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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

The O II /7319-7330 A/ dayglow

The paper is concerned with a more detailed determination of the quenching rates of O(+)(2-P) ions by electrons, molecular nitrogen, and atomic oxygen using data from the Atmosphere Explorer C and D satellites. It is found that the orbit examined by Walker et al. (1975) was contaminated by zodiacal emissions. Production of the cited ions in the daytime is primarily due to photoionization excitation of neutral atomic oxygen. The quenching rate coefficients which best modified the 7319-A source functions to satisfy the data are determined by a least squares fitting technique. Molecular nitrogen is shown to dominate the quenching over most of the altitude ranges. Electrons become the most important quenching agent at high altitudes but are still a factor of 10 less important than radiation.

Rusch, D. W.↗
NASA NTRS1996

Theoretical Chemistry At NASA Ames Research Center

The theoretical work being carried out in the Computational Chemistry Branch at NASA Ames will be overviewed. This overview will be followed by a more in-depth discussion of our theoretical work to determine molecular opacities for the TiO and water molecules and a discussion of our density function theory (DFT) calculations to determine the harmonic frequencies and intensities to the vibrational bands of polycyclic aromatic hydrocarbons (PAHs) to assess their role as carriers to the unidentified infrared (UIR) bands. Finally, a more in-depth discussion of our work in the area of computational molecular nanotechnology will be presented.

Langhoff, Stephen↗
NASA NTRS1994

Dense molecular shocks and accretion onto protostellar disks

We have examined the physical and chemical processes which accompany the propagation of a J-type shock through molecular astrophysical gas of density 10(exp 7.5) - 10(exp 12) H nuclei per cu cm. Our study is primarily relevant to the high-density accretion shocks which are associated with the supersonic infall of material during the collapse of a molecular cloud core to form a protostar. We have carried out a general parameter study to determine the characteristic infrared emission spectrum of dense molecular shocks and the extent of grain destruction within such shocks as a function of relevant shock parameters. Accretion shocks with mass accretion rates approximately greater than 10(exp -5) solar masses per y are plausible sources of the CO v = 2-0 vibrational band emission observed in many protostars, at least for sources of moderate CO v = 2-0 luminosity (approximately less than few x 10(exp 23) W). Rovibrational emissions from H2O and OH are also predicted to be luminous in dense molecular accretion shocks. Vaporization is the dominant mechanism of grain destruction within dense molecular shocks, leading to the efficient removal of those grains which are heated to their vaporization temperature by the combined effects of radiative heating, drag heating, and thermal heating by the hot postshock gas. The criteria for grain vaporization are obtained for grains composed of several different materials: metallic iron, silicate, troilite, refractory organic materials, volatile organic materials, and water ice.

Neufeld, David A.↗
NASA NTRS1968

Real fluid properties of normal and parahydrogen

Computer program calculates the real fluid properties of normal or parahydrogen using a library of single function calls without initial estimates. Accurate transport and thermodynamic properties of molecular hydrogen are needed for advanced propulsion systems.

Goldberg, F. N.↗
NASA NTRS1973

The San Marco 3 neutral atmosphere composition experiment

The experimental instrumentation of the San Marco 3 satellite is described along with the calibration and operation. The instrumentation for the following experiments was included: an air density experiment for measuring the instantaneous drag force, and thus the neutral particle total mass density; a neutral atmosphere composition experiment for measuring the densities of helium, atomic and molecular oxygen, molecular nitrogen and argon; and a neutral atmosphere temperature experiment to determine the gas kinetic temperature by measuring molecular nitrogen density variations in an orificed spherical chamber as a function of angle of attack.

Pelz, D. T.↗
NASA NTRS1973

Interstellar molecular hydrogen observed in the ultraviolet spectrum of delta Scorpii

The ultraviolet spectrogram of delta Scorpii is analyzed for its interstellar molecular hydrogen signatures. Plots of the measured relative flux as a function of wavelength show the positions of the hydrogen lines in the Lyman and Werner bands. In general, each observed band is composed of transitions arising from the lowest rotational level and the first excited rotational level of the ground state, and of a single transition arising from the J = 1 level of the ground state only. Column densities of H2 molecules as well as cloud temperature are deduced.

Smith, A. M.↗
NASA NTRS1981

Computations of transmittance and radiance in infrared water vapor sounding channels

The wing-scaling approximation/k-distribution method, previously developed for computing solar heating rates (Chou and Arking, 1981) was applied to the computation of the transmittance and outgoing radiance in infrared water vapor sounding channels. Functions necessary for the transmittance and radiance computations were computed from molecular line parameters using line-by-line methods. The method was applied to the three HIRS/2 water vapor sounding channels on the TIROS-N satellite, and its accuracy was tested using 11 widely separated atmospheres which ranged from hot-wet tropical atmospheres to cold-dry subarctic atmospheres. Compared to line-by-line calculations, maximum errors were shown to be less than 0.017 in transmittance and 0.4 K in brightness temperature for all cases. The rms errors are less than 0.009 in transmittance and 0.2 K in brightness temperature, the brightness temperature rms error being much smaller than the instrument noise.

Chou, M.-D.↗
NASA NTRS1982

A study comparing several isocyanate and isothiocyanate derivatives of Porasil C for the separation of lower hydrocarbons by GC

Several isocyanate and isothiocyanate derivatives of Porasil C were synthesized and evaluated for the separation of the low-molecular-weight saturated and unsaturated hydrocarbons. It was shown that different functional groups significantly affect the retention behavior of the more polar unsaturated hydrocarbons, and that reproducible results can be obtained if dry carrier gas is used.

Pollock, G. E.↗
NASA NTRS1987

Dynamic characterization of viscoelastic polymer solutions in a lubricated cylinder - Plate apparatus

The characterization of several viscoelastic lubricants which are oil or water based has been studied in an apparatus consisting of a lubricated cylinder-plate contact. The friction loads were measured as a function of speed. The experimental results show the influence of the molecular weight and of the concentration of the polymeric additive as well as the influence of the viscosity of the oil-base on the load and friction coefficient. Also a test for mechanical degradation was performed on the polymer solutions. Several additives can favor a viscoelastic lubrication.

Doremus, P.↗
NASA NTRS1992

Effect of atmospheric extinction on laser rangefinder performance at 1.54 and 0.6 microns

Extinction of laser rangefinder (LRF) pulses by the atmosphere depends on the wavelength, weather conditions, and aerosol concentration along the optical path. In the IR, extinction is due to absorption by molecular constituents and scattering and absorption by aerosols. The total atmospheric extinction alpha(lambda) is the sum of the molecular and aerosol contributions, alpha(sub m)(lambda)and Alpha(sub a)(lambda). We present simple expressions for alpha(sub m)(lambda) and alpha(sub a)(lambda) for two LRF sources: Er:glass and CO2 which operate at 1.54 and 10.6 microns, respectively. The expressions are based on accepted models of atmospheric aerosols and molecular extinction and give an estimate of alpha(lambda) as a function of standard meteorological parameters, assuming horizontal beam propagation. Signal-to-noise ratios of LRF returns, measured from a reference target under different weather conditions are compared to predictions based on the estimate of alpha(lambda).

Hutt, D. L.↗
NASA NTRS1992

The complete UV spectrum of SO2 and electron impact. II - The middle ultraviolet spectrum

Measurements of the middle ultraviolet (MUV) electron impact induced fluorescence spectrum of SO2 from 200 to 430 nm in a crossed beam experiment are reported. The spectrum is dominated by two features at the experimental resolution of 0.5 nm; these two features are referred to as MUV1 and MUV2. MUV1 is the SO band system extending from 240 to 265 nm produced by dissociative excitation. MUV2 is a blend of the SO2 and SO2(+) molecular band systems in the range 264-430 nm. The excitation function measurements of MUV2 indicate that low-energy electrons effectively prepare SO2 in one or more electronically excited triplet states that involve the SO2 state by direct excitation and/or cascading. The peak cross section for MUV1 occurs at 20 eV with a value of 25.0 +/-5.5 x 10 exp -19 sq cm. The peak cross section for MUV2 arises at 9 eV with a value of 368 +/-81 x 10 exp -19 sq cm. The laboratory results provide a plausible explanation of the Io auroral hot spots observed by Voyager 2.

Ajello, Joseph M.↗
NASA NTRS1993

Condensed-matter energetics from diatomic molecular spectra

Analyses of molecular spectra and compression data from crystals show that a single function successfully describes the dependence on interatomic separation of both the potential energy of diatomic molecules and the cohesive binding energy of condensed matter. The empirical finding that one function describes interatomic energies for such diverse forms of matter and over a wide range of conditions can be used to extend condensed-matter equations of state but warrants further theoretical study.

Kim, In H.↗
NASA NTRS1991

Surface disordering of Pb(110)

A molecular dynamics simulation of Pb(110), using embedded atom method energy functional and two-body potential derived for the purpose, shows that near 400 K the three surface layers begin to disorder well before the bulk (interior) layers. Transfer of atoms from the first subsurface layer to the surface layer occurs. Disordering propagates beyond the top three layers above 550 K, accompanied by formation of an adlayer and vacancies in the top three layers. Behavior of the two-dimensional layer structure factors indicates that disordering is anisotropic. Simulation results are consistent with experimental observations of surface roughening near 400 K and more extensive surface ordering above 525 K. Results are consistent with simulations for Ni and Al.

Tibbits, P.↗
NASA NTRS1982

A Study Comparing Several Isocyanate and Isothiocyanate Derivatives of Porasil C for the Separation of Lower Hydrocarbons by GC

Several isocyanate and isothiocyanate derivatives Porasil C were synthesized and evaluated for the separation of the low-molecular-weight saturated and unsaturated hydrocarbons. It was shown that different functional groups significantly affect the retention behavior of the more polar unsaturated hydrocarbons, and that reproducible results can be obtained if dry carrier gas is used.

Pollock, Glenn E.↗
NASA NTRS1999

Waterproof Silicone Coatings of Thermal Insulation and Vaporization Method

Thermal insulation composed of porous ceramic material can be waterproofed by producing a thin silicone film on the surface of the insulation by exposing it to volatile silicone precursors at ambient conditions. When the silicone precursor reactants are multi-functional siloxanes or silanes containing alkenes or alkynes carbon groups higher molecular weight films can be produced. Catalyst are usually required for the silicone precursors to react at room temperature to form the films. The catalyst are particularly useful in the single component system e.g. dimethylethoxysilane (DNMS) to accelerate the reaction and decrease the time to waterproof and protect the insulation. In comparison to other methods, the chemical vapor technique assures better control over the quantity and location of the film being deposited on the ceramic insulation to improve the waterproof coating.

Cagliostro, Domenick E.↗