/sq m depending on core size and composition) may equal 5 to 20 pct. of the average absorbed insolation. On a global scale, this additional energy input appreciably increases the thermal emissivity required to be consistent with the observed surface temperature. Brown et al. also speculated that spatial variations of the internal flux may change the local sublimation deposition balance enough to lead to observable modifications of the distribution of volatiles on Triton's surface. An attempt is made to estimate the magnitude of internal heat flux variations due to the insulating effect of the polar caps, to mantle convection, and to cryovolcanism; the importance is evaluated of these variations in modifying the volatile distribution.

Kirk, R. L.↗
NASA NTRS1951

On the turbulent friction layer for rising pressure

Among the information presented are included displacement, momentum, and kinetic energy thicknesses, shearing stress distributions across boundary layer, and surface friction coefficients. The Gruschwitz method and its modifications are examined and tested. An energy theorem for the turbulent boundary layer is introduced and discussed but does not lead to a method for the prediction of the behavior of the turbulent boundary layer because relations for the shearing stress and the surface friction are lacking.

SKIN FRICTION - PLATES↗
NASA NTRS2008

Molecular Dynamics Simulations of Adhesion at Epoxy Interfaces

The effect of moisture on adhesives used in aerospace applications can be modeled with chemically specific techniques such as molecular dynamics simulation. In the present study, the surface energy and work of adhesion are calculated for epoxy surfaces and interfaces, respectively, by using molecular dynamics simulation. Modifications are made to current theory to calculate the work of adhesion at the epoxy-epoxy interface with and without water. Quantitative agreement with experimental values is obtained for the surface energy and work of adhesion at the interface without water. The work of adhesion agrees qualitatively with the experimental values for the interface with water: the magnitude is reduced 15% with respect to the value for the interface without water. A variation of 26% in the magnitude is observed depending on the water configuration at a concentration of 1.6 wt%. The methods and modifications to the method that are employed to obtain these values are expected to be applicable for other epoxy adhesives to determine the effects of moisture uptake on their work of adhesion.

Frankland, Sarah-Jane V.↗
NASA NTRS1999

The Topography and Basin Deposits of the Equatorial Highlands: A MGS-Viking Synergistic Study

One of the greatest unresolved issues concerns the evolution of Mars early in its history; during the time period that accretion was winding down but the frequency of impacting debris was still heavy. Ancient cratered terrain that has only been moderately modified since the period of heavy bombardment covers about a quarter of the planet's surface but the environment during its formation is still uncertain. This terrain was dominantly formed by cratering. But unlike on the airless Moon, the impacting craters were strongly modified by other contemporary surface processes that have produced distinctive features such as: 1) dendritic channel networks, 2) rimless, flatfloored craters, 3) obliteration of most craters smaller than a few kilometers in diameter (except for post heavy-bombardment impacts), and 4) smooth intercrater plains. The involvement of water in these modification processes seems unavoidable, but interpretations of the surface conditions on early Mars range from the extremes of: 1) the "cold" model which envisions a thin atmosphere and surface temperatures below freezing except for local hydrothermal springs; and 2) the "warm" model, which invokes a thick atmosphere, seasonal temperatures above freezing in temperate and equatorial regions, and at least occasional precipitation as part of an active hydrological cycle. The nature of hydrologic cycles, if they occurred on Mars, would have been critically dependent on the environment. The resolution of where along this spectrum the actual environment of early Mars occurred is clearly a major issue, particularly because the alternate scenarios have much different implications about the possibility that life might have evolved on Mars. Additional information is contained in the original extended abstract.

Moore, J. M.↗
NASA NTRS1999

Topographic Evaluation of Mars 2001 Candidate Landing Sites: A MGS-Viking Synergistic Study

One of the greatest unresolved issues concerns the evolution of Mars early in its history; during the time period that accretion was winding down but the frequency of impacting debris was still heavy. Ancient cratered terrain that has only been moderately modified since the period of heavy bombardment covers about a quarter of the planet's surface but the environment during its formation is still uncertain. This terrain was dominantly formed by cratering. But unlike on the airless Moon, the impacting craters were strongly modified by other contemporary surface processes that have produced distinctive features such as 1) dendritic channel networks, 2) rimless, flatfloored craters, 3) obliteration of most craters smaller than a few kilometers in diameter (except for post heavy-bombardment impacts), and 4) smooth intercrater plains. The involvement of water in these modification processes seems unavoidable, but interpretations of the surface conditions on early Mars range from the extremes of 1) the "cold" model which envisions a thin atmosphere and surface temperatures below freezing except for local hydrothermal springs; and 2) the "warm" model, which invokes a thick atmosphere, seasonal temperatures above freezing in temperate and equatorial regions, and at least occasional precipitation as part of an active hydrological cycle. The nature of hydrologic cycles, if they occurred on Mars, would have been critically dependent on the environment. The resolution of where along this spectrum the actual environment of early Mars occurred is clearly a major issue, particularly because the alternate scenarios have much different implications about the possibility that life might have evolved on Mars.

Moore, J. M.↗
NASA NTRS1976

Correction factory techniques for improving aerodynamic prediction methods

A method for correcting discrete element lifting surface theory to reflect given experimental data is presented. Theoretical pressures are modified such that imposed constraints are satisfied while minimizing the changes to the pressures. Several types of correction procedures are presented and correlated; (1) scaling of pressures; (2) scaling of downwash values; and (3) addition of an increment to the downwash that is proportioned to pressure. Some special features are included in these methods and they include: (1) consideration of experimental data from multiple deflection modes, (2) limitation of the amplitudes of the correction factors, and (3) the use of correction factor mode shapes. These methods are correlated for cases involving all three Mach Number ranges using a FORTRAN IV computer program. Subsonically, a wing with an oscillating partial span control surface and a wing with a leading edge droop are presented. Transonically a two-dimensional airfoil with an oscillating flap is considered. Supersonically an arrow wing with and without camber is analyzed. In addition to correction factor methods an investigation is presented dealing with a new simplified transonic modification of the two-dimensional subsonic lifting surface theory. Correlations are presented for an airfoil with an oscillating flap.

Giesing, J. P.↗
NASA NTRS1977

The clouds of Venus. II - An investigation of the influence of coagulation on the observed droplet size distribution

An approximate numerical technique is used to investigate the influence of coagulation, sedimentation and turbulent motions on the observed droplet size distribution in the upper layers of the Venus clouds. If the cloud mass mixing ratio is less than 0.000001 at 250 K or the eddy diffusivity throughout the cloud is greater than 1,000,000 sq cm per sec, then coagulation is unimportant. In this case, the observed droplet size distribution is the initial size distribution produced by the condensation of the droplets. It is found that all cloud models with droplet formation near the cloud top (e.g., a photochemical model) must produce the observed droplet size distribution by condensation without subsequent modification by coagulation. However, neither meteoritic or surface dust can supply sufficient nucleating particles to account for the observed droplet number density. If the cloud droplets are formed near the cloud bottom, the observed droplet size distribution can be produced solely by the interaction of coagulation and dynamics; all information about the initial size distribution is lost. If droplet formation occurs near the cloud bottom, the lower atmosphere of Venus is oxidizing rather than reducing.

Rossow, W. B.↗
NASA NTRS1979

Silicon Solar Cell Process Development, Fabrication and Analysis, Phase 1

Solar cells from RTR ribbons, EFG (RF and RH) ribbons, dendritic webs, Silso wafers, cast silicon by HEM, silicon on ceramic, and continuous Czochralski ingots were fabricated using a standard process typical of those used currently in the silicon solar cell industry. Back surface field (BSF) processing and other process modifications were included to give preliminary indications of possible improved performance. The parameters measured included open circuit voltage, short circuit current, curve fill factor, and conversion efficiency (all taken under AM0 illumination). Also measured for typical cells were spectral response, dark I-V characteristics, minority carrier diffusion length, and photoresponse by fine light spot scanning. the results were compared to the properties of cells made from conventional single crystalline Czochralski silicon with an emphasis on statistical evaluation. Limited efforts were made to identify growth defects which will influence solar cell performance.

Yoo, H. I.↗