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Laboratory Demonstration of High Contrast with the PIAACMC Coronagraph on an Obstructed and Segmented Aperture

Coronagraphs (together with starshades) are an important tool to directly image and characterize exoplanets, and enable the search for biomarkers in reflected light on potentially habitable worlds. Their performance and efficiency has steadily been improving over the past several decades, but has not yet reached performance limits. In particular, the expected exoplanet yield for missions such as the Astro2020-recommended “IR/O/UV Flagship” can still be improved by factors of at least 2-3, simply by continued improvements in coronagraph performance, before they plateau due to physics limits. One possible architecture that can enable at least a part of this improvement is the Phase-Induced Amplitude Apodization Complex Mask Coronagraph (PIAACMC). Itoffersthe advantages of high throughput, small inner working angle (IWA),and almost noloss inPSF sharpness, and natively supports obstructed and segmented apertures, which is essential to the Astro2020 “IR/O/UV Flagship”mission. Historically, key disadvantages of PIAA have been poor tolerance to stellar angular sizes and maturity, but latest designs and demonstrations have made significant strides in this respect.In this paper, we present the current status and overview of our program to mature the PIAACMC technology. We first review PIAACMC designs for LUVOIR-A and B, which resultedin improved expected yield of Exo-Earths relative tothe baselines for both mission concepts. In particular, for LUVOIR-B, the yield improves from 28 to 42due to improvedtolerance to stellar angular size in our design. The improvement in yield is marginal for LUVOIR-A, but our design enables detecting planets around smaller diameter stars (nearby K-dwarfs and/or farther FG stars). We also describe our modeling and vacuum demonstrationsfor the LUVOIR-A aperture(which is more challengingthan LUVOIR-B due to the central obstruction).The demonstration included a LUVOUR-A pupil mask, an on-axis PIAA set of 2 mirrors with central holes, a Boston Micromachines DM, a patterned CMC mask, Lyot stop, and supporting masks and optics. Demonstrations were conducted at JPL’s High Contrast Imaging Testbed (HCIT) using several characterization andwavefront control techniques (primarily standard EFC, several experimental techniques were attempted, as well as speckle nulling). So far, our results include 1.9e-8 raw contrast in 10% broadband light between 3.5 and 8 l/D; 4.1e-8 and 1.6e-9 coherent contrasts in monochromatic light between 2-4 and 4-8 l/D, respectively. We also present measurements and analysis of sensitivity to tip/tilt jitter and stellar angular size. Finally, we compare our test results to models, present an analysis of our limiting factors, and explorefuture prospectsfor improvement based on validated models.

Coronagraph↗

The Habitability of Proxima Centauri b II. Possible Climates and Observability

Radial velocity monitoring has found the signature of a M sin i = 1.3 M(sub ⨁) planet located within the habitable zone (HZ) of Proxima Centauri. Despite a hotter past and an active host star, the planet Proxima b could have retained enough volatiles to sustain surface habitability. Here we use a 3D Global Climate Model (GCM) to simulate the atmosphere and water cycle of Proxima b for its two likely rotation modes (1:1 and 3:2 spin-orbit resonances), while varying the unconstrained surface water inventory and atmospheric greenhouse effect. Any low-obliquity, low-eccentricity planet within the HZ of its star should be in one of the climate regimes discussed here. We find that a broad range of atmospheric compositions allow surface liquid water. On a tidally locked planet with sufficient surface water inventory, liquid water is always present, at least in the substellar region. With a non-synchronous rotation, this requires a minimum greenhouse warming (~10 mbar of CO2 and 1 bar of N2). If the planet is dryer, ~0.5 bar or 1.5 bars of CO2 (for asynchronous or synchronous rotation, respectively) suffice to prevent the trapping of any arbitrary, small water inventory into polar or nightside ice caps. We produce reflection and emission spectra and phase curves for the simulated climates. We find that atmospheric characterization will be possible via direct imaging with forthcoming large telescopes. The angular separation of 7 λ/D at 1 μm (with the E-ELT) and a contrast of ~10(exp -7) will enable high-resolution spectroscopy and the search for molecular signatures, including H2O, O2, and CO2. The observation of thermal phase curves can be attempted with the James Webb Space Telescope, thanks to a contrast of 2 × 10(exp -5) at 10 μm. Proxima b will also be an exceptional target for future IR interferometers. Within a decade it will be possible to image Proxima b and possibly determine whether the surface of this exoplanet is habitable.

Proxima Cen↗

Development and implementation of an in situ high-resolution isotopic microscope for measuring metabolic interactions in soil mesocosms (Final Report)

Many of our planet’s ecosystems rely on the activities of soil microbial communities. These microbes have significant and wide-ranging effects: they metabolize carbon and other nutrients, interact with plants and fungi, and perform other processes important to soil health. However, our ability to directly observe the enzymatic and metabolic activities of microbes within soil is currently limited, not only by the complexity of soil microbial communities themselves, but also by the lack of experimental tools to study them and their molecular interactions in situ. These challenges hinder our understanding of the life-sustaining processes of biomass decomposition and the manner in which it contributes to the movement of freed carbon within soil ecosystems. Here we aimed to develop a novel ultrahigh-resolution isotopic microscope that combines complementary imaging modalities to gain insights into metabolic cycling in soil. This final report covers both the portion of this work that was initially completed at the University of North Carolina at Chapel Hill from 2018 to 2019 (as award DE-SC0019012) and then from 2020 to 2022 (2023 in NCE) at the University of Massachusetts Chan Medical School. This goal was to build an integrated platform consisting of fluorescence microscopy, Raman microspectroscopy, and nanospray desorption electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (nanoDESI-FTICR-MS) to directly investigate microbial activities and molecular transformations occurring in soil by exploiting the use of both fluorescent labels and stable isotope probing. Specifically, our instrument was conceived as integrating: (A) fluorescence detection to localize soil microbes, identify bacteria taking up polysaccharides, and monitor gene expression of enzymes involved in decomposition; (B) Raman microspectroscopy to determine which microbes incorporate decomposition products into their biomass, as well as which decomposers are metabolically active; and (C) nanoDESI-FTICR-MS imaging to spatially probe, in real-time, the metabolites in the surrounding area, which we expect will reveal the distributions of the products of the enzymatic breakdown of polysaccharides, as well as specialized metabolites acting as cell-cell signals between decomposers. To enable these measurements, we exploited fluorescence-based probes to map the microbes that are enzymatically active (per A) and utilized stable isotope-labeled substrates to visualize both the microbial and molecular fate of decomposed biomass (B and C, respectively). To accomplish our goal, we combined the expertise of a multidisciplinary group of scientists to pursue the construction of this microscope and to investigate scientific questions that would be facilitated by such a capability. We aimed to employ this spatially informative, high-resolution isotopic microscope to visualize the critical steps of biomass degradation and the molecular fate of other environmentally relevant substrates within soil mesocosms. Accordingly, this technology will enhance our understanding of the microbial and metabolic interactions occurring within soil communities that are relevant to carbon degradation and other soil processes. The instrument has been developed and housed at EMSL, where it will be available to the entire EMSL User Base, enabling a variety of related DOE-relevant systems to be interrogated in the future by diverse scientific research groups.

59 BASIC BIOLOGICAL SCIENCES↗

Towards Simulating a Realistic Planetary Seismic Wavefield: The Contribution of the Megaregolith and Low-Velocity Waveguides

Lunar seismograms are distinctly different from their terrestrial counterparts. The Apollo lunar seismometers recorded moonquakes without distinct P- or S-wave arrivals; instead waves arrive as a diffuse coda that decays over several hours making the identification of body waves difficult. The unusual character of the lunar seismic wavefield is generally tied to properties of the megaregolith: it consists of highly fractured and broken crustal rock, the result of extensive bombardment of the Moon. The megaregolith extends several kilometers into the lunar crust, possibly into the mantle in some regions, and is covered by a thin coating of fine-scale dust. These materials possess very low seismic velocities that strongly scatter the seismic wavefield at high frequencies. Directly modeling the effects of the megaregolith to simulate an accurate lunar seismic wavefield is a challenging computational problem, owing to the inherent 3-D nature of the problem and the high frequencies (greater than 1 Hz) required. Here we focus on modeling the long duration code, studying the effects of the low velocities found in the megaregolith. We produce synthetic seismograms using 1-D slowness integration methodologies, GEMINI and reflectivity, and a 3-D Cartesian finite difference code, Wave Propagation Program, to study the effect of thin layers of low velocity on the surface of a planet. These codes allow us generate seismograms with dominant frequencies of approximately 1 Hz. For background lunar seismic structure we explore several models, including the recent model of Weber et al., Science, 2011. We also investigate variations in megaregolithic thickness, velocity, attenuation, and seismogram frequency content. Our results are compared to the Apollo seismic dataset, using both a cross correlation technique and integrated envelope approach to investigate coda decay. We find our new high frequency results strongly support the hypothesis that the long duration of the lunar seismic codes is generated by the presence of the low velocity megaregolith, and that the diffuse arrivals are a combination of scattered energy and multiple reverberations within this layer. The 3-D modeling indicates the extreme surface topography of the Moon adds only a small contribution to scattering effects, though local geology may play a larger role. We also study the effects of the megaregolith on core reflected and converted phases and other body waves. Our analysis indicates detection of core interacting arrivals with a polarization filter technique is robust and lends the possibility of detecting other body waves from the Moon.

Schmerr, Nicholas C.↗

Ultraviolet Photooxidation of Smectite-Bound Fe(II) and Implications for the Origin of Martian Nontronites

Clay minerals detected with orbital and in situ instruments in ancient Martian terrains constrain Mars' climate and aqueous alteration history. Early in its history, Mars experienced an atmospheric redox change and iron-bearing clay minerals may preserve the effects of that transition. Ferrous smectites, the thermodynamically predicted product of chemical weathering of basalts under anoxic conditions, may have undergone oxidation by exposure to chemical oxidants in the atmosphere or regolith, or by direct photooxidation at the surface. To assess these potential oxidation pathways, ferrous trioctahedral smectites of varying initial iron content were synthesized and subjected to oxidation by ultraviolet (UV) irradiation. Experimental UV irradiation under an anoxic atmosphere equivalent to approximately 7 years of flux on the Martian surface caused partial oxidation of smectite-bound Fe (Fe3+/ΣFe = 16–18%) and octahedral sheet contraction. Metal-OH vibrational bands in visible/near infrared (VNIR) reflectance spectra of oxidized smectites changed in band depth and asymmetry with higher iron content. X-ray diffraction patterns of UV irradiated samples indicate the formation of a mixed di- and trioctahedral smectite or a secondary nontronite phase, possibly on the surfaces of higher iron content smectites. These experiments suggest that UV irradiation is able to oxidize structurally bound iron in smectites without the presence of other chemical oxidants. Photooxidation may have influenced the mineralogy, both syndepositionally and postdepositionally, of Martian alteration assemblages formed near the surface and this process needs not be limited to one part of their formation history. Plain Language Summary: Martian mineral assemblages observed with orbiters and rover instruments allow us to understand the planet's past climate and aqueous activity. Hydrated minerals that contain Fe(II) are of particular interest as they would have been affected by the early atmosphere becoming more oxidizing overtime, changing the structural iron into Fe(III). In this study, we synthesized Fe(II) smectites with varying iron content and irradiated them with an ultraviolet (UV) light source to test whether they could be photooxidized. Iron in the smectite minerals was incompletely oxidized by UV radiation after being exposed for the equivalent of approximately 7 years of exposure on the early Mars surface. The smectites with higher iron content showed more changes with photooxidation in their visible/near infrared spectra as well as in their X-ray diffraction patterns, two datasets collected by instruments on currently active Martian missions. These results suggest that UV photooxidation is a plausible contributor to the mineralogy and redox state of clay mineral assemblages observed at the Martian surface.

V. B. Rivera Banuchi↗

NASA's Earth Science Enterprise: Future Science Missions, Objectives and Challenges

NASA has been actively involved in studying the planet Earth and its changing environment for well over thirty years. Within the last decade, NASA's Earth Science Enterprise has become a major observational and scientific element of the U.S. Global Change Research Program. NASA's Earth Science Enterprise management has developed a comprehensive observation-based research program addressing all the critical science questions that will take us into the next century. Furthermore, the entire program is being mapped to answer five Science Themes (1) land-cover and land-use change research (2) seasonal-to-interannual climate variability and prediction (3) natural hazards research and applications (4) long-term climate-natural variability and change research and (5) atmospheric ozone research. Now the emergence of newer technologies on the horizon and at the same time continuously declining budget environment has lead to an effort to refocus the Earth Science Enterprise activities. The intent is not to compromise the overall scientific goals, but rather strengthen them by enabling challenging detection, computational and space flight technologies those have not been practically feasible to date. NASA is planning faster, cost effective and relatively smaller missions to continue the science observations from space for the next decade. At the same time, there is a growing interest in the world in the remote sensing area which will allow NASA to take advantage of this by building strong coalitions with a number of international partners. The focus of this presentation is to provide a comprehensive look at the NASA's Earth Science Enterprise in terms of its brief history, scientific objectives, organization, activities and future direction.

Habib, Shahid↗

Our Sun V: A Bright Young Sun Consistent with Helioseismology and Warm Temperatures on Ancient Earth and Mars

The relatively warm temperatures required on early Earth and Mars have been difficult to account for with warming from greenhouse gases. A slightly more massive young Sun would be brighter than predicted by the standard solar model, simultaneously resolving this problem for both Earth and Mars. We computed high-precision solar models with seven initial masses, from Mi = 1.01 to 1.07 solar mass - the latter being the maximum permitted if the early Earth is not to lose its water via a moist greenhouse effect. The relatively modest early mass loss that is required remains consistent with observational limits on mass loss from young stars and with estimates of the past solar wind obtained from lunar rocks. We considered three types of mass loss rates: (1) a reasonable choice of a simple exponential decline, (2) an extreme step-function case that gives the maximum effect consistent with observations, and (3) the radical case of a linear decline which is inconsistent with the solar wind mass loss estimates from lunar rocks. Our computations demonstrated that mass loss leaves a fingerprint oil the Sun's internal structure large enough to be detectable with helioseismic observations. All of our mass-losing solar models were consistent with the helioseismic observations; in fact, our preferred mass-losing cases were in marginally better agreement with the helioseismology than the standard solar model was, although this difference was smaller than the effects of other uncertainties in the input physics and in the solar composition. Mass loss has only a relatively minor effect on the predicted lithium depletion; the major portion of the solar lithium depletion must still be due to rotational mixing. Thus the modest mass loss cases considered here cannot be ruled out by observed lithium depletions. For the three mass loss types considered, the preferred initial masses were 1.07 solar mass for the exponential case and 1.04 solar mass for the step-function and linear cases; all of these provided high enough solar fluxes at Mars 3.8 Gyr ago to be consistent with the existence of liquid water. For a more massive early Sun, the planets would have had to be closer to the young Sun in order to end up in their present orbits; the orbital radii of the planets would vary inversely with the solar mass. Both of these effects contribute to the fact that the early solar flux at the planets would have been considerably higher than that of the standard solar model at that time. In fact, the 1.07 solar mass exponential case has a flux at birth 5% higher than the present solar flux, while the radical 1.04 solar mass linear case has a nearly constant flux over the first 3 Gyr only about 10% lower than at present. The early solar evolution would be in the opposite direction in the H-R diagram to that of the standard Sun.

Sackmann, I.-Juliana↗

Stereoscopic Machine-Vision System Using Projected Circles

A machine-vision system capable of detecting obstacles large enough to damage or trap a robotic vehicle is undergoing development. The system includes (1) a pattern generator that projects concentric circles of laser light forward onto the terrain, (2) a stereoscopic pair of cameras that are aimed forward to acquire images of the circles, (3) a frame grabber and digitizer for acquiring image data from the cameras, and (4) a single-board computer that processes the data. The system is being developed as a prototype of machine- vision systems to enable robotic vehicles ( rovers ) on remote planets to avoid craters, large rocks, and other terrain features that could capture or damage the vehicles. Potential terrestrial applications of systems like this one could include terrain mapping, collision avoidance, navigation of robotic vehicles, mining, and robotic rescue. This system is based partly on the same principles as those of a prior stereoscopic machine-vision system in which the cameras acquire images of a single stripe of laser light that is swept forward across the terrain. However, this system is designed to afford improvements over some of the undesirable features of the prior system, including the need for a pan-and-tilt mechanism to aim the laser to generate the swept stripe, ambiguities in interpretation of the single-stripe image, the time needed to sweep the stripe across the terrain and process the data from many images acquired during that time, and difficulty of calibration because of the narrowness of the stripe. In this system, the pattern generator does not contain any moving parts and need not be mounted on a pan-and-tilt mechanism: the pattern of concentric circles is projected steadily in the forward direction. The system calibrates itself by use of data acquired during projection of the concentric-circle pattern onto a known target representing flat ground. The calibration- target image data are stored in the computer memory for use as a template in processing terrain images. During operation on terrain, the images acquired by the left and right cameras are analyzed. The analysis includes (1) computation of the horizontal and vertical dimensions and the aspect ratios of rectangles that bound the circle images and (2) comparison of these aspect ratios with those of the template. Coordinates of distortions of the circles are used to identify and locate objects. If the analysis leads to identification of an object of significant size, then stereoscopicvision algorithms are used to estimate the distance to the object. The time taken in performing this analysis on a single pair of images acquired by the left and right cameras in this system is a fraction of the time taken in processing the many pairs of images acquired in a sweep of the laser stripe across the field of view in the prior system. The results of the analysis include data on sizes and shapes of, and distances and directions to, objects. Coordinates of objects are updated as the vehicle moves so that intelligent decisions regarding speed and direction can be made. The results of the analysis are utilized in a computational decision-making process that generates obstacle-avoidance data and feeds those data to the control system of the robotic vehicle.

Mackey, Jeffrey R.↗

Detection of Aerosols at Microbar Pressures in an Exoplanet Atmosphere

The formation of hazes at microbar pressures has been explored by theoretical models of exoplanet atmospheres to explain Rayleigh scattering and/or featureless transmission spectra; however observational evidence of aerosols in the low-pressure formation environments has proved elusive. Here, we show direct evidence of aerosols existing at ~1 microbar pressures in the atmosphere of the warm sub-Saturn WASP-69b using observations taken with the Space Telescope Imaging Spectrograph and Wide Field Camera 3 instruments on the Hubble Space Telescope. The transmission spectrum shows a wavelength-dependent slope induced by aerosol scattering that covers 11 scale heights of spectral modulation. Drawing on the extensive studies of haze in our solar system, we model the transmission spectrum based on a scaled version of Jupiter’s haze-density profile to show that the WASP-69b transmission spectrum can be produced by scattering from an approximately constant density of particles extending throughout the atmospheric column from 40 millibar to microbar pressures. These results are consistent with theoretical expectations based on microphysics of the aerosol particles that have suggested haze can exist at microbar pressures in exoplanet atmospheres.

47 OTHER INSTRUMENTATION↗

The Origin and Evolution of Saturn's 2011-2012 Stratospheric Vortex

The planet-encircling springtime storm in Saturn's troposphere (December 2010-July 2011, Fletcher, L.N. et al. [2011]. Science 332, 1413-1414; Sánchez-Lavega, A. et al. [2011]. Nature 475, 71-74; Fischer, G. et al. [2011]. Nature 475, 75-77) produced dramatic perturbations to stratospheric temperatures, winds and composition at mbar pressures that persisted long after the tropospheric disturbance had abated. Thermal infrared (IR) spectroscopy from the Cassini Composite Infrared Spectrometer (CIRS), supported by ground-based IR imaging from the VISIR instrument on the Very Large Telescope and the MIRSI instrument on NASA's IRTF, is used to track the evolution of a large, hot stratospheric anticyclone between January 2011 and March 2012. The evolutionary sequence can be divided into three phases: (I) the formation and intensification of two distinct warm airmasses near 0.5 mbar between 25 and 35degN (B1 and B2) between January-April 2011, moving westward with different zonal velocities, B1 residing directly above the convective tropospheric storm head; (II) the merging of the warm airmasses to form the large single 'stratospheric beacon' near 40degN (B0) between April and June 2011, disassociated from the storm head and at a higher pressure (2 mbar) than the original beacons, a downward shift of 1.4 scale heights (approximately 85 km) post-merger; and (III) the mature phase characterised by slow cooling (0.11 +/- 0.01 K/day) and longitudinal shrinkage of the anticyclone since July 2011. Peak temperatures of 221.6 +/- 1.4 K at 2 mbar were measured on May 5th 2011 immediately after the merger, some 80 K warmer than the quiescent surroundings. From July 2011 to the time of writing, B0 remained as a long-lived stable stratospheric phenomenon at 2 mbar, moving west with a near-constant velocity of 2.70 +/- 0.04 deg/day (24.5 +/- 0.4 m/s at 40degN relative to System III longitudes). No perturbations to visible clouds and hazes were detected during this period. With no direct tracers of motion in the stratosphere, we use thermal windshear calculations to estimate clockwise peripheral velocities of 200-400 m/s at 2 mbar around B0. The peripheral velocities of the two original airmasses were smaller (70-140 m/s). In August 2011, the size of the vortex as defined by the peripheral collar was 65deg longitude (50,000 km in diameter) and 25deg latitude. Stratospheric acetylene (C2H2) was uniformly enhanced by a factor of three within the vortex, whereas ethane (C2H6) remained unaffected. The passage of B0 generated a new band of warm stratospheric emission at 0.5 mbar at its northern edge, and there are hints of warm stratospheric structures associated with the beacons at higher altitudes (p < 0.1 mbar) than can be reliably observed by CIRS nadir spectroscopy. Analysis of the zonal windshear suggests that Rossby wave perturbations from the convective storm could have propagated vertically into the stratosphere at this point in Saturn's seasonal cycle, one possible source of energy for the formation of these stratospheric anticyclones.

evolution↗

Large Interferometer For Exoplanets (LIFE) XIII. The value of Combining Thermal Emission and Reflected Light for the Characterization of Earth Twins

Context. Following the recommendations to NASA (in the Astro2020 Decadal survey) and ESA (through the Voyage2050 process), the search for life on exoplanets will be a priority in the next decades. Two concepts for direct imaging space missions are being developed for this purpose: the Habitable Worlds Observatory (HWO) and the Large Interferometer for Exoplanets (LIFE). These two concepts operate in different spectral regimes: HWO is focused on reflected light spectra in the ultraviolet, visible, and near-infrared (UV/VIS/NIR), while LIFE will operate in the mid-infrared (MIR) to capture the thermal emission of temperate exoplanets. Aims. In this study, we aim to assess the potential of HWO and LIFE to characterize a cloud-free Earth twin orbiting a Sun-like star at a distance of 10 pc, both as separate missions and in synergy with each other. We aim to quantify the increase in information that can be gathered by joint atmospheric retrievals on a habitable planet. Methods. We performed Bayesian retrievals on simulated data obtained by an HWO-like mission and a LIFE-like one separately, then jointly. We considered the baseline spectral resolutions currently assumed for these concepts and used two increasingly complex noise simulations, obtained using state-of-the-art noise simulators. Results. An HWO-like concept would allow one to strongly constrain H 2 O, O 2 , and O 3 in the atmosphere of a cloud-free Earth twin, while the atmospheric temperature profile is not well constrained (with an average uncertainty ≈100 K). LIFE-like observations would strongly constrain CO 2 , H 2 O, and O 3 and provide stronger constraints on the thermal atmospheric structure and surface temperature (down to ≈10 K uncertainty). For all the investigated scenarios, both missions would provide an upper limit on CH 4 . A joint retrieval on HWO and LIFE data would accurately define the atmospheric thermal profile and planetary parameters. It would decisively constrain CO 2 , H 2 O, O 2 , and O 3 and find weak constraints on CO and CH 4 . The significance of the detection is in all cases greater than or equal to the single-instrument retrievals. Conclusions. Both missions provide specific information that is relevant for the characterization of a terrestrial habitable exoplanet, but the scientific yield can be maximized by considering synergistic studies of UV/VIS/NIR+MIR observations. The use of HWO and LIFE together will provide stronger constraints on biosignatures and life indicators, with the potential to be transformative for the search for life in the Universe.

E Alei↗

The HOSTS Survey for Exozodiacal Dust: Observational Results from the Complete Survey

The Large Binocular Telescope Interferometer (LBTI) enables nulling interferometric observations across the N band (8 to 13 μm) to suppress a star's bright light and probe for faint circumstellar emission. We present and statistically analyze the results from the LBTI/Hunt for Observable Signatures of Terrestrial Systems survey for exozodiacal dust. By comparing our measurements to model predictions based on the solar zodiacal dust in the N band, we estimate a 1σ median sensitivity of 23 zodis times the solar system dust surface density in its habitable zone (HZ; 23 zodis) for early-type stars and 48 zodis for Sun-like stars, where 1 zodi is the surface density of HZ dust in the solar system. Of the 38 stars observed, 10 show significant excess. A clear correlation of our detections with the presence of cold dust in the systems was found, but none with the stellar spectral type or age. The majority of Sun-like stars have relatively low HZ dust levels (best-fit median: 3 zodis, 1σ upper limit: 9 zodis, 95% confidence: 27 zodis based on our N band measurements), while ~20% are significantly more dusty. The solar system's HZ dust content is consistent with being typical. Our median HZ dust level would not be a major limitation to the direct imaging search for Earth-like exoplanets, but more precise constraints are still required, in particular to evaluate the impact of exozodiacal dust for the spectroscopic characterization of imaged exo-Earth candidates.

Exozodiacal dust↗

Pluto's Ultraviolet Spectrum, Surface Reflectance, and Airglow Emissions

During the New Horizons spacecraft’s encounter with Pluto, the Alice ultraviolet spectrograph conducted a series of observations that detected emissions from both the interplanetary medium (IPM) and Pluto. In the direction of Pluto, the IPM was found to be 133.4 ± 0.6 R at Lyα, 0.24 ± 0.02 R at Lyβ, and <0.10 R at He i 584 Å. We analyzed 3900 s of data obtained shortly before closest approach to Pluto and detect airglow emissions from H i, N i, N ii, N{sub 2}, and CO above the disk of Pluto. We find Pluto’s brightness at Lyα to be 29.3 ± 1.9 R, in good agreement with preencounter estimates. The detection of the N ii multiplet at 1085 Å marks the first direct detection of ions in Pluto’s atmosphere. We do not detect any emissions from noble gases and place a 3σ upper limit of 0.14 R on the brightness of the Ar i 1048 Å line. We compare preencounter model predictions and predictions from our own airglow model, based on atmospheric profiles derived from the solar occultation observed by New Horizons, to the observed brightness of Pluto’s airglow. Although completely opaque at Lyα, Pluto’s atmosphere is optically thin at wavelengths longer than 1425 Å. Consequently, a significant amount of solar far-UV light reaches the surface, where it can participate in space weathering processes. From the brightness of sunlight reflected from Pluto, we find the surface has a reflectance factor (I/F) of 17% between 1400 and 1850 Å. We also report the first detection of a C{sub 3} hydrocarbon molecule, methylacetylene, in absorption, at a column density of ∼5 × 10{sup 15} cm{sup −2}, corresponding to a column-integrated mixing ratio of 1.6 × 10{sup −6}.

79 ASTRONOMY AND ASTROPHYSICS↗

Active Volcanoes of Kamchatka as Suitable Terrestrial Analogs for Future Landing Missions and for Change Detection Analysis on Venus

The next decade will see the return to Venus due to a number of missions which have been recently selected and proposed for launch. The selected missions NASA DAVINCI and VERITAS, Roscosmos Venera-D, and ESA EnVision, along with the proposed missions ISRO Shukrayaan- 1, and CNSA VOICE, will open a new era for the exploration of the Earth’s hellish twin planet. These missions will shed new light on the science questions such as: (a) whether recent volcanic activity is locally constrained, or active volcanism occurs on a global scale; (b) the rate of the present-day volcanic activity; (c) the styles of volcanism on Venus, including possible occurrences of pyroclastic/explosive volcanism; and (d) how does the extreme environment on Venus effect volcanic activity. In preparation for these future missions to Venus, the Analogs for VENus’ GEologically Recent Surfaces (AVENGERS) initiative has the scope to select and analyze a number of active terrestrial volcanoes as suitable analogs for the identification and analysis of active volcanism on Venus. The Roscosmos Venera-D is the only mission, among the currently selected or planned mission, equipped with a lander to analyze the elemental and mineralogical composition of the surface. Therefore, it is crucial to find applicable volcanic areas on Earth to perform operational tests such as surface drilling and in-situ elemental composition analysis. To this regard, we propose the analysis of active volcanoes of the Kamchatka Peninsula, which is in a geodynamic setting (subduction) contrasting to that of the volcanic rises on Venus (hot spot). Thus, Kamchatka may represent a helpful geodynamic endmember to put the expected landing site of the Venera-D mission within the context of the entire variety of volcanic landforms and surface chemistry. The Kamchatka Peninsula is located on the eastern margin of the Eurasian plate, in proximity to the Kuril-Kamchatka subduction zone. The frequent eruptions characterizing the volcanoes of the Kamchatka Peninsula make them a suitable terrestrial analog for the possible detection of ongoing eruptions on Venus by future missions, which can be achieved by comparing a sequence of radar images of the same volcano and its surroundings taken at different times. Moreover, it is possible to collect samples of both unweathered and weathered volcanic deposits, to analyze their near infrared spectra in the laboratory for direct comparison with the spectra to be provided by the future missions to Venus. The chemical analyses of Venusian surface materials from the previous Soviet Venera and Vega missions are consistent with that of tholeiitic basalts. Since the volcanism of the Kamchatka Peninsula is characterized by both basaltic lava flows eruptions and pyroclastic activity, performing operational tests in the Kamchatka Peninsula also offers the unique opportunity to provide us the tools to potentially interpret the diverse output given by both effusive and explosive volcanic products.

Piero D'Incecco↗

Cassini atmospheric chemistry mapper. Volume 1. Investigation and technical plan

The Cassini Atmospheric Chemistry Mapper (ACM) enables a broad range of atmospheric science investigations for Saturn and Titan by providing high spectral and spatial resolution mapping and occultation capabilities at 3 and 5 microns. ACM can directly address the major atmospheric science objectives for Saturn and for Titan, as defined by the Announcement of Opportunity, with pivotal diagnostic measurements not accessible to any other proposed Cassini instrument. ACM determines mixing ratios for atmospheric molecules from spectral line profiles for an important and extensive volume of the atmosphere of Saturn (and Jupiter). Spatial and vertical profiles of disequilibrium species abundances define Saturn's deep atmosphere, its chemistry, and its vertical transport phenomena. ACM spectral maps provide a unique means to interpret atmospheric conditions in the deep (approximately 1000 bar) atmosphere of Saturn. Deep chemistry and vertical transport is inferred from the vertical and horizontal distribution of a series of disequilibrium species. Solar occultations provide a method to bridge the altitude range in Saturn's (and Titan's) atmosphere that is not accessible to radio science, thermal infrared, and UV spectroscopy with temperature measurements to plus or minus 2K from the analysis of molecular line ratios and to attain an high sensitivity for low-abundance chemical species in the very large column densities that may be achieved during occultations for Saturn. For Titan, ACM solar occultations yield very well resolved (1/6 scale height) vertical mixing ratios column abundances for atmospheric molecular constituents. Occultations also provide for detecting abundant species very high in the upper atmosphere, while at greater depths, detecting the isotopes of C and O, constraining the production mechanisms, and/or sources for the above species. ACM measures the vertical and horizontal distribution of aerosols via their opacity at 3 microns and, particularly, at 5 microns. ACM recovers spatially-resolved atmospheric temperatures in Titan's troposphere via 3- and 5-microns spectral transitions. Together, the mixing ratio profiles and the aerosol distributions are utilized to investigate the photochemistry of the stratosphere and consequent formation processes for aerosols. Finally, ring opacities, observed during solar occultations and in reflected sunlight, provide a measurement of the particle size and distribution of ring material. ACM will be the first high spectral resolution mapping spectrometer on an outer planet mission for atmospheric studies while retaining a high resolution spatial mapping capability. ACM, thus, opens an entirely new range of orbital scientific studies of the origin, physio-chemical evolution and structure of the Saturn and Titan atmospheres. ACM provides high angular resolution spectral maps, viewing nadir and near-limb thermal radiation and reflected sunlight; sounds planetary limbs, spatially resolving vertical profiles to several atmospheric scale heights; and measures solar occultations, mapping both atmospheres and rings. ACM's high spectral and spatial resolution mapping capability is achieved with a simplified Fourier Transform spectrometer with a no-moving parts, physically compact design. ACM's simplicity guarantees an inherent stability essential for reliable performance throughout the lengthy Cassini Orbiter mission.

Smith, William Hayden↗

Radar Studies in the Solar System

We aid in study of the solar system by means of ground-based radar. We have concentrated on: (1) developing the ephemerides needed to acquire radar data at Arecibo Observatory and (2) analyzing the resultant data to: test fundamental laws of gravitation; determine the size , shape, topography, and spin vectors of the targets; and study the surface properties of these objects, through their scattering law and polarization characteristics. We are engaged in radar observations of asteroids and comets, both as systematically planned targets and as "targets of opportunity." In the course of the program, we have prepared ephemerides for about 80 asteroids and three comets, and the radar observations have been made or attempted at the Arecibo Observatory, in most cases successfully, and in some cases on more than one apparition. The results of these observations have included echo spectra for the targets and, in some cases, delay - Doppler images and measurements of the total round-trip delay to the targets. Perhaps the most dramatic of these results are the images obtained for asteroids (4179) Toutatis and 1989PB (Castalia), which were revealed to be double-lobed objects by the radar images. Besides these direct results, the radar observations have furnished information on the sizes and shapes of the targets through analysis of the Doppler width of the echoes as a function of time, and on the surface properties (such as composition, bulk density, and roughness) through analysis of the reflectivity and of the polarization state of the echoes. We have also refined the orbits of the observed asteroids as a result of the Doppler (and in some cases delay) measurements from the radar observations. Although the orbits of main-belt asteroids accessible to ground-based radar are quite well known from the available optical data, some near-Earth objects have been seen by radar very soon after their optical discovery (for example, 199OMF, just eight days after discovery). In such cases. the radar results ensure that the object in question can be anticipated and identified at the next apparition. We have also participated in radar studies of the terrestrial planets. The results of these studies have included both planetary topography profiles from the analysis of round-trip delays to points along the target Doppler equator and determinations of the target spin state. The latter is of special interest in the case of Venus, which is very close to, but not on, a multi-body spin-orbit resonance such that Venus rotates 12 times for every 8 Earth orbits and 13 Venus orbits. As a result, Venus presents nearly the same face toward Earth at each inferior conjunction. Our latest results confirm that the spin state of Venus is slightly off the resonance. The delay measurements from planetary 2 ranging have also been used in combination with other types of range data in testing general relativity with increasing accuracy. We have also been engaged in radar studies of planetary satellites. Using our ephemerides, Arecibo made radar observations of the Galilean satellites of Jupiter and of Mars' satellite Phobos during the favorable opposition seasons (1988-1992 for Jupiter and 1990 for Mars). An attempt was also made to observe Deimos, but without detecting an echo. In 1997, an attempt was made to observe Saturn's satellite Titan, using the newly upgraded Arecibo radar system for transmitting and the Goldstone radar for receiving, but no echo was detected. The study of satellites by radar is in many ways similar to that of asteroids. The results from these observations have included characterization of the surface properties from the reflectivity and polarization ratio, as well as (in the case of the large satellites of Jupiter) the variation of reflectivity with incidence angle.

Shaprio, Irwin I.↗

Lunar Impact Flash Locations from NASA's Lunar Impact Monitoring Program

Meteoroids are small, natural bodies traveling through space, fragments from comets, asteroids, and impact debris from planets. Unlike the Earth, which has an atmosphere that slows, ablates, and disintegrates most meteoroids before they reach the ground, the Moon has little-to-no atmosphere to prevent meteoroids from impacting the lunar surface. Upon impact, the meteoroid's kinetic energy is partitioned into crater excavation, seismic wave production, and the generation of a debris plume. A flash of light associated with the plume is detectable by instruments on Earth. Following the initial observation of a probable Taurid impact flash on the Moon in November 2005,1 the NASA Meteoroid Environment Office (MEO) began a routine monitoring program to observe the Moon for meteoroid impact flashes in early 2006, resulting in the observation of over 330 impacts to date. The main objective of the MEO is to characterize the meteoroid environment for application to spacecraft engineering and operations. The Lunar Impact Monitoring Program provides information about the meteoroid flux in near-Earth space in a size range-tens of grams to a few kilograms-difficult to measure with statistical significance by other means. A bright impact flash detected by the program in March 2013 brought into focus the importance of determining the impact flash location. Prior to this time, the location was estimated to the nearest half-degree by visually comparing the impact imagery to maps of the Moon. Better accuracy was not needed because meteoroid flux calculations did not require high-accuracy impact locations. But such a bright event was thought to have produced a fresh crater detectable from lunar orbit by the NASA spacecraft Lunar Reconnaissance Orbiter (LRO). The idea of linking the observation of an impact flash with its crater was an appealing one, as it would validate NASA photometric calculations and crater scaling laws developed from hypervelocity gun testing. This idea was dependent upon LRO finding a fresh impact crater associated with one of the impact flashes recorded by Earth-based instruments, either the bright event of March 2013 or any other in the database of impact observations. To find the crater, LRO needed an accurate area to search. This Technical Memorandum (TM) describes the geolocation technique developed to accurately determine the impact flash location, and by association, the location of the crater, thought to lie directly beneath the brightest portion of the flash. The workflow and software tools used to geolocate the impact flashes are described in detail, along with sources of error and uncertainty and a case study applying the workflow to the bright impact flash in March 2013. Following the successful geolocation of the March 2013 flash, the technique was applied to all impact flashes detected by the MEO between November 7, 2005, and January 3, 2014.

Moser, D. E.↗

Comet Shoemaker-Levy 9, Jupiter, and Impact Shock Chemistry

Four years ago this month, a hitherto unknown comet in loose orbit around Jupiter passed so near the giant planet that it was torn apart into 20 fragments by tides. One orbit later, two years ago this month, the fragments of doomed comet P/Shoemaker Levy (SL9) fell into Jupiter. The enormous energies of these impacts (the largest fragments were nearly 1 km across and, hitting at 60 km/s, released some 2-4 x 10(exp 27) ergs) produced enormous explosions. Several of the ejecta plumes were imaged towering 3000 km above Jupiter's limb. The heat released when the plumes fell was considerable and easily observed on Earth. The impacts produced strong shocks, both promptly at the impact site and again, later, and over thousands of kilometers, when the ejecta plume reentered the atmosphere. The focus of this talk will be to discuss what the SL9 impacts taught us about impact shock chemistry - the processes, the ingredients, the results - and what inferences we may draw for impacts on early Earth. Shock chemistry generates a suite of molecules not usually seen on Jupiter. The most surprising report was of a huge amount of diatomic sulfur S2 at the site of the G impact. Other unusual products include CS, CS2, OCS, H2S, SO2, HCN, CO, and H2O; although H2S and H2O are doubtless abundant below the visible clouds. Hot or enhanced CH4 and NH3 were also detected. A general rule of shock chemistry is that CO forms until either C or O is exhausted. If O greater than C, the other products are oxidized, and excess O goes to H2O. If C greater than O, the other products are reduced, and excess C goes to HCN, C2H2, and a wide variety of more complicated organics. Ultimately, given time, the carbon would react all the way to graphite, but in practice the reactions are incomplete. The dark ejecta debris were probably composed in part of carbonaceous particles generated by the shocks. In a sense, the SL9 impacts performed the famous Miller-Urey experiment on a grand scale, with one result being the production of a lot of complex brown organic solids (called "tholins"). We use, a straightforward chemical kinetics model for the H, N, C, O, S system to follow the nonequilibrium chemistry behind the shocks. The model traces the evolving chemical composition of a parcel of gas by directly integrating the web of chemical reactions. Pressure and temperature histories of the parcels are patterned after those calculated by numerical hydrodynamic simulations of the ejecta plume. A given plume parcel is generally shocked twice; t.e a parcel shocked near the impact site is ejected at high velocity and is shocked again when it reenters the atmosphere. The final state of the gas depends mostly on the second shock, provided that the latter is hot enough. The chemical evidence is ambiguous, but most indications are that C greater than O in the shocked, reacting gas. Telltale signatures of abundant oxygen - SO2, SO, CO2, O2 - were not seen, while signatures of abundant carbon - CS, CS2, and HCN - were. On the other hand, abundant H2O would appear to require O greater than C, and two other observed sulfur species, S2 and OCS, appear to form more easily in a somewhat oxidized gas, presumable vaporized from the comet itself. Since on general principles one expects the -comet to have had a more-or-less cosmic composition, i.e. O greater than C, the production of CS, CS2, and HCN probably requires C greater than O in the shocked jovian air. This in turn implies that even the largest fragments released the bulk of their energy above the jovian water table, in all likelihood above 5 bars . There is no evidence in favor of the proposition that a significant amount of wet jovian air was shocked strongly enough to coax water to react; i.e. wet jovian air saw only temperatures significantly below 2000 K.

Zahnle, Kevin↗