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At least 361 records · Page 20

Model-Based Approaches to Generate Knowledge from Data in a Plant Reliability Context

One challenge that nuclear power plant system engineers are facing is that the amount of equipment reliability (ER) data being continuously generated are extremely large. These data elements come in different forms: textual (e.g., condition reports) and numeric (e.g., generated by monitoring systems) and they provide system engineers with valuable insights and information regarding the discovery of anomalous behaviors or degradation trends, the identification of the possible causes behind such behaviors and trends, and the prediction of their direct consequences. This paper directly targets the generation of knowledge from ER data by putting “data into context”. Here, we employ model-based system engineering (MBSE) models of systems and assets to represent and capture their architecture and functional (i.e., cause-effect) relations. ER data elements are processed by identifying first which elements of the developed MBSE elements they are referring to. This task is much harder for textual data since the information contained in issue or maintenance reports needs to “be understood” by a computational tool. Here we called this process “knowledge extraction” where our methods to extract knowledge from textual data. Lastly, once numeric and textual ER data elements have been processed and “understood”, we discover possible cause-effect relations among them. This is performed by observing if a logical connection through the MBSE models exists, and if there is a temporal relation among them. The logic and temporal are the two main ingredients to perform “machine reasoning” from ER data.

97 MATHEMATICS AND COMPUTING↗

Bayesian High-Rank Hankel Matrix Completion for Nonlinear Synchrophasor Data Recovery

Phasor measurement units (PMUs) provide high temporal-resolution synchrophasor measurements for power system monitoring and control. The frequent data quality issues, such as missing and bad data, prevent the incorporation of synchrophasor data in real-time operations. Most existing data-driven data recovery methods assume the power system dynamics can be approximated by a linear dynamical system, and the recovery performance degrades significantly when the power system is experiencing nonlinear dynamics during significant events. Here, this paper proposes a data-driven Bayesian nonlinear synchrophasor data recovery method (Ba-NSDR) that can recover a consecutive time period of simultaneous data losses or errors across all channels, even when the underlying system is highly nonlinear. The idea is to lift the Hankel matrix of the spatial-temporal synchrophasor data to a higher dimension such that the lifted Hankel matrix is low-rank in that space and can be processed with the kernel trick. Our proposed Bayesian method then infers the probabilistic distributions of synchrophasor from the partial observations. Some distinctive features of Ba-NSDR include an uncertainty index to measure the accuracy of the recovery result and the robustness to parameter selections. Our method is verified on both synthetic and recorded event datasets.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Power distribution estimation method for SMR using ex-core detectors: experimental demonstration by plural control rod patterns at KUCA

The power distribution estimation method based on the ex-core detectors, or PHOEBE, was demonstrated at Kyoto University Critical Assembly, KUCA. Generally, core monitoring systems use in-core neutron detectors. Since inside the core is a harsh environment, the maintainability and reliability of the detectors are deteriorated. On the other hand, the environment outside the core is milder: core monitoring by the ex-core detectors improves the maintainability and reliability especially for small modular reactors and micro-reactors. However, neutron information from the inner region of the core is lost at the ex-core detectors. To recover the information, the authors proposed to utilize the power correlation between the fuel regions. PHOEBE concept was demonstrated at KUCA with distorted power distributions simulated by control rod patterns. The relative power distribution estimated by PHOEBE agreed with that calculated by Monte Carlo simulation code MVP. PHOEBE approximately reproduced the trend of the distorted power distributions calculated by MVP code. By contrast, the case of without power correlation between fuel regions produced significant different power distributions. Therefore, the advantage of considering the power correlation between fuel regions was also demonstrated. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Estimation Matrix Calibration of PMU Data-driven State Estimation Using Neural Network

Linear state estimation (LSE) is a phasor measurement unit (PMU) data-based power system state estimation that incorporates a linear measurement model in rectangular coordinates. Due to the high computational efficiency and high observational time-resolution, LSE can act as a supplementary state estimation in a wide-area monitoring system (WAMS). The performance of LSE is relatively sensitive to noises in measurements. Therefore, the estimation accuracy relies heavily on the accuracy of the estimation matrix, which is directly influenced by the measurement weight matrix. This paper proposes two novel calibration method of the estimation matrix using neural networks. One is based on the minimum absolute network loss (ANL), and the other is based on the minimum average squared network loss (ASNL). Both methods are tested and compared with LSE algorithms on the IEEE 14-bus system

neural network↗

Development and testing of a continuous maritime monitor for radionuclide aerosols

Monitoring airborne concentrations of radionuclide activity may provide a timely warning to sea-based assets to avoid contamination from a radioactive plume. The development and testing of an automated aerosol monitoring system that can capture and detect radioactive particulate from marine air is presented. A custom electrostatic precipitator (ESP) was designed to capture particulate onto a reusable collection media. The collection efficiency of the ESP system for radon progeny was determined to be ~23%. A conservative calculation of the minimum detectable concentration of 214 Bi was estimated as 0.3-8 Bq/m 3 . The system was demonstrated in continuous operation, without consumables and limited maintenance, in a marine environment at the PNNL campus in Sequim, Washington. In conclusion, a successful 2-month deployment indicates the feasibility of the approach for continuous maritime monitoring for radionuclide aerosols.

Moore, Michael E. [Pacific Northwest National Labo↗

Development of Analysis Methods that Integrate Numeric and Textual Equipment Reliability Data

Within the Light Water Reactor Sustainability (LWRS) program, the Risk-Informed Systems Analysis (RISA) Pathway is performing collaborative research on the development and deployment of technologies designed to assist operating nuclear power plants (NPPs) to reduce operating costs improve plant reliability and availability. One of the RISA research areas is focusing on the development of methods and tools designed to optimize plant operations (e.g., maintenance/replacement schedules, optimal maintenance postures for plant structures, systems, and components [SSCs]) in a manner that is more cost effective than current approaches and makes better use of available SSC health data. The Risk-Informed Asset Management (RIAM) project targets this research area by creating a direct bridge between component equipment reliability (ER) data and system engineer decision making regarding maintenance activity scheduling and component aging management. In this respect, one challenge that NPP system engineers are facing is that the amount of ER data being continuously generated is not only extremely large in size, but it comes in different forms: textual (e.g., condition or maintenance reports) and numeric (e.g., generated by monitoring systems). All these data elements provide them with valuable insights and information regarding: 1) the discovery of anomalous behaviors or degradation trends, 2) the identification of the possible causes behind such behaviors/trends, and 3) the prediction of their direct consequences. However, several challenges have proved to be roadblocks to this process. While some of these challenges are technical in nature (i.e., data are often distributed over several physical servers/databases), others are conceptual in nature: data elements come in different formats (e.g., numeric or textual), and measured values have different scales (e.g., vibration spectra and oil temperature). The activities performed by the RIAM project during FY23 directly tackles the need to simultaneously integrate the analysis of ER data in all its forms, numeric and textual. Note that such task has never been performed before due to the complexity of the systems under consideration but, most importantly, because of the technical challenges behind the harmonization of ER data formats and the lack of adequate computational methods to analyze them. Our approach borrows ideas and concepts from the medical field where integration of several data sources is vital to assist medical practitioners to perform correct diagnosis and indicate optimal treatments. In our view a NPP asset is equivalent to a patient in a medical context. The main difference is the complexity of a human body is a magnitude more complex when compared to typical assets commonly present in NPPs (e.g., centrifugal pumps, or motor operated valves). This simplifies our first requirement when analyzing heterogenous ER data formats: to put data into “context”. Context is here intended as the additional piece of information that is needed by ER data analysis tools to understand what these data elements are referring to, i.e., which king of knowledge they are generating. In our context, this knowledge can be translated into models that capture the form and functional architecture of assets/systems, their dependencies, and how they interact. These models actually emulate the knowledge that that NPP system engineers possess about assets and systems; this is their key of success when analyzing ER data, their challenge is ability to handle large amount of data. Here, we employ model-based system engineering (MBSE) models of systems and assets to represent and capture their architecture and functional, i.e. cause-effect, relations. Then, ER data elements are processed by identifying first of all which elements of the developed MBSE elements they are referring to. For numeric ER data this task is fairly easy since it is possible to precisely pinpoint what MBSE elements the corresponding sensor are observing (e.g., bearing temperature of a centrifugal pump). Task is much harder for textual data since the information contained in issue or maintenance reports needs to “be understood” by a computational tool. Here we called this process as “knowledge extraction”. Once again, we borrow the experience in the medical field where methods to extract knowledge from textual data have been developed in the past decade. The missing element for us is the availability of a complete dictionary of NPP related concepts (in addition to the MBSE models presented earlier) that can put “text into context”. In FY23, such dictionary has been developed along with all the computational elements required for knowledge extraction. Lastly, once numeric and textual ER data elements have been processed and “understood”, then the last step is the discovery of possible cause-effect relations among them. This is performed by observing if a logical connection through the MBSE models exists, and if the

97 MATHEMATICS AND COMPUTING↗

FPMS_XPeRT_INL_Poster

As nuclear energy expands and experimental programs increasingly rely on the facilities at Idaho National Laboratory (INL) for reactor and fuel testing, research capabilities must also expand to meet these demands. A new Fission Product Monitoring System (FPMS) has been deployed at the Advanced Test Reactor (ATR) at the Auxiliary Lead-out Experiment (ALE) House to support this expanding fuel testing mission. By tracking gaseous fission products releases from test fuel in near real-time, release rates, calculated from FPMS data, can be used to characterize the effectiveness of fuel cladding, especially for Tri-structural Isotropic (TRISO) fuel concepts. The new iteration of the FPMS supports up to 14 fission product monitors for online fission-product tracking via gamma-ray spectroscopy of the experiment’s effluent gas. Each monitor consists of a nominally 10% HPGe detector housed in a copper-lined lead shield with a warm gas trap. The new system features gamma-ray count rate information with a five-second temporal resolution and provides isotopic activity every five minutes, capable of resolving multiple overlapping fission product releases over a broad range of activities in near real-time. This work includes data from ATR cycle 175D data to demonstrate these capabilities. The hourly resolution data shows general trends and significant releases over the cycle, while the 5-minute resolution data allows for a more detailed examination of events due to unexpected particle releases.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Assessment of the 3420 Building Filtered Exhaust Stack Sampling Probe Location: Stack Verification Following Fan and Air Blender Additions

The Pacific Northwest National Laboratory (PNNL) 3420 Building, which is part of the Physical Sciences Facility (PSF), houses radiological capabilities that results in the requirement that emissions monitoring must be conducted for potential radionuclides in the exhaust air discharge of this building. The air monitoring system is required to conform to Title 40 of the Code of Federal Regulations part 61 (40 CFR 61) Subpart H, which in turns requires a sampling probe in the exhaust stream to conform to the criteria of American National Standards Institute / Health Physics Society (ANSI/HPS) N13.1-2011, Sampling and Monitoring Releases of Airborne Radioactive Substances from the Stack and Ducts of Nuclear Facilities. To support the air emissions permit for the 3420 Building on the PNNL campus, stack testing that used computational fluid dynamics (CFD) modeling as a surrogate stack and verification tests of velocity uniformity and flow angle on the retrofitted facility stack was performed. The ANSI/HPS N13.1-2011 criteria for the air monitoring probe location are that velocity uniformity, gaseous tracer uniformity, and particulate tracer uniformity must be less than or equal to 20%COV. Furthermore, no point in the sampling location may have a gaseous tracer concentration that varies from the mean concentration by more than 30%. Additionally, the flow angle at the sampling location must not be more than 20°. The CFD modeling of the stack, as reported by Recknagle et al. (2018) demonstrated that the stack meets the criteria at the probe location. The velocity uniformity and flow angle results from the 3420 stack verification tests, performed in October 2020, demonstrated that the CFD model results may be used to support the qualification of the stack sampling location. The measured velocity uniformity verification test result was 1.4%COV. This value is well within the uniformity criterion, which is that the velocity uniformity be =20%COV. Additionally, this value is well within the criterion that the actual stack measurement must be within 5% of the surrogate stack result of 2.1%COV when all four fans were operating. Additionally, the measured average flow angle at the 3420 stack monitor location was 15.5 degrees. Although this is higher than expected based on the CFD model, the result is =20 degrees, so the criterion is met. Based on these stack verification test results, the reconfigured 3420 Building filtered exhaust stack meets the qualification criteria given in the ANSI/HPS N13.1-2011 standard. Further changes to the system configuration or operating conditions that are outside the bounds described in this and the CFD report (Recknagle et al., 2018) may require additional tests and additional analysis to determine compliance with the standard.

3420 Building↗

The DUNE-DAQ Application Framework

The deep underground neutrino experiment (DUNE) is a next-generation neutrino experiment that will probe the properties of these elusive particles with unparalleled precision. It will also act as an observatory for neutrino bursts caused by nearby supernovae, in the event that one occurs, while the experiment is in operation. Given these goals, the DUNE trigger and DAQ system must be able to maintain extremely high uptime and provide a path for full readout of the detectors for very long times (up to 100 s). To achieve these ends, we have designed the DUNE DAQ system around a flexible “application framework,” which provides a modular interface for specific tasks while handling the interconnections between them. The application framework collects modules into applications, which can then be interacted with as units by the control, configuration, and monitoring systems. One of the key features of the framework is its communication abstraction layer, which allows for modules to interact with both internal queues and external network connections with a single transport-agnostic interface. We will report on the architecture and features of the framework.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

2021 NIRT Mini Drill (After Action Report)

During the summer and fall of 2021, several functional area drills were held that focused on exercising Consequence Management’s (CM) ability to extract and use data from RadResponder for the purpose of answering intermediate-phase questions presented as technical inject requests for information (RFI) in Sandia National Laboratories (SNL) Consequence Management Operational System (COSMOS) software. The scenario chosen was that of Northern Lights 2016 (NL16) which was a large-scale nuclear power plant (NPP) release exercise in the state of Minnesota. The NL16 data was extracted from the Radiological Assessment and Monitoring System (RAMS) event where it was created and was reformatted for implanting to a new RadResponder event. Next, the beta-version of a laboratory sample data simulator was used to generate more sample data that was injected to the event. Five “mini-drills” were devised with each prompt defined by a data-based need. For each drill, a team of assessment and NARAC scientists worked the problem using the drill prompt and the available data in RadResponder. The teams held a kickoff meeting, had several days to work the problem, and then reported their results as well as observations in a hotwash. Several areas for improvement in both the software and process were identified during the course of these drills. This report will document the process of addressing each RFI and the discovered gaps in both software capability and methodology so that they can be considered for future development and investment by the CM and NIRT programs.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

The DUNE DAQ Application Framework

The Deep Underground Neutrino Experiment (DUNE) is a next-generation neutrino experiment that will probe the properties of these elusive particles with unparalleled precision. It will also act as an observatory for neutrino bursts caused by nearby supernovae, in the event that one occurs while the experiment is in operation. Given these goals, the DUNE trigger and DAQ system must be able to maintain extremely high uptime and provide a path for full readout of the detectors for very long times (up to 100s). To achieve these ends, we have designed the DUNE DAQ system around a flexible “application framework”, which provides a modular interface for specific tasks while handling the interconnections between them. The application framework collects modules into applications which can then be interacted with as units by the control, configuration and monitoring systems. One of the key features of the framework is its communications abstraction layer, which allows for modules to interact with both internal queues and external network connections with a single transport-agnostic interface. We will report on the architecture and features of the framework.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Qualification of ANSI/HPS N13.1-2011 Mixing Criteria by Computational Fluid Dynamics Modeling for the 3430 Building Fan Addition and Increased Ventilation Capacity

Additional ventilation capacity has been designed for the 3430 Building filtered exhaust stack system. The updated system will increase the number of fans from two to three and include new ductwork with a larger diameter to integrate the new fan into the existing stack. Stack operations will involve running various fan combinations at any given time. The air monitoring system of the existing two-fan stack previously was found to comply with the American National Standards Institute/Health Physics Society (ANSI/HPS) N13.1-1999 standard. Full-scale, three-dimensional computational fluid dynamics (CFD) modeling was used to evaluate the modified three-fan system for compliance with the ANSI/HPS N13.1-2011 standard, which essentially is equivalent to the ANSI/HPS N13.1-1999 standard. The four mixing criteria evaluated are 1) flow angle, 2) velocity, 3) gas tracer, and 4) particle tracer. Benchmarking of the CFD modeling methodology showed good agreement with previous testing used to qualify the stack, and modeling of the existing two-fan system showed good agreement with test data collected from the 3430 Building stack. Modeling was performed to develop a suitable three-fan design. Initial modeling of the three-fan design and basic ductwork showed that flow angles and velocity uniformity were acceptable; however, the gas tracer and particle tracer mixing results were not acceptable. To meet ANSI/HPS N13.1-2011 criteria, an air blender was added to the stack design.

42 ENGINEERING↗

Qualification of ANSI/HPS N13.1-2011 Mixing Criteria by Computational Fluid Dynamics Modeling for the 3430 Building Fan Addition and Increased Ventilation Capacity

Additional ventilation capacity has been designed for the 3430 Building filtered exhaust stack system. The updated system will increase the number of fans from two to three and include new ductwork with a larger diameter to integrate the new fan into the existing stack. Stack operations will involve running various fan combinations at any given time. The air monitoring system of the existing two-fan stack previously was found to comply with the American National Standards Institute/Health Physics Society (ANSI/HPS) N13.1-1999 standard. Full-scale, three-dimensional computational fluid dynamics (CFD) modeling was used to evaluate the modified three-fan system for compliance with the ANSI/HPS N13.1-2011 standard, which essentially is equivalent to the ANSI/HPS N13.1-1999 standard. The four mixing criteria evaluated are 1) flow angle, 2) velocity, 3) gas tracer, and 4) particle tracer. Benchmarking of the CFD modeling methodology showed good agreement with previous testing used to qualify the stack, and modeling of the existing two-fan system showed good agreement with test data collected from the 3430 Building stack. Modeling was performed to develop a suitable three-fan design. Initial modeling of the three-fan design and basic ductwork showed that flow angles and velocity uniformity were acceptable; however, the gas tracer and particle tracer mixing results were not acceptable. To meet ANSI/HPS N13.1-2011 criteria, an air blender was added to the stack design. This revision models the individual maximum fan reduced flow capacity from 38,000 cfm to 31,200 cfm; no changes to the duct design are made.

42 ENGINEERING↗

SSTDR and FDR Detection of Un-Energized and Energized Cable Anomalies Including Thermal Degradation Using Machine Learning

Historically, cables are initially qualified for nuclear power plant use for 40 years. As plants extend their operating license to 60 and 80 years, continued use of these cables must shift to a performance-based approach since it is cost prohibitive to completely replace cables that are likely still capable of performing their design function. A variety of cable tests are available and are commonly applied during outages when the cables can be taken out of service. Frequency domain reflectometry (FDR) is one of these test methods that is being more broadly accepted and used because it not only detects anomalies along the cable with a low-voltage signal that does not stress the cable insulation, but the technique also locates the anomalies. This supports follow-up local inspection and local repair or partial replacement of a damaged cable segment. Currently, FDR testing is only applied to cables that are taken out of service since the test instrument would be damaged by operational voltages. A related technology that has found some acceptance in the aircraft and rail industry is spread spectrum time domain reflectometry (SSTDR). This technology has been implemented with a custom commercial instrument by LiveWire Innovation that is designed to operate on live cables up to 1000 volts and with a bandwidth of 48 MHz. Initial evaluation by the Pacific Northwest National Laboratory (PNNL) of the Live Wire system indicated that a broader bandwidth (BW) SSTDR may be better for many kinds of flaws. This led PNNL to develop an SSTDR laboratory instrument suitable for tests up to 500 MHz bandwidth. Testing on energized cables is also desirable for online monitoring systems so an inductive clamshell coupler was developed that allows energized cables to be tested up to at least 5 kV and likely higher voltage levels. Dielectric spectroscopy and tan delta testing plus various laboratory destructive tests were included in this data acquisition campaign directed to feed a machine learning (ML) study. With these kinds of developments, online energized cable tests may be possible with industrial adoption of such hardware advances but it will be completely impractical to have highly skilled data analysts continually examine these complex signals for indications of damage or compromised conditions. If online testing is to be implemented in new test hardware, it must be accompanied by software that can interpret the signals and alert plant operators of changing or degraded conditions. The thermally aged, shielded cable investigated here was separately treated for ML analysis. Visual analysis of electrical data showed generally increasing peaks where the cable entered and exited the oven. These peaks were not exactly aligned with expected locations, but these differences were attributed to velocity of propagation calibration errors. Only supervised ML was applied to the thermally aged data as this data was only available shortly before the committed publication date of this report. The supervised ML was structured to divide the 0 to 70-day responses as ‘normal’ from 0 to 35 days or ‘anomalous’ from 36 to 70 days, based on cable tensile elongation at break (EAB) insulation characterization. Using 80% of the data for training and 20% for testing, the supervised ML predicted normal versus anomalous was 70% accurate. Important conclusions include: • Accuracy to predict the presence of cable damage is improved from the 2023 effort by more training data. Weighted accuracies for comparisons among the instruments ranged from 67 to 89 % for unsupervised ML and 71 to 99% for supervised ML. • Based on the synthetic data tests, the unsupervised models are more generalizable to unseen anomalies. The Multi-Layer Perceptron classifier (MLP) model reported as high as 99.7% accuracy on the test data, but this dropped to 58.3% when tested on the synthetic data. In contrast, the unsupervised Pointwise model only achieved 89.7% accuracy on the experimental data but reported 78.3% accuracy on the synthetic data. • The best anomaly indicators are higher frequency (400 MHz BW) FDR data. Other tests may be interesting but for this study, this was the best predicter.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

The EGS Collab Project: Status and Accomplishments

The EGS Collab project, supported by the US Department of Energy, is addressing challenges in implementing enhanced geothermal systems (EGS). This includes improving understanding of the stimulation of crystalline rock to create appropriate flow pathways, and the ability to effectively simulate both the stimulation and the flow and transport processes in the resulting fracture network. The project is performing intensively monitored rock stimulation and flow tests at the 10-m scale in an underground research laboratory. Data and observations from the field test are compared to simulations to understand processes and to build confidence in numerical modeling of the processes. In Experiment 1, we examined hydraulic fracturing an underground test bed at the Sanford Underground Research Facility (SURF) in Lead, South Dakota, at a depth of approximately 1.5 km. We drilled eight sub-horizontal boreholes in a well-characterized phyllite. Six of the boreholes were instrumented with many sensor types to allow careful monitoring of stimulation events and flow tests, and the other two boreholes were used for water injection and production. We performed a number of stimulations and flow tests in the testbed. Our monitoring systems allowed detailed observations and collection of numerous data sets of processes occurring during stimulation and during dynamic flow tests. Long-term ambient temperature and chilled water flow tests were performed in addition to many tracer tests to examine system behavior. Data were rapidly analyzed, allowing adaptive control of the tests. Numerical simulation was used to answer key experimental design questions, to forecast fracture propagation trajectories and extents, and to analyze and evaluate results. Many simulations were performed in near-real-time in conjunction with the field experiments, with more detailed process study simulations performed on a longer timeframe. Experiment 2 will examine hydraulic shearing in a test bed being built at the SURF at a depth of about 1.25 km in amphibolite under a different set of stress and fracture conditions than Experiment 1. Five sets of fracture orientations were considered in design, and three orientations seem to be consistently observed.

EGS Collab↗

Industrial Energy Management During a Pandemic: Lessons Learned from DOE Better Plants Program Partners

The COVID-19 pandemic is causing many challenges for manufacturers, especially those that depend on workers whose jobs cannot be performed remotely. This has detrimentally impacted the energy management workforce, energy support system performance, as well as operations and supply chains.This article discusses four primary challenges for industrial energy management caused by the pandemic, strained budget for energy projects, increased energy intensity caused by low production rates and other safety practices, limited access to energy systems, and the lost knowledge and experience of senior staff. This article also proposes some potential solutions for these challenges that include implementing no- and low-cost energy conservation measures, adopting alternative financing options, improving shutdown procedures, reducing baseloads, creating an effective online energy-monitoring system, performing virtual energy assessments, building a robust EnMS, and attending online and in-person training events.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Online Monitoring of Catalytic Processes by Fiber-Enhanced Raman Spectroscopy

An innovative solution for real-time monitoring of reactions within confined spaces, optimized for Raman spectroscopy applications, is presented. This approach involves the utilization of a hollow-core waveguide configured as a compact flow cell, serving both as a conduit for Raman excitation and scattering and seamlessly integrating into the effluent stream of a cracking catalytic reactor. The analytical technique, encompassing device and optical design, ensures robustness, compactness, and cost-effectiveness for implementation into process facilities. Notably, the modularity of the approach empowers customization for diverse gas monitoring needs, as it readily adapts to the specific requirements of various sensing scenarios. As a proof of concept, the efficacy of a spectroscopic approach is shown by monitoring two catalytic processes: CO 2 methanation (CO 2 + 4H 2 → CH 4 + 2H 2 O) and ammonia cracking (2NH 3 → N 2 + 3H 2 ). Leveraging chemometric data processing techniques, spectral signatures of the individual components involved in these reactions are effectively disentangled and the results are compared to mass spectrometry data. This robust methodology underscores the versatility and reliability of this monitoring system in complex chemical environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Recent Advances in Machine Learning for Fiber Optic Sensor Applications

Over the last three decades, fiber optic sensors (FOS) have gained a lot of attention for their wide range of monitoring applications across many industries, including aerospace, defense, security, civil engineering, and energy. FOS technologies hold great promise to form the backbone for next‐generation intelligent sensing platforms that offer long‐distance, high‐accuracy, distributed measurement capabilities and multiparametric monitoring with resilience to harsh environmental conditions. The major limitations posed by FOS are 1) cross‐sensitivity, 2) enormous volume and large data generation, 3) low data processing speed, 4) degradation of signal‐to‐noise ratio over the fiber length, and 5) overall cost of sensor and interrogator systems. These challenges can be overcome by building advanced data analytics engines enabled by recent breakthroughs in machine learning (ML) and artificial intelligence (AI). This article presents a comprehensive review of recent studies that integrate ML and AI algorithms with FOS technologies. This review also highlights several FOS technology development directions that promise a significant impact on widespread use for several industrial applications, with an emphasis on energy systems monitoring. A perspective on future directions for further research development is also provided.

97 MATHEMATICS AND COMPUTING↗