Epr studies on oh radical identification in irradiated h20
Electron paramagetic resonance spectrum of irradiated single crystals of ice at cryogenic temperatures
CRYOGENIC TEMPERATURE↗
SEARCH · Engineering Papers
Results for “resonator temperature”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Absolute rate constants for the reaction of atomic hydrogen with ketene from 298 to 500 K
Rate constants for the reaction of atomic hydrogen with ketene have been measured at room temperature by two techniques, flash photolysis-resonance fluorescence and discharge flow-resonance fluorescence. The measured values are (6.19 + or - 1.68) x 10 to the -14th and (7.3 + or - 1.3) x 10 to the -14th cu cm/molecule/s, respectively. In addition, rate constants as a function of temperature have been measured over the range 298-500 K using the FP-RF technique. The results are best represented by the Arrhenius expression k = (1.88 + or - 1.12) x 10 to the -11th exp(-1725 + or - 190/T) cu cm/molecule/s, where the indicated errors are at the two standard deviation level.
Michael, J. V.↗
Design of Microwave Resonant Cavity Transducer. Development of sensor performance model of microwave cavity flow meter for advanced reactor high temperature fluids
High-temperature fluid reactors, such as molten salt cooled reactors (MSCR) and sodium fast reactors (SFR), are a promising advanced reactor option. Measurement of high-temperature fluid process variables, in particular the flow inside the pressure vessel, is a challenging task because of harsh environment, which includes high radiation, high temperature, and contact with highly corrosive coolant fluid. We are investigating a microwave cavity-based transducer for high-temperature fluid flow sensing. This sensor is a hollow metallic cylindrical cavity, which can be fabricated from stainless steel, and as such is expected to be resilient to radiation, high temperature and corrosive environment of MSCR and SFR. The principle of sensing consists of making one wall of the cylindrical cavity flexible enough so that dynamic pressure, which is proportional to fluid velocity, will cause membrane deflection. A cavity is characterized by its resonant frequencies. Membrane deflection causes cavity volume change, which leads to a shift in the resonant frequency. Feasibility of the flow sensor is evaluated with signal sensitivity using COMSOL computer simulations. A right cylinder geometry stainless steel cavity with dimeter of 0.8in was investigated. We choose membrane thickness of 10mil, so that corrosion anticipated to proceed at the rate of 1mil/year in liquid sodium would affect no more than 10% of the membrane. Using the properties of liquid sodium fluid, and stainless-steel material property values at 500oC, we calculate frequency shift for a range of values of fluid velocity from 0.5m/s to 2m/s. Results of computer simulations indicate measurable sensitivity to flow for this cavity design. Following these simulations, we have developed a preliminary design for fabrication of a transducer operating in microwave K-band for proof-of-principle tests.
22 GENERAL STUDIES OF NUCLEAR REACTORS↗
Two-level systems in nucleated and non-nucleated epitaxial alpha-tantalum films
Building usefully coherent superconducting quantum processors depends on reducing losses in their constituent materials. Tantalum, like niobium, has proven utility as the primary superconducting layer within highly coherent qubits. However, unlike Nb, high temperatures are typically used to stabilize the desirable body-centered-cubic phase, α-Ta, during thin film deposition. It has long been known that a thin Nb layer permits the room-temperature nucleation of α-Ta, but here we observe the epitaxial process and present few-photon microwave loss measurements in Nb-nucleated Ta films. We compare resonators patterned from Ta films grown at high temperature (500 °C) and films nucleated at room temperature, in order to understand the impact of the crystalline order on quantum coherence. In both cases, films grew with Al 2 O 3 (001) ∥ Ta (110), indicating that the epitaxial orientation is independent of temperature and is preserved across the Nb/Ta interface. We use conventional low-power spectroscopy to measure two level system (TLS) loss as well as an electric-field bias technique to measure the effective dipole moments of TLS in the surfaces of resonators. In our measurements, Nb-nucleated Ta resonators had greater loss tangent (1.5 ± 0.1 × 10 -5 ) than non-nucleated (5 ± 1× 10 -6 ) in approximate proportion to defect densities as characterized by x-ray diffraction (0.27° vs 0.18° [110] reflection width) and electron microscopy (30 vs 70 nm domain size). Furthermore, the dependence of the loss tangent on domain size indicates that the development of more ordered Ta films is likely to lead to improvements in qubit coherence times. Moreover, low-temperature α-Ta epitaxy may enable the growth of microstate-free heterostructures, which would not withstand high temperature processing.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
High-Temperature Superconducting/Ferroelectric Structures for Tunable Microwave Components
At the NASA Lewis Research Center, ferroelectric films, such as SrTiO3 and Ba(x)Sr(1-x)TiO3, are being used in conjunction with YBa2Cu3O(7-delta) high-temperature superconducting (HTS) thin films to fabricate tunable microwave components, such as filters, varactors, and local oscillators. These structures capitalize on the variation of the dielectric constant of the ferroelectric film upon the application of a dc electric field as well as on the low microwave losses exhibited by the high-temperature superconducting films relative to their conventional conductor counterparts. (For example, the surface resistance for a YBa2Cu3O(7-delta) thin film at 10 GHz and 77 K is more than two orders of magnitude lower than that of copper at the same frequency and temperature.) SrTiO3 and Ba(x)Sr(1-x)TiO3 films are used because their crystal structure and lattice parameters are similar to those of YBa2Cu3O(7-delta), thus enabling the growth of highly textured YBa2Cu3O(7-delta) films with high critical current densities on the underlying ferroelectric film, or alternatively, of highly textured ferroelectric film on the underlying YBa2Cu3O(7-delta) film. Our efforts have been concentrated so far in determining the deposition parameters required for optimal ferroelectric thin-film growth (i.e., maximum tunability and lowest loss) and in investigating different varactor configurations to determine which geometry is the most advantageous in terms of tunability, losses, and required bias for a given communication application. For example, we have observed that for optimized SrTiO3 films in a parallel plate capacitor, tunabilities of up to 47 percent and dissipation losses (tan d) of 0.05 are attainable at 1 MHz , 80 K, and within the 0- to 5-V bias range. In contrast, for an interdigital configuration, tunabilities of up to 70 percent and tan d ranging from 0.015 to 0.001 (depending on bias) have been observed at 1 MHz and 77 K within the 0- to 100-V bias range. Efforts are underway to use these results in developing tunable receiver front-end preselect filters as well as in low-phase noise, tunable local oscillators for K-band applications. These components represent a hitherto unavailable technology to meet the stringent performance requirements of foreseeable satellite and wireless communication systems (e.g., bandwidth, in-band insertion losses, out-of-band rejection, and noise, amongst others) in a more advantageous fashion than with currently available technology (e.g., dielectric-filled cavity and waveguide filters, and dielectric resonator oscillators). Prototypes of high-temperature superconducting/ferroelectric tunable components such as a low-phase noise K-band local oscillator, a preselect C-band filter, and a low-loss K-band phase shifter are under development at NASA Lewis.
Miranda, Felix A.↗
Detection of a two-phonon mode in a cuprate superconductor via polarimetric resonant inelastic x-ray scattering
Recent improvements in the energy resolution of resonant inelastic x-ray scattering experiments (RIXS) at the Cu-L 3 edge have enabled the study of lattice, spin, and charge excitations. Here, we report on the detection of a low-intensity signal at 140 meV, twice the energy of the bond-stretching (BS) phonon mode, in the cuprate superconductor Bi 2 Sr 2 CaCu 2 O 8+x (Bi-2212). Ultrahigh-resolution polarimetric RIXS measurements allow us to resolve the outgoing polarization of the signal and identify this feature as a two-phonon excitation. Further, here we study the connection between the two-phonon mode and the BS one-phonon mode by constructing a joint density of states toy model that reproduces the key features of the data.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Iridium Oxide Coordinatively Unsaturated Active Sites Govern the Electrocatalytic Oxidation of Water
A special membrane electrode assembly to measure operando X-ray absorption spectra and resonant photoemission spectra of mesoporous templated iridium oxide films is used. These films are calcined to different temperatures to mediate the catalyst activity. By combining operando resonant photoemission measurements of different films with ab initio simulations these are able to unambiguously distinguish µ 2 -O (bridging oxygen) and µ 1 -O (terminal oxygen) in the near-surface regions of the catalysts. The intrinsic activity of iridium oxide scales with the formation of µ1-O (terminal oxygen) is found. Importantly, it is shown that the peroxo species do not accumulate under reaction conditions. Rather, the formation of µ 1 -O species, which are active in O-O bond formation during the OER, is the most oxidized oxygen species observed, which is consistent with an O-O rate-limiting step. Thus, the oxygen species taking part in the electrochemical oxidation of water on iridium electrodes are more involved and complex than previously stated. This result highlights the importance of employing theory together with true and complementary operando measurements capable of probing different aspects of catalysts surfaces during operation.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Procedures for Tuning a Multiresonator Photonic Filter
Two procedures have been devised for tuning a photonic filter that comprises multiple whispering-gallery mode (WGM) disk resonators. As used here, tuning signifies locking the filter to a specific laser frequency and configuring the filter to obtain a desired high-order transfer function. The main problem in tuning such a filter is how to select the correct relative loading of the resonators to realize a prescribed filter function. The first of the two procedures solves this problem. As temperature gradients develop during operation, the spectra of individual resonators tend to drift, primarily because of the thermorefractive effect. Thus, there arises the additional problem of how to adjust the tuning during operation to maintain the desired transfer function. The second of the two procedures solves this problem. To implement the procedures, it is necessary to incorporate the resonators into an apparatus like that of Figure 1. In this apparatus, the spectrum of each resonator can be adjusted individually, via the electro-optical effect, by adjusting a bias voltage applied to that resonator. In addition, the positions of the coupling prisms and resonators can be adjusted to increase or reduce the gaps between them, thereby reducing or increasing, respectively, the optical coupling between them. The optical power (Pi) in resonator i is monitored by use of a tracking photodiode. Another tracking diode monitors the power reflected from the input terminal (Pr), and still others monitor the input power (Pin) and output power (Po). The readings of these photodiodes are used to guide the tuning adjustments described in this paper.
Matsko, Andrey↗
Structural origin of resonant diffraction in RuO2
We report Ru L3-edge resonant X-ray diffraction studies on single crystal and (001) oriented epitaxial films of RuO2. We investigate the distinct Q = (100) and (001) Bragg-forbidden reflections as a function of incident energy, azimuthal angle, and temperature. The results show that the observed resonant diffraction in RuO2 is fully consistent with a resonant charge anisotropy signal of structural origin permitted by the parent (non-magnetic) rutile P42/mnm space group. These results significantly constrain the magnetic contribution to the resonant diffraction signal and indicate the unlikely existence of k = 0 antiferromagnetic order in RuO2.
36 MATERIALS SCIENCE↗
A new approach for resonance treatment of doubly heterogeneous fuel using the RSE method
A new resonance calculation method for the doubly-heterogeneous (DH) fuels such as high- temperature gas-cooled reactor fuel is proposed based on the resonance calculation based on Spectral Expansion (RSE) method. The concept of pointwise disadvantage factor for fuel grain is taken into account to treat the DH fuels. The verification calculation is carried out for simplified single fuel cell and fuel compact consisting of five fuel cells and graphite moderator. The calculation results indicate that the present method can appropriately handle the space- dependent self-shielding effect for DH fuels. (authors)
22 GENERAL STUDIES OF NUCLEAR REACTORS↗
Magnetic excitations and absence of charge order in the van der Waals ferromagnet Fe 4.75 GeTe 2
Understanding the ground state of van der Waals (vdW) magnets is crucial for designing devices leveraging these platforms. Here, we investigate the magnetic excitations and charge order in Fe 4.75 GeTe 2 , a vdW ferromagnet with ≈ 315 K Curie temperature. Using Fe L 3 -edge resonant inelastic X-ray scattering, we observe a dual nature of magnetic excitations, comprising a coherent magnon and a broad non-dispersive continuum extending up to 150 meV, 50% higher than in Fe 2.72 GeTe 2 . The continuum intensity is sinusoidally modulated along the stacking direction L, with a period matching the inter-slab distance. Our results indicate that while the dual character of the magnetic excitations is generic to Fe-Ge-Te vdW magnets, Fe 4.75 GeTe 2 exhibits a longer out-of-plane magnetic correlation length, suggesting enhanced 3D magnetic character. Furthermore, resonant X-ray diffraction reveals that previously reported ±(1/3, 1/3, L) peaks originate from crystal structure rather than from charge order.
Ferromagnetism↗
Gapped magnetic ground state in quantum spin liquid candidate {kappa}-(BEDT-TTF){sub 2}Cu{sub 2}(CN){sub 3}.
Geometrical frustration, quantum entanglement, and disorder may prevent long-range ordering of localized spins with strong exchange interactions, resulting in an exotic state of matter. kappa-(BEDT-TTF)(2)Cu-2(CN)(3) is considered the prime candidate for this elusive quantum spin liquid state, but its ground-state properties remain puzzling. We present a multifrequency electron spin resonance (ESR) study down to millikelvin temperatures, revealing a rapid drop of the spin susceptibility at 6 kelvin. This opening of a spin gap, accompanied by structural modifications, is consistent with the formation of a valence bond solid ground state. We identify an impurity contribution to the ESR response that becomes dominant when the intrinsic spins form singlets. Probing the electrons directly manifests the pivotal role of defects for the low-energy properties of quantum spin systems without magnetic order.
Miksch, Bjorn↗
Ground-State In-Plane Light-Holes in GaAs/AlGaAs Structures [Book Chapter]
We have performed low-temperature magnetoluminescence, far-infrared cyclotron resonance, and magneto-transport measurements on narrow (4.5 nm) GaAs/Al 0.25 Ga 0.75 As single quantum-wells. The ground state in-plane valence band was found to be light and very nonparabolic, i.e., at zone center, the valence band mass is m v ≈ 0. 1 and for E f ≈ 10 meV, m v ≈ 0.25.
36 MATERIALS SCIENCE↗
The electrostatic energy per degree of freedom of a two-temperature plasma.
Electrostatic energy per degree of freedom of two-temperature plasma examined for validity of resonant approximations in ion wave region
PLASMA WAVE↗
Temperature-dependent hyperfine coupling constants of Mn super 2 super plus in fluorides.
Hyperfine coupling constants of positive divalent Mn ion in calcium and barium fluorides, measuring temperature dependence by analyzing electron spin resonance spectrum
Gigante, J.↗
Development of procedures for calculating stiffness and damping properties of elastomers in engineering applications. Part 2: Elastomer characteristics at constant temperature
Dynamic properties of a commerical polybutadiene compound were determined at a constant temperature of 32 C by a forced-vibration resonant mass type of apparatus. The constant thermal state of the elastomer was ensured by keeping the ambient temperature constant and by limiting the power dissipation in the specimen. Experiments were performed with both compression and shear specimens at several preloads (nominal strain varying from 0 to 5 percent), and the results are reported in terms of a complex stiffness as a function of frequency. Very weak frequency dependence is observed and a simple power law type of correlation is shown to represent the data well. Variations in the complex stiffness as a function of preload are also found to be small for both compression and shear specimens.
Gupta, P. K.↗
Laser applications to atmospheric sciences: A bibliography
A bibliography is given of 1460 references of the applications of lasers to atmospheric sciences. The subjects covered include: aerosols; clouds; the distribution and motion of atmospheric natural and man-made constituents; winds; temperature; turbulence; scintillation; elastic, Raman and resonance scattering; fluorescence; absorption and transmission; the application of the Doppler effect and visibility. Instrumentation, in particular lidar, is included, also data handling, and interpretation of the data for meteorological processes. Communications, geodesy and rangefinding are not included as distinct areas. The application to the atmosphere is covered, but not the ocean or its surface.
Harris, F. S., Jr.↗
EUV limb spectra of a surge observed from Skylab
The EUV spectra of a surge observed at plus 8 in. and plus 20 in. above the white light limb from Skylab are examined. The shape of the differential emission measure determined at 8 in. and 20 in. is nearly the same as for a quiet Sun spectrum at 8 in., but the emission measure of the surge at 8 in. is about an order of magnitude greater than for the quiet Sun. At 20 in. the emission measure of the surge is initially close to the quiet Sun distribution, but decreases by a factor of 4 within 6 min. The optically thin lines formed near 10 to the 5th power K show nonthermal broadening at 8 in., and electron densities near this temperature are derived from intersystem to resonance ratios. The volume of the emitting plasma at 8 in. above the limb was determined, concluding that a continuous energy input is required to explain the observations.
Doschek, G. A.↗