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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Possible production by lightning of aerosols and trace gases in Titan's atmosphere

Although lightning has not yet been observed in Titan's atmosphere, the presence of condensable vapors and the deposition of a significant amount of solar energy at the surface suggest the possibility of lightning activity. Based on an understanding of the relationship of lightning activity to the amount of convective energy available on Titan, a lightning energy dissipation rate of 4 x 10 to the -6th W/sq m can be expected. This value is much lower than that for earth or Jupiter, and is a result of both the reduced solar flux at Titan and the absorption of sunlight by the aerosols that lie above the convective layer. For this dissipation rate, the amount of HCN and C2N2 produced by lightning should be greater than that by solar UV, but could be less than that produced by electron precipitation and galactic cosmic rays. Equilibrium calculations indicate that large mole fractions of elemental solid phase carbon will also be produced. Using a simplified model of aerosol formation, coagulation, and settling, it is estimated that a lightning-produced aerosol could have a typical optical depth of 0.01, with values as high as 0.1. The accumulation of soot over geological time might reach a meter or more in depth.

Borucki, W. J.↗
NASA NTRS1985

Bolometric albedos of Titan, Uranus, and Neptune

The energy budgets of Titan, Uranus, and Neptune are reevaluated using new observational data on energy input as well as unpublished data on energy output. The bolometric geometric albedo of each object was determined, and preliminary determinations of the phase functions were used to compute the Bond albedos and effective temperatures. The values for the latter are 83 + or - 2 K for Titan, 57 + or - 2 K for Uranus, and 47 + or - 2 K for Neptune. The effective temperature of Titan is greater than the observed brightness temperatures in the thermal infrared region of the spectrum, indicating that the emissivity is less than unity for this part of the spectrum. An internal luminosity of (3.9 + or 1.1) x 10 to the 15th W is found for Neptune, and an upper limit of (0.6 + or - 1.4) x 10 to the 15th W is found for Uranus.

Neff, J. S.↗
NASA NTRS1985

Project Cassini - A potential collaborative ESA/NASA Saturn Orbiter and Titan Probe mission

Project Cassini is concerned with a potential collaborative mission to Saturn and Titan. The project has been the subject of a joint ESA/NASA Technical Assessment Study from April 1984 to July 1985. The spacecraft consists of a Saturn Orbiter and a Titan entry Probe. Science objectives with respect to Titan include a determination of the abundances of atmospheric constituents and isotope ratios, a study of the distribution of trace gases, cloud physics, and a determination of the state of the surface. Other science objectives are related to Saturn, the rings, icy satellites, the magnetosphere of Saturn, and asteroids. Attention is given to mission design, the spacecraft, and future prospects.

Beckman, J.↗
NASA NTRS1985

Titan's organic chemistry

Voyager discovered nine simple organic molecules in the atmosphere of Titan. Complex organic solids, called tholins, produced by irradiation of the simulated Titanian atmosphere, are consistent with measured properties of Titan from ultraviolet to microwave frequencies and are the likely main constituents of the observed red aerosols. The tholins contain many of the organic building blocks central to life on earth. At least 100-m, and possibly kms thicknesses of complex organics have been produced on Titan during the age of the solar system, and may exist today as submarine deposits beneath an extensive ocean of simple hydrocarbons.

Sagan, C.↗
NASA NTRS1987

Monodeuterated methane in the outer Solar System. Part 3: Its abundance on Titan

The 3 nu 2 band of CH3D has been detected in spectra of Titan recorded at 1.6 microns with the Fourier Transform Spectrometer (FTS) at the 4 m telescope of the Kitt Peak National Observatory (NOAO). We have obtained a value of the CH3D/CH4 mixing ratio of 6.6 (+6.6 or -3.3) x 10 to the -4 from a comparison between the observed Titan spectra and synthetic spectra. This value is approx. 2 times higher than the value measured on Uranus (de Bergh et al. 1986) and approx. 6 times higher than on Jupiter and on Saturn (Courtin et al. 1984; de Bergh et al. 1986). It corresponds to D/H of 1.65 (+1.65 or -0.8) x 10 the -4, nominally 8 times higher than the most commonly accepted value for the protosolar D/H = 2 x 10 to the -5 (Geiss and Reeves 1981). The value we find on Titan for D/H in methane is comparable to the D/H ratio measured in terrestrial H2O.

Debergh, C.↗
NASA NTRS1986

Amino acidis derived from Titan tholins

The production of amino acids by acid treatment of Titan tholin is experimentally investigated. The synthesis of Titan tholin and the derivatization of amino acids to N-trifluoroacetyl isopropyl esters are described. The gas chromatography/mass spectroscopy analysis of the Titan tholins reveals the presence of glycine, alpha and beta alainine, and aspartic acid, and the total yield of amino acids is about 0.01.

Khare, Bishun N.↗
NASA NTRS1987

Interpretation of electrostatic noise observed by Voyager 1 in Titan's wake

During the Voyager 1 spacecraft flyby of Titan on November 12, 1980, an intense broadband low frequency electric field noise was observed in the inbound wake. This so-called sheath noise is believed to be generated by an ion beam-plasma interaction between the ions in the corotational Saturnian magnetospheric plasma and nearly stationary plasma created by the ionization of Titan's atmosphere. The analysis is based on the information from Voyager 1 and reasonable assumptions. The results agree quite well with the observation. The analysis shows that the instability only occurs where the density of the corotational ions is comparable to the density of ions originating from Titan's atmosphere. The growth rate is high enough to generate the observed noise, and the calculated and observed frequency ranges are in good agreement.

Ma, T. Z.↗
NASA NTRS1988

Monodeuterated methane in the outer solar system. III - Its abundance of Titan

The 3nv2 band of CH3D has been detected in spectra of Titan recorded at 1.6 microns with the Fourier transform spectrometer at the 4 m telescope of the Kitt Peak National Observatory. A value of the CH3D/Ch4 mixing ratio is obtained from a comparison between the observed Titan spectra and synthetic spectra. This value is about 2 times higher than the value measured on Uranus (de Bergh et al. 1981, 1986) and about 6 times higher than on Jupiter and on Saturn (Courtin et al. 1984; de Bergh et al.). The value found on Titan for D/H in methane is comparable to the D/H ratio measured in terrestrial H2O.

De Bergh, C.↗
NASA NTRS1988

Constraints on Titan's ionosphere

The near flyby of Saturn's moon Titan by Voyager 1 revealed a Venus-like interaction between the moon and Saturn's magnetospheric plasma. Although neither the radio science experiment occultation observation nor the in-situ measurements directly detected the ionosphere, plasma of ionospheric origin was observed as Voyager 1 passed through Titan's wake. Balancing the magnetic pressure in this low-beta region of Saturn's magnetosphere with ionospheric particle pressure yields an upper limit on the ionospheric density. Using an ionospheric temperature equal to the exospheric temperature of 200 K yields a charge density of about 3000/cu cm, which is consistent with the peak ionospheric electron density inferred from a balance of electron impact ionization of molecular nitrogen and recombination loss. Both of these quantities are consistent with limits derived from Voyager 1 observations. Good constraints on these quantities are important in planning the Cassini mission to orbit Saturn and probe Titan's ionosphere and atmosphere at the beginning of the next century.

Mcnutt, Ralph L., Jr.↗
NASA NTRS1988

Pressure-induced absorption coefficients for radiative transfer calculations in Titan's atmosphere

The semiempirical theory of Birnbaum and Cohen (1976) is used to calculate the FIR pressure-induced absorption (PIA) spectra of N2, CH4, N2 + Ar, N2 + CH4, and N2 + H2 under conditions like those in the Titan troposphere. The results are presented graphically and compared with published data from laboratory measurements of PIA in the same gases and mixtures (Dagg et al., 1986; Dore et al., 1986). Good agreement is obtained, with only a slight underestimation of PIA at 300-400/cm in the case of CH4. The absorption coefficients are presented in tables, and it is suggested that the present findings are of value for evaluating the effects of tropospheric clouds on the Titan FIR spectrum and studying the greenhouse effect near the Titan surface.

Courtin, Regis↗
NASA NTRS1990

Role of the methylene amidogen (H2CN) radical in the atmospheres of Titan and Jupiter

The methylene amidogen (H2CN) radical can be shown to be an important intermediate in models for the formation of HCN (via N + CH3) and the recombination of H to H2 (via H + HCN) on Titan as well as in models for the formation of HCN (via NH2 + C2H3) in the atmosphere of Jupiter. Experiments in our laboratory in a discharge flow system with mass spectrometric detection of both reactants and products have established that the major product channel (90 percent for the reaction N + CH3 is that leading to H2CN + H. The same result was obtained for N + CD3 yields D2CN + D. The rate constant for the reaction D + D2CN yields DCN + D2 was measured for the first time and k(298 K) greater than 7 x 10(exp -11) cu cm/s was found. The same result was obtained for the H atom reaction. This is the final step in the reaction sequence leading to HCN on both Titan and Jupiter and to formation of H2 from H on Titan. The first measurement of the ionization potentials for H2CN and D2CN was also made. From electron impact studies I.P. = (9.6 + or - 1.0) eV was obtained for both radicals. An upperlimit of I.P. less than 11.6 eV came from observations of the H2CN radical by photoionization mass spectrometry using an Ar resonance lamp (106.7 nm). Further photoionization experiments are planned using synchrotron radiation plus monochromator as a tunable vacuum UV light source.

Nesbitt, F. L.↗
NASA NTRS1990

Titan and other icy satellites - Dielectric properties of constituent materials and implications for radar sounding

Radar sounding observations of Titan and the other outer solar system icy satellites have been conducted in order to ascertain the materials present, their dielectric properties, and the degree of radar signal penetration. Deep penetration is possible at long wavelengths, while strong reflections may occur due to pockets or layers of H2O-NH3 solution. Attention is given to the case of Titan, using models to calculate radar reflection S/N ratios; the models involve H2O ice covered by a 100-m thick layer of organic sediments that are overlain by an ocean of liquid CH4-C2H6-N2. At 13.6-cm wavelength, a greater-than-10 dB S/N is computed from the ocean-sediment and sediment-ice interfaces, suggesting that the geology of Titan may be investigated by such a sounding mode despite deep ocean coverage of the satellite.

Thompson, W. Reid↗
NASA NTRS1991

Nitrogen airglow sources - Comparison of Triton, Titan, and earth

The individual contributions of direct solar excitation, photoelectron excitation, and magnetospheric electron excitation of Triton and Titan airglow observed by the Voyager Ultraviolet Spectrometer (UVS) are quantified. The principal spectral features of Triton's airglow are shown to be consistent with precipitation of magnetospheric electrons with power dissipation about 500 million W. Solar excitation rates of the dominant N2 and N(+) emission features are factors of 2-7 weaker than magnetospheric electron excitation. On Titan, the calculated disk center and bright limb N(+) 1085 A intensities due to solar excitation agree with observed values, while the 970 A feature is mostly N21 c5 band emission. The calculated LBH intensity by photoelectrons suggests that magnetospheric electrons play a minor role in Titan's UV airglow. On earth, solar/photoelectron excitation explains the observed N(+) 1085 A and LBH intensites and accounts for only 40 percent of the N(+) 916 A intensity.

Strobel, Darrell F.↗
NASA NTRS1991

The greenhouse and antigreenhouse effects on Titan

The parallels between the atmospheric thermal structure of the Saturnian satellite Titan and the hypothesized terrestrial greenhouse effect can serve as bases for the evaluation of competing greenhouse theories. Attention is presently drawn to the similarity between the roles of H2 and CH4 on Titan and CO2 and H2O on earth. Titan also has an antigreenhouse effect due to a high-altitude haze layer which absorbs at solar wavelengths, while remaining transparent in the thermal IR; if this haze layer were removed, the antigreenhouse effect would be greatly reduced, exacerbating the greenhouse effect and raising surface temperature by over 20 K.

Mckay, Christopher P.↗
NASA NTRS1991

Cassini Titan Radar Mapper

The Cassini Titan Radar Mapper is a multimode radar instrument designed to probe the optically inaccessible surface of Titan, Saturn's largest moon. The instrument is to be included in the payload of the Cassini Saturn Mission, scheduled for launch in 1995. The individual modes of Cassini Radar Mapper will allow topographic mapping and surface imaging at few hundred meters resolution. The requirements that lay behind the design are briefly discussed, and the configuration and capability of the instrument are described. The present limited knowledge of Titan's surface and the measurement requirements imposed on the radar instrument are addressed. Also discussed are the Cassini mission and the projected orbits, which imposed another set of design constraints that led to the multitude of modes and to an unconventional antenna configuration. The antenna configuration and the different radar modes are described.

Elachi, Charles↗
NASA NTRS1991

Photochemical reactions of cyanoacetylene and dicyanoacetylene: Possible processes in Titan's atmosphere

Titan has an atmosphere which is subject to dramatic chemical evolution due mainly to the dramatic effect of the UV flux from the Sun. The energetic solar photons and other particles are converting the methane-nitrogen atmosphere into the unsaturated carbon compounds observed by the Voyager probes. These same solar photons are also converting some of these unsaturated reaction products into the aerosols observed in the atmosphere which obscure the view of the surface of Titan. In particular, the photochemical reactions of cyanoacetylene, dicyanoacetylene, acetylene and ethylene may result in the formation of the higher hydrocarbons and polymers which result in the aerosols observed in Titan's atmosphere. Polymers are the principal reaction products formed by irradiation of cyanoacetylene and dicyanoacetylene. Irradiation of cyanoacetylene with 185 nm of light also yields 1,3,5-tricyanobenzene while irradiation at 254 nm yields 1,2,4-tricyanobenzene and tetracyano cyclooctatetraenes. Photolyses of mixtures of cyanoacetylene and acetylene yields mono- and di- cyanobenzenes. The 1-Cyanocyclobutene is formed from the photochemical addition of cyanoacetylene with ethylene. The photolysis of dicyanoacetylene with acetylene yields 2,3-dicyano-1,3-butadiene and 1,2-dicyanobenzene. Tetracyano cyclooctatetraene products were also observed in the photolysis of mixtures of dicyanoacetylene and acetylene with 254 nm light. The 1,2-Dicyano cyclobutene is obtained from the photolysis dicyanoacetylene and ethylene. Reaction mechanisms will be proposed to explain the observed photoproducts.

Ferris, J. P.↗
NASA NTRS1991

Optimum data analysis procedures for Titan 4 and Space Shuttle payload acoustic measurements during lift-off

Analytical expressions have been derived to describe the mean square error in the estimation of the maximum rms value computed from a step-wise (or running) time average of a nonstationary random signal. These analytical expressions have been applied to the problem of selecting the optimum averaging times that will minimize the total mean square errors in estimates of the maximum sound pressure levels measured inside the Titan IV payload fairing (PLF) and the Space Shuttle payload bay (PLB) during lift-off. Based on evaluations of typical Titan IV and Space Shuttle launch data, it has been determined that the optimum averaging times for computing the maximum levels are (1) T (sub o) = 1.14 sec for the maximum overall level, and T(sub oi) = 4.88 f (sub i) (exp -0.2) sec for the maximum 1/3 octave band levels inside the Titan IV PLF, and (2) T (sub o) = 1.65 sec for the maximum overall level, and T (sub oi) = 7.10 f (sub i) (exp -0.2) sec for the maximum 1/3 octave band levels inside the Space Shuttle PLB, where f (sub i) is the 1/3 octave band center frequency. However, the results for both vehicles indicate that the total rms error in the maximum level estimates will be within 25 percent the minimum error for all averaging times within plus or minus 50 percent of the optimum averaging time, so a precise selection of the exact optimum averaging time is not critical. Based on these results, linear averaging times (T) are recommended for computing the maximum sound pressure level during lift-off.

Piersol, Allan G.↗
NASA NTRS1992

Ground-based observations of Titan's thermal spectrum

Past, present and future observations of Titan's thermal spectrum are discussed. Ground based observations of Titan's mid-infrared thermal spectrum gave the first indications of the temperature regime and the role of hydrocarbons in the chemical composition. Significant progress exploring Titan using ground based observations may be achieved by increasing the spectral resolution, exploring new spectral regions, and by searching for seasonal or time dependent changes of the spectrum.

Orton, Glenn↗