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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

K-alpha X-rays from cosmic ray oxygen

Equilibrium charge fractions are calculated for subrelativistic cosmic ray oxygen ions in the interstellar medium. These are used to determine the expected flux of K-alpha rays arising from atomic processes for a number of different postulated interstellar oxygen spectra. Relating these results to the diffuse X-ray background measured at the appropriate energy level suggests an observable line feature. If the flux of low energy cosmic ray oxygen is sufficiently large, K-alpha X-ray line emission from these nuclei will comprise a significant fraction of the total diffuse flux at approximately 0.6 keV. A satellite borne detector with a resolution greater than 30 percent could observe this feature if the subrelativistic interstellar cosmic ray oxygen spectrum is as large as certain theoretical estimates expressed in the text.

Pravdo, S. H.↗
NASA NTRS1983

Dynamics and spectroscopy of asymmetrically heated coronal loops

Numerical models of steady flows along coronal magnetic flux tubes of varying cross sectional areas are investigated. The flows are induced by altering the spatial symmetry of the heating. In two cases the flux tube geometry is symmetric about the top of the loop, but the spatial dependence of the heating rate is changed from a symmetric deposition which supports a stationary equilibrium to a time-independent asymmetric deposition. In a third case the volumetric heating rate is uniform, but one half of the loop is larger in volume than the other. The resulting velocity structure varies significantly with changes in the flux tube geometry. Calculations of the ionization balance and line emission for a number of ionization stages of oxygen suggest that heating induced flows may be responsible for the redshifts seen in spectral lines formed in the network at transition region temperatures.

Mariska, J. T.↗
NASA NTRS1987

Satellite observations of new particle and field signatures associated with SAR arc field lines at magnetospheric heights

Enhancements in thermal ion densities, an oxygen dominated ring current at energies below 17 keV, and invariant latitude-limited bands of intense ELF hiss have been discovered on Stable Auroral Red (SAR) arc field lines at magnetospheric heights. These new signatures were revealed by an examination of 31 coordinated data sets taken simultaneously at magnetospheric and ionospheric heights by the De-1 and -2 satellites during SAR arc traversals within the period September 1981 through April 1982. Data sets from DE-2, for the first time, provide information on the location of a SAR arc (determined by the F region electron temperature enhancement) during the nearly simultaneous passage of these field lines by DE-1 in the magnetosphere. These new high altitude signatures are examined in the context of possible magnetospheric SAR arc energy source mechanisms.

Kozyra, J. U.↗
NASA NTRS1989

The application of electrochemical impedance spectroscopy for characterizing the degradation of Ni(OH)2/NiOOH electrodes

Electrochemical impedance spectra of rolled and bonded and sintered porous nickel battery electrodes were recorded periodically during charge/discharge cycling in concentrated KOH solution at various temperatures. A transmission line model (TLM) was adopted to represent the impedance of the porous electrodes, and various model parameters were adjusted in a curve fitting routine to reproduce the experimental impedances. Degradation processes for rolled and bonded electrodes were deduced from changes in model parameters with electrode cycling time. In developing the TLM, impedance spectra of planar (non-porous) electrodes were used to represent the pore wall and backing plate interfacial impedances. These data were measured over a range of potentials and temperatures, and an equivalent circuit model was adopted to represent the planar electrode data. Cyclic voltammetry was used to study the characteristics of the oxygen evolution reaction on planar nickel electrodes during charging, since oxygen evolution can affect battery electrode charging efficiency and ultimately electrode cycle life if the overpotential for oxygen evolution is sufficiently low. Transmission line modeling results suggest that porous rolled and bonded nickel electrodes undergo restructuring during charge/discharge cycling prior to failure.

Macdonald, D. D.↗
NASA NTRS1993

Oxygen isotopic relationships between the LEW85332 carbonaceous chondrite and CR chondrites

LEW85332, originally described as a unique C3 chondrite, was shown to be a C2 chondrite with important linkages to the CR clan. An important petrologic aspect of LEW85332 is that it contains anhydrous chondrules and hydrated matrix, and new oxygen isotopic data on chondrules, matrix and whole rock are consistent with the petrology. Chondrules fall on the equilibrated chondrite line (ECL), with a slope near 1, which goes through ordinary chondrite chondrules. This contrasts with the CR chondrule line which has a lower slope due to hydrated components. LEW85332 chondrules define a new carbonaceous chondrite chondrule line, parallel to the anhydrous CV chondrule line (CCC), consistent with the well-established concept of two oxygen isotopic reservoirs. Matrix and whole rock fall on the CR line. The whole rock composition indicates that the chondrite is dominated by chondrules, and that most of them contain light oxygen similar to that of anhydrous olivine and pyroxene separates in the Renazzo and Al Rais CR chondrites.

Prinz, M.↗
NASA NTRS1987

Fine-scale motion in NGC 6514 and NGC 6523

Velocity maps of the inner regions of the bright H II regions NGC 6514 and NGC 6523 were made with unprecedented spatial and spectral resolution in the 5007 A line of forbidden O III. In addition to the advantages of an instrumental full width at half-maximum intensity of only 5.4 km/s, the small thermal width of the heavy oxygen ion also allows determination of accurate line widths and velocities. The CCD spectra were numerically fitted to Gaussian line profiles and revealed two separate velocity systems in NGC 6523. The data sets of radial velocities were used to derive the dependence of the most probable turbulent velocities upon the sample sizes, and the spatial dependence of the structure function. These relationships are the basic functions for comparison with the predictions of the models for turbulence in H II regions.

O'Dell, C. R.↗
DOE OSTI2021

J2229+2725: an extremely low metallicity dwarf compact star-forming galaxy with an exceptionally high [O iii ]λ5007/[O ii ]λ3727 flux ratio of 53

ABSTRACT Using the Large Binocular Telescope (LBT)/Multi-Object Dual Spectrograph (MODS), we have obtained optical spectroscopy of one of the most metal-poor dwarf star-forming galaxies (SFGs) in the local Universe, J2229+2725. This galaxy with a redshift z = 0.0762 was selected from the Data Release 16 of the Sloan Digital Sky Survey (SDSS). Its properties derived from the LBT observations are most extreme among SFGs in several ways. Its oxygen abundance 12 + logO/H = 7.085 ± 0.031 is among the lowest ever observed for an SFG. With its very low metallicity, an absolute magnitude Mg = −16.39 mag, a low stellar mass M⋆ = 9.1 × 106 M⊙, and a very low mass-to-light ratio M⋆/Lg ∼ 0.0166 (in solar units), J2229+2725 deviates strongly from the luminosity–metallicity relation defined by the bulk of the SFGs in the SDSS. J2229+2725 has a very high specific star formation rate sSFR ∼ 75 Gyr−1, indicating very active ongoing star formation. Three other features of J2229+2725 are most striking, being the most extreme among lowest metallicity SFGs: (1) a ratio O32 = I([O iii]λ5007)/I([O ii]λ3727) ∼ 53, (2) an equivalent width of the H β emission line EW(H β) of 577 Å, and (3) an electron number density of ∼1000 cm−3. These properties imply that the starburst in J2229+2725 is very young. Using the extremely high O32 in J2229+2725, we have improved the strong-line calibration for the determination of oxygen abundances in the most metal-deficient galaxies, in the range 12 + logO/H $\lesssim$ 7.3.

Izotov, Y. I.↗
NASA NTRS1994

X-ray spectroscopy of SNR E0102-72 with the ASCA satellite

The Advanced Satellite for Cosmology and Astrophysics (ASCA) satellite has obtained a moderate-resolution energy spectrum of E0102-72, the brightest Supernova Remnant (SNR) in the Small Magellanic Cloud (SMC). This paper reports on the first results of the analysis of the high quality spectrum of E0102-72. The spectrum shows resolved emission lines of He-like K alpha, H-like K alpha and K beta from oxygen, neon, and magnesium. The intensity ratios of these lines cannot be explained by a multi-component plasma model with uniform abundances, but requires abundance inhomogeneity in the plasma. We demonstrate how the spectral capabilities of the ASCA SIS make available new diagnostics of X-ray plasmas in a state of non-equilibrium ionization. Some interpretation based on the spectral analysis is also given.

Hayashi, Ichizo↗
NASA NTRS1982

Observations of the 145.5 micron (OI) emission line in the Orion nebula

A first set of observations of the (OI) 3P to 3P1 (145.5 micron) transition was obtained. The line was observed both in a beam centered on the Trapezium, and in a 7 times wider beam encompassing most of the Orion Nebula. A wide beam map of the region was constructed which shows that most of the emission is confined to the central regions of the nebula. These observations may be compared with reported measurement of the 3P1 to 3P2 (63.2 micron) transition in Orion and are consistent with optically thin emission in the 145.5 micron line and self-adsorbed 63.2 micron emission lines. Mechanisms are discussed for the excitation of neutral oxygen. It is included that much of the observed emission originates in the thin, radio-recombination-line-emitting CII/HI envelope bordering on the HII region.

Stacey, G. J.↗
NASA NTRS1993

Do it yourself remote sensing: Generating an inexpensive, high tech, real science lake mapping project for the classroom

The utilization of modest equipment and software revealed bottom contours and water column conditions of a dynamic water body. Classroom discussions of field techniques and equipment capabilities followed by exercises with the data sets in cause-and-effect analysis all contributed to participatory education in the process of science. This project is presented as a case study of the value of engaging secondary and collegiate level students in planning, executing and appraising a real world investigation which they can directly relate to. A 1 km wide bay, experiencing marsh inflow, along an 8 km long lake situated 120 km north of Ottawa, Canada, on the glaciated Canadian Precambrian Shield was mapped in midsummer for submerged topography, bottom composition, temperature profile, turbudity, dissolved oxygen and biota distribution. Low level aerial photographs scanned into image processing software are permitting spatial classification of bottom variations in biology and geology. Instrumentation consisted of a portable sport fishing SONAR depth finder, an electronic lead line multiprobe with photocell, thermistor and dissolved oxygen sensors, a selective depth water sampler, portable pH meter, an underwater camera mounted on a home-made platform with a bottom-contact trigger and a disposable underwater camera for shallow survey work. Sampling transects were referenced using a Brunton hand transit triangulating several shore markers.

Metzger, Stephen M.↗
DOE OSTI2022

Intergranular oxidation and oxygen transport in Ni-20Cr during exposure to model dry and wet oxidation environments

Selective oxidation is a critical component of the proposed internal oxidation mechanism of stress corrosion cracking (SCC) for Ni-based alloys in primary water reactor (PWR) operation. To isolate and study this process, the binary Ni-20Cr was exposed to pressurized water and a CO/CO2 gas mixture. In both environments, the oxygen potential was kept under the Ni/NiO line to stimulate penetrative intergranular attack. A combination of electron microscopy and atom probe tomography was used to study the nanometer-scale details of the passivation and penetrative intergranular oxidation processes at high-energy grain boundaries. Oxygen transport towards the terminating oxidation front is elucidated with dedicated usage of oxygen isotopic tracer exchange experiments to support classical theories of internal oxidation, revealing preferred oxygen transport paths were visualized with sub-nanometer resolution.

Weiser, Martin↗
NASA NTRS1976

Joule-Thomson data curves

Series of graphs shows temperature-pressure relationship for air, nitrogen, helium, oxygen, and hydrogen when flowing across line restriction over wide range of temperatures and pressures. Graphs can be applied as engineering guides for component manufacturers and piping system designers.

Beimgraben, H. W.↗
NASA NTRS1975

A cloud physics investigation utilizing Skylab data

The author has identified the following significant results. A number of new scattering calculations for various models were performed. An atmospheric transmittance program to calculate transmittances on a line-by-line basis was developed for the oxygen A band. A copy of the LOWTRAN 2 program was obtained and modified slightly. Thermodynamic results were obtained from snow, cirrus, and coastal stratus to indicate that 1(1.6)/1(2.125) ratio is probably not a reliable indicator of snow, ice particles, or water droplets.

Alishouse, J.↗
NASA NTRS1978

O VI gas - Circumstellar or interstellar

Observations in the UV spectra from the Copernicus satellite have revealed absorption lines from five-times ionized oxygen atoms. To explain this abundance, two explanations have been advanced to supplant the traditional model of steady loss from nearby stars. One, ionization from circumstellar bubbles, is said to result from rapidly rotating stars. The other, examined in more detail, suggests a mechanism whereby shock waves from explosive disturbances in nearby supernovae preferentially channel coronal-type O VI regions in the interstellar medium into areas of high temperature (above 100,000 K). An examination of column densities with increasing distribution is proposed to examine the hypotheses, although the results are as yet inconclusive.

Jenkins, E. B.↗
NASA NTRS1983

Evolutionary connections of biological kingdoms based on protein and nucleic acid sequence evidence

Prokaryotic and eukaryotic evolutionary trees are developed from protein and nucleic-acid sequences by the methods of numerical taxonomy. Trees are presented for bacterial ferredoxins, 5S ribosomal RNA, c-type cytochromes , cytochromes c2 and c', and 5.8S ribosomal RNA; the implications for early evolution are discussed; and a composite tree showing the branching of the anaerobes, aerobes, archaebacteria, and eukaryotes is shown. Single lines are found for all oxygen-evolving photosynthetic forms and for the salt-loving and high-temperature forms of archaebacteria. It is argued that the eukaryote mitochondria, chloroplasts, and cytoplasmic host material are descended from free-living prokaryotes that formed symbiotic associations, with more than one symbiotic event involved in the evolution of each organelle.

Dayhoff, M. O.↗
NASA NTRS1993

The application of laser induced predissociation fluorescence to the measurement of vibrational temperatures in a shock layer flow

Single shot spatially and spectrally resolved laser induced predissociation fluorescence measurements in a shock layer around a cylinder in a pulsed supersonic free stream are presented. Fluorescence signals were produced using the tuned output of an argon fluoride excimer laser to excite a mixture of rovibrational transitions in molecular oxygen. The signals produced along a line inside the shock layer were focussed onto a two dimensional detector coupled to a spectrometer, thus allowing spectral and spatial resolution of the fluorescence. In this way, it was possible to detect two fluorescence signals from two different transitions simultaneously, allowing the determination of vibrational temperatures without the need for calibration. However, to minimize problems associated with low signal to noise ratios, background subtraction and spatial averaging was required. The experimental measurements are compared with theoretical inviscid shock layer calculations for nonequilibrium air. A description of the strategies employed in these calculations is also provided.

Sutton, D. J.↗
NASA NTRS1997

Infrared Radiative Forcing and Atmospheric Lifetimes of Trace Species Based on Observations from UARS

Observations from instruments on the Upper Atmosphere Research Satellite (UARS) have been used to constrain calculations of infrared radiative forcing by CH4, CCl2F2 and N2O, and to determine lifetimes Of CCl2F2 and N2O- Radiative forcing is calculated as a change in net infrared flux at the tropopause that results from an increase in trace gas amount from pre-industrial (1750) to contemporary (1992) times. Latitudinal and seasonal variations are considered explicitly, using distributions of trace gases and temperature in the stratosphere from UARS measurements and seasonally averaged cloud statistics from the International Satellite Cloud Climatology Project. Top-of-atmosphere fluxes calculated for the contemporary period are in good agreement with satellite measurements from the Earth Radiation Budget Experiment. Globally averaged values of the radiative forcing are 0.536, 0.125, and 0.108 W m-2 for CH4, CCl2F2, and N2O, respectively. The largest forcing occurs near subtropical latitudes during summer, predominantly as a result of the combination of cloud-free skies and a high, cold tropopause. Clouds are found to play a significant role in regulating infrared forcing, reducing the magnitude of the forcing by 30-40% compared to the case of clear skies. The vertical profile of CCl2F2 is important in determining its radiative forcing; use of a height-independent mixing ratio in the stratosphere leads to an over prediction of the forcing by 10%. The impact of stratospheric profiles on radiative forcing by CH4 and N2O is less than 2%. UARS-based distributions of CCl2F2 and N2O are used also to determine global destruction rates and instantaneous lifetimes of these gases. Rates of photolytic destruction in the stratosphere are calculated using solar ultraviolet irradiances measured on UARS and a line-by-line model of absorption in the oxygen Schumann-Runge bands. Lifetimes are 114 +/- 22 and 118 +/- 25 years for CCl2F2 and N2O, respectively.

Minschwaner, K.↗
NASA NTRS1985

Palladium silicide formation under the influence of nitrogen and oxygen impurities

The effect of impurities on the growth of the Pd2Si layer upon thermal annealing of a Pd film on 100 line-type and amorphous Si substrates is investigated. Nitrogen and oxygen impurities are introduced into either Pd or Si which are subsequently annealed to form Pd2Si. The complementary techniques of Rutherford backscattering spectrometry, and N-15(p, alpha)C-12 or O-18(p, alpha)N-15 nuclear reaction, are used to investigate the behavior of nitrogen or oxygen and the alterations each creates during silicide formation. Both nitrogen and oxygen retard the silicide growth rate if initially present in Si. When they are initially in Pd, there is no significant retardation; instead, an interesting snow-plowing effect of N or O by the reaction interface of Pd2Si is observed. By using N implanted into Si as a marker, Pd and Si appear to trade roles as the moving species when the silicide front reaches the nitrogen-rich region.

Ho, K. T.↗