A closed-host bi-layer dense/porous solid electrolyte interphase for enhanced lithium-metal anode stability
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Efaw, Corey M.↗
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Design Principles of Artificial Solid Electrolyte Interphases for Lithium-Metal Anodes
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Yu, Zhiao↗
Multivalent Ion Transport in Anti-Perovskite Solid Electrolytes
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Kim, Kwangnam↗
Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte Interphase
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Cao, Chuntian↗
Probing the Lithium Substructure and Ionic Conductivity of the Solid Electrolyte Li[subscript 4]PS[s
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Strauss, Florian↗
Structure and Properties of Na 2 S–SiS 2 –P 2 S 5 –NaPO 3 Glassy Solid Electrolytes
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Chemistry↗
Interfacial Electron Transfer and Ion Solvation in the Solid Electrolyte Interphase
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Chemistry↗
Inorganic Solid Electrolyte Interphase Engineering Rationales Inspired by Hexafluorophosphate Decomposition Mechanisms
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Role of Polysulfide Anions in Solid-Electrolyte Interphase Formation at the Lithium Metal Surface in Li–S Batteries
Delineating intricate interactions between highly reactive Li-metal electrodes and the diverse constituents of battery electrolytes has been a long-standing scientific challenge in materials design for advanced energy storage devices. Here, we isolated lithium polysulfide anions (LiS 4 - ) from an electrolyte solution based on their mass-to-charge ratio and deposited them on Li-metal electrodes under clean vacuum conditions using ion soft landing (ISL), a highly controlled interface preparation technique. The molecular level precision in the construction of these model interfaces with ISL, coupled with in situ x-ray photoelectron spectroscopy and ab initio theoretical calculations, allowed us to obtain unprecedented insight into the parasitic reactions of well-defined polysulfides on Li-metal electrodes. Our study reveals that the oxide-rich surface layer, which is amenable to direct electron exchange, drives multielectron sulfur oxidation (S o → S 6+ ) processes. Furthermore, our results have substantial implications for the rational design of future Li-S batteries with improved efficiency and durability.
25 ENERGY STORAGE↗