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At least 361 records · Page 20

A fluidic sounding rocket motor ignition system.

Fluidic sounding rocket motor ignition has been found to be feasible using a system without stored energy and with the complete absence of electrical energy and wiring. The fluidic ignitor is based on a two component aerodynamic resonance heating device called the pneumatic match. Temperatures in excess of 600 C were generated in closed resonance tubes which were excited by a free air jet from a simple convergent nozzle. Using nitrocellulose interface material, ignition of boron potassium nitrate was accomplished with air supply pressures as low as 45 psi. This paper describes an analytical and experimental program which established a fluidic rocket motor ignition system concept incorporating a pneumatic match with a simple hand pump as the only energy source.

Marchese, V. P.↗

Extensive 1-year survey of trace elements and compounds in the airborne suspended particulate matter in Cleveland, Ohio

Concentrations of 75 chemical constituents in the airborne particulate matter were measured in Cleveland, Ohio, during 1971 and 1972. Values covering a 1-year period (45 to 50 sampling days) at each of 16 sites are presented for 60 elements. A lesser number of values is given for sulfate, nitrate, fluoride, acidity, 10 polynuclear aromatic hydrocarbon compounds, and the aliphatic hydrocarbon compounds as a group. Methods used included instrumental neutron activation, emission spectroscopy, gas chromatography, combustion techniques, and colorimetry. Uncertainties in the concentrations associated with the sampling procedures, the analysis methods, the use of several analytical facilities, and samples with concentrations below the detection limits are evaluated in detail. The data is discussed in relation to other studies and source origins. The trace constituent concentrations as a function of wind direction are used to suggest a practical method for air pollution source identification.

King, R. B.↗

Propellant material compatibility program and results

The effects of long-term (up to 10 years) contact of inert materials with earth-storable propellants were studied for the purpose of designing chemical propulsion system components that can be used for current as well as future planetary spacecraft. The primary experimental work, and results to date are reported. Investigations include the following propellants: hydrazine, hydrazine-hydrazine nitrate blends, monomethyl-hydrazine, and nitrogen tetroxide. Materials include: aluminum alloys, corrosion-resistant steels, and titanium alloys. More than 700 test specimen capsules were placed in long-term storage testing at 43 C in the special material compatibility facility. Material ratings relative to the 10-year requirement have been assigned.

Toth, L. R.↗

Global measurements of gaseous and aerosol trace species in the upper troposphere and lower stratosphere from daily flights of 747 airliners

Extensive measurements include ozone, carbon monoxide, water vapor, and aerosol and condensation nuclei number density. Less extensive measurements include chlorofluoromethanes, sulfates and nitrates. Certain meteorological and flight information are also recorded at the time of these measurements. World routes range in latitude from about 60 deg N near North America to about 40 deg S over Australia and 23 deg S over South America. Typical data show significant changes in ozone, carbon monoxide, and water vapor when crossing the tropopause either during changes in altitude or at cruise altitude. These gases as well as light scattering particles and condensation nuclei exhibit considerable variability along a flight route.

Perkins, P. J.↗

Analysis of Skylab follow-on orbital neutron environmental data

The data base and techniques developed for Skylab experiment ED76 were used to process and analyze data from 54 solid dielectric track recorders. The processing of mica and cellulose nitrate for neutron and proton detectors is described. The measured time integrated fission rates for seven detectors is given.

Source record↗

Environmental Effects of Space Shuttle Solid Rocket Motor Exhaust Plumes

The deposition of NOx and HCl in the stratosphere from the space shuttle solid rocket motors (SRM) and exhaust plume is discussed. A detailed comparison between stratospheric deposition rates using the baseline SRM propellant and an alternate propellant, which replaces ammonium perchlorate by ammonium nitrate, shows the total NOx deposition rate to be approximately the same for each propellant. For both propellants the ratio of the deposition rates of NOx to total chlorine-containing species is negligibly small. Rocket exhaust ground cloud transport processes in the troposphere are also examined. A brief critique of the multilayer diffusion models (presently used for predicting pollutant deposition in the troposphere) is presented, and some detailed cloud rise calculations are compared with data for Titan 3C launches. The results show that, when launch time meteorological data are used as input, the model can reasonably predict measured cloud stabilization heights.

Hwang, B.↗

NASA Global Atmospheric Sampling Program (GASP) data report for tape VL0004

The NASA Global Atmospheric Sampling Program (GASP) is obtaining measurements of atmospheric trace constituents in the upper troposphere and lower stratosphere using fully automated air sampling systems on board several commercial B-747 aircraft in routine airline service. Atmospheric ozone, water vapor, and related flight and meteorological data were obtained during 139 flights of a United Airlines B-747 and a Pan American World Airways B-747 from December 1975 through March 1976. In addition, sample bottles were exposed during three flights and analyzed for trichlorofluoromethane, and filter samples were exposed during five flights and analyzed for sulfates, nitrates, and chlorides. Flight routes and dates, instrumentation, data processing procedures, data tape specifications, and selected analyses are discussed.

Holdeman, J. D.↗

NASA Global Atmospheric Sampling Program (GASP) data report for tape VL0006

The NASA Global Atmospheric Sampling Program (GASP) is obtaining measurements of atmospheric trace constituents in the upper troposphere and lower stratosphere using fully automated air sampling systems on board several commercial B-747 aircraft in routine airline service. Atmospheric ozone, and related flight and meteorological data were obtained during 245 flights of a Qantas Airways of Australia B-747 and two Pan American World Airways B-747s from July 1976 through September 1976. In addition, whole air samples, obtained during three flights, were analyzed for trichlorofluoromethane, and filter samples, obtained during four flights, were analyzed for sulfates, nitrates, fluorides, and chlorides. Flight routes and dates, instrumentation, data processing procedures, data tape specifications, and selected analyses are discussed.

Gauntner, D. J.↗

Monte Carlo analysis of uncertainty propagation in a stratospheric model. 1: Development of a concise stratospheric model

A concise model has been developed to analyze uncertainties in stratospheric perturbations, yet uses a minimum of computer time and is complete enough to represent the results of more complex models. The steady state model applies iteration to achieve coupling between interacting species. The species are determined from diffusion equations with appropriate sources and sinks. Diurnal effects due to chlorine nitrate formation are accounted for by analytic approximation. The model has been used to evaluate steady state perturbations due to injections of chlorine and NO(X).

Rundel, R. D.↗

Description and review of global measurements of atmospheric species from GASP

Aerosol composition data were collected with a NASA F-106 aircraft. Present measurements include ozone, carbon monoxide, water vapor, aerosol and condensation nuclei number densities, sulphates, nitrates, and the chlorofluoromethanes. Meteorological and flight parameters are also recorded for use in data analysis. The present aircraft operations obtain data between 6 and 13.5 km from 65 degree N between Europe and the north Pacific, and from 23 degree S over South America and 42 degree S over New Zealand. Typical constituent data from the aircraft operations during the first one and a half years are presented. Instrumentation is discussed.

Gauntner, D. J.↗

Halobacterium saccharovorum sp. nov., a carbohydrate-metabolizing, extremely halophilic bacterium

The previously described extremely halophilic bacterium, strain M6, metabolizes a variety of carbohydrates with the production of acid. In addition, the organism produces nitrite (but no gas) from nitrate, is motile, and grows most rapidly at about 50 C. These characteristics distinguish it from all previously described halophilic bacteria in the genus Halobacterium. It is suggested that it be designated as a new species, Halobacterium saccharovorum.

Tomlinson, G. A.↗

A study of the chemical degradation of ClONO2 in the stratosphere

The flash photolysis-resonance fluorescence system described by Davis et al. (1974) is used to measure the rate constants for the reactions of chlorine nitrate (ClONO2) with stratospheric O(3-P) and OH. Both reactions are examined in a pyrex cell with an internal volume of about 150 cu cm, where the reaction mixture was maintained at 245 K by circulating methanol from a thermostated circulation bath through the outer jacket of the reaction cell. The relative chemical degradation rates as a function of altitude for both reactions are tabulated, which shows that the chemical degradation pathways contribute less than 10% to the total rate of ClONO2 destruction at altitudes less than 30 km. Since the concentration of ClONO2 is calculated to be near its maximum around 25 km and drops off very significantly at higher altitudes, it is concluded that the photochemical decomposition of ClONO2 in the stratosphere is by far the most important degradation path for this molecule.

Ravishankara, A. R.↗

Photochemistry of nitrogen in the Martian atmosphere

Models are developed for the photochemistry of a CO2-H2O-N2 atmosphere on Mars. Estimates are given for the concentrations of N, NO, NO2, NO3, N2O5, HNO2, HNO3, and N2O as a function of altitude. Nitric oxide is the most abundant form of odd nitrogen, present with a mixing ratio relative to CO2 of the order of 1 hundred-millionth. Deposition rates for nitrite and nitrate minerals could be as large as 300,000 N equivalent atoms per sq cm/sec under present conditions and may have been higher in the past.

Yung, Y. L.↗

Urea transport through composite polyallylamine membranes

Polyallylamine composite reverse osmosis membranes were prepared by plasma polymerization and deposition onto small-pored cellulose acetate/cellulose nitrate films. The polyallylamine coated the porous substrate with a thin uniform polymer film which exhibited water permeability and urea rejection, of interest because of the potential application of reverse osmosis to urine purification in closed environmental systems. The flux of C-14 labeled urea was studied under the influence of osmotic gradients provided by sodium chloride solutions. The urea flux was found to be enhanced by an osmotic pressure gradient in the same direction and diminished, but not prevented, by an opposing osmotic pressure gradient. Consideration is given to the mechanism of the urea transport, as well as to the influence of concentration polarization on the experimental results. The minimization of coupled flow in pores of a critical size range is apparently necessary to improve urea rejection.

Ballou, E. V.↗

Compounds in airborne particulates - Salts and hydrocarbons

Concentrations of 10 polycyclic aromatic hydrocarbons (PAH), the aliphatics as a group, sulfate, nitrate, fluoride, acidity, and carbon in the airborne particulate matter were measured at 16 sites in Cleveland, OH over a 1-year period during 1971 and 1972. Analytical methods used included gas chromatography, colorimetry, and combustion techniques. Uncertainties in the concentrations associated with the sampling procedures, and the analytical methods are evaluated. The data are discussed relative to other studies and source origins. High concentrations downwind of coke ovens for 3,4 benzopyrene are discussed. Hydrocarbon correlation studies indicated no significant relations among compounds studied.

King, R. B.↗

Corrosion inhibitors for solar-heating and cooling

Report describes results of tests conducted to evaluate abilities of 12 candidate corrosion inhibitors to protect aluminum, steel, copper, or stainless steel at typical conditions encountered in solar heating and cooling systems. Inhibitors are based on sodium salts including nitrates, borates, silicates, and phosphates.

Humphries, T. S.↗

Global atmospheric sampling program

Automated instruments were installed on a commercial B-747 aircraft, during the program, to obtain baseline data and to monitor key atmospheric constituents associated with emissions of aircraft engines in order to determine if aircraft are contributing to pollution of the upper atmosphere. Data thus acquired on a global basis over the commercial air routes for 5 to 10 years will be analyzed. Ozone measurements in the 29,000 to 45,000 foot altitude were expanded over what has been available from ozonesondes. Limited aerosol composition measurements from filter samples show low levels of sulfates and nitrates in the upper troposphere. Recently installed instruments for measurement of carbon monoxide and condensation nuclei are beginning to return data.

Lezberg, E. A.↗

Global sensing of gaseous and aerosol trace species using automated instrumentation on 747 airliners

The Global Atmospheric Sampling Program (GASP) by NASA is collecting and analyzing data on gaseous and aerosol trace species in the upper troposphere and lower stratosphere. Measurements are obtained from automated systems installed on four 747 airliners flying global air routes. Advances were made in airborne sampling instrumentation. Improved instruments and analysis techniques are providing an expanding data base for trace species including ozone, carbon monoxide, water vapor, condensation nuclei and mass concentrations of sulfates and nitrates. Simultaneous measurements of several trace species obtained frequently can be used to uniquely identify the source of the air mass as being typically tropospheric or stratospheric. A quantitative understanding of the tropospheric-stratospheric exchange processes leads to better knowledge of the atmospheric impact of pollution through the development of improved simulation models of the atmosphere.

Perkins, P. J.↗