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At least 361 records · Page 20

Possible identifications of the 3.4 micrometer feature

A feature at 3.4 micrometer was first detected in Comet Halley by the IKS spectrometer on board the Vega 1 probe; and subsequently from the ground. The feature has since been reported in Comet Wilson. The presence of the feature is of considerable interest for a number of reasons. First, it may represent the detection of a new parent molecule, and when combined with data from Giotto and Vega yield new information on cometary chemistry and the early solar system composition. Secondly, it may represent a link to the interstellar medium, the feature corresponds in wavelength and shape with an interstellar feature seen in absorption in a luminous star, towards the Galactic center known as GC-IRS7. The feature in turn is thought to be related with a growing family of unidentified infrared emission features seen in stellar objects, planetary nebulae, reflection nebulae, HII regions and extra galactic sources. These features occur at wavelengths 3.3, 3.4, 3.5, 6.2, 7.7, 8.6, and 11.25 micrometers. Further identification theory is given.

Danks, Anthony C.↗

Experimental constraints on the origin of chondrules

Chrondule formation was an important (perhaps ubiguitous) process in the early solar system, yet their origins remain elusive. Some points, however, are clear. The precursor material of chondules (dust) was rapidly heated at rates of perhaps thousands of degrees per second and was cooled more slowly. It was proposed to investigate chondrule formation in the Space Station environment via a dust-box (a chamber in which dust can be suspended, heated, and cooled. A microgravity environment is conducive to this kind of experiment because of the significant retardation of settling rates compared with a terrestrial laboratory environment. These long-duration experiments might require the development of technologies to counteract even the small, but finite and permanent gravitation field of the Space Station. Simple, but interesting experiments on dust suspensions immediately present themselves.

Boynton, W. V.↗

Thermal metamorphism

Most chondrites have experienced thermal metamorphism, resulting in changes in texture, mineralogy and possibly chemical composition. The physical conditions for metamorphism range from approximately 400 to 1000 C at low lithostatic pressure. Metamorphism may have resulted from decay of short-lived radionuclides, electromagnetic induction or accretion of hot materials. Several thermal models for chondrite parent bodies have been proposed. The least metamorphosed type-3 chondrites probably carry the most information about the early solar system, but even these have been affected to some degree by thermal processing.

Mcsween, Harry Y., Jr.↗

Irradiation records in meteorites

The approximately 4.6 billion-year history of a meteorite will encompass at least one episode of exposure to such energetic particles as cosmic rays; measurements of such exposure allow determination of how long a meteorite existed as a meter-sized body prior to earth impact. Meteorite exposure to energetic particles before their ejection from a parent body entails that the meteorite reside in the upper several m of that parent regolith. At the periods closest to the 4.6 billion year horizon, early solar system conditions may have been characterized by much gas and dust; irradiation records from this period may prove invaluable in reconstructing its characteristics.

Caffee, M. W.↗

Moderately volatile elements

That the fractionation of moderately volatile and highly volatile elements was a major process in the early solar system is reflected in the variable concentrations of Rb and associated variations in initial Sr-isotopic ratios in chondritic meteorites. Greater knowledge of processes leading to volatile depletion would place stronger constraints on the formation conditions of solid material in the solar system. It will especially become possible to ascertain whether evaporation or incomplete condensation was the major process in establishing the elemental abundance patterns observed in primitive meteorites and planets.

Palme, H.↗

Circumstellar material in meteorites - Noble gases, carbon and nitrogen

In addition to preserving a record of isotopically distinct reservoirs in the early solar system, some primitive meteorites contain discrete grains of presolar origin. Such grains are distinguished by the isotopically anomalous noble-gas components they contain. One such component consists of monoisotopic Ne-22, produced by decay of radioactive Na-22 with a 2.6 yr half-life. Two xenon components have also been identified: one synthesized apparently in a supernova, the other probably in a red giant star. Most of the grains that carry these noble-gas components are carbonaceous and contain isotopically anomalous C, N, or both. They include diamond and silicon carbide. Two unidentified carriers of isotopically anomalous nitrogen, unaccompanied by noble gases, occur in the brecciated stony iron meteorite, Bencubbin.

Anders, Edward↗

The relationship between interstellar dust and the isotopic anomalies in meteorites

Work on the ways in which the isotopic anomalies found in meteorites can be regarded as the chemical memory of even larger anomalies found in interstellar dust is outlined. This approach constitutes one theory of the isotopic anomalies, standing in contrast to the idea of a spatial inhomogeneity in the early solar system owing to inhomogeneous admixture from a neighboring supernova. The four mechanisms of isotopic chemical memory in interstellar dust are: (1) thermal condensation within expanding events of nucleosynthesis; (2) different isotopic mappings onto the grain size spectrum; (3) dust components of differing age; and (4) isotope-dependent interstellar chemistry. Specific examples of each mechanism are given to illustrate how each may have contributed to known isotopic anomalies.

Clayton, D. D.↗

Ion bombardment experiments suggesting an origin for organic particles in pre-cometary and cometary ices

During the Giotto and Vega encounters with Comet Halley both organic particles called CHON and energetic ions were detected. The acceleration of ions to hundreds of keV in the vicinity of the bow shock and near the nucleus may be a demonstration of a situation occurring in the early solar system (perhaps during the T Tauri stage) that led to the formation of organic particles only now released. Utilizing a Van de Graaff accelerator and a target chamber having cryogenic and mass spectrometer capabilities, frozen gases were bombarded at 10 K with 175 keV protons with the result that fluffy solid material remains after sublimation of the ice. Initial experiments were carried out with a gas mixture in parts of 170 carbon monoxide, 170 argon, 25 water, 20 nitrogen, and 15 methane formulated to reflect an interstellar composition in experiments involving the freezing out of the products of a plasma. The plasma experiments resulted in a varnish-like film residue that exhibited luminescence when excited with ultraviolet radiation, while the ion bombardment created particulate material that was not luminescent.

Wdowiak, Thomas J.↗

Cosmic Dust Collection Facility: Scientific objectives and programmatic relations

The science objectives are summarized for the Cosmic Dust Collection Facility (CDCF) on Space Station Freedom and these objectives are related to ongoing science programs and mission planning within NASA. The purpose is to illustrate the potential of the CDCF project within the broad context of early solar system sciences that emphasize the study of primitive objects in state-of-the-art analytical and experimental laboratories on Earth. Current knowledge about the sources of cosmic dust and their associated orbital dynamics is examined, and the results are reviewed of modern microanalytical investigations of extraterrestrial dust particles collected on Earth. Major areas of scientific inquiry and uncertainty are identified and it is shown how CDCF will contribute to their solution. General facility and instrument concepts that need to be pursued are introduced, and the major development tasks that are needed to attain the scientific objectives of the CDCF project are identified.

Hoerz, Fred↗

The possible presence of interstellar PAHs in meteorites and interplanetary dust particles

The Raman spectra of interplanetary dust particles (IDPs) collected in the stratosphere show two bands at about 1350 and 1600 delta cm(-1) and a broader feature between 2200 and 3300 delta cm(-1) that are characteristic of aromatic molecular units with ordered domains smaller than 25A in diameter. This suggests that the carbonaceous material in IDPs may be similar to the polymeric component seen in meteorites, where this material is thought to consist of aromatic molecular units that are randomly inter-linked by short aliphatic bridges. The features in the Raman spectra of IDPs are similar in position and relative strength to interstellar infrared emission features that have been attributed to vibrational transitions in free molecular polycyclic aromatic hydrocarbons (PAHs). The Raman spectra of some IDPs also showed photoluminescence that is similar to the excess red emission from some astronomical objects and that has also been attributed to PAHs and PAH-related materials. Moreover, a part of the carbonaceous phase in IDPs contains deuterium to hydrogen ratios that are far greater than those found in terrestrial samples. Deuterium enrichment is expected in small free PAHs that are exposed to ultraviolet radiation in the interstellar medium. Taken together, these observations suggest that some fraction of the carbonaceous material in IDPs may have been produced in circumstellar dust shells and only slightly modified in interstellar space. Since many, if not most, IDPs come from comets, this supports the view that cometary material contains primitive components which can provide clues about early solar system (and perhaps even interstellar and circumstellar) processes.

Allamandola, L. J.↗

Enstatite meteorites and their parent bodies

The properties of enstatite meteorites (which are known to be comprised of the EH and EL chondrites and the aubrites) are discussed together with the nature and number of their parent bodies. It is pointed out that the bulk compositional differences in nonvolatile major elements exhibited by EH and EL chondrites in nonvolatile major elements were established by nebular rather than planetary processes. The occurrence of abundant breccias among these chondirites and a lack of clasts suggest that EH and EL chondrites represent two separate parent bodies. Aubrites are considered to represent samples from a third enstatite meteorite parent body, which may have experienced collisional break-up and gravitational reassembly of the debris. Shallowater may be a sample from yet a fourth enstatite meteorite parent body. It is suggested that, if unipolar dynamo induction by a primordial T Tauri sun was the dominant heat source that heated asteroidal-sized bodies in the early solar system, then the aubrite and Shallowater parent bodies may have melted because they were of intermediate sizes, whereas the EH and EL bodies did not melt.

Keil, Klaus↗

Nd-142/Nd-144 in SNCs and early differentiation of a heterogeneous Martian mantle

Sm/Nd correlated variations in Nd-142/Nd-144 have been observed for mineral phases of achondrites from decay of live Sm-146 in the early solar system. Crystallization ages of shergottites-nakhlites-Chassigny (SNC) meteorites are less than or = 1.3 Ga, so variations of Nd-142/Nd-144 among mineral phases of the SNC's are not expected. However, if SNC's were derived from source reservoirs of differing Sm/Nd ratios, established while Sm-146 was still alive, and which remained isolated except for magma extraction, then variations in Nd-142/Nd-144 would exist among individual SNC meteorites. Rb-Sr and U-Pb isotopic data for the shergottites imply differentiation of their parent planet approximately 4.6 Ga ago. The confirmation of the conclusion that the nakhlites and shergottites were derived from different source regions, and that, consequently, the shergottite parent body (SPB) mantle was heterogeneous is presented.

Nyquist, L. E.↗

Identification and characterization of extraterrestrial non-chondritic interplanetary dust

Interplanetary dust particles (IDPs) are among the most pristine and primitive extraterrestrial materials available for direct study. Most of the stratospheric particles selected for study from the JSC Curatorial Collection were chondritic in composition (major element abundances within a factor of two of chondritic meteorites) because this composition virtually ensures that the particle is from an extraterrestrial source. It is likely that some of the most interesting classes of IDP's have not been recognized simply because they are not chondritic or do not fit established criteria for extraterrestrial origin. Indeed, mass spectroscopy data from the Giotto Flyby of comet Halley indicate that a substantial fraction of the dust is in the submicron size range and that a majority of these particles contain C, H, O, and/or N as major elements. The preponderance of CHON particles in the coma of Halley implies that similar particles may exist in the JSC stratospheric dust collection. However, the JSC collection also contains a variety of stratospheric contaminants from terrestrial sources which have these same characteristics. Because established criteria for extraterrestrial origin may not apply to such particles in individual cases, and integrated approach is required in which a variety of analysis techniques are applied to the same particle. Non-chondritic IDP's, like their chondritic counterparts, can be used to elucidate pre- and early solar system processes and conditions. The study of non-chondritic IDP's may additionally yield unique information which bears on the nature of cometary bodies and the processing of carbonaceous and other low atomic number materials. A suite of complementary techniques, including Low Voltage Scanning Electron Microscopy (LVSEM), Energy-Dispersive X-ray Microanalysis (EDX), Secondary Ion Mass Spectrometry (SIMS) isotope-ratio imaging and Analytical Electron Microscopy (AEM), were utilized to accomplish the following two objectives: (1) to develop criteria for the unequivocal identification of extraterrestrial non-chondritic IDP's; and (2) to infer IDP parent body, solar nebula, and pre-solar conditions through the study of phases, textures, and components contained within non-chondritic IDP's. The general approach taken is designed to maximize the total information obtained from each particle. Techniques will be applied in order from least destructive to most destructive.

Blake, D. F.↗

Origin of the Uranian satellites

The current understanding of the origin of the Uranian satellites is assessed by reviewing relevant data on the Uranian satellites, including those obtained by Voyager, and comparing these properties with those of the satellites of the other outer planets. The nature of the early solar system, including the origin of the giant planets, is discussed as a preface to alternative hypotheses for the origin of the nebular disk within which the Uranian satellites formed. The chemical and physical properties of this disk are discussed, as well as the accretion of the satellites from disk solid matter. Predictions of alternative scenarios for the satellites' origin with the relevant observational constraint are compared. The orbital evolution of the larger satellites of Uranus is discussed to gain an understanding of their present orbital properties and possibly important past tidal heating episodes.

Pollack, James B.↗

What heated the parent meteorite planets?

The plausibility of the two most wide discussed mechanisms, decay of short-lived Al-26 and solar wind induction heating, for heating the small planetesimals in which the meteorites formed are examined and shown to have significant problems. The main problem for the Al-26 decay mechanism is the fact that eucritic lavas, melted by the mysterious heating mechanism in some early planetesimal, did not contain enough Al-26 to decay to radiogenic Mg-26 when they erupted to their planetesimal surface and cooled. It is necessary to postulate that the lavas lingered underground while their Al-26 decayed away. The solar wind induction heat concept has the problem that astrophysical evidence has made is seem increasingly unlikely that an intense solar wind flux blew past planetesimals in the early solar system. Instead, it was probably collimated in the direction of the sun's poles by the persistence of the solar nebula during the T Tauri epoch.

Wood, John A.↗

Thin-sectioning and analysis of fine-grained meteoritic materials

The overall theme of the work was the identification of the sources and formation/aggregation mechanisms of the various classes of interplanetary dust particles (IDP's) and to clarify the relationship between IDP's and conventional meteorites. IDP's are believed to be derived from a much broader range of parent bodies than conventional meteorites. Some of these parent bodies (e.g., comets) have escaped that post accretional processing that has affected the parent bodies of meteorites. Therefore, IDP's are likely to preserve a record of early solar system and possibly presolar grain forming reactions. Using analytical electron microscopy (AEM) and more recently micro-infrared (IR) microspectroscopy to examine ultramicrotomed thin sections, we have addressed the questions of IDP formation mechanisms, sources, and their relationship to conventional meteorites. The following sections describe specific findings resulting from these studies.

Brooks, Donald A.↗

Geochemistry and petrology of primitive achondrite meteorites LEW 88280, MAC 88177, ALHA 81187, EET 84302, and LEW 88663

Primitive achondrites are meteorites that have mineral and bulk chemical compositions similar to the most primitive meteorites (chondrites) but have textures similar to more evolved meteorites (achondrites). The unique geochemistry and texture of the primitive achondrites suggest these meteorites may be genetic intermediates between chondrites and achondrites and may preserve evidence of processes occurring in the early solar system. Five primitive achondrites LEW 88280, MAC 88177, ALHA 81187, EET 84302, and LEW 88663 were examined in this study in order to classify the meteorites and to determine processes that have affected them. Bulk chemical analyses of Nap, K2O, CaO, FeO, Cr, Co, Ni, Sc, Ir, Au, As, Sb, Se, Br, Cs, Ba, La, Ce, Nd, Sm, Eu, Tb, Yb, and Lu were determined for each meteorite by Instrumental Neutron Activation Analysis (INAA). Concentrations of Hf, U, and Th were determined for some meteorites. Polished thin sections of the five meteorites were examined in transmitted and reflected light microscopy to identify minerals and examine petrographic relationships. Minerals found in the meteorites include olivine, orthopyroxene, clinopyroxene, plagioclase, Cr-spinel, phosphates, troilite, kamecite, and taenite along with other minor phases. Mineral compositions were determined with an electron microprobe. The initial study suggests that the meteorites have been altered by metamorphic processes although igneous processes may also have played a role in the evolution of these rocks. Further studies of isotope and bulk chemistry are planned for these meteorites.

Field, Stephen W.↗