DOE OSTI2017
The aim of this project was to introduce a new class of technology—that of high-efficiency silicon-based tandem photovoltaic (PV) modules—that, with follow-on development, has a clear path to reduced levelized cost of electricity (LCOE) for utility-scale power generation. In particular, the objective of the project was to demonstrate the first 30%-efficient III-V/silicon module in outdoor conditions using a tandem geometry in which the sub-cells are detached physically but coupled optically. In present PV power plants installed in the US, the module makes up only approximately one-third of the cost; area-dependent balance-of-systems (BOS) costs such as installation materials, labor, land, and site prep made up an additional third, and area-independent BOS costs round out the final third. With this pricing structure, (annually averaged) module efficiency is a clear market driver: increase the annual energy output per module and the effective costs translated into $/W of both the module and the area-dependent BOS—two-thirds of the total cost—decrease proportionately. However, the dominant PV technology—flat-plate silicon modules—is reaching its theoretical efficiency limit, and thus a tandem technology in which silicon is coupled with a wider-bandgap cell is a promising route to remain responsive to market forces. As it is not trivial to couple silicon with other cells in conventional two-terminal geometries due to, e.g., lattice mismatch, this project introduced a new, four-terminal configuration using a “PVMirror.” A PVMirror utilizes PV cells as a three-in-one technology—they act as a concentrating mirror, spectrum splitter, and high-efficiency light-to-electricity converter. Light is incident upon a full-aperture dichroic mirror that reflects visible light and transmits infrared light. The transmitted light is absorbed in silicon PV cells that are placed behind the dichroic mirror and that convert IR photons to electricity with high efficiency. The dichroic mirror and silicon PV cells are affixed to a curved glass trough that tracks the sun about a single, North-South axis such that the reflected VIS light is concentrated at a common line focus, at which is placed a second, wider-bandgap GaAs PV cell having high efficiency at shorter wavelengths. The innovation of PVMirrors lies in their design, which maximizes annual energy output and minimizes the constraints placed on the sub-cells. In particular, the cells are free of lattice- and current-matching restrictions, neither cell requires a transparent rear electrode, and either sub-cell can be placed at the focus depending on their relative costs. Furthermore, the greatest benefit of PVMirrors is that they make use of a portion of the diffuse light whereas concentrator tandems cannot. This results in a benefit in energy yield and extends PVMirrors’ competitive range. Over the course of this one-year project, a silicon PVMirror and GaAs receiver were fabricated, characterized, and placed outdoors on a sun tracker, where the efficiency of the tandem “module” was measured for three days. Notable results include the first demonstration of this flexible tandem configuration, a maximum tandem efficiency of 29.6% (just shy of the 30% overall project goal), successful conversion of diffuse light into electricity, a thorough loss analysis indicating a path to over 31% efficiency, and a roadmap to cost-competitive PVMirror tandems using a wide-bandgap polycrystalline PVMirror and a silicon receiver. Development of a >18%-efficient wide-bandgap polycrystalline cell—the key enabler of this envisioned tandem—should be a future research focus. This project has laid the groundwork for a PV technology that, with continued development, has the potential to reach LCOEs as low as $0.03/kWh according to our calculations. Such a system would provide the public with inexpensive, clean solar power.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗