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Results for “effective diffusivity”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Characteristics and mathematical modeling of apple slice drying in an electrohydrodynamic system with a needle‐plate electrode

Abstract The drying of apple slices in an electrohydrodynamic (EHD) system with a needle‐plate electrode was characterized and mathematically modeled at voltages of 30, 40, and 50 kV and with distances between needles of 5, 6, and 7 cm. The results showed that the drying rate, effective water diffusion coefficient, and rehydration ratio of the apple slices, and specific energy consumption of drying, all increased with increasing voltage. Initially, there was a period when the drying rate was approximately constant in the low‐voltage EHD, but not in the high voltage conditions. At the same voltage, the drying rate was highest when the distance between needles was 6 cm. The voltage and distance between needles had a significant ( p < .05) interactive effect on the effective water diffusion coefficient and specific energy consumption, but not on the rehydration ratio. General mathematical models for drying can be used to represent the drying behavior of apple slices. The Midilli and Kucuk model and the Logarithmic model had the best fits, with correlation coefficients of 0.998803 and 0.998267, respectively. Predictive functions for the moisture ratio of apple slices based on voltage and distance between needles were established and verified. The results indicated that the Logarithmic model could more accurately predict the moisture ratio of apple slices dried using the EHD method. Practical Applications As a new drying technology, electrohydrodynamic (EHD) drying has unequaled advantages. According to the results, using the appropriate voltage and distance between needles improves not only drying efficiency, but also the rehydration ratio of apple slices, which reflects the quality of dried products. The Logarithmic model can accurately predict the EHD drying behavior of apple slices, which is of great significance in optimizing actual production.

Li, Bowen↗
DOE OSTI2019

Theoretical Analysis of the EPR Spectrum Saturation Effect with Account for Spectral Diffusion in a System with a Gaussian Distribution of Spin Resonance Frequencies

We have analyzed the effect of saturation of the EPR spectrum for the model situation when a set of resonance frequencies of spin packets is described by a Gaussian distribution and spectral diffusion, which is a random process without correlation, exists. We have obtained the form of the spectrum for arbitrary values of magnetic–resonant parameters: relaxation times for the longitudinal and transverse components of the magnetization vector of the system, the spectral diffusion rate, the dispersion of the Gaussian distribution of resonance frequency, and the magnetic induction of the microwave field. We have derived an analytic expression for the saturation curve of the EPR spectrum. Detailed analysis of the dependence of the spectrum saturation curve on the spin system parameters is performed for the optimal case when the microwave field frequency coincides with the average frequency of the Gaussian distribution for resonance frequencies. The value of the microwave field induction at which the peak of the saturation curve is attained has been determined for arbitrary values of the paramagnetic relaxation time, spectral diffusion rate, and dispersion of the Gaussian spin frequency distribution. We have formulated the algorithm for determining the spin–lattice relaxation time using the experimentally determined microwave field induction for which the saturation curve passes through the peak. It should be noted that numerical calculations have been performed for parameters typical of EPR spectroscopy. The general analytic expression derived for the shape of the spectrum in the saturation conditions and qualitative conclusions concerning the effect of spectral diffusion on the saturation of stationary spectra obtained in this study can also be used in other fields of spectroscopy.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2014

Lateral carrier diffusion and current gain in terahertz InGaAs/InP double-heterojunction bipolar transistors

The DC current gain in In{sub 0.53}Ga{sub 0.47}As/InP double-heterojunction bipolar transistors is computed based on a drift-diffusion model, and is compared with experimental data. Even in the absence of other scaling effects, lateral diffusion of electrons to the base Ohmic contacts causes a rapid reduction in DC current gain as the emitter junction width and emitter-base contact spacing are reduced. The simulation and experimental data are compared in order to examine the effect of carrier lateral diffusion on current gain. The impact on current gain due to device scaling and approaches to increase current gain are discussed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

ISD3: a particokinetic model for predicting the combined effects of particle sedimentation, diffusion and dissolution on cellular dosimetry for in vitro systems

The development of particokinetic models describing the delivery of insoluble or poorly soluble nanoparticles to cells in liquid cell culture systems has improved the basis for dose-response analysis, hazard ranking from high-throughput systems, and now allows for translation of exposures across in vitro and in vivo test systems. Complimentary particokinetic models that address processes controlling delivery of both particles and released ions to cells, and the influence of particle size changes from dissolution on particle delivery for cell-culture systems would help advance our understanding of the role of particles ion dosimetry on cellular toxicology. We developed ISD 3 , an extension of our previously published model for insoluble particles, by deriving a specific formulation of the Population Balance Equation for soluble particles. ISD3 describes the time, concentration and particle size dependent dissolution of particles, their delivery to cells, and the delivery and uptake of ions to cells in in vitro liquid test systems. The model is modular, and can be adapted by application of any empirical model of dissolution, alternative approaches to calculating sedimentation rates, and cellular uptake or treatment of boundary conditions. We apply the model to calculate the particle and ion dosimetry of nanosilver and silver ions in vitro after calibration of two empirical models, one for particle dissolution and one for ion uptake. The results demonstrate utility and accuracy of the ISD 3 framework for dosimetry in these systems. Total media ion concentration, particle concentration and total cell-associated silver time-courses were well described by the model, across 2 concentrations of 20 and 110 nm particles. ISD 3 was calibrated to dissolution data for 20 nm particles as a function of serum protein concentration, but successfully described the media and cell dosimetry time-course for both particles at all concentrations and time points. We also report the finding that protein content in media has effects both on the initial rate of dissolution and the resulting near-steady state ion concentration in solution.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Leaching Model of Radionuclides in Metal-Organic Framework Particles

Metal-organic frameworks (MOFs) have been used to sequester radionuclides and seal them inside of porous scaffolds using postsynthetic modification procedures. Experiments show that certain Zr-MOF with different capping linkers significantly affects the radionuclide release kinetics. In this work, we developed a leaching model of radionuclides in Zr-MOF particles. The model assumes that uranyl species occupy two energetically favored sites: the metal node and the MOF pores. For a given overall concentration of uranyl species, the partitions of uranyl species at the metal nodes and within the pores are determined by their chemical potentials. The model also considers the effect of particle surface and concentration on chemical potentials and diffusivity. The effects of spatial and structural dependent chemical potentials and diffusivity as well as particle sizes on leaching kinetics are investigated with the model. Predicted and measured uranyl leaching kinetics in Zr-MOF particles under batch experiments are compared. The results demonstrate the model’s capability for exploring the mechanisms of leaching and provide guidance for material design.

Metal-Organic Framework, Diffusion, uranyl, Leachi↗
DOE OSTI2014

Turbine exhaust diffuser with a gas jet producing a coanda effect flow control

An exhaust diffuser system and method for a turbine engine includes an inner boundary and an outer boundary with a flow path defined therebetween. The inner boundary is defined at least in part by a hub structure that has an upstream end and a downstream end. The outer boundary may include a region in which the outer boundary extends radially inward toward the hub structure and may direct at least a portion of an exhaust flow in the diffuser toward the hub structure. The hub structure includes at least one jet exit located on the hub structure adjacent to the upstream end of the tail cone. The jet exit discharges a flow of gas substantially tangential to an outer surface of the tail cone to produce a Coanda effect and direct a portion of the exhaust flow in the diffuser toward the inner boundary.

42 ENGINEERING↗
DOE OSTI2014

Diffusion-assisted selective dynamical recoupling: A new approach to measure background gradients in magnetic resonance

Dynamical decoupling, a generalization of the original NMR spin-echo sequence, is becoming increasingly relevant as a tool for reducing decoherence in quantum systems. Such sequences apply non-equidistant refocusing pulses for optimizing the coupling between systems, and environmental fluctuations characterized by a given noise spectrum. One such sequence, dubbed Selective Dynamical Recoupling (SDR) [P. E. S. Smith, G. Bensky, G. A. Álvarez, G. Kurizki, and L. Frydman, Proc. Natl. Acad. Sci. 109, 5958 (2012)], allows one to coherently reintroduce diffusion decoherence effects driven by fluctuations arising from restricted molecular diffusion [G. A. Álvarez, N. Shemesh, and L. Frydman, Phys. Rev. Lett. 111, 080404 (2013)]. The fully-refocused, constant-time, and constant-number-of-pulses nature of SDR also allows one to filter out “intrinsic” T{sub 1} and T{sub 2} weightings, as well as pulse errors acting as additional sources of decoherence. This article explores such features when the fluctuations are now driven by unrestricted molecular diffusion. In particular, we show that diffusion-driven SDR can be exploited to investigate the decoherence arising from the frequency fluctuations imposed by internal gradients. As a result, SDR presents a unique way of probing and characterizing these internal magnetic fields, given an a priori known free diffusion coefficient. This has important implications in studies of structured systems, including porous media and live tissues, where the internal gradients may serve as fingerprints for the system's composition or structure. The principles of this method, along with full analytical solutions for the unrestricted diffusion-driven modulation of the SDR signal, are presented. The potential of this approach is demonstrated with the generation of a novel source of MRI contrast, based on the background gradients active in an ex vivo mouse brain. Additional features and limitations of this new method are discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

On the Spectral Curvature of VHE Blazar 1ES 1011+496: Effect of Spatial Particle Diffusion

A detailed multi-epoch study of the broadband spectral behavior of the very high energy (VHE) source 1ES 1011+496 provides us with valuable information regarding the underlying particle distribution. Simultaneous observations of the source at optical/UV/X-ray/γ-ray during three different epochs, as obtained from Swift-UVOT/Swift-XRT/Fermi-LAT, are supplemented with the information available from the VHE telescope array, HAGAR. The long-term flux variability at the Fermi-LAT energies is clearly found to be lognormal. It is seen that the broadband spectral energy distribution of 1ES 1011+496 can be successfully reproduced by synchrotron and synchrotron self Compton emission models. Notably, the observed curvature in the photon spectrum at X-ray energies demands a smooth transition of the underlying particle distribution from a simple power law to a power law with an exponential cutoff, or a smooth broken power law distribution, which may possibly arise when the escape of the particles from the main emission region is energy dependent. Specifically, if the particle escape rate is related to its energy as E{sup 0.5}, then the observed photon spectrum is consistent with the ones observed during the various epochs.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

CMB anisotropies from patchy reionisation and diffuse Sunyaev-Zel'dovich effects

Anisotropies in the Cosmic Microwave Background (CMB) can be induced during the later stages of cosmic evolution, and in particular during and after the Epoch of Reionisation. Inhomogeneities in the ionised fraction, but also in the baryon density, in the velocity fields and in the gravitational potentials are expected to generate correlated CMB perturbations. We present a complete relativistic treatment of all these effects, up to second order in perturbation theory, that we solve using the numerical Boltzmann code (\SONG). The physical origin and relevance of all second order terms are carefully discussed. In addition to collisional and gravitational contributions, we identify the diffuse analogue of the blurring and kinetic Sunyaev-Zel'dovich (SZ) effects. Our approach naturally includes the correlations between the imprint from patchy reionisation and the diffuse SZ effects thereby allowing us to derive reliable estimates of the induced temperature and polarisation CMB angular power spectra. In particular, we show that the B -modes generated at intermediate length-scales (ℓ ≅ 100) have the same amplitude as the B -modes coming from primordial gravitational waves with a tensor-to-scalar ratio r =10{sup −4}.

79 ASTRONOMY AND ASTROPHYSICS↗