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At least 361 records · Page 20

Clarification of creep deformation mechanism in heat-affected zone of 9Cr steels with In Situ experiments

This work quantified nonuniform creep deformation across the heterogeneous heat-affected zone (HAZ) of Grade 91 steel with sophisticated experiments, including an electric-thermal finite element model–assisted Gleeble thermomechanical simulation and a high-temperature creep testing with in situ digital image correlation (DIC). High temperature creep properties of HAZ sub-zones were quantitatively measured by the DIC. Furthermore, by utilizing peak temperature, hardness, local creep strain, and underlying microstructures, creep deformation mechanisms in HAZ were further understood. DIC measurements reveal a creep-vulnerable zone (CVZ) exposed to a peak temperature of 932°C (close to A C3 ) in the intercritical HAZ experienced the fastest creep strength degradation instead of the soft zone with the lowest hardness prior to creep. The significantly reduced precipitation strengthening from misplacement of undissolved and coarsened M 23 C 6 carbides led to a faster recrystallization of tempered martensite in the CVZ. Weak untransformed tempered martensite (ferrite grains) stabilized by local Cr enrichment from dissolved M 23 C 6 also harmed the CVZ's creep resistance.

36 MATERIALS SCIENCE↗

Probabilistic Assessment of Above Zone Pressure Predictions at a Geologic Carbon Storage Site

Carbon dioxide (CO2) storage into geological formations is regarded as an important mitigation strategy for anthropogenic CO2 emissions to the atmosphere. This study first simulates the leakage of CO2 and brine from a storage reservoir through the caprock. Then, we estimate the resulting pressure changes at the zone overlying the caprock also known as Above Zone Monitoring Interval (AZMI). A data-driven approach of arbitrary Polynomial Chaos (aPC) Expansion is then used to quantify the uncertainty in the above zone pressure prediction based on the uncertainties in different geologic parameters. Finally, a global sensitivity analysis is performed with Sobol indices based on the aPC technique to determine the relative importance of different parameters on pressure prediction. The results indicate that there can be uncertainty in pressure prediction locally around the leakage zones. The degree of such uncertainty in prediction depends on the quality of site specific information available for analysis. The scientific results from this study provide substantial insight that there is a need for site-specific data for efficient predictions of risks associated with storage activities. The presented approach can provide a basis of optimized pressure based monitoring network design at carbon storage sites.

54 ENVIRONMENTAL SCIENCES↗

Thin Fresnel zone plate lenses for focusing underwater sound

A Fresnel zone plate (FZP) lens of the Soret type creates a focus by constructive interference of waves diffracted through open annular zones in an opaque screen. For underwater sound below MHz frequencies, a large FZP that blocks sound using high-impedance, dense materials would have practical disadvantages. We experimentally and numerically investigate an alternative approach of creating a FZP with thin (0.4λ) acoustically opaque zones made of soft silicone rubber foam attached to a thin (0.1λ) transparent rubber substrate. An ultra-thin (0.0068λ) FZP that achieves higher gain is also proposed and simulated which uses low-volume fraction, bubble-like resonant air ring cavities to construct opaque zones. Laboratory measurements at 200 kHz indicate that the rubber foam can be accurately modeled as a lossy fluid with an acoustic impedance approximately 1/10 that of water. Measured focal gains up to 20 dB agree with theoretical predictions for normal and oblique incidence. The measured focal radius of 0.68λ (peak-to-null) agrees with the Rayleigh diffraction limit prediction of 0.61 λ/NA (NA = 0.88) for a low-aberration lens.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DEAD ZONE IN THE POLAR-CAP ACCELERATOR OF PULSARS

We study plasma flows above pulsar polar caps using time-dependent simulations of plasma particles in the self-consistent electric field. The flow behavior is controlled by the dimensionless parameter {alpha} = j/c{rho}{sub GJ}, where j is the electric current density and {rho}{sub GJ} is the Goldreich-Julian charge density. The region of the polar cap where 0 < {alpha} < 1 is a {sup d}ead zone{sup -}in this zone, particle acceleration is inefficient and pair creation is not expected even for young, rapidly rotating pulsars. Pulsars with polar caps near the rotation axis are predicted to have a hollow-cone structure of radio emission, as the dead zone occupies the central part of the polar cap. Our results apply to charge-separated flows of electrons (j < 0) or ions (j > 0). In the latter case, we consider the possibility of a mixed flow consisting of different ion species, and observe the development of two-stream instability. The dead zone at the polar cap is essential for the development of an outer gap near the null surface {rho}{sub GJ} = 0.

79 ASTRONOMY AND ASTROPHYSICS↗

THE HUNT FOR EXOMOONS WITH KEPLER (HEK). III. THE FIRST SEARCH FOR AN EXOMOON AROUND A HABITABLE-ZONE PLANET

Kepler-22b is the first transiting planet to have been detected in the habitable zone of its host star. At 2.4 R{sub ⊕}, Kepler-22b is too large to be considered an Earth analog, but should the planet host a moon large enough to maintain an atmosphere, then the Kepler-22 system may yet possess a telluric world. Aside from being within the habitable zone, the target is attractive due to the availability of previously measured precise radial velocities and low intrinsic photometric noise, which has also enabled asteroseismology studies of the star. For these reasons, Kepler-22b was selected as a target-of-opportunity by the 'Hunt for Exomoons with Kepler' (HEK) project. In this work, we conduct a photodynamical search for an exomoon around Kepler-22b leveraging the transits, radial velocities, and asteroseismology plus several new tools developed by the HEK project to improve exomoon searches. We find no evidence for an exomoon around the planet and exclude moons of mass M{sub S} > 0.5 M{sub ⊕} to 95% confidence. By signal injection and blind retrieval, we demonstrate that an Earth-like moon is easily detected for this planet even when the time-correlated noise of the data set is taken into account. We provide updated parameters for the planet Kepler-22b, including a revised mass of M{sub P} < 53 M{sub ⊕} to 95% confidence and an eccentricity of 0.13{sub -0.13}{sup +0.36} by exploiting Single-body Asterodensity Profiling. Finally, we show that Kepler-22b has a >95% probability of being within the empirical habitable zone but a <5% probability of being within the conservative habitable zone.

79 ASTRONOMY AND ASTROPHYSICS↗

PLANETARY CHAOTIC ZONE CLEARING: DESTINATIONS AND TIMESCALES

We investigate the orbital evolution of particles in a planet's chaotic zone to determine their final destinations and their timescales of clearing. There are four possible final states of chaotic particles: collision with the planet, collision with the star, escape, or bounded but non-collision orbits. In our investigations, within the framework of the planar circular restricted three body problem for planet-star mass ratio μ in the range 10{sup –9} to 10{sup –1.5}, we find no particles hitting the star. The relative frequencies of escape and collision with the planet are not scale-free, as they depend upon the size of the planet. For planet radius R{sub p} ≥ 0.001 R{sub H} where R{sub H} is the planet's Hill radius, we find that most chaotic zone particles collide with the planet for μ ≲ 10{sup –5}; particle scattering to large distances is significant only for higher mass planets. For fixed ratio R{sub p} /R{sub H} , the particle clearing timescale, T {sub cl}, has a broken power-law dependence on μ. A shallower power law, T {sub cl} ∼ μ{sup –1/3}, prevails at small μ where particles are cleared primarily by collisions with the planet; a steeper power law, T {sub cl} ∼ μ{sup –3/2}, prevails at larger μ where scattering dominates the particle loss. In the limit of vanishing planet radius, we find T {sub cl} ≈ 0.024 μ{sup –3/2}. The interior and exterior boundaries of the annular zone in which chaotic particles are cleared are increasingly asymmetric about the planet's orbit for larger planet masses; the inner boundary coincides well with the classical first order resonance overlap zone, Δa {sub cl,} {sub int} ≅ 1.2 μ{sup 0.28} a{sub p} ; the outer boundary is better described by Δa {sub cl,} {sub ext} ≅ 1.7 μ{sup 0.31} a{sub p} , where a{sub p} is the planet-star separation.

79 ASTRONOMY AND ASTROPHYSICS↗

CHAOTIC ZONES AROUND GRAVITATING BINARIES

The extent of the continuous zone of chaotic orbits of a small-mass tertiary around a system of two gravitationally bound primaries of comparable masses (a binary star, a binary black hole, a binary asteroid, etc.) is estimated analytically, as a function of the tertiary's orbital eccentricity. The separatrix map theory is used to demonstrate that the central continuous chaos zone emerges (above a threshold in the primaries' mass ratio) due to overlapping of the orbital resonances corresponding to the integer ratios p:1 between the tertiary and the central binary periods. In this zone, the unlimited chaotic orbital diffusion of the tertiary takes place, up to its ejection from the system. The primaries' mass ratio, above which such a chaotic zone is universally present at all initial eccentricities of the tertiary, is estimated. The diversity of the observed orbital configurations of biplanetary and circumbinary exosystems is shown to be in accord with the existence of the primaries' mass parameter threshold.

79 ASTRONOMY AND ASTROPHYSICS↗

Effect of tilt on circular zone plate performance

Fresnel zone plates are frequently used as focusing and imaging optics in x-ray microscopy, as they provide the ease of use of normal incidence optics. We consider here the effects of tilt misalignment on their optical performance, both in the thin optics limit and in the case of zone plates that are sufficiently thick so that volume diffraction effects come into play. Using multislice propagation, we show that simple analytical models describe the tilt sensitivity of thin zone plates and the thickness at which volume diffraction must be considered, and examine numerically the performance of example zone plates for soft x-ray focusing at 0.5 keV and hard x-ray focusing at 10 keV.

47 OTHER INSTRUMENTATION↗

Monitoring Vadose Zone Desiccation with Geophysical Methods

Soil desiccation was recently field tested as a potential vadose zone remediation technology. Desiccation removes water from the vadose zone and significantly decreases the aqueous-phase permeability of the desiccated zone, thereby decreasing movement of moisture and contaminants. The 2-D and 3-D distribution of moisture content reduction over time provides valuable information for desiccation operations and for determining when treatment goals have been reached. This type of information can be obtained through use of geophysical methods. Neutron moisture logging, cross-hole electrical resistivity tomography, and cross-hole ground penetrating radar approaches were evaluated with respect to their ability to provide effective spatial and temporal monitoring of desiccation during a treatability study conducted in the vadose zone of the DOE Hanford Site in WA.

geophysics↗

Long-Term Colloid Mobilization and Colloid-Facilitated Transport of Radionuclides in a Semi-Arid Vadose Zone

The main purpose of this project was to improve the fundamental mechanistic understanding and quantification of long-term colloid mobilization and colloid-facilitated transport of radionuclides in the vadose zone, with special emphasis on the semi-arid Hanford site. While we focused some of the experiments on hydrogeological and geochemical conditions of the Hanford site, many of our results apply to colloid and colloid-facilitated transport in general. Specific objectives were (1) to determine the mechanisms of colloid mobilization and colloid-facilitated radionuclide transport in undisturbed Hanford sediments under unsaturated flow, (2) to quantify in situ colloid mobilization and colloid-facilitated radionuclide transport from Hanford sediments under field conditions, and (3) to develop a field-scale conceptual and numerical model for colloid mobilization and transport at the Hanford vadose zone, and use that model to predict long-term colloid and colloid- facilitated radionuclide transport. To achieve these goals and objectives, we have used a combination of experimental, theoretical, and numerical methods at different spatial scales, ranging from microscopic investigations of single particle attachment and detachment to larger-scale field experiments using outdoor lysimeters at the Hanford site. Microscopic and single particle investigations provided fundamental insight into mechanisms of colloid interactions with the air-water interface. We could show that a moving air water interface (such as a moving water front during infiltration and drainage) is very effective in removing and mobilizing particles from a stationary surface. We further demonstrated that it is particularly the advancing air-water interface which is mainly responsible for colloid mobilization. Forces acting on the colloids calculated from theory corroborated our experimental results, and confirm that the detachment forces (surface tension forces) during the advancing air-water interface movement were stronger than during the receding movement. Theory indicates that, for hydrophilic colloids, the advancing interface movement generally exerts a stronger detachment force than the receding, except when the hysteresis of the colloid-air-water contact angle is small. These results of our study are particularly relevant for colloid mobilization and transport related to three process in the vadose zone at Hanford: (1) water infiltration into sediments during rainfall or snowmelt events, (2) groundwater fluctuations as caused by river stage fluctuations, and (3) steady-state, low-flow recharge in deep vadose zone sediments. Transient water flow, like during infiltration or groundwater level fluctuations, are most conducive for colloid mobilization, but even during steady-state, low-flow recharge, colloids can be mobile, although to a much lesser extent. The results of this project have led to a comprehensive and fundamental understanding of colloid transport and mobilization under unsaturated flow conditions at the Hanford site.

58 GEOSCIENCES↗

Conceptual Model of Uranium in the Vadose Zone for Acidic and Alkaline Wastes Discharged at the Hanford Site Central Plateau

Historically, uranium was disposed in waste solutions of varying waste chemistry at the Hanford Site Central Plateau. The character of how uranium was distributed in the vadose zone during disposal, how it has continued to migrate through the vadose zone, and the magnitude of potential impacts on groundwater are strongly influenced by geochemical reactions in the vadose zone. These geochemical reactions can be significantly influenced by the disposed-waste chemistry near the disposal location. This report provides conceptual models and supporting information to describe uranium fate and transport in the vadose zone for both acidic and alkaline wastes discharged at a substantial number of waste sites in the Hanford Site Central Plateau. The conceptual models include consideration of how co-disposed acidic or alkaline fluids influence uranium mobility in terms of induced dissolution/precipitation reactions and changes in uranium sorption with a focus on the conditions near the disposal site. This information, when combined with the extensive information describing uranium fate and transport at near background pH conditions, enables focused characterization to support effective fate and transport estimates for uranium in the subsurface.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Mitochondrial Genomes of the United States Distribution of Gray Fox (Urocyon cinereoargenteus) Reveal a Major Phylogeographic Break at the Great Plains Suture Zone

We examined phylogeographic structure in gray fox (Urocyon cinereoargenteus) across the United States to identify the location of secondary contact zone(s) between eastern and western lineages and investigate the possibility of additional cryptic intraspecific divergences. We generated and analyzed complete mitochondrial genome sequence data from 75 samples and partial control region mitochondrial DNA sequences from 378 samples to investigate levels of genetic diversity and structure through population- and individual-based analyses including estimates of divergence (FST and SAMOVA), median joining networks, and phylogenies. We used complete mitochondrial genomes to infer phylogenetic relationships and date divergence times of major lineages of Urocyon in the United States. Despite broad-scale sampling, we did not recover additional major lineages of Urocyon within the United States, but identified a deep east-west split (~0.8 million years) with secondary contact at the Great Plains Suture Zone and confirmed the Channel Island fox (Urocyon littoralis) is nested within U. cinereoargenteus. Genetic diversity declined at northern latitudes in the eastern United States, a pattern concordant with post-glacial recolonization and range expansion. Beyond the east-west divergence, morphologically-based subspecies did not form monophyletic groups, though unique haplotypes were often geographically limited. Gray foxes in the United States displayed a deep, cryptic divergence suggesting taxonomic revision is needed. Secondary contact at a common phylogeographic break, the Great Plains Suture Zone, where environmental variables show a sharp cline, suggests ongoing evolutionary processes may reinforce this divergence. Follow-up study with nuclear markers should investigate whether hybridization is occurring along the suture zone and characterize contemporary population structure to help identify conservation units. Comparative work on other wide-ranging carnivores in the region should test whether similar evolutionary patterns and processes are occurring.

54 ENVIRONMENTAL SCIENCES↗

Determining Coalbed Methane Production and Composition from Individual Stacked Coal Seams in a Multi-Zone Completed Gas Well

This work proposes a novel and cost-effective approach to determine coalbed methane (CBM) production and composition from individual coal seams in a multi-zone completed CBM well. The novel method uses water to cover individual coal seams in a low pressure CBM well followed by an Echometer fluid level survey to determine the water level. Corresponding gas flow measurements and natural gas chromatography analysis are used to determine gas production and composition from unique zones. A field test using this technology is conducted in Central Appalachia for a multi-zone CBM well containing 18 coal seams. Test results show that the shallow coal seams contribute the majority of the total CBM production in this multi-zone well, and the deeper coal seams contain more heavy hydrocarbons like ethane and propane.

01 COAL, LIGNITE, AND PEAT↗

Low stress drop earthquakes in the rupture zone of the 1992 Nicaragua tsunami earthquake

Tsunami earthquakes, events that generate larger than expected tsunami and are deficient in high-frequency seismic radiation, are rare but hazardous to coastal populations. One model for these events is shallow rupture through low-strength materials. We calculate here seismic moment, corner frequency, and stress drop for 216 earthquakes (2.1 < M w < 4.7, November 2005 to June 2006) within and external to the 1992 Nicaragua tsunami earthquake rupture zone to test the hypothesis that differences in fault zone properties defined the limits of the 1992 tsunami rupture zone and continue to produce spatial variations in earthquake source properties. Mean stress drop of events within the rupture area is 1.2 MPa, and 5.5 MPa for events just outside of the rupture zone, with similar magnitude earthquakes in each group. Our results demonstrate different source parameter characteristics for microseismicity in the region of a past tsunami earthquake.

58 GEOSCIENCES↗

Preserved Neoproterozoic Continental Collision in Southeastern North America: The Brunswick Suture Zone and Osceola Continental Margin Arc

A series of exotic terranes were accreted to the eastern margin of southeastern Laurentia beginning in the Siluro-Devonian (Acadian event), and to the northeastern Laurentian margin beginning earlier (late Taconian). Many of these terranes have unclear tectonostratigraphic relationships to each other and to their parental cratons, but their accretionary history is critical to understanding the evolution of the Appalachian orogen. Two of these, the Gondwanan Suwannee and Charleston terranes, accreted during the Alleghanian orogeny and now lie beneath the Atlantic Coastal Plain in southeastern North America. Reanalysis of deep seismic reflection and well data reveals a preserved Neoproterozoic continental collision zone and associated continental margin arc, the Osceola arc, related to their juxtaposition. The subduction zone and associated strain are recorded in the newly termed Brunswick suture zone (BSZ). The BSZ is readily identified on a series of eight deep seismic reflection transects across the Brunswick Magnetic Anomaly (BMA), which we interpret as the boundary between the Charleston and Suwannee terranes. While originally interpreted to be the Late Paleozoic Alleghanian suture, new age constraints provided by the overlapping Gondwanan Paleozoic Suwannee Basin strata require the BSZ to predate the Early to Middle Paleozoic passive margin sequence of the Suwannee Basin. These results provide new insights into the tectonostratigraphic evolution of the Charleston and Suwannee terranes, the controversy surrounding the age and origin of the dipping seismic reflectors, previously attributed to the suturing of the Suwannee terrane to Laurentia, and the relationship of this suture zone to the origin of the BMA.

58 GEOSCIENCES↗

When interflow also percolates: downslope travel distances and hillslope process zones.

In hillslopes with soils characterized by deep regoliths, such as Ultisols,Oxisols, and Alfisols, interflow occurs episodically over impeding layers near and parallel to the soil surface such as low-conductivity B horizons (e.g.Newman et al., 1998; Buttle andMcDonald, 2002; Du et al., In Review), till layers (McGlynn et al., 1999; Bishop et al., 2004), hardpans (McDaniel et al., 2008), C horizons (Detty and McGuire, 2010), and permeable bedrock (Tromp van Meerveld et al., 2007). As perched saturation develops within and above these impeding but permeable horizons, flow moves laterally downslope, but the perched water also continues to percolate through the impeding horizon to the unsaturated soils and saprolite below. Perched water and solutes will eventually traverse the zone of perched saturation above the impeding horizon and then enter and percolate through the impeding horizon. In such flow situations, only lower hillslope segments with sufficient downslope travel distance will deliver water to the riparian zone within the time scale of a storm.farther up the slope, lateral flow within the zone of perched saturation. will act mainly to shift the point of percolation (location where a water packet leaves the downslope flow zone in the upper soil layer and enters the impeding layer) down the hillslope from the point of infiltration. In flatter parts of the hillslope or in areas with little contrast between the conductivities of the upper and impeding soil layers, lateral flow distances will be negligible.

60 APPLIED LIFE SCIENCES↗

Soil Organic Matter Dynamics in the Critical Zone

Soil is the thin, vital layer of Earth’s surface that forms the foundation of the Critical Zone and sustains life. This chapter explores the intricate dynamics of soil organic matter within the critical zone, focusing on three key thematic areas: deep soil organic matter, wildfire organic matter interactions, and organic matter erosion. Soil organic matter, although a small fraction of soil mass, plays a crucial role in soil function and ecosystem stability. The complexity of soil organic matter arises from its diverse chemical composition and interactions with minerals, which influence its persistence in the environment. This chapter begins by examining deep soil organic matter, which constitutes a significant portion of global carbon storage. We discuss how deep soil organic matter, typically isolated from surface processes, may become vulnerable to decomposition and carbon release due to disturbances. Next, we explore the impacts of fire on soil organic matter, particularly the formation and stability of pyrolyzed organic matter. The decomposition of pyrolyzer organic matter is influenced by its chemical composition and the surrounding environmental conditions, with implications for carbon cycling and soil fertility in post-fire ecosystems. Finally, the chapter addresses the role of erosion in soil organic matter dynamics. Erosion, accelerated by human activities, redistributes soil organic matter across landscapes, affecting its turnover and the broader biogeochemical cycles. We consider how micro-topographic features and erosion processes interact to influence soil OM stability and carbon sequestration. By synthesizing recent advances in these areas, this chapter provides a comprehensive overview of the complex and dynamic nature of soil organic matter in the critical zone, highlighting its importance in understanding the critical zone in the face of environmental change.

Moreland, Kimber↗

CT-guided Irreversible Electroporation in an Acute Porcine Liver Model: Effect of Previous Transarterial Iodized Oil Tissue Marking on Technical Parameters, 3D Computed Tomographic Rendering of the Electroporation Zone, and Histopathology

PurposeTo evaluate the effect of previous transarterial iodized oil tissue marking (ITM) on technical parameters, three-dimensional (3D) computed tomographic (CT) rendering of the electroporation zone, and histopathology after CT-guided irreversible electroporation (IRE) in an acute porcine liver model as a potential strategy to improve IRE performance.MethodsAfter Ethics Committee approval was obtained, in five landrace pigs, two IREs of the right and left liver (RL and LL) were performed under CT guidance with identical electroporation parameters. Before IRE, transarterial marking of the LL was performed with iodized oil. Nonenhanced and contrast-enhanced CT examinations followed. One hour after IRE, animals were killed and livers collected. Mean resulting voltage and amperage during IRE were assessed. For 3D CT rendering of the electroporation zone, parameters for size and shape were analyzed. Quantitative data were compared by the Mann–Whitney test. Histopathological differences were assessed.ResultsMean resulting voltage and amperage were 2,545.3 ± 66.0 V and 26.1 ± 1.8 A for RL, and 2,537.3 ± 69.0 V and 27.7 ± 1.8 A for LL without significant differences. Short axis, volume, and sphericity index were 16.5 ± 4.4 mm, 8.6 ± 3.2 cm{sup 3}, and 1.7 ± 0.3 for RL, and 18.2 ± 3.4 mm, 9.8 ± 3.8 cm{sup 3}, and 1.7 ± 0.3 for LL without significant differences. For RL and LL, the electroporation zone consisted of severely widened hepatic sinusoids containing erythrocytes and showed homogeneous apoptosis. For LL, iodized oil could be detected in the center and at the rim of the electroporation zone.ConclusionThere is no adverse effect of previous ITM on technical parameters, 3D CT rendering of the electroporation zone, and histopathology after CT-guided IRE of the liver.

62 RADIOLOGY AND NUCLEAR MEDICINE↗