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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Beamline K11 DIAD: a new instrument for dual imaging and diffraction at Diamond Light Source

The Dual Imaging and Diffraction (DIAD) beamline at Diamond Light Source is a new dual-beam instrument for full-field imaging/tomography and powder diffraction. This instrument provides the user community with the capability to dynamically image 2D and 3D complex structures and perform phase identification and/or strain mapping using micro-diffraction. The aim is to enable in situ and in operando experiments that require spatially correlated results from both techniques, by providing measurements from the same specimen location quasi-simultaneously. Using an unusual optical layout, DIAD has two independent beams originating from one source that operate in the medium energy range (7–38 keV) and are combined at one sample position. Here, either radiography or tomography can be performed using monochromatic or pink beam, with a 1.4 mm × 1.2 mm field of view and a feature resolution of 1.2 µm. Micro-diffraction is possible with a variable beam size between 13 µm × 4 µm and 50 µm × 50 µm. One key functionality of the beamline is image-guided diffraction, a setup in which the micro-diffraction beam can be scanned over the complete area of the imaging field-of-view. This moving beam setup enables the collection of location-specific information about the phase composition and/or strains at any given position within the image/tomography field of view. The dual beam design allows fast switching between imaging and diffraction mode without the need of complicated and time-consuming mode switches. Real-time selection of areas of interest for diffraction measurements as well as the simultaneous collection of both imaging and diffraction data of (irreversible) in situ and in operando experiments are possible.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Seasonal Precipitation Classification during Surface Atmosphere Integrated Field Laboratory Campaign

The Surface Atmosphere Integrated Field Laboratory (SAIL) campaign, conducted from September 2021 to June 2023 in Crested Butte, Colorado, aimed to characterize precipitation processes in the Upper Colorado River Basin (UCRB). This increased observations of snowfall accumulation in this hydrologically significant watershed would be useful for quantitative precipitation estimates (QPE). Therefore, the Surface Quantitative Precipitation Estimate (SQUIRE) product was developed using the ARM-supported Colorado State University (CSU) X-band Precipitation Radar. Although SQUIRE will be only released for snowfall, by categorizing precipitation types, users can effectively utilize relevant datasets under diverse meteorological conditions. Moreover, the dataset facilitates validation of the QPE product and the analysis of seasonal variations in precipitation types at the surface. Hydrometeors classes are organized based on their phase and physical characteristics mapping the CSU (both winter Summer) and Py-ART classifications into four groups. 1. Liquid Precipitation: includs drizzle, rain, and large raindrops. 2. Frozen Snow and Ice : Pure Snow, combining ice crystals, aggregates, and vertically oriented ice structures. 3. Dense and Large frozen hydrometeors: including low- and high-density graupel and dry hail. 4.Melting: Wet Snow and Melting Hail, hydrometeors exhibiting both liquid and frozen characteristics.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Formation and Characterization of Zein-Based Oleogels

Oleogels are interesting as a result of their ability to hold large amounts of oil in a semi-solid gel structure. In the food industry, oleogels are most often investigated as substitutes for saturated and trans fats. In this work, the lyotropic formation of ethanol/zein/oleic acid gels was observed qualitatively and ternary phase diagrams were constructed to map the observations. The viscoelastic parameters G' and G'' were measured to confirm gel formation as observed in phase diagrams. Ultrasmall X-ray scattering was used to study the microstructural organization of ethanol/zein/oleic acid gels. Furthermore, data suggested that the primary unit or building block for gel network structures was the rod-shaped zein molecule. Ultrasmall X-ray data suggested that zein/oleic acid gels have a highly organized microstructure, possibly the result of zein self-assembly. Zein was considered an effective oleogelator in ethanol/zein/oleic acid systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage

Water under nanoconfinement at ambient conditions has exhibited low-dimensional ice formation and liquid–solid phase transitions, but with structural and dynamical signatures that map onto known regions of water’s phase diagram. Using terahertz (THz) absorption spectroscopy and ab initio molecular dynamics, we have investigated the ambient water confined in a supramolecular tetrahedral assembly, and determined that a dynamically distinct network of 9 ± 1 water molecules is present within the nanocavity of the host. The low-frequency absorption spectrum and theoretical analysis of the water in the Ga 4 L 6 12– host demonstrate that the structure and dynamics of the encapsulated droplet is distinct from any known phase of water. A further inference is that the release of the highly unusual encapsulated water droplet creates a strong thermodynamic driver for the high-affinity binding of guests in aqueous solution for the Ga 4 L 6 12– supramolecular construct.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Topographic and nanomechanical mapping of plutonium surfaces

Atomic force microscopy of gallium-stabilized δ-phase plutonium coupons has been used to map their topography and qualitative mechanical character, including Derjaguin-Muller-Toporov modulus, adhesion, deformation, and dissipation. Initial topographical results demonstrate that the plutonium surface is considerably rough and heterogeneous. Qualitative nanomechanical mapping revealed distinct striation patterns that are not observed in the topography images. Further investigation of the striations in the nanomechanical modes of imaging suggest that they are not measurement artifacts, or plutonium specific features. Similar investigations of stainless steel surfaces established a strong correlation between the mechanical working of the surface (i.e. cutting and grinding) and the appearance of the striations. Reimaging of the plutonium surface after moderate oxidation occurring within an inert Ar atmosphere (~1 ppm O 2 ) over the course of 13 months revealed a diminished striation pattern. It is suggested that surface stress/strain induced by the mechanical working of the metal surfaces results in the patterns of variable modulus, adhesion, deformation, and dissipation, and that these patterns are affected by the chemical changes and aging of the plutonium surface.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Integrated laser ablation-dropletProbe-mass spectrometry for absolute drug quantitation, metabolite detection, and distribution in tissue

Rationale: Spatially resolved and accurate quantitation of drug-related compounds in tissue is a much-needed capability in drug discovery research. In this work, application of an integrated laser ablation-dropletProbe-mass spectrometry surface sampling system (LADP-MS) is reported, which achieved absolute quantitation of propranolol measured from <500 × 500 μm thin tissue samples. Methods: Mouse liver and kidney thin tissue sections were coated with parylene C and analyzed for propranolol by a laser ablation/liquid extraction workflow. Non-coated adjacent sections were microdissected for validation and processed using standard bulk tissue extraction protocols. High-performance liquid chromatography with positive ion mode electrospray ionization tandem mass spectrometry was applied to detect the drug and its metabolites. Results: Absolute propranolol concentration in ~500 × 500 μm tissue regions measured by the two methods agreed within ±8% and had a relative standard deviation within ±17%. Quantitation down to ~400 × 400 μm tissue regions was shown, and this resolution was also used for automated mapping of propranolol and phase II hydroxypropranolol glucuronide metabolites in kidney tissue. Conclusions: This study exemplifies the capabilities of integrated laser ablation-dropletProbe-mass spectrometry (LADP-MS) for high resolution absolute drug quantitation analysis of thin tissue sections. This capability will be valuable for applications needing to quantitatively understand the spatial distribution of small molecules in tissue.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Electronic structure, magnetic properties, and exchange splitting of gadolinium intermetallics

Here, we report here the electronic structure calculations of the magnetic moment, magneto-crystalline anisotropy energy (MAE), and density of states (DOS) of Gd-metal, GdAl 2 , GdAl 3 , GdCo 2 , GdCo 3 , and GdCo 5 . From the DOS, the exchange splitting energy is derived to map ferrimagnetic to paramagnetic phase transition (Curie temperature, T C ). The employed theoretical method here is based on advanced density functional theory, specifically the linearized augmented plane wave method (LAPW) within the local spin density approximation (LSDA), including spin–orbit coupling (SOC) and Hubbard model parameter (U). DOS analysis of both Gd-Al and Gd-Co systems reveals a strong correlation between exchange splitting energy and T C . The Gd-Co system exhibits an enormous exchange splitting energy among Co-3d electrons, vastly overwhelming the vanishing Gd 5d exchange splitting. Finally, these findings suggest that exchange splitting of Co-3d electrons plays a key role in the ground state magnetism and magnetic transition temperatures in these materials.

36 MATERIALS SCIENCE↗
DOE OSTI2023

A novel design of transitional layer structure between reduced activation ferritic martensitic steels and tungsten for plasma facing materials

Plasma-facing components (PFCs) are among the most critical gaps for fusion energy to establish technical and economic feasibility. Tungsten as a first wall/blanket material in PFCs requires to be integrating with reduced activation ferritic martensitic (RAFM) steels as a structural component. Currently, major drawbacks are the requirement of brazing, the formation of a brittle interface, and a large difference between the coefficients of thermal expansion of tungsten and steel. Here, a novel transitional multilayer structure was designed and investigated to join tungsten and RAFM steels using three interlayers. The composition of each interlayer was selected based on computational thermodynamics and diffusion kinetics to ensure a body-centered cubic (bcc) single-phase structure and prevent the formation of a brittle intermetallic phase region in the temperature range of 600–1150 °C. Although the transitional layer structure was designed for additive manufacturing, spark plasma sintering (SPS) as proof of concept was used to bond the individual layers. Interfaces were investigated using scanning and transmission electron microscopy methods but no layered intermetallic phase was observed. Nanoindentation maps across the interface suggest major hardness differences at the interface between tungsten and the vanadium interlayer, as well as the interface between RAFM steel and the FeCrAl interlayer.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Topological Hall effect and magnetic states in the Nowotny chimney ladder compound Cr 11 Ge 19

In this report, we have investigated the magnetic and charge transport properties of single crystals of the Nowotny chimney ladder compound Cr 11 Ge 19 and mapped out a comprehensive phase diagram reflecting the complicated interplay between the Dzyaloshinskii-Moriya (DM) interaction, the dipolar interaction, and the magnetic anisotropy. We have identified a set of interesting magnetic phases and attributed a finite topological Hall effect to the recently discovered biskyrmion phase. These data also suggest the existence of an antiskyrmion state at finite fields for temperatures just below the magnetic ordering temperature T c as indicated by a distinct change in sign of the topological Hall effect. Above T c , we discovered a region of enhanced magnetic response corresponding to a disordered phase likely existing near the ferromagnetic critical point under small magnetic fields. Strong spin chirality fluctuations are demonstrated by the large value of the topological Hall resistivity persisting up to 1 T, which is most likely due to the existence of the DM interaction. We argue that changes to the topological Hall effect correspond to different topological spin textures that are controlled by magnetic dipolar and DM interactions that vary in importance with temperature

36 MATERIALS SCIENCE↗
DOE OSTI2021

Electronic properties of epitaxial La 1- x Sr x RhO 3 thin films

Here, we report on the synthesis and electronic properties of epitaxial perovskite La 1- x Sr x RhO 3 thin films. Thin films with a Sr content ranging from $\textit{x}$ = 0 to 0.5 have been grown using molecular beam epitaxy. Transport and x-ray photoemission spectroscopy data reveal an insulator-metal-insulator transition, accompanied by a $\textit{p-}$ to $\textit{n}-$ type carrier change observed in Hall measurements. Combined with theoretical calculations, we find that the addition of Sr does not directly dope carriers into the conduction band, but rather induces localized Rh 4$\textit{d}$ states within the LaRhO 3 band gap. The bandwidth of the impurity band increases with Sr content, eventually causing the valence band (VB) and the localized Rh 4$\textit{d}$ band to overlap, which explains the first insulator-to-metal transition occurring at $\textit{x}$ = 0.35. For Sr content $\textit{x}$ > 0.4, possible cation ordering results in an increase of the gap between the VB and the Rh 4$\textit{d}$ band, leading to the second metal-to-insulator transition. We map out the electronic phase diagram of the Sr-doped LaRhO 3 system and suggest strategies to engineer the electronic states in rhodate systems via delocalizing the Rh 3+ states.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Coexistence of non-Abelian chiral spin liquid and magnetic order in a spin-1 antiferromagnet

We study the ground-state properties of a spin-1 Heisenberg model on a square lattice with the first- and second-nearest-neighbor antiferromagnetic couplings $J_1$ and $J_2$ and a three-spin scalar chirality term $J_\chi$. Using the density matrix renormalization group calculation, we map out a global phase diagram including various magnetic order phases and an emergent quantum spin liquid phase. The nature of the spin liquid is identified as a bosonic non-Abelian Moore-Read state from the fingerprint of the entanglement spectra and identification of a full set of topological sectors. We further unveil a stripe magnetic order coexisting with this spin liquid. Furthermore, our results not only establish a rare example of non-Abelian spin liquids in simple spin systems but also demonstrate the coexistence of fractionalized excitations and magnetic order beyond mean-field descriptions.

2-dimensional systems↗
DOE OSTI2024

Magnetic, charge, and bond order in the two-dimensional Su-Schrieffer-Heeger-Holstein model

Most nonperturbative numerical studies of electron-phonon interactions focus on model Hamiltonians where the electrons interact with a phonon branch via a single type of microscopic mechanism. Two commonly explored couplings in this context are the Holstein and Su-Schrieffer-Heeger (SSH) interactions, which describe phonons modulating the on-site energy and intersite electron hopping, respectively. Many materials, however, have multiple phonon branches that can each interact with electronic degrees of freedom in different ways. We present here a determinant quantum Monte Carlo study of the half-filled two-dimensional (bond) SSH-Holstein Hamiltonian, where electrons couple to different phonon branches via either the Holstein or SSH mechanism. As a result, we map the model's phase diagram and determine the nature of the transitions between charge-density wave, bond-order wave, and antiferromagnetic order.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1988

Microgravity two-phase fluid flow pattern modeling

When gas and liquid mixtures flow in a pipe, the distribution of the two phases may take many forms. A flow pattern, or flow regime, is the characteristic spatial distribution of the phases of flow in a pipe. Because heat transfer and pressure drop are dependent on the characteristic distribution of phases, it is necessary to describe flow patterns in an appropriate manner so that a hydrodynamic or heat transfer theory applicable to that can be chosen. A theoretical two phase flow regime transition map under a microgravity environment was developed on physical concepts. These transitions use four basic flow patterns: dispersed flow, slug flow, stratified flow, and annular flow. The forces considered are body force, surface tension force, inertial force, friction, and the force from eddy turbulent fluctuation. Three dimensionless parameters were developed. Because these transition boundaries were developed based on physical concepts, they should be applicable to flow regimes occurring in various design conditions. Because the flow pattern data from KC-135 experiments are insufficient to verify these theoretical transition lines completely, an adiabatic experiment for flow regime analysis is recommended.

Lee, Doojeong↗
NASA NTRS1989

Experimental study of the dynamics of a ruby laser pumped by a CW argon-ion laser

A study of the dynamics of a ruby laser pumped by a CW argon-ion laser is presented. The ruby laser is predominantly stable but has two accessible unstable states. One state exhibits chaotic output, while the other results in regular self-pulsing. The conditions needed for instability are discussed and homodyne spectra and temporal maps of the phase-space attractors are obtained. In addition, a numerical simulation of nonlinear beam propagation in ruby is presented that shows that strong deviations from plane-wave behavior exist, and that transverse effects must be incorporated into theoretical models of the instability.

Afzal, R. S.↗
NASA NTRS2004

Refinement of Phobos Ephemeris Using Mars Orbiter Laser Altimeter Radiometry

Radiometric observations from the Mars Orbiter Laser Altimeter (MOLA) can be used to improve the ephemeris of Phobos, with particular interest in refining estimates of the secular acceleration due to tidal dissipation within Mars. We have searched the Mars Orbiter Laser Altimeter (MOLA) radiometry data for shadows cast by the moon Phobos, finding 7 such profiles during the Mapping and Extended Mission phases, and 5 during the last two years of radiometry operations. Preliminary data suggest that the motion of Phobos has advanced by one or more seconds beyond that predicted by the current ephemerides, and the advance has increased over the 5 years of Mars Global Surveyor (MGS) operations.

Neumann, G. A.↗
NASA NTRS2007

Screening of Potential Landing Gear Noise Control Devices at Virginia Tech For QTD II Flight Test

In support of the QTD II (Quiet Technology Demonstrator) program, aeroacoustic measurements of a 26%-scale, Boeing 777 main landing gear model were conducted in the Virginia Tech Stability Tunnel. The objective of these measurements was to perform risk mitigation studies on noise control devices for a flight test performed at Glasgow, Montana in 2005. The noise control devices were designed to target the primary main gear noise sources as observed in several previous tests. To accomplish this task, devices to reduce noise were built using stereo lithography for landing gear components such as the brakes, the forward cable harness, the shock strut, the door/strut gap and the lower truck. The most promising device was down selected from test results. In subsequent stages, the initial design of the selected lower truck fairing was improved to account for all the implementation constraints encountered in the full-scale airplane. The redesigned truck fairing was then retested to assess the impact of the modifications on the noise reduction potential. From extensive acoustic measurements obtained using a 63-element microphone phased array, acoustic source maps and integrated spectra were generated in order to estimate the noise reduction achievable with each device.

Ravetta, Patricio A.↗