Molybdenum Disulfide/Diselenide-Laser-Induced Graphene–Glycine Oxidase Composite for Electrochemical Sensing of Glyphosate
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Zribi, Rayhane [Department of Engineering, Univers↗
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Hydrological and Thermal Dynamics of a Supra‐Permafrost Subterranean Estuary
Subterranean estuaries (STEs), where groundwater interacts with seawater, influence surface and subsurface coastal ecology and biogeochemistry. In Arctic-STEs overlying permafrost, groundwater flow and heat transport determine the fate of organic matter. Yet, direct observations of groundwater flow and heat and solute transport processes in Arctic STEs remain limited. This study characterized groundwater flow paths and fluxes and heat transport within an Arctic-STE along Alaska's Beaufort Sea coast during thawing, summer, and freeze-up. Intertidal seabed temperature-depth profiles collected along a 10-m transect captured the active groundwater flow period, from thaw and flow onset in mid-June to freeze-up in late-September. During this period, aquifer geometry evolved non-uniformly due to spatially varying thaw rates across the STE (mean (m) thaw depths–beach: 0.25 to 0.55–0.6 m on 20 June, 25 July, 1 October; seabed: 0.6–0.9 m from 25 July to 1 October). Groundwater and surface water levels, salinity, and subsurface temperature profiles measured over tidal time scales were interpreted alongside groundwater flow-heat transport numerical simulations. Fresh groundwater discharge was sporadic during thawing (m: 0.32 m 3 /day/m), abundant in summer (m: 0.45 m 3 /day/m), and was largely absent during freeze-up. During freeze-up, groundwater flow was driven exclusively by seawater recirculation via tidal pumping (from thawing to summer to freeze-up: 0.00025–0.15–0.5 m3/day/m) and convection. Heat advection dominated near aquatic interfaces (shaping intertidal ice), and conduction controlled vertical temperature gradients in low-flow and unsaturated sediments. These findings will help predict how prolonged summers will alter Arctic-STE cryo-hydrology and biogeochemistry.
54 ENVIRONMENTAL SCIENCES↗
The XPS of Azines: A Comparative Study
A detailed analysis is presented of the X-ray Photoelectron Spectroscopy, XPS, of thin films of three Azines: Pyrazine, Pyridine and Pyrimidine. This includes not only the binding energies of the various core ionizations but also their intensities. A major focus is to compare our theoretical predictions with our measured XPS for N(1s) and C(1s) as a basis for assigning the features and for justifying the broadening parameters that must be applied to the theoretical results. The C(1s) XPS of Pyridine and Pyrimidine are significantly broadened because of unresolved XPS for their inequivalent C atoms. The extent of the binding energy, BE, shifts and the XPS intensities for the unique C atoms, which are responsible for this broadening, are obtained from the theory. The additional broadening parameters to be applied to the theory to enable comparison with measured XPS are discussed in terms of lifetime broadening, experimental resolution, and BE shifts in different layers of the thin film. A novel feature of our analysis is that it is necessary to invoke surface core level shifts to explain and to justify the broadenings needed to apply to the theoretical results to have a complete comparison with the measured XPS. The results presented have general value for extracting chemical and physical information from XPS.
Bagus, Paul↗
Constraints on the origin of the radio synchrotron background via angular correlations
ABSTRACT The origin of the radio synchrotron background (RSB) is currently unknown. Its understanding might have profound implications in fundamental physics or might reveal a new class of radio emitters. In this work, we consider the scenario in which the RSB is due to extragalactic radio sources and measure the angular cross-correlation of Low-Frequency Array (LOFAR) images of the diffuse radio sky with matter tracers at different redshifts, provided by galaxy catalogues and cosmic microwave background lensing. We compare these measured cross-correlations to those expected for models of RSB sources. We find that low-redshift populations of discrete sources are excluded by the data, while higher redshift explanations are compatible with available observations. We also conclude that at least 20 per cent of the RSB surface brightness level must originate from populations tracing the large-scale distribution of matter in the Universe, indicating that at least this fraction of the RSB is of extragalactic origin. Future measurements of the correlation between the RSB and tracers of high-redshift sources will be crucial to constraining the source population of the RSB.
79 ASTRONOMY AND ASTROPHYSICS↗
Clean quantum point contacts in an InAs quantum well grown on a lattice-mismatched InP substrate
Strong spin-orbit coupling, the resulting large g factor, and small effective mass make InAs an attractive material platform for inducing topological superconductivity. The surface Fermi level pinning in the conduction band enables highly transparent ohmic contact without excessive doping. In this study, we investigate electrostatically defined quantum point contacts (QPCs) in a deep-well InAs two-dimensional electron gas. Despite the 3.3% lattice mismatch between the InAs quantum well and the InP substrate, we report clean QPCs with up to eight pronounced quantized conductance plateaus at zero magnetic field. Source-drain dc bias spectroscopy reveals a harmonic confinement potential with a nearly 5 meV subband spacing. We find a many-body exchange interaction enhancement for the out-of-plane g factor |$g^{*}_{⊥}$|=27±1 , whereas the in-plane g factor is isotropic |$g^{*}_{x}$|=|$g^{*}_{y}$|=12±2 , close to the bulk value for InAs.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Impacts of the Additive Manufacturing Process on the Roughness of Engine Scale Vanes and Cooling Channels
Abstract By leveraging the additive manufacturing (AM) platform, development time and costs for turbine component testing can be reduced relative to traditional investment casting. Surface roughness is a key characteristic of the additive manufacturing process that can impact flow, heat transfer, and mechanical integrity of printed components. There are multiple design and build considerations that result in variability in surface roughness, especially when additively fabricating complicated three-dimensional vanes and internal cooling passages. This study characterizes the surface roughness of internal cooling passages, vanes, and flat external surface samples made using additive manufacturing, specifically the direct metal laser sintering process. The samples were manufactured with various wall thicknesses, layer thicknesses, build locations, build directions, and on different AM machines. A combination of computed tomography scanning and optical profilometry was used to evaluate surface roughness levels. The data indicate that the dominant factors in roughness for a given layer thickness are a function of wall thickness, build location, and build direction.
Engineering↗
Rotating holder permits accurate grinding of metallurgical microsamples
Metallurgical microsamples are held in a fixture which rotates the sample across a rotating grinding wheel. The dual rotation results in a level, flat surface on the sample.
Cramer, D. L.↗
Structural response to inflight acoustic and aerodynamic environments
Estimation of inflight acoustic and fluctuating aerodynamic environments and resulting surface vibration levels
STRUCTURAL VIBRATION↗
Measurements of sound radiation from cavities at subsonic speeds
To better understand the physical mechanisms responsible for noise generated by flow over cavities with a range of dimensions common to commercial aircraft, a series of measurements of farfield sound pressure level, fluctuating surface pressure, and drag coefficient was made. An examination of the resultant data shows that two theoretical models are needed for this range of dimensions. The shallow cavity (width-to-depth ratio larger than 1.0) can be approximated by a dipole located near the downstream edge of the cavity and the deep cavity (ratio less than 1.0) can be approximated by a dipole located near the downstream edge with the superimposed effects of the upstream edge of the cavity.
Yu, Y. H.↗
A linearized theory method of constrained optimization for supersonic cruise wing design
A linearized theory wing design and optimization procedure which allows physical realism and practical considerations to be imposed as constraints on the optimum (least drag due to lift) solution is discussed and examples of application are presented. In addition to the usual constraints on lift and pitching moment, constraints are imposed on wing surface ordinates and wing upper surface pressure levels and gradients. The design procedure also provides the capability of including directly in the optimization process the effects of other aircraft components such as a fuselage, canards, and nacelles.
Miller, D. S.↗
Surface photovoltage due to photo-thermo-ionization of surface states - GaAs
Surface photovoltage spectroscopy was employed for studying the mechanism of subbandgap photoionization transitions from surface states in GaAs surfaces. It was found that the photoionization cross-section exhibits a maximum for a photon energy of about 0.9 eV. This finding indicates a photo-thermal mechanism of photovoltage, i.e., photo-induced transitions between surface state levels and the subsequent thermal ejection of electrons from the upper level into the conduction band.
Morawski, A.↗
Moon-Mercury - Large impact structures, isostasy and average crustal viscosity
It is shown that Mercury's surface has only 70% as many large craters (of at least 200 km in diameter) as the moon. The density of Mercurian impact craters having diameters over 400 km is 30% of that of the moon, and for craters with diameters between 400 and 700 km, Mercurian density is 21% of that of the moon. The size-frequency distribution curve of Mercury is the same as the lunar cumulative -2 slope. The Mercurian curve, however, lies well below the 10% surface saturation level of the lunar curve. This may indicate that the old, heavily-cratered Mercurian terrain is not presently in a state of cratering equilibrium. The differences in crater and basin densities observed between Mercury and the moon may be functions of crater-production rates or of different crustal histories. The total isostatic compensation of impact craters having diameters of about 800 km suggests that the average viscosity of the Mercurian crust during approximately the past 4 eons was the same as that of the moon.
Schaber, G.↗
Nonreflective boundary control of a vibrating string
One of the important applications in the developing Large Space Systems Technology will be the electrostatically controlled membrane mirror antenna. A high level of surface quality is achievable using electrostatically tensioned membranes in which surface accuracy is obtained through active control. Electrostatic actuators behind the membrane surface would provide a means of obtaining the prescribed surface shape and also be utilized to suppress the structural vibrations in the system. The surface quality, in this case, would be limited by the size, force field shape, and the number of the electrostatic actuators. An additional control capability is to introduce boundary control at the membrane perimeter. Using this additional control mechanism, structural vibrations can be absorbed at the boundary without being reflected back into the interior regions of the membrane antenna. In this paper, boundary control of a vibrating string is studied. For this system, a nonreflective boundary control is developed in which waves reaching the boundary are absorbed by the appropriate control movement of the boundary. The control is closed-loop and utilizes a single measurement close to the boundary. The closed-loop control is a delay of the measurement. The delay is determined by the velocity of wave propagation in the string and the location of the sensor.
Caglayan, A. K.↗
Flowfield calculations past an entry probe with ablated nose shape
The effects of ablated nose shapes on the flowfield solutions are studied, using a time-dependent finite-difference method developed by Kumar, et al. (1979). Solutions are obtained for the laminar flow of a radiating mixture of H-He in chemical equilibrium past a blunt axisymmetric body at zero angle of attack. The freestream conditions correspond to a point on a typical Jovian entry trajectory, and the initial probe shape is a 45-deg half-angle spherically blunted cone. It is found that as nose bluntness increases, the following occur: in the nose region, shock standoff distances and radiative heating rates increase substantially; surface pressure level increases, but convective heating rates decrease.
Kumar, A.↗
Response of stiffened sandwich panels
An increasingly important part of the design of skin-stringer systems, such as those found in flight vehicles, is the ability to reduce surface vibration levels when they are subjected to the dynamic loads of jet, or propeller noise. One common method of reducing the response of these structures is by layered construction using viscoelastic materials. Thus analytical methods to describe such systems are essential.
Slazak, M.↗
Determination of turbidity patterns in Lake Chicot from LANDSAT MSS imagery
A historical analysis of all the applicable LANDSAT imagery was conducted on the turbidity patterns of Lake Chicot, located in the southeastern corner of Arkansas. By examining the seasonal and regional turbidity patterns, a record of sediment dynamics and possible disposition can be obtained. Sketches were generated from the suitable imagery, displaying different intensities of brightness observed in bands 5 and 7 of LANDSAT's multispectral scanner data. Differences in and between bands 5 and 7 indicate variances in the levels of surface sediment concentrations. High sediment loads are revealed when distinct patterns appear in the band 7 imagery. Additionally, the upwelled signal is exponential in nature and saturates in band 5 at low wavelengths for large concentrations of suspended solids.
Lecroy, S. R.↗
Determination of circulation and turbidity patterns in Kerr Lake from LANDSAT MSS imagery
The LANDSAT imagery was historically analyzed to determine the circulation and turbidity patterns of Kerr Lake, located on the Virginia-North Carolina border. By examining the seasonal and regional turbidity and circulation patterns, a record of sediment transport and possible disposition can be obtained. Sketches were generated, displaying different intensities of brightness observed in bands 5 and 7 of LANDSAT's multispectral scanner data. Differences in and between bands 5 and 7 indicate variances in the levels of surface sediment concentrations. High sediment loads are revealed when distinct patterns appear in the band 7 imagery. The upwelled signal is exponential in nature and saturates in band 5 at low wavelengths for large concentrations of suspended solids.
Lecroy, S. R.↗
Determination of turbidity patterns in Lake Chicot from LANDSAT MSS imagery
A historical analysis of all the applicable LANDSAT imagery was conducted on the turbidity patterns of Lake Chicot, located in the southeastern corner of Arkansas. By examining the seasonal and regional turbidity patterns, a record of sediment dynamics and possible disposition can be obtained. Sketches were generated from the suitable imagery, displaying different intensities of brightness observed in bands 5 and 7 of LANDSAT's multispectral scanner data. Differences in and between bands 5 and 7 indicate variances in the levels of surface sediment concentrations. High sediment loads are revealed when distinct patterns appear in the band 7 imagery. Additionally, the upwelled signal is exponential in nature and saturates in band 5 at low wavelengths for large concentrations of suspended solids.
Lecroy, S. R.↗