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At least 361 records · Page 20

Oxidation of metals and alloys in controlled atmospheres using in situ transmission electron microscopy and Auger spectrography

Single-crystalline thin films of copper were oxidized at an isothermal temperature of 425 C and at an oxygen partial pressure of .005 Torr in situ in a high-resolution electron microscope. The specimens were prepared by epitaxial vapor deposition onto polished 100 and 110 faces of rocksalt and mounted in a hot stage inside an ultra-high-vacuum specimen chamber of the microscope. Large amounts of sulfur, carbon, and oxygen were detected by Auger electron spectroscopy on the surface of the as-received films and were removed in situ by ion-sputter etching immediately prior to the oxidation. The nucleation and growth characteristics of Cu2O on Cu were studied. Results show that neither stacking faults nor dislocations are associated with the Cu2O nucleation sites. The growth of Cu2O nuclei is linear with time. The experimental findings, including results from oxygen dissolution experiments and from repetitive oxidation-reduction-oxidation sequences, fit well into the framework of an oxidation process involving (a) the formation of a surface-charge layer, (b) oxygen saturation in the metal and (c) nucleation, followed by surface diffusion of oxygen and bulk diffusion of copper for lateral and vertical oxide growth, respectively.

Rao, D. B.↗

A spectroscopic, photometric, and magnetic study of the starspot on II Pegasi

A description is presented of extensive observations of II Peg during 1977 and 1978, taking into account multicolor broad-band photometry, high-dispersion spectroscopy, low-dispersion spectrophotometry, and Zeeman analysis. During this time the star showed periodic light variations in excess of a 0.4 mag range attributable to the presence of a large starspot or an equivalent nonuniform surface brightness distribution. The high-precision multicolor photometry, which differed greatly from previous photometric results, illustrates that the starspots on II Peg are continually evolving on time scales of approximately 1 year or less. A low-dispersion spectrum of the large spot showed pronounced VO and TiO molecular adsorption features. A high-resolution, high signal-to-noise Reticon spectrum at lambda 6707 does not show any compelling evidence of previously reported lithium in this star.

Vogt, S. S.↗

The 12 micron band of ethane - High-resolution laboratory analysis with candidate lines for infrared heterodyne searches

Attention is given to the results of a laboratory study of the v9 band of ethane at 12 microns, using both high resolution Fourier transform and diode laser absorption spectroscopy. The analysis to which about 2000 transitions in this band have been subjected includes the normal rotational terms as well as the higher order effects of l-doubling, l-resonance, internal rotation, and a Coriolis resonance with the 3v4 state. A model is presented for the v9 band which is able to reproduce the observed features to an accuracy of better than 0.001/cm, and a list has been compiled for v9 transitions, occurring near C-14O2 laser lines, that are good candidates for laser heterodyne searches.

Atakan, A. K.↗

Observing Comet Halley with Space Telescope

The NASA Space Telescope (ST) to be launched into LEO by STS in late 1985 is characterized, and its potential use for observations of Comet Halley shortly after the perihelion passage in February, 1986, is discussed. The ST comprises a 2.4-m MgF2-coated primary reflector (with maximum field of view 2.7 x 2.7 arcmin, wavelength coverage 120-1100 nm, and maximum tracking rate 0.21 arcsec/sec) and five first-generation scientific instruments (wide-field planetary camera, faint-object camera, high-resolution and faint-object spectrographs, and high-speed photometer). Planned ST observations of Halley include periods of continuous observation much longer than can be obtained from the ground, provision of supplementary data and navigation information to Giotto and other deep-space missions, emission spectroscopy, UV polarimetry, and possible detection of 124-nm H2O absorption. Before March 11, 1986, earth occultation or similar procedures will be required to observe Halley because it will be within the ST 50-deg solar-elongation-distance limit.

Caldwell, J.↗

An assessment of OH airglow interference on the remote sensing of stratospheric HCl via limb sounding in the near-I.R.

Chemiluminescent emission from the formation of vibrationally excited OH at an altitude of approximately 85 km presents a barrier to earth-limb measurements of NIR emissions originating in the stratosphere. High-resolution measured spectra of OH airglow have not been reported, and thus it is difficult to assess its impact on moderately-high-resolution earth-limb spectroscopy capable of looking between strong OH lines. Low-resolution rocketborne spectrometer earth-limb measurements of OH airglow are mathematically inverted to recover vibrational-state populations that are used to simulate a higher resolution spectrum in the neighbourhood of 2843/cm. Implications for remote sensing HCl are presented.

Mergenthaler, J. L.↗

High-Resolution Detector For X-Ray Diffraction

Proposed x-ray-sensitive imaging detector offers superior spatial resolution, counting-rate capacity, and dynamic range. Instrument based on laser-stimulated luminescence and reusable x-ray-sensitive film. Detector scans x-ray film line by line. Extracts latent image in film and simultaneously erases film for reuse. Used primarily for protein crystallography. Principle adapted to imaging detectors for electron microscopy and fluorescence spectroscopy and general use in astronomy, engineering, and medicine.

Carter, Daniel C.↗

Transmission X-ray diffraction grating alignment using a photoelastic modulator

A high-resolution alignment technique which utilizes the partial polarization property of fine period transmission gratings has been developed. It is especially useful when the grating period is sufficiently small so that there are no visible diffracted orders. This technique uses a photoelastic modulator (PEM) to produce an intensity signal that is proportional to the sine of twice the angle between the grating lines and the PEM crystal axis. The experimentally demonstrated resolution of this technique on 200-nm period gold transmission gratings is better than 1 arc sec. This technique was developed to align X-ray transmission gratings for spectroscopy and interferometry applications.

Anderson, Erik H.↗

A high-resolution gamma-ray and hard X-ray spectrometer for solar flare observations in Max 1991

A long duration balloon flight instrument for Max 1991 designed to study the acceleration of greater than 10 MeV ions and greater than 15 keV electrons in solar flares through high resolution spectroscopy of the gamma ray lines and hard X-ray and gamma ray continuum is described. The instrument, HIREGS, consists of an array of high-purity, n-type coaxial germanium detectors (HPGe) cooled to less than 90 K and surrounded by a bismuth germanate (BGO) anticoincidence shield. It will cover the energy range 15 keV to 20 MeV with keV spectral resolution, sufficient for accurate measurement of all parameters of the expected gamma ray lines with the exception of the neutron capture deuterium line. Electrical segmentation of the HPGe detector into a thin front segment and a thick rear segment, together with pulse-shape discrimination, provides optimal dynamic range and signal-to-background characteristics for flare measurements. Neutrons and gamma rays up to approximately 0.1 to 1 GeV can be detected and identified with the combination of the HPGe detectors and rear BGO shield. The HIREGS is planned for long duration balloon flights (LDBF) for solar flare studies during Max 1991. The two exploratory LDBFs carried out at mid-latitudes in 1987 to 1988 are described, and the LDBFs in Antarctica, which could in principle provide 24 hour/day solar coverage and very long flight durations (20 to 30 days) because of minimal ballast requirements are discussed.

Lin, R. P.↗

High-resolution Interferometer Sounder (HIS), phase 2

The High-resolution Interferometer Sounder (HIS) was successfully built, tested, and flight proven on the NASA U-2/ER-2 high altitude aircraft. The HIS demonstration has shown that, by using the technology of Fourier Transform Spectroscopy (FTS), it is possible to measure the spectrum of upwelling infrared radiance needed for temperature and humidity sounding with high spectral resolution and high radiometric precision. By resolving individual carbon dioxide lines, the retrieved temperature profiles have vertical resolutions of 1 to 2 km and RMS errors less than 1 C, about 2 to 4 times better than possible with current sounders. Implementing this capability on satellite sounders will greatly enhance the dynamical information content of temperature measurements from space. The aircraft model HIS is now a resource which should be used to support field experiments in mesoscale meteorology, to monitor trace gas concentrations and to better understand their effects on climate, to monitor the surface radiation budget and the radiative effects of clouds, and to collect data for research into retrieval techniques, especially under partially cloudy conditions.

Source record↗

The relation between X-ray emission and rotation in late-type stars from the perspective of X-ray selection

An X-ray-selected sample of 128 late-type (F-M) stars analyzed. These stars were identified as optical counterparts to serendipitous X-ray detections made by the Einstein Observatory Extended Medium Sensitivity Survey. Once identified as X-ray sources, the sample was followed up by an extensive program of optical observations, including high-resolution and low-resolution spectroscopy and photometry. Spectral types, luminosity classes, distances, X-ray luminosities, projected rotation rates (v sin i), radial velocities, and binary status have been determined for the sample.

Fleming, Thomas A.↗

Space Shuttle Main Engine nozzle mounted optic for throat plane spectroscopy

A program intended to develop a flight-capable nozzle mounted optic for monitoring emissions from metals entrained in the Space Shuttle Main Engine (SSME) flowfield is described. The optic will collect light emitted from metal atoms within the high-temperature, high-pressure SSME chamber and transfer the optical signal to a high-resolution spectrometer via a fiber-optic cable. The nozzle mounted optic makes it possible to conduct earth-to-orbit monitoring of flowfield emissions without requiring modifications to the SSME.

Bickford, R. L.↗

First results from the Goddard High-Resolution Spectrograph - Element abundances as a function of velocity in the neutral gas toward Xi Persei

Observations of ultraviolet interstellar absorption lines toward Xi Persei obtained with the echelle mode of the Goddard High-Resolution Spectrograph (GHRS) aboard the HST at a resolution of 3.5 km/s are presented. The data for O I, C II, Mg II, S II, Fe II, Si II, Mn II, and Zn II are converted into representations of apparent column density per unit velocity, Na(v), over the velocity range from -30 to +40 km/s. The profiles for ions that are the dominant state of ionization in neutral clouds permit a study of the variation of element abundance with velocity caused by changes in the gas phase depletion in the different absorbing regions situated toward Xi Per. In the denser portions of the diffuse clouds, heavy element depletions are very large. However, in absorbing components near -5 and +25 km/s, the depletions are less severe, with a nearly solar gas phase abundance ratio being found for the gas in the +25 km/s component. The measurements confirm that the GHRS is well suited for diagnostic spectroscopy of interstellar gas.

Savage, Blair D.↗

Thermal spectroscopy of Neptune - The stratospheric temperature, hydrocarbon abundances, and isotopic ratios

NASA-IRTF observations of Neptune's disk-averaged spectrum are presently used, in conjunction with a lower-resolution spectrum, to furnish a more reliable absolute intensity calibration of portions of Neptune's disk-averaged spectrum. The temperature profile adopted is consistent with the size and shape of the H2 J = 3-1 quadrupole feature detected in the emission. High-resolution measurements of (C-13C-12)H6 and (C-12)2H6 imply C-12/C-13 of 78 +/- 26; this is consistent with solar and telluric values.

Orton, Glenn S.↗

High-resolution study of luminous infrared galaxies. I - The composite nature of the Seyfert 1 galaxy IRAS 20044-6114 (NGC 6860)

The physical conditions in the ionized gas, the stellar population, and the kinematics of the Seyfert 1 galaxy IRAS 20044-6114 (NGC 6860) are studied by high spatial resolution optical imaging and optical and near-IR spectroscopy of this luminous IR source. The broadband images show a compact nucleus, two weak spiral arms, a bar, a bulge, an inner ring, and a possible outer ring. The I-alpha image reveals bright emission-line regions associated with the Seyfert nucleus and an inner ring of intense star formation. The forbidden O III 5007-A image shows that the high-excitation gas is elongated perpendicularly to the direction of the bar, and reveals a bright compact object at about 40 arcsec NE of the nucleus which is undetectable in the broadband images. This object is interpreted as a dwarf young H II galaxy. The optical, near-IR, and FIR results show clear evidence that the nuclear and circumnuclear regions have composite and complex structure: a variable Seyfert 1 nucleus embedded in an intense and dusty star formation. environment.

Lipari, Sebastian↗

Measurement of atmospheric composition by the ATMOS instrument from Table Mountain Observatory

Following its first flight on board the Space Shuttle 'Challenger' as part of the Spacelab 3 payload, the Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument has been operated at the Jet Propulsion Laboratory's Table Mountain Observatory (TMO; 34.4 deg N, 117.7 deg W, 2.23 km altitude) in the San Gabriel Mountains of Southern California. With the delay in the resumption of regular Shuttle flights, ATMOS has acquired a large number of high-quality, high-resolution infrared solar absorption spectra, spanning a period between late-1985 and mid-1990. These spectra are being analyzed to derive the column abundances of several atmospheric species including O3, HCl, HF, and HNO3. Although limited in temporal coverage, the preliminary results for these gases are discussed here in the context of the requirement and contribution to be made by similar instruments in detecting long term changes in stratospheric composition.

Gunson, Michael R.↗

High-resolution Y-axis readout for delay-line microchannel anodes

We have devised a method to obtain a high-resolution Y-axis event position determination from microchannel plate delay-line detectors. The method is based on the double-delay-line wedge-wedge charge partition principle of Lampton et al. (1990), where the X axis is read out by a pair of side-by-side delay lines and the Y-axis coordinate is determined by comparing the charges on the two parallel delay lines. However, our new method abandons the common field return path of the two delay lines, and splits them into two adjacent but independent transformer coupled timing circuits having no common ground connection except via the charge-measurement amplifiers. Thus we eliminate the large electrostatic capacitance of the delay lines from the input of the charge-measuring system. Over its limited working field, the spatial resolution in the Y coordinate can easily equal the resolution provided in the X coordinate by the delay line. Applications to extreme and FUV photon-counting spectroscopy are envisioned.

Raffanti, R.↗

The Balmer-dominated northeast limb of the Cygnus loop supernova remnant

We present a comprehensive investigation of the Balmar-dominated northeast limb of the Cygnus Loop supernova remnant. Data presented include H alpha (O III), and X-ray images, UV and visible spectrophotometry, and high-resolution spectroscophy. The two relatively bright Balmer-dominated filaments visible on the POSS prints are seen to be part of a very smooth and regular complex of filaments. These filaments mark the current location of the blast wave and are seen to bound the sharply limb-brightened X-ray emission, including the previously reported X-ray, 'halo.' The (O III)/h beta ratio throughout the region is approximately 0.1, except for regions in which the shock is undergoing a transition from nonradiative to incomplete radiative to incomplete radiative conditions. At these locations (O III) emission from the cooling region is quite strong, while collisionally excited Balmer-line emission can be weak because of photoionization of the preshock medium by UV from the nascent cooling region. As a result (O III)/H beta is greater than 100 in some locations. The nonradiative/radiative transition is best studied along the length of the northwestern of the two brightest filaments, where the shock velocity and swept-up column go from approximately 180 km/s and 10(exp 17)/sq cm at one end to approximately 140 km/s and 8 x 10(exp 17)/cm at the other. There are also a number of locations of such incomplete radiative emission where the shock has recently encountered denser regions with characteristic sizes of approximately 10(exp 18) cm. There is a considerable amount of evidence that the shock has decelerated from approximately 400 km/s to less than 200 km/s in the last 1000 yr. We interpret this as the result of the blast wave hitting the wall of a cavity which surround the supernova precursor and succeed in matching a wide range of data with a reflected shock model in which the density ofthe cavity wall is approximately 1.2/cu cm and the density in the interior of the cavity is about 0.09/cu cm. This analysis supports previous suggestions that the Cygnus Loop was a cavity explosion. We opredict that the X-ray shell will continue to brighten for the next 1000 years or so, during which time the shock front will become radiative throughout the northeast region. The similarity of the time scales for post-shock cooling, shock deceleration, and the 1ressure evolution of the region violates assumptions of steady flow, and greatly complicated interpretation of shock specptra in the region. This may be a common and important effect in many supernova remnants. High-resolutoin spectroscopy of the H alpha line profile shows that the broad component is surprisingly narrow (approximately 130 km/s). Consistency between this line width and the shock velocity inferred from spectrophotometry requires either rapid postshock equilibration of T(sub i) and T(sub e), or that the shock front has declerated from 180 km/s to 150 km/s in the last approximately 200 yr. While we cannot unambiguously distinquish between these models, the required deceleration is consistent with extrapolation of the shock decleration rate inferred over the last 1000 years. The width of the narrow component of the h alpha line profile is approximately 3 km/s, which indicates that the preshock medium has been heated to approximately 25,000 K by a shock precursor. The most promising types of precursor are heating either by fast neutrals which overtake the shock or by cosmic rays. In the latter case the observed properties of the precursor constrain the cosmic-ray diffusion coefficient to be between about 10(exp 23) sq cm/s. The characteristics of the precursor seem to be about right to explain the presence of weak (S II) and (N II) emission previously reported by Fesen & Itoh (1985).

Hester, J. Jeff↗

Long-Term Trends in the Concentrations of SF6, CHClF2, and COF2 in the Lower Stratosphere from Analysis of High-Resolution Infrared Solar Occultation Spectra

Long-term trends in the concentrations of SF6, CHClF2 (CFC-22), and COF2 in the lower stratosphere have been derived from analysis of ca. 1980 and more recent infrared solar occultation spectra recorded near 32 deg N latitude at approx. 0.02/ cm resolution. Consistent sets of line parameters and spectral calibration methods have been used in the retrievals to minimize systematic error effects. Quoted error limits are 1 sigma estimated precisions. The SF6 and CHClF2 results are based on spectra recorded by balloon-borne interferometers in March 1981 and June 1988 and a comparison of these results with the Atmospheric Trace Molecule Spectroscopy (ATMOS) Experiment/Spacelab 3 measurements obtained in May 1985 near 30 deg N latitude. In the 13-18 km altitude range the mean measured SF6 mixing ratio in parts per trillion by volume (pptv) increased from 1.17 +/- 0.21 in March 1981 to 2.02 +/- 0.20 pptv in June 1988, and the CHClF2 mixing ratio below 15 km altitude increased from 51 +/- 8 pptv in March 1981 to 102 +/- 10 pptv in June 1988. The CHClF2 retrievals used new empirical CHClF2 line parameters derived from 0.03/cm resolution laboratory spectra recorded at six temperatures between 203 and 293 K; the derived mixing ratios are approx. 30% higher than obtained with earlier sets of line parameters, thereby removing a large discrepancy noted previously between IR and in situ measurements of CHClF2. Assuming an exponential growth model for fitting the trends, SF6 and CHClF2 mean increase rates of 7.4% +/- 1.9% and 9.4% +/- 1.3% /year, are obtained, respectively, which correspond to cumulative increases by factors of approx. 1.7 and -2.0 in the concentrations of these gases over the 7.2-year measurement period. Analysis of spectra recorded in October 1979 and April 1989 yields COF2 volume mixing ratios that are respectively 0.44 +/- 0.17 and 1.21 +/- 0.24 times the ATMOS/Spacelab 3 values, from which an average COF2 increase rate of 10.3 +/- 1.8%/ year over this time period has been estimated. The present results are compared with previously reported observations and trends and with one-dimensional model calculations. The model calculated trends are in reasonably good agreement with the observations.

Rinsland, C. P.↗