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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS1971

CO2 laser experiments using nuclear reactions as the ionization source.

Experimental studies show that the output of a CO2 laser is significantly increased by products of the nuclear reaction He-3 (n,p)T. Helium-3 was used in lieu of the natural helium normally present in the 1:1:8 CO2:N2:He laser gas mixture (pressure = 6 torr). The laser assembly was then exposed to a reactor thermal neutron flux of about 100 million neutrons/sq cm/sec. Power output of the laser doubled while the electrical power input decreased; electrical efficiency was thus more than doubled. Results indicate that additional ionization by the energetic charged particles may be responsible for the improved laser performance.

Rhoads, H. S.↗
NASA NTRS1979

Nuclear-pumped CO2 laser

The He-3 (n,p)T reaction was examined as an energy source for a CO2 laser. For this purpose He-3 was added to a functioning CO2 electrically excited laser. Initially the laser was run electrically with 12 torr total pressure. The gas mixture was 1:1:8, CO2:N2:He. At zero reactor power, the laser was tested in place next to the core of the Georgia Tech. Research Reactor. After verification of laser action He-3 was added to the system. The He-3 partial pressures of 10 torr, 50 torr, and 300 torr were added in three separate reactor runs. Reactor power ranged from zero to 5 million watts, which corresponds to a peak flux of 10 to the 14th power/sq cm. At reactor powers greater than 10 kW, gain of up to 30 percent was shown. However, indications are this may be due to gamma excitation rather than caused by the He-3 (n,p)T reaction. These results do agree with the data of past CO2 nuclear pumped laser experiments.

Rowe, M.↗
NASA NTRS2019

Experimental Measurements of the High-Temperature Oxidation of Carbon Fibers

We carried out laboratory experiments to study the decomposition of carbon fibers at high temperature and studied the material used in charring carbon phenolic ablators for planetary probe heatshields. Porous plug samples were exposed to controlled rates of molecular oxygen, carbon dioxide, and carbon monoxide at furnace-heated flow-tube reactor temperatures between 700 and 1500 K and pressures between 2000 and 6200 Pa. We used calibrated mass spectroscopy to make time-resolved quantitative measurements of decomposition products of the gases downstream of the test sample. Absolute and differential pressure measurements were used to determine the high-temperature permeability of the material and to monitor changes during material decomposition, and we characterized the microstructure of the porous sample using scanning electron microscopy. We found substantial carbon fiber oxidation for O2 flows, resulting in increasing CO/CO2 production ratios with increasing temperature. The CO2 was shown to react with carbon fibers following a Boudouard reaction at temperatures above 1200 K.

Francesco Panerai↗
NASA NTRS1981

Kinetics of the reaction OH + HO2 yields H2O + O2 at 296 K

The rate constant of the title reaction was measured in a discharge-flow reactor by addition of excess HO2 from a movable double injector to a gas stream containing small concentrations of OH. The concentration of OH was measured by laser-induced fluorescence, HO2 by conversion to OH, and H and O by vacuum-UV resonance fluorescence. Five sets of experiments, each with different excess concentration of HO2, gave an average rate constant of (7.5 + or - 1.2) x 10 to the -11th cu cm/s where the error limits (single sigma) include uncertainties of all experimental parameters. This result is compared with other findings and is discussed in terms of its importance in stratospheric chemistry and in rate theory.

Sridharan, U. C.↗
NASA NTRS1989

Design challenges for space bioreactors

The design of bioreactors for operation under conditions of microgravity presents problems and challenges. Absence of a significant body force such as gravity can have profound consequences for interfacial phenomena. Marangoni convection can no longer be overlooked. Many speculations on the advantages and benefits of microgravity can be found in the literature. Initial bioreactor research considerations for space applications had little regard for the suitability of the designs for conditions of microgravity. Bioreactors can be classified in terms of their function and type of operation. The complex interaction of parameters leading to optimal design and operation of a bioreactor is illustrated by the JSC mammalian cell culture system. The design of a bioreactor is strongly dependent upon its intended use as a production unit for cell mass and/or biologicals or as a research reactor for the study of cell growth and function. Therefore a variety of bioreactor configurations are presented in rapid summary. Following this, a rationale is presented for not attempting to derive key design parameters such as the oxygen transfer coefficient from ground-based data. A set of themes/objectives for flight experiments to develop the expertise for design of space bioreactors is then proposed for discussion. These experiments, carried out systematically, will provide a database from which engineering tools for space bioreactor design will be derived.

Seshan, P. K.↗
NASA NTRS1977

High efficiency thermionic converter studies

Research in thermionic energy conversion technology is reported. The objectives were to produce converters suitable for use in out of core space reactors, radioisotope generators, and solar satellites. The development of emitter electrodes that operate at low cesium pressure, stable low work function collector electrodes, and more efficient means of space charge neutralization were investigated to improve thermionic converter performance. Potential improvements in collector properties were noted with evaporated thin film barium oxide coatings. Experiments with cesium carbonate suggest this substance may provide optimum combinations of cesium and oxygen for thermionic conversion.

Huffman, F. N.↗
NASA NTRS1997

Computational Modeling as a Design Tool in Microelectronics Manufacturing

Plans to introduce pilot lines or fabs for 300 mm processing are in progress. The IC technology is simultaneously moving towards 0.25/0.18 micron. The convergence of these two trends places unprecedented stringent demands on processes and equipments. More than ever, computational modeling is called upon to play a complementary role in equipment and process design. The pace in hardware/process development needs a matching pace in software development: an aggressive move towards developing "virtual reactors" is desirable and essential to reduce design cycle and costs. This goal has three elements: reactor scale model, feature level model, and database of physical/chemical properties. With these elements coupled, the complete model should function as a design aid in a CAD environment. This talk would aim at the description of various elements. At the reactor level, continuum, DSMC(or particle) and hybrid models will be discussed and compared using examples of plasma and thermal process simulations. In microtopography evolution, approaches such as level set methods compete with conventional geometric models. Regardless of the approach, the reliance on empricism is to be eliminated through coupling to reactor model and computational surface science. This coupling poses challenging issues of orders of magnitude variation in length and time scales. Finally, database development has fallen behind; current situation is rapidly aggravated by the ever newer chemistries emerging to meet process metrics. The virtual reactor would be a useless concept without an accompanying reliable database that consists of: thermal reaction pathways and rate constants, electron-molecule cross sections, thermochemical properties, transport properties, and finally, surface data on the interaction of radicals, atoms and ions with various surfaces. Large scale computational chemistry efforts are critical as experiments alone cannot meet database needs due to the difficulties associated with such controlled experiments and costs.

Meyyappan, Meyya↗
NASA NTRS1994

Laboratory measurements of polar stratospheric cloud rate parameters

It is now clear that heterogeneous reactions play an important role in controlling the concentration of ozone in the stratosphere. In this work, the loss of N2O5 on ice substrates has been studied in a flow reactor in an attempt to gain a more fundamental understanding of these reactions. The apparent reaction probability in this system was found to decrease as the substrate was exposed to N2O5. A model which corrected for the loss of surface sites was developed and although it appears to fit the data for a given experiment quite well, it is concluded that the loss of reactive sites is not the full explanation. In addition, the results of an experimental and modeling study suggest that reaction on the internal surface of the ice substrates is not a major loss mechanism for N2O5 in the current work.

Kenner, Rex D.↗
NASA NTRS1978

Experimental Studies of the Formation/Deposition of Sodium Sulfate in/from Combustion Gases

Processes related to the hot corrosion of gas turbine components were examined in two separate investigations. Monochromatic laser light was used to probe condensation onset and condensate film growth (via interference of reflected light) on electrically heated ribbons immersed in seeded, flat flame combustion product gases. Boron trichloride is used as the seed gas in these preliminary experiments conducted to obtain precise measurements of the dew point/deposition rates. Because of the importance of gaseous Na(g) as a precursor to NaSO4 formation, the kinetics and mechanisms of the heterogeneous reaction H(g) + NaCl(s) yields Na(g) + HCl(g) was studied using atomic absorption spectroscopy combined with microwave discharge-vacuum flow reactor techniques at moderate temperatures. Preliminary results indicate the H-atom attack of solid NaCl vaporization is negligible; hence the corresponding gas phase (homogeneous) reaction no role in the observed Na(g) production.

Rosner, D. E.↗
NASA NTRS2006

Experimental Evaluation of a Water Shield for a Surface Power Reactor

As part of the Vision for Space Exploration the end of the next decade will bring man back to the surface of the moon. One of the most critical issues for the establishment of human presence on the moon will be the availability of compact power sources. The establishment of man on the moon will require power from greater than 10's of kWt's in follow on years. Nuclear reactors are extremely we11 suited to meet the needs for power generation on the lunar or Martian surface. reactor system. Several competing concepts exist for lightweight, safe, robust shielding systems such as a water shield, lithium hydride (LiH), Boron Carbide, and others. Water offers several potential advantages, including reduced cost, reduced technical risk, and reduced mass. Water has not typically been considered for space reactor applications because of the need for gravity to remove the potential for radiation streaming paths. The water shield concept relies on predictions of passive circulation of the shield water by natural convection to adequately cool the shield. This prediction needs to be experimentally evaluated, especially for shields with complex geometries. MSFC has developed the experience and fac necessary to do this evaluation in the Early Flight Fission - Test Facility (EFF-TF).

Pearson, J. Boise↗
NASA NTRS2013

Ongoing Development of a Series Bosch Reactor System

Future manned missions to deep space or planetary surfaces will undoubtedly require highly robust, efficient, and regenerable life support systems that require minimal consumables. To meet this requirement, NASA continues to explore a Bosch‐based carbon dioxide reduction system to recover oxygen from CO2. In order to improve the equivalent system mass of Bosch systems, we seek to design and test a "Series Bosch" system in which two reactors in series are optimized for the two steps of the reaction, as well as to explore the use of in situ materials as carbon deposition catalysts. Here we report recent developments in this effort including assembly and initial testing of a Reverse Water‐Gas Shift reactor (RWGSr) and initial testing of two gas separation membranes. The RWGSr was sized to reduce CO2 produced by a crew of four to carbon monoxide as the first stage in a Series Bosch system. The gas separation membranes, necessary to recycle unreacted hydrogen and CO2, were similarly sized. Additionally, we report results of preliminary experiments designed to determine the catalytic properties of Martian and Lunar regolith simulant for the carbon deposition step.

Abney, Morgan↗
NASA NTRS2013

Ongoing Development of a Series Bosch Reactor System

Future manned missions to deep space or planetary surfaces will undoubtedly incorporate highly robust, efficient, and regenerable life support systems that require minimal consumables. To meet this requirement, NASA continues to explore a Bosch-based carbon dioxide reduction system to recover oxygen from CO2. In order to improve the equivalent system mass of Bosch systems, we seek to design and test a "Series Bosch" system in which two reactors in series are optimized for the two steps of the reaction, as well as to explore the use of in situ materials as carbon deposition catalysts. Here we report recent developments in this effort including assembly and initial testing of a Reverse Water-Gas Shift reactor (RWGSr) and initial testing of two gas separation membranes. The RWGSr was sized to reduce CO2 produced by a crew of four to carbon monoxide as the first stage in a Series Bosch system. The gas separation membranes, necessary to recycle unreacted hydrogen and CO2, were similarly sized. Additionally, we report results of preliminary experiments designed to determine the catalytic properties of Martian regolith simulant for the carbon formation step.

Abney, Morgan B↗
NASA NTRS2024

The CapiSorb Visible System (CVS) Demonstrations on ISS

Falling liquid film amine sorbent reactors have been successfully employed to scrub CO 2 aboard submarines for decades. However, applying such proven methods aboard orbiting and coast spacecraft is significantly challenged by the nearly weightless environment, where liquid sprays and films do not fall, and vapor bubbles and gases do not rise. The Capillary Sorbent (CapiSorb) Visible System (CVS) is a technology demonstration experiment performed aboard the ISS April 18 – 21, 2023. The system establishes stable steady thin liquid film flows in Contactor (absorber) and Degasser (desorber/stripper) replacing the passive role of gravity with the combined passive roles of surface tension, wetting, and system geometry. A TOX-0 fructose ersatz liquid sorbent is employed enabling ‘transparent’ experiments performed and filmed by the crew safely in the open cabin of the ISS. Completed objectives include demonstrations of stable passive ‘massively’ parallel planar thin film capillary flows across atmospheric pressure Contactor and sealed heated Degasser. The impacts of varying flow rate, flow direction, heat input, viscosity, positive and negative Degasser pressures, condensate collection and return, fluid distribution, interfacial stability, and others are reported. At least 49 diagnostics are recorded for digitization and subsequent thermal-fluids model validation by a single HD video downlink during the nearly 22 hours of operations. An overview of the flight hardware including description of the components, diagnostics, crew procedures, flight operations, and summary of accomplishments is reported in Ref. 1. Further details of the diagnostics, tests performed, and data reduction is reported in Ref. 2. This report collects both1,2 into a single report adding methods of data digitization, reduction, and archive along with analyses and discussions of technology impacts.

microgravity↗
NASA NTRS1982

Carbon deposition in the Bosch process with ruthenium and ruthenium-iron alloy catalysts

The effectiveness of ruthenium and the alloys 50Ru50Fe and 33Ru67Fe as alternatives to iron, nickel, and cobalt catalysts in recovering oxygen from metabolic carbon dioxide was investigated. Carbon deposition boundaries over the unsupported alloys are reported. Experiments were also carried out over 50Ru50Fe and 97Ru3Fe3 catalysts supported on gamma-alumina to determine their performance in the synthesis of low molecular weight olefins. High production of ethylene and propylene would be beneficial for an improvement of an overall Bosch process, as a gas phase containing high olefin content would enhance carbon deposition in a Bosch reactor.

Manning, M. P.↗
NASA NTRS1986

Investigation and modeling of space shuttle main engine shutdown transient chugging

The space shuttle main engines experience a low frequency pressure pulsation in both the fuel and oxidizer preburners during the shutdown transient. This pressure pulsation, called chugging, has been linked to undesirable bearing loads and possible damage to the spark ignitor supply piping for the fuel preburner. The problem is briefly described and a model is proposed that includes: (1) a transient stirred tank reactor model for the combustion chamber, (2) a resistance capacitance model for the supply piping and (3) purge gas/liquid oxygen interface tracking.

George, P. E., II↗
NASA NTRS1999

A Theory of Oscillating Edge Flames

It has been known for some years that when a near-limit flame spreads over a liquid pool of fuel, the edge of the flame can oscillate relative to a frame moving with the mean speed. Each period of oscillation is characterized by long intervals of modest motion during which the edge gases radiate like those of a diffusion flame, punctuated by bursts of rapid advance during which the edge gases radiate like those in a deflagration. Substantial resources have been brought to bear on this issue within the microgravity program, both experimental and numerical. It is also known that when a near-asphyxiated candle-flame burns at zero gravity, the edge of the (hemispherical) flame can oscillate violently prior to extinction. Thus a web-surfer, turning to the NASA web-site at http://microgravity.msfc.nasa.gov, and following the trail combustion science/experiments/experimental results/candle flame, will find photographs and a description of candle burning experiments carried out on board both the Space-shuttle and the Russian space station Mir. A brief report can also be found in the proceedings of the Fourth Workshop. And recently, in a third microgravity program, the leading edge of the flame supported by injection of ethane through the porous surface of a plate over which air is blown has been found to oscillate when conditions are close to blow-off. A number of important points can be made with respect to these observations: It is the edge itself which oscillates, advancing and retreating, not the diffusion flame that trails behind the edge; oscillations only occur under near limit conditions; in each case the Lewis number of the fuel is significantly larger than 1; and because of the edge curvature, the heat losses from the reacting edge structure are larger than those from the trailing diffusion flame. We propose a general theory for these oscillations, invoking Occam's 'Law of Parsimony' in an expanded form, to wit: The same mechanism is responsible for the oscillations in all three experiments; and no new mechanism is invoked (Occam's original 'Razor'). Such a strategy eliminates Marangoni effects as the source, for these are absent in the second and third experiments. And it eliminates arguments that point to numerically predicted gas eddies as the source, a new mechanism, unelucidated. Indeed, we hypothesize that the essential driving mechanism for the instability is a combination of large Lewis number and heat losses from the reacting structure near the flame edge. Instabilities driven by these mechanisms are commonplace in 1D configurations. Chemical reactor theory, for example, leads to system responses which mimic the response of the candle flame - steady flame, oscillations, extinction. In a combustion context, oscillating instabilities were first reported for diffusion flames in a theoretical study by Kirkby and Schmitz, and here also the instabilities are associated with near-extinction conditions, large Lewis numbers, and heat losses. And deflagrations will oscillate if the Lewis number is large enough, oscillations that are exacerbated when heat losses are present, whether global or to a surface.

Buckmaster, J.↗
NASA NTRS1959

Longitudinal Laminar Flow Between Cylinders Arranged in Regular Array

The increasing complexity of heat transfer and process situations which involve fluid flow has demanded the frequent use of flow passages of unusual geometrical configuration. The present investigation is concerned with one such novel configuration, namely the longitudinal flow between solid cylindrical rods which are arranged in regular array. A schematic diagram of the situation under study. The rods may be located either in triangular or square array. The flow will be taken to be laminar and fully developed. The aim of this analysis is to determine the pressure drop, shear stress, and velocity-distribution characteristics of the system. The starting point of this study is the basic law of momentum conservation. The resulting differential equation has been solved in an approximate, but almost exact, manner by the use of truncated trigonometric series. Results are obtained over a wide range of porosity values for both the triangular and square arrays. Heat transfer has not been considered. The configuration under investigation has potential application in compact heat exchangers for nuclear reactors and other situations. Further the results should also be of interest in the theory of flow through unconsolidated porous beds (ia, 9a). The only related analytical work known to the authors is that of Emersleben (S), who considered only the square array. His rather involved solution, based on complex zeta functions, appears to be valid only at high porosities. Experiments covering a porosity range of 0.093 to 0.984 have been made by Sullivan (4) using parallel-oriented fibers, most of the tests being for fibers in random array. These previous investigations will be compared with the present theory in a later section.

Sparrow, E. M.↗
NASA NTRSDate not supplied

CNTR: Explanation of Propellant Flow and Description of Initial Experiments

The Centrifugal Nuclear Thermal Rocket (CNTR) is one of few designs that could enable extremely rapid missions to Mars using currently available technologies. McCarthy conducted the first conceptual study of high performance nuclear thermal propulsion (NTP) and published his findings in 1954. High performance NTP was further investigated by Princeton researchers in the early 1960s and continued by other researchers throughout the 60s, 70s, and 80s. An interagency panel conducted in 1991 demonstrated the potential of liquid core nuclear rockets, such as the Liquid Annular Reactor System (LARS), to reach temperatures up to 5000 K and specific impulses (Isp) up to 2000 s. A more recent study of versatile NTP asserts that a similar propulsion system, the Centrifugal Gas Core Reactor (CGCR), can reach an estimated Isp of 1800 s[4]. An Isp of that magnitude significantly reduces travel times and consequently health risks to flight crews. The CNTR seeks to build on the work of previous liquid core NTP systems and aims to reach an Isp in the range of 1500 s to 1800 s while using hydrogen as the propellant. However, the CNTR is not limited to hydrogen and can instead utilize other volatiles such as ammonia, methane, or water at about half the Isp of hydrogen. This flexibility expands the CNTR’s mission range considerably by providing propellant storability and the potential for directly using volatiles available in-situ.

Nuclear Thermal Propulsion Human Mars↗