SEARCH · Engineering Papers

Results for “progress properties”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 361 records · Page 20

All sources NASA NTRS DOE OSTI

DOE OSTI2025

Structural and Spectroscopic Trends in Alkali Tris(Acetato)Actinyl(VI) Complexes

A series of alkali tris(acetato)actinyl(VI) compounds M[AnO 2 (CH 3 COO) 3 ] (M=Na, K, Rb, Cs and An=U, Np, Pu) is reported, applying a combination of singlecrystal X-ray diffraction, solid-state Raman spectroscopy, and U(VI) luminescence spectroscopy for their structural and spectroscopic characterization. The results show that complexes formed from the same alkali metal but different actinyl ions are mostly isostructural. The symmetric actinyl stretch (ν 1 (An=O yl )) in these isostructural complexes undergoes a redshift within the actinide series despite the shortening of the actinyl bond due to the actinide contraction. Complexes formed from the same actinyl but co-crystallized with different alkali metals show a progression toward lower space group symmetry. While the actinyl bond length remains unmodulated within the alkali series, a small redshift of ν 1 (An=O yl ) is observed, indicating minor changes in the vibrational properties of the actinyl moiety caused by the structural progression towards lower symmetry. This subtle change is also evidenced by a redshift of the U(VI) luminescence spectra within the M[UO 2 (CH 3 COO) 3 ] series.

Raman↗

DOE OSTI2020

A review of Sb 2 Se 3 photovoltaic absorber materials and thin-film solar cells

Energy generated from environmentally friendly, cost-effective solar cells is a key aspect for developing a clean renewable-energy economy. Non-toxic and Earth-abundant materials with high absorption coefficient (>10 5 cm -1 ) and optimal bandgap (1-1.5 eV) have received great attention as photovoltaic (PV) absorber layers during the last few decades. Among them, antimony selenide (Sb 2 Se 3 ) has been a promising PV absorber, with steadily increasing power-conversion efficiency (PCE) compared to other emerging compounds. Very recent studies showed that high-quality ZnO:Al/ZnO/CdS/TiO 2 /Sb 2 Se 3 /MoSe 2 /Mo devices with PCE of 9.2% can be fabricated using cost-effective novel compounds. Considering these recent advances, this article provides an overview of the material properties of Sb2Se3 thin films and the recent progress made with Sb 2 Se 3 -based solar cells. Furthermore, analysis of Sb 2 Se 3 -based thin-film solar cells has also shown that the devices have relatively good light management due to their suitable bandgap and high absorption coefficient, whereas carrier management, i.e. collection efficiency of photo-generated carriers, needs significant improvement. Overall, this study provides background knowledge on material properties and device performance and suggests main research directions to overcome the limiting factors of solar cell performance.

14 SOLAR ENERGY↗

NASA NTRS1992

Extraction of volatiles and metals from extraterrestrial materials

Recent progress in defining the physical, orbital, and chemical properties of the Earth-crossing asteroid and comet population was integrated into an elaborate Monte Carlo model of the fluxes of bodies in the inner Solar System. This model is of use in projecting flight opportunities to as-yet undiscovered near-Earth objects and in assessing the impact hazard to life on Earth and the evolutionary consequences of impacts on the other terrestrial planets. Further progress was made in defining desirable transportation system architectures for the use of non-terrestrial volatiles and metals, including the delivery of propellants to near-Earth space for fueling of space exploration initiative (SEI) type expeditions, the construction and resupply of Solar Power Satellite constellations in various Earth orbits (including geosynchronous earth orbit (GEO) and Highly Eccentric Earth Orbit (HEEO)), and retrieval of He-3 for use as a clean fusion fuel on Earth. These studies suggest a greater future role for SERC in the exploration of space energy sources to meet Earth's 21st-century energy requirements. Laboratory studies of volatilization and deposition of ferrous metal alloys demonstrated deposition of strong iron films from carbonyl chemical vapor deposition (CVD), showing the crucial role of additive gases in governing the CVD process, and pointing the way to specific experiments on extraction and deposition of ferrous metals from nonterrestrial materials.

Lewis, J. S.↗

NASA NTRSDate not supplied

Assessment of the Accuracy and Consistency of Cloud Property Retrievals from Passive Radiometers with Varying Spectral Information

Over the past few decades, space-based passive radiometers have been used to study the spatial distribution of clouds and some of their basic properties. Modern radiometers have significantly higher spatial resolution and collect more spectral information (i.e., have more spectral bands) than early instruments, and these advances have allowed researchers to characterize cloud physical and microphysical properties with greater detail. There is significant interest in utilizing as much of the existing satellite record as possible to study global and regional changes in cloud occurrence and distribution as well as the associated changes in reflected shortwave and outgoing longwave fluxes. Cloud property retrieval algorithms such as the NASA Satellite Cloud Optical and Radiative Property System (SatCORPS) have traditionally utilized as much spectral information as possible in order to maximize the accuracy of the retrievals. However, changes to the retrieval algorithm over time in order to take advantage of progressively more spectral information results in inconsistencies in cloud properties which in turn results in inconsistencies with products derived from these properties. It is not possible to implement modern state-of-the-art algorithms to earlier instruments which lack diverse spectral information, but many instruments since the early 2000s generally have approximately similar spectral bands in the visible (~0.65 microns), longwave infrared (~11 microns), and in many cases, the midwave infrared (~3.8 microns) and water vapor absorption (~6.7 microns), portions of the electromagnetic spectrum. Different versions of SatCORPS have been implemented with either the full set of spectral information collected by imagers such as GOES-16 and MODIS or with a reduced set of spectral bands in order to be more consistent with past imagers that lack such diverse spectral information. This study uses independent cloud property retrievals from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) to assess the accuracy of the retrievals (e.g., cloud fraction, thermodynamic phase, altitude) from the different retrieval methods and to demonstrate the advantages and disadvantages of using a reduced set of common spectral bands in order to achieve temporal and spatial consistency across different instruments.

Christopher R. Yost↗

DOE OSTI2022

A Review of Irradiation Damage and Effects in α-Uranium

Understanding irradiation damage and effects in α-uranium (α-U) is critical to modeling the behavior of U-based metallic fuels. The aim of this review is to address the renewed interest in U-based metallic fuels by examining the state-of-the-art knowledge associated with the effect of irradiation on the microstructure, dimensional changes, and properties of α-U. We critically review the research progress on irradiation-induced growth and swelling, the enhancement of plastic flow and superplasticity by irradiation, and the effect of irradiation on thermal and electrical properties of α-U. Finally, we outline the research directions that require advancements, specifically the need to carry out fundamental research on several of the less understood mechanisms of irradiation damage and effects in α-U.

36 MATERIALS SCIENCE↗

DOE OSTI2023

High-Temperature Mobility of Tungsten Grain Boundaries

The objective of this study is to assess the effect of hydrogen isotopes on mechanical properties of tungsten relevant to first-wall applications in a tokamak. We report progress on calculation of the mobility of tungsten grain boundaries at high temperature, a key property in the process of recrystallization. In prior work we studied tungsten grain boundary properties such as the energies of boundaries with various orientations and misorientations, including energies of grain boundary phases that differ in structure from those at low temperature. We have calculated properties associated with the grain boundary mobility including the response of grain boundaries to applied shear stress. Here we report direct calculation of the motion of curved grain boundaries at high temperature using molecular dynamics. We compute how the mobility increases with temperature and how the mobility depends on the grain boundary misorientation. These calculations form baseline data to calculate the change when hydrogen or other defects are present.

36 MATERIALS SCIENCE↗

DOE OSTI2022

FY22 Progress on Multicontinuum Methods in Containment

Estimation of two-phase fluid flow properties is important to understand and predict water and gas movement through the vadose zone for agricultural, hydrogeological, and engineering applications, such as containment transport and/or containment of gases in the subsurface. To estimate rock fluid flow properties and subsequently predict physically realistic processes such as patterns and timing of water, gas, and energy (e.g., heat) movement in the subsurface, laboratory spontaneous water imbibition with simultaneous temperature measurement and numerical modeling methods are presented in the FY22 progress report. A multiple-overlapping-continua conceptual model is used to explain and predict observed complex multi-phenomenological laboratory test behavior during spontaneous imbibition experiments. This report primarily addresses two complexities that arise during the experiments: 1) capturing the late-time behavior of spontaneous imbibition tests with dual porosity; and 2) understanding the thermal perturbation observed at or ahead of the imbibing wetting front, which are associated with adsorption of water in initially dry samples. We use numerical approaches to explore some of these issues, but also lay out a plan for further laboratory experimentation and modeling to best understand and leverage these unique observations.

58 GEOSCIENCES↗

DOE OSTI2021

Controllable Thin‐Film Approaches for Doping and Alloying Transition Metal Dichalcogenides Monolayers

Abstract Two‐dimensional (2D) transition metal dichalcogenides (TMDs) exhibit exciting properties and versatile material chemistry that are promising for device miniaturization, energy, quantum information science, and optoelectronics. Their outstanding structural stability permits the introduction of various foreign dopants that can modulate their optical and electronic properties and induce phase transitions, thereby adding new functionalities such as magnetism, ferroelectricity, and quantum states. To accelerate their technological readiness, it is essential to develop controllable synthesis and processing techniques to precisely engineer the compositions and phases of 2D TMDs. While most reviews emphasize properties and applications of doped TMDs, here, recent progress on thin‐film synthesis and processing techniques that show excellent controllability for substitutional doping of 2D TMDs are reported. These techniques are categorized into bottom–up methods that grow doped samples on substrates directly and top–down methods that use energetic sources to implant dopants into existing 2D crystals. The doped and alloyed variants from Group VI TMDs will be at the center of technical discussions, as they are expected to play essential roles in next‐generation optoelectronic applications. Theoretical backgrounds based on first principles calculations will precede the technical discussions to help the reader understand each element's likelihood of substitutional doping and the expected impact on the material properties.

36 MATERIALS SCIENCE↗

DOE OSTI2016

Recent charge-breeding developments with EBIS/T devices (invited)

Short breeding times, narrow charge state distributions, low background, high efficiency, and the flexible time structure of the ejected low-emittance ion pulses are among the most attractive features of electron beam ion source or trap (EBIS/T) based charge breeders. Significant progress has been made to further improve these properties: Several groups are working to increase current densities towards 10{sup 3} or even 10{sup 4} A/cm{sup 2}. These current densities will become necessary to deliver high charge states of heavy nuclei in a short time and/or provide sufficient space-charge capacity to handle high-current ion beams in next-generation rare-isotope beam (RIB) facilities. Efficient capture of continuous beams, attractive because of its potential of handling highest-current ion beams, has become possible with the development of high-density electron beams of >1 A. Requests for the time structure of the charge bred ion pulse range from ultra-short pulses to quasi-continuous beams. Progress is being made on both ends of this spectrum, by either dividing the extracted charge in many pulse-lets, adjusting the extraction potential for a near-uniform long pulse, or adding dedicated devices to spread the ion bunches delivered from the EBIS/T in time. Advances in EBIS/T charge state breeding are summarized, including recent results with NSCL’s ReA EBIS/T charge breeder.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2018

Ab initio simulations of liquid electrolytes for energy conversion and storage

Understanding physicochemical properties of liquid electrolytes is essential for predicting and optimizing device performance for a wide variety of emerging energy technologies, including photoelectrochemical water splitting, supercapacitors, and batteries. We review recent progress and open challenges in predicting structural, dynamical, and electronic properties of the liquids using first-principles approaches. We briefly summarize the basic concepts of first-principles molecular dynamics (FPMD), and we discuss how FPMD methods have enriched our understanding of a number of liquids, including aqueous solutions, organic electrolytes and ionic liquids. We also discuss technical challenges in extending FPMD simulations to the study of liquid electrolytes in more complex environments, including the interface between electrolytes and electrodes, which is a key component in many energy storage and conversion systems.

25 ENERGY STORAGE↗

DOE OSTI2020

Advances in Two-Dimensional Organic-Inorganic Hybrid Perovskites

Two-dimensional (2D) perovskites have attracted considerable interest for their promising applications for solar cells and other optoelectronics, such as light-emitting diodes, spintronics, and photodetectors. In this paper, we review the recent achievements of 2D perovskites for various optoelectronic applications. First, we discuss the basic structure and optoelectronic properties of 2D perovskites, including band structure, optical properties, and charge transport. We then highlight recent achievements using 2D perovskites in solar cells and beyond solar cells, including progress on various synthesis strategies and their impact on structural and optoelectronic properties. Finally, we discuss current challenges and future opportunities to further develop 2D perovskites for various applications.

14 SOLAR ENERGY↗

NASA NTRS1948

Metallurgical Research Relating to the Development of Metals and Alloys for Use in the High-Temperature Components of Jet-Engines, Gas Turbines and Other Aircraft Propulsion Systems

Considerable work has been done on report preparation. All items listed in the March program report will be reported during July. Fundamental studies are in progress to establish the fundamental processes by which treatments and composition control properties of commercial alloys at high temperatures. As yet work has been confined to Low-Carbon N155 alloy and progress has been reported twice previously. The work is divided into two sections: studies of solution treated and aged material and studies of rolled structures. Electron microscopic work has been started as an additional technique for the studies. Brief descriptions of experimental techniques used, results, and interpretation of the data obtained since the last report covering this field are summarized below. Since the work outlined is to a large extent still in progress, the discussion given is to be considered tentative and subject to further modification as additional data becomes available.

Source record↗

NASA NTRS1986

Research in planetary astronomy and operation of the 2.2-meter telescope

The turn-around in the secular change in brightness of Pluto was detected, the planet is now beginning to brighten. The spectral signature was found of an ammonia bearing compound in the surface ices of Europa. Specific Io volcanic hotspots were detected from infrared photometry of the mutual events of the Jovian satellites. The polarized emission from the volcanic hotspots on Io was discovered and the locations of those hotspots were determined. The orbit of Charon was refined from speckle observations of the Pluto-Charon system. The spectral properties of liquid nitrogen-methane mixtures with reference to the infrared spectrum of Triton were studied. Major progress was made in modeling asteroid lightcurves from a modern theory of photometric properties of the asteroid surfaces. Several additional olivine-rich asteroids from near-infrared spectrophotometry were discovered. Important photometric, spectroscopic, narrow-band imaging data on Comet P/Halley was acquired, along with Schmidt photographs of Comet P/Halley and its tail.

Hall, D. N. B.↗

DOE OSTI2023

Synchrotron based transient x-ray absorption spectroscopy for emerging solid-state energy materials

The rational design of cutting-edge materials for an efficient solar energy conversion process is a challenging task, which demands a fundamental understanding of the mechanisms operative during the photoinduced physical and chemical reactions. In response to these issues, progress in the field has steered attention toward the use of time-resolved spectroscopic techniques to resolve the multiple intermediate species involved in these photoinduced reactions. Thanks to the advent of pump–probe technique, which leads to the development of various time-resolved spectroscopic methods, significant progress has been made in understanding the photophysical and photochemical properties (e.g., excited state dynamics, charge transfer mechanism, charge separation dynamics, etc.) of energy materials. Synchrotron-based x-ray transient absorption (XTA) spectroscopy is one of the most important time-resolved techniques to unravel the direct correlation of the material structure with their photophysical properties owing to its unique capability in directly observing electronic and structural evolution simultaneously. As a result, the aim of this work is to provide a systematic overview of the recent progress in using XTA for capturing the structural dynamics associated with excited state and charge separation dynamics in emerging solid-state energy materials.

14 SOLAR ENERGY↗

NASA NTRS1989

New secondary batteries utilizing electronically conductive polymer cathodes

The objectives of this project are to characterize the transport properties in electronically conductive polymers and to assess the utility of these films as cathodes in lithium/polymer secondary batteries. During this research period, progress has been made in a literature survey of the historical background, methods of preparation, the physical and chemical properties, and potential technological applications of polythiophene. Progress has also been made in the characterization of polypyrrole flat films and fibrillar films. Cyclic voltammetry and potential step chronocoulometry were used to gain information on peak currents and potentials switching reaction rates, charge capacity, and charge retention. Battery charge/discharge studies were also performed.

Martin, Charles R.↗

DOE OSTI2016

Adsorption properties of subtropical and tropical variable charge soils: Implications from climate change and biochar amendment

This review paper attempts to summarize the progress made in research efforts conducted over the last years to study the surface chemical properties of the tropical and subtropical soils, usually called variable charge soils, and the way they response to different management practices. The paper is composed of an introductory section that provides a brief discussion on the surface chemical properties of these soils, and five other review sections. The focus of these sections is on the evolution of surface chemical properties during the development of the variable charge properties (second section), interactions between oppositely charged particles and the resulting effects on the soil properties and especially on soil acidity (third section), the surface effects of low molecular weight organic acids sorbed to mineral surfaces and the chemical behavior of aluminum (fourth section), and the crop straw derived biochar induced changes of the surface chemical properties of these soils (fifth section). A discussion on the effect of climate change variables on the properties of the variable charge soils is included at the end of this review paper (sixth section).

Adsorption properties↗

DOE OSTI2016

Thin-film semiconductor perspective of organometal trihalide perovskite materials for high-efficiency solar cells

Organolead trihalide perovskites (OTPs) are arising as a new generation of low-cost active materials for solar cells with efficiency rocketing from 3.5% to over 20% within only five years. From “dye” in dye sensitized solar cells to “hole conductors” and “electron conductors” in mesoscopic heterojunction solar cells, there has been a dramatic conceptual evolution on the function of OTPs in photovoltaic devices. OTPs were originally used as dyes in Gratzel cells, achieving a high efficiency above 15% which, however, did not manifest the excellent charge transport properties of OTPs. An analogy of OTPs to traditional semiconductors was drawn after the demonstration of highly efficient planar heterojunction structure OTP devices and the observation of their excellent bipolar transport properties with a large diffusion length exceeding 100 nm in CH 3 NH 3 PbI 3 (MAPbI 3 ) polycrystalline thin films. Here, this review aims to provide the most recent advances in the understanding of the origin of the high OTP device efficiency. Specifically we will focus on reviewing the progress in understanding 1) the characterization of fantastic optoelectronic property of OTPs, 2) the unusual defect physics that originate the optoelectronic property; 3) morphology control of the perovskite film from fabrication process and film post-treatment, and 4) device interface and charge transport layers that dramatically impact device efficiency in the OTP thin film devices; 5) photocurrent hysteresis; 6) tandem solar cells; 7) stability of the perovskite materials and solar cell devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2026

IR side of bounds on theories with spontaneously broken Lorentz symmetry

In nature, some UV features of dynamics are reflected in IR quantities. In fully relativistic theories, this connection can be probed through the analyticity properties of scattering amplitudes, allowing one to understand which IR theories respect the UV assumptions of quantum field theory. The ensuing analyticity bounds can usually be rephrased as the absence of faster-than-light propagation for low-energy excitations. While it is interesting to understand these relations and their IR characterization for theories that have less idealized properties, it is also more difficult to derive analyticity bounds in these cases. For theories that spontaneously break Lorentz symmetry, recent progress was made by considering correlators of conserved currents and their analyticity properties. In this work, we focus on such theories and work to close the gap from the IR side, finding a natural way to express the known analyticity bounds purely in terms of low-energy kinematical quantities. Our analysis shows that the bounds require gapped excitations to have a slower speed than the gapless ones, at least for momenta that are low with respect to the mass gap. These results suggest a way to interpret the UV/IR connection in more complex theories.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗