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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Mark 3 VLBI system: Tropospheric calibration subsystems

Tropospheric delay calibrations are implemented in the Mark 3 system with two subsystems. Estimates of the dry component of tropospheric delay are provided by accurate barometric data from a subsystem of surface meteorological sensors (SMS). An estimate of the wet component of tropospheric delay is provided by a water vapor radiometer (WVR). Both subsystems interface directly to the ASCII Transceiver bus of the Mark 3 system and are operated by the control computer. Seven WVR's under construction are designed to operate in proximity to a radio telescope and can be commanded to point along the line-of-sight to a radio source. They should provide a delay estimate that is accurate to the + or - 2 cm level.

Resch, G. M.↗
NASA NTRS1979

Overview of the NASA tropospheric environmental quality remote sensing program

This paper will summarize the current NASA Tropospheric Environmental Quality Remote Sensing Program for studying the global and regional troposphere from space, airborne and ground-based platforms. As part of the program to develop remote sensors for utilization from space, NASA has developed a series of passive and active remote sensors which have undergone field test measurements from airborne and ground platforms. Recent measurements with active lidar and passive gas filter correlation and infrared heterodyne techniques will be summarized for measurements of atmospheric aerosols, CO, SO2, O3, and NH3. These measurements provide the data base required to assess the sensitivity of remote sensors for applications to urban and regional field measurement programs. Studies of Earth Observation Satellite Systems are currently being performed by the scientific community to assess the capability of satellite imagery to detect regions of elevated pollution in the troposphere. The status of NASA sponsored research efforts in interpreting satellite imagery for determining aerosol loadings over land and inland bodies of water will be presented, and comments on the potential of these measurements to supplement in situ and airborne remote sensors in detecting regional haze will be made.

Allario, F.↗
NASA NTRS1981

The sulfur budget of the troposphere

A one dimensional photochemical tropospheric model was used to calculate the vertical profiles of tropospheric species. Particular attention is focused on the recent inclusion of the chemistry of the sulfur group, which consists of 13 species involving a total of 45 chemical reactions. It is found that the chemistry of the sulfur species, because it is largely anthropogenic, plays an increasingly important role in the distribution of tropospheric gases. The calculated vertical profiles were compared to available measurements and generally found to be in good agreement.

Tiwari, S. N.↗
NASA NTRS1982

Tropospheric passive remote sensing: Introduction

Measurement needs regarding chemical and transport parameters were identified. Measurement of those gases involved in tropospheric photochemistry (O3, CO, CH4, NOx, HNO3, SO2, NH3, and CH3CCl3) and quantification of their sources and sinks, as well as a fundamental understanding of atmospheric chemical transformations were discussed. The photochemistry of OH and its role as a sink are summarized. The concentrations and lifetimes of the tropospheric gases were considered. Major concerns in tropospheric transport are the making of representative remote measurements of trace gases and aerosols and the dependence of these measurements on structural differences in the atmosphere.

Source record↗
NASA NTRS1982

The Seasat altimeter wet tropospheric range correction

It is found that the difference between the wet tropospheric corrections obtained with the Seasat Multichannel Microwave Radiometer (SMMR) algorithm and corrections based on near-coincident radiosonde meteorological measurements has a standard deviation of 2.79 cm, which is consistent with the independent value for water vapor determination accuracy reported by the SMMR Evaluation Team. Because the difference between the radiosonde corrections and those obtained by means of interpolated surface meteorological data has a standard deviation of 5.73 cm, the SMMR wet tropospheric correction is recommended for investigations sensitive to the wet tropospheric height correction accuracy.

Tapley, B. D.↗
NASA NTRS1982

The effects of isotropic multiple scattering and surface albedo on the photochemistry of the troposphere

The present study is believed to be the first investigation which combines a detailed tropospheric photochemical model with a radiative code that realistically considers the important physical processes in the cloudless troposphere which control the transfer of incoming solar radiation. It is found in most cases that the inclusion of the multiple scattering code significantly alters the photolytic reaction frequencies. This in turn alters the vertical distribution of some key tropospheric species. In the case of ozone a decrease was found, while O(1D) and OH showed increased concentrations. The increases are especially evident for the species which are highly dependent on photolysis processes that occur shortward of about 320 nm. The photolysis frequencies for ozone photolysis calculated with the Anderson-Meier model are in general in excellent agreement with recent measurements

Augustsson, T. R.↗
NASA NTRS1982

Carbon monoxide measurements in the troposphere

Approximately 35 hours of radiometric measurements were obtained of the CO mixing ratio in the middle troposphere, upper troposphere, and lower stratosphere, by means of the Measurement of Air Pollution from Satellites (MAPS) experiment carried in the OSTA-1 payload of the second Space Shuttle flight. In view of gas filter radiometer data in the 4.67-micron band, gathered over the 38 N-38 S latitude region during both daytime and nighttime, the performance of MAPS was excellent. Significant gradients have been found in the middle tropospheric CO mixing ratio with both latitude and longitude over the North Atlantic, the Mediterranean Sea, and the Middle East.

Reichle, H. G., Jr.↗
NASA NTRS1983

Remote sensing of tropospheric gases and aerosols with airborne DIAL system

The multipurpose airborne DIAL system developed at NASA Langley Research Center is characterized, and the published results of tropospheric O3, H2O, and aerosol-backscatter remote-sensing experiments performed in 1980 and 1981 are summarized. The system comprises two tunable dye lasers pumped by frequency-doubled Nd:YAG lasers, dielectric-coated steering optics, a 36-cm-diameter Cassegrain receiver telescope, gateable photomultiplier tubes, and a minicomputer data-processing unit for real-time calculation of gas concentrations and backscattering profiles. The transmitted energy of the 100-microsec-separated dye-laser pulses is 40, 80, or 50 mJ/pulse at around 300, 600, or 720-nm wavelength, respectively. Good agreement was found between DIAL-remote-sensed and in-situ H2O and O3 profiles of the lower troposphere and O3 profiles of the tropopause region, and the usefulness of DIAL backscattering measurements in the study of boundary-layer and tropospheric dynamics is demonstrated. The feasibility of DIAL sensing of power-plant or urban plume SO2, of urban-area (or rural-area column-content) NO2, and of temperature and H2O (simultaneously using a third laser) has been suggested by simulation studies.

Browell, E. V.↗
NASA NTRS1983

Kinetics and mechanism of the oxidation of S(IV) by ozone in aqueous solution with particular reference to SO2 conversion in nonurban tropospheric clouds

Results are presented from a laboratory study of the kinetics of the S(IV)-O3 reaction in aqueous solution, including measurements of the effects of UV radiation, dissolved transition metals, and an antioxidant (hydroquinone) on the rate. On the basis of the results, relative rates of S(IV) conversion by O3 in tropospheric cloud water are compared with those predicted for H2O2 and for O2. The reaction mechanism is discussed, with an outline given of the elements of a possible reaction scheme. Application of the rate constants obtained to SO2 conversion in cloud water predicts conversion rates by ozone to be competitive with those by H2O2 at pH above about 4.5 and to dominate at pH above about 5.5. It is pointed out that since these pH's are typical for nonurban tropospheric cloud water, ozone is a potentially important contributor to the overall oxidative conversion of SO2 to sulfate in the nonurban troposphere.

Maahs, H. G.↗
NASA NTRS1984

The effect of clouds on photolysis rates and ozone formation in the unpolluted troposphere

The photochemistry of the lower atmosphere is sensitive to short- and long-term meteorological effects; accurate modeling therefore requires photolysis rates for trace gases which reflect this variability. As an example, the influence of clouds on the production of tropospheric ozone has been investigated, using a modification of Luther's two-stream radiation scheme to calculate cloud-perturbed photolysis rates in a one-dimensional photochemical transport model. In the unpolluted troposphere, where stratospheric inputs of odd nitrogen appear to represent the photochemical source of O3, strong cloud reflectance increases the concentration of NO in the upper troposphere, leading to greatly enhanced rates of ozone formation. Although the rate of these processes is too slow to verify by observation, the calculation is useful in distinguishing some features of the chemistry of regions of differing mean cloudiness.

Thompson, A. M.↗
NASA NTRS1984

Assessment of Techniques for Measuring Tropospheric H Sub x O Sub y

In its continuing efforts to direct its applications programs towards relevant national needs, NASA is conducting the Tropospheric Chemistry Program, the long-range objective of which is to apply NASA's space technology to assess and predict human impact on the troposphere, particularly on the regional to global scale. One area of required research is instrumentation development, which is aimed at improving the capability to measure important trace gases and aerosols which are key species in the major atmospheric biogeochemical cycles. To focus on specific needs, the Instrumentation Worksphop for H(x)O(y) Tropospheric Species was conducted in August 1982. The workshop discussed current measurement needs and instrument capabilities for H(x)O(y) species, including OH, HO2, and H2O2. The workshop activities and conclusions are documented.

Hoell, J. M.↗
NASA NTRS1984

A numerical analysis of transient planetary waves and the vertical structure in a meso-strato-troposphere model, part 1.4A

The structure of unstable planetary waves is computed by a quasi-geostrophic model extending from the surface up to 80 km by means of eigenvalue-eigenfunction techniques in spherical coordinates. Three kinds of unstable modes of distinct phase speeds and vertical structures are identified in the winter climate state: (1) the deep Green mode with its maximum amplitude in the stratosphere; (2) the deep Charney mode with its maximum amplitude in the troposphere: and (3) the shallow Charney mode which is largely confined to the troposphere. Both the Green mode and the deep Charney mode are characterized by very slow phase speeds. They are mainly supported by upward wave energy fluxes, but the local baroclinic energy conversion within the stratosphere also contributes in supporting these deep modes. The mesosphere and the troposphere are dynamically independent in the summer season decoupled by the deep stratospheric easterly. The summer mesosphere supports the easterly unstable waves 1-4. Waves 3 and 4 are identified with the observed mesospheric 2-day wave and 1.7-day wave, respectively.

Zhang, K. S.↗
NASA NTRS1984

A one-dimensional photochemical model of the troposphere with planetary boundary-layer parameterization

A time-dependent, one-dimensional photochemical model of the troposphere is used to describe the vertical distribution of atmospheric trace constituents for summer-time conditions at midlatitudes in the Northern Hemisphere. The model incorporates a planetary boundary layer (PBL) parametrization and a detailed chemical mechanism that includes the photochemistry of important nonmethane hydrocarbon species formed during the oxidation process. One result of the parametrized PBL is that the concentrations of some trace species in the free troposphere are 20-30 percent higher than when mixing processes are described by a vertical eddy diffusion coefficient which is held constant with respect to height and time. The lifetime of the oxides of nitrogen against photochemical conversion to nitric acid during summertime conditions is on the order of six hours. This lifetime is short enough to deplete most of the NO(x) in the PBL so that other reactive nitrogen species are more abundant than NO(x) throughout the free troposphere.

Fishman, J.↗
NASA NTRS1984

Vertical distribution of disequilibrium species in Jupiter's troposphere

Sources of organic matter and inorganic tracers on Jupiter, including solar UV photolysis, lightning discharges, and convective quenching of hot gases from the lower atmosphere, are reviewed in light of earth-based and Voyager data with the purpose of predicting the tropospheric steady-state abundances and vertical distributions of HCN, CH2O, and other species. It is concluded that a steady-state mole fraction of HCN in the Jovian troposphere of only about 10 to the -12th could be maintained by vertical transport of hot gases from the deep atmosphere. The observed HCN abundance, roughly X(HCN) = 10 to the -9th, appears to be due to photochemical reactions. After HCN, the most abundant organic-disequilibrium species in the troposphere is probably C2H6, derived from direct photolysis of CH4 at high altitudes, with a mole fraction of about 10 to the -10th at the H2O cloud level. Inorganic tracers of disequilibrium processes are also briefly summarized.

Lewis, J. S.↗
NASA NTRS1985

Rossby wavetrains in the stratosphere forced by localised disturbances in the troposphere

Studies have linked elements of the stratospheric circulation with particular localized features in the tropospheric circulation. This suggests a study of the response of the stratosphere to forcing by localized disturbances in the troposphere. A multilevel, primitive equation model is used of the stratosphere and mesosphere the height of whose lower boundary at 300 mb can be prescribed. Localized height disturbances which grow to steady amplitude are applied at this lower boundary, and the response of the initially axially symmetric stratosphere is studied. The perturbation, centered at 45 deg N, has a Gaussian distribution with a half width of 15 deg., corresponding roughly to the size of persistent troughs and blocking ridges in the troposphere. The forcing is nearly at fully amplitude 10 days after being switched on, and thereafter remains steady. Two types of experiments are conducted: in one the forcing is of small amplitude (100 gpm) and in the other it is of large amplitude (600 gpm). These pairs of experiments are compared to determine how nonlinear processes affect the perturbation fields. This is done locally by defining the perturbation response to the forcing as an anomaly, i.e., as a departure from the response in a controlled experiment in which no asymmetric forcing was applied at the lower boundary of the model. Experiments have been conducted for a number of atmospheric states obtained as zonal means of observations made by a stratospheric sounding unit (SSU). In this summary, results for the zonal mean flow on January 19, 1982 are outlined.

Marks, C. J.↗
NASA NTRS1985

Intrusion process of stratospheric ozone into the troposphere over Japan

The stratospheric-tropospheric exchanges play an important role in determining the distribution and residence time of ozone, aerosol and other substances in the stratosphere and troposphere. The ozone transport is estimated from the stratosphere into the troposphere by so-called tropopause folding event associated with the polar front jet stream. It is shown that in winter ozone transport occurs mainly in the region to the north of Japan in Asia. The ozone transport rate is estimated. Vertical velocity was estimated by marking the air parcel of an observation aircraft and tracking is on the isentropic surface.

Muramatsu, H.↗
NASA NTRS1985

The photochemistry of synoptic-scale ozone synthesis Implications for the global tropospheric ozone budget

The oxidation of nonmethane hydrocarbons represents a source of tropospheric ozone that is primarily confined to the boundary layers of several highly industrialized regions. (Each region has an area greater than one million km/sq cm). Using a photochemical model, the global tropospheric ozone budget is reexamined by including the in-situ production from these localized regimes. The results from these calculations suggest that the net source due to this photochemistry, which takes place on the synoptic scale, is approximately as large as the amount calculated for global scale photochemical processes which consider only the oxidation of methane and carbon monoxide. Such a finding may have a considerable impact on our understanding of the tropospheric ozone budget. The model results for ozone show reasonable agreement with the climatological summer distribution of ozone and the oxides of nitrogen at the surface and with the vertical distribution of ozone and nonmethane hydrocarbons obtained during a 1980 field program.

Fishman, J.↗
NASA NTRS1986

World-wide increase in tropospheric methane, 1978-1983

Techniques used to assess methane concentration in the troposphere are described, and data obtained during the period from 1978 to 1983 are presented in detail. Tropospheric methane concentrations in remote locations averaged a yearly world-wide increase of 0.018 + or - 0.002 parts per million by volume (ppmv). Average world-wide tropospheric concentration of methane in dry air was 1.625 ppmv at the end of 1983 measured against an NBS standard certified as 0.97 ppmv. Contributing to this steady increase in methane concentration are increases in the source strengths from cattle and rice fields, which in turn result from CO, CH4 and HO coupling. Among the physical and chemical effects is an increase in greenhouse warming of about 0.04 C per decade.

Blake, D. R.↗