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At least 361 records · Page 20

Reliability-Informed Economic and Energy Evaluation for Design for Remanufacturing: A Case Study on a Hydraulic Manifold

Design for Remanufacturing (DfRem) is an attractive approach for sustainable product development. Evaluation of DfRem strategies, from both economic and environmental perspectives, at an early design stage can allow the designers to make informed decisions when choosing the best design option. Studying the long-term implications of a particular design scenario requires quantifying the benefits of remanufacturing for multiple life cycles while considering the reliability of the product. In addition to comparing designs on a one-to-one basis, we find that including reliability provides a different insight into comparing design strategies. We present a reliability-informed cost and energy analysis framework that accounts for product reliability for multiple remanufacturing cycles within a certain warranty policy. The variation of reuse rate over successive remanufacturing cycles is formulated using a branched power-law model which provides probabilistic scenarios of reusing or replacing with new units. To demonstrate the utility of this framework, we use the case study of a hydraulic manifold, which is a component of a transmission used in some agricultural equipment, and use real-world field reliability data to quantify the transmission’s reliability. Three design improvement changes are proposed for the manifold and we quantify the costs and energy consumption associated with each of the design changes for multiple remanufacturing cycles.

design for remanufacturing↗

Data for Production of a δ-Lactam from Glucose through Integrating Biological and Chemical Catalysis

We present a new strategy for the production of a δ-lactam from glucose that integrates biological production of triacetic acid lactone (TAL, 4-hydroxy-6-methyl-2H-2-one) with catalytic transformation of TAL into 6-methylpiperidin-2-one (MPO) through metabolic engineering, isomerization, amination, and catalytic hydrogenation/hydrogenolysis. We developed a sustainable and antibiotic-free fed-batch fermentation using genetically modified Rhodotorula toruloides IFO0880. This process achieved a yield of 2-hydroxy-6-methyl-4H-pyran-4-one (2H4P) at 0.05 g/g of glucose, corresponding to a 9.9 g/L titer. By adjusting the pH of the fermentation broth to 2, 2H4P was quantitatively converted into TAL. The TAL in the fermentation broth was directly converted by aminolysis into 4-hydroxy-6-methylpyridin-2(1H)-one (HMPO), which achieved an 18.5% yield with 94.3% purity. The HMPO yield was lower in the fermentation broth than in a clean feedstock (32.2%), suggesting that the biological impurities are inhibitors in this reaction. Further investigation revealed that lower pH levels and reduced TAL concentrations in the fermentation broth significantly decreased HMPO yields. Subsequently, the precipitated HMPO was filtered and dried and then subjected to the final catalytic conversion in H2O solvent, achieving a MPO yield of 91.8%. This integrated approach demonstrated the direct use of TAL in the filtered aqueous fermentation broth without the need to isolate TAL.

Catalysis↗

Supramolecular dynamic binary complexes with pH and salt-responsive properties for use in unconventional reservoirs

Hydraulic fracturing of unconventional reservoirs has seen a boom in the last century, as a means to fulfill the growing energy demand in the world. The fracturing fluid used in the process plays a substantial role in determining the results. Hence, several research and development efforts have been geared towards developing more sustainable, efficient, and improved fracturing fluids. Herein, we present a dynamic binary complex (DBC) solution, with potential to be useful in the hydraulic fracturing domain. It has a supramolecular structure formed by the self-assembly of low molecular weight viscosifiers (LMWVs) oleic acid and diethylenetriamine into an elongated entangled network under alkaline conditions. With less than 2 wt% constituents dispersed in aqueous solution, a viscous gel that exhibits high viscosities even under shear was formed. Key features include responsiveness to pH and salinity, and a zero-shear viscosity that could be tuned by a factor of ~280 by changing the pH. Furthermore, its viscous properties were more pronounced in the presence of salt. Sand settling tests revealed its potential to hold up sand particles for extended periods of time. In conclusion, this DBC solution system has potential to be utilized as a smart salt-responsive, pH-switchable hydraulic fracturing fluid.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Adhesion in thermomechanically processed seaweed-lignocellulosic composite materials

The increasing concerns associated with petroleum-derived polymers motivate the development of sustainable, renewably sourced alternatives. In ubiquitous applications such as structural materials for infrastructure, the built environment as well as packaging, where natural materials such as wood are used, we rely on nonrenewable and nondegradable polymers to serve as adhesives. In wood panels, such as medium density fiberboards (MDFs), formaldehyde-based resins are predominantly used to bond wood fibers and to provide strength to the materials. To further mitigate the environmental impact of construction materials, more sustainable adhesives need to be investigated. Here, in this article, we introduce Ulva seaweed as an adhesive to enable cohesion and strength in hot-pressed wood panels. Upon hot-pressing, powdered Ulva flows in between the wood particles, generating a matrix, which provides strong binding. We show that the flexural strength of Ulva-bonded wood biocomposites increases with increasing Ulva concentrations. At an Ulva concentration of 40 wt%, our composites reach an average elastic modulus of 6.1 GPa, and flexural strength of 38.2 MPa (compared to 4.7 GPa and 22.6 MPa, respectively, for pure wood compressed at the same pressing conditions). To highlight the bonding mechanisms, we performed infrared and x-ray photoelectron spectroscopy and identified indications of fatty acid mobility during hot-pressing. In addition, we demonstrate that the presence of Ulva improves other properties of the composites such as water resistance and fame retardancy. Ulva is also shown to behave as an excellent adhesive agent between two prepressed beams. Finally, we perform an in-depth analysis of the environmental impact of wood-Ulva biocomposites.

36 MATERIALS SCIENCE↗

Atmospheric Radiation Measurement (ARM) Management Plan

Mission and Vision Statements for the U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) Climate Research Facility Mission The ARM Climate Research Facility, a DOE scientific user facility, provides the climate research community with strategically located in situ and remote-sensing observatories designed to improve the understanding and representation, in climate and earth system models, of clouds and aerosols as well as their interactions and coupling with the Earth’s surface. Vision To provide a detailed and accurate description of the Earth atmosphere in diverse climate regimes to resolve the uncertainties in climate and Earth system models toward the development of sustainable solutions for the nation's energy and environmental challenges.

54 ENVIRONMENTAL SCIENCES↗

From Interstellar Cloud to Star to Laboratory: Frontier HEDP Studies of Magnetized Colliding Plasma Flows with Strong Radiative Cooling (Final Report)

High-speed flows of gas are the norm in astrophysics where exploding stars, winds from the regions around black holes and streams of galactic material create “supersonic flows”. As the flows collide, strong shock waves are formed where gas is compressed and heated. The regions behind these shock waves are of great interest to scientists. New stars can form in these shock regions in the context of galaxies. In the context of planets like our Earth, the shocks waves come from the interaction of the solar wind with our planets’ magnetic field causing Aurora and placing astronauts and satellites in jeopardy. Thus, understanding supersonic flows of magnetized plasmas is essential for progress in many fields of astronomy and space physics (relevant to planets and the Earth). Remarkably, we can also create these kinds of flows in the laboratory using Z-pinches and laser driven experiments that include magnetic fields. The exploration of these forms of “High Energy Density Physics” (HEDP) flows is also critical in order to achieve Inertial Confinement Fusion, which is a step towards developing a sustainable source of Fusion energy.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NRIC EBR-II Test Bed Pre-Conceptual Design Report

Authorized by the Nuclear Energy Innovation Capabilities Act (NEICA), the National Reactor Innovation Center (NRIC) provides private sector technology developers access to strategic infrastructures and assets for commercial nuclear energy research, development, demonstration, and deployment activities. The mission is to support a timely and cost-effective path to the licensing and commercialization of new nuclear energy systems. To meet these needs, NRIC is developing two test beds at Idaho National Laboratory (INL). The ZPPR Test bed (ZTB) and the EBR-II Test bed (ETB). The EBR-II test bed will support the demonstration of systems that operate at less than 10 MWt. The baseline objective is for the EBR-II Dome to act as a safety significant containment structure capable of siting reactors that utilize Safeguards Category 4 material for operations. The major areas addressed in the pre-conceptual design include: • Installation of an access door • Electrical Power • Heat Removal • Ventilation in the Dome • Module handling system Along with the design for ETB a concept of operations (COP) has also been developed. The COP is intended to facilitate a common understanding of ideas, challenges, and issues. As systems continue to evolve in complexity System Engineers and Project Directors will utilize the COP to develop and sustain a common vision of the system for stakeholders.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

ZPPR Test Bed (ZTB) Pre-Conceptual Design Report

Authorized by the Nuclear Energy Innovation Capabilities Act (NEICA), the National Reactor Innovation Center (NRIC) provides private sector technology developers access to strategic infrastructures and assets for commercial nuclear energy research, development, demonstration, and deployment activities. The mission is to support a timely and cost-effective path to the licensing and commercialization of new nuclear energy systems. To meet these needs, NRIC is developing two reactor demonstration test beds at Idaho National Laboratory (INL), the ZPPR Test bed (ZTB) and the EBR-II Test bed (ETB). ZTB will support the demonstration of systems that operate at less than 500 kWt. The baseline objective is for the ZPPR Cell to act as a confinement structure capable of siting reactors that utilize Safeguards Category 1 material for operations. The major areas addressed in the pre-conceptual design include: • Installation of an access door • Electrical Power • Heat Removal • Ventilation in the Cell • Reactor Installation Along with the design for ZTB, a concept of operations (COP) has also been developed. The COP is intended to facilitate a common understanding of ideas, challenges, and issues. As systems continue to evolve in complexity System Engineers and Project Directors will utilize and update the COP to develop and sustain a common vision of the system for stakeholders.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Nuclear Forensics in Support of National Response Plans [Slides]

Become familiar with nuclear forensics methodologies in support of nuclear security investigations and how Los Alamos National Laboratory supports the development of sustainable global nuclear forensics capacities.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

South Africa: Framework for Energy Efficiency Demand Side Management

In July 2022, President Cyril Ramaphosa announced an emergency response plan to address the growing electricity crisis in South Africa, which included the necessity for customers of Eskom, South Africa’s primary electricity supplier, to implement demand-side energy efficiency measures. This report is the second of two reports that provides the foundation for a strategic Demand-Side Management (DSM) approach to reduce load shedding and maximize energy savings in South Africa, though inter-governmental collaboration and increased coordination of energy efficiency activities. The first report focuses on the experience of Eskom’s rate-funded Integrated Demand Management (IDM) programme, from its beginning in 2004 to today, highlighting the factors that led to failed support for the programme. This second report focuses on addressing the challenges identified in the first report and describes the elements of a policy framework to develop a sustained DSM program to meet the government’s energy efficiency goals in terms of greenhouse gas emissions reduction and social equity and inclusion to achieve a just transition.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Overcoming Barriers in Plant Transformation: A Focus on Bioenergy Crops

Although 2023 marked the 40th anniversary of the first transgenic plant, routine transformation of most plant genotypes remains elusive. Rapid systems to overexpress, interfere, or knock out genes— collectively defined in this report as “transformation and editing technologies”—are needed to understand plant gene function. This understanding in turn is crucial for efficiently developing new, sustainable, high-yielding, and climate-resilient crops to meet the growing demand for food, feed, fiber, and fuel. In particular, the ability to apply transformation and editing technologies to bioenergy crops has remained largely unrealized. To address this opportunity, the U.S. Department of Energy (DOE) Biological and Environmental Research Program convened a workshop on September 18–20, 2023, to define transformation and editing needs and barriers focused on bioenergy crops. The main conclusions are summarized below.

09 BIOMASS FUELS↗

High Performance Metal-Supported SOFC System for Range Extension of Commercial Aviation

The DOE ARPA-E REEACH program [1] has enabled this Phase 1 study that conceptualizes a commercial 154 passenger electric aircraft using renewable aviation fuel for range extension while meeting similar mission performance levels as current commercial aircraft. Commercial aviation accounts for about 2.5% of global CO2 emissions, and close to 5% of overall anthropogenic climate change due to the added accounting of contrail’s effects [2]. The sector has adopted a goal of carbon neutrality by 2050 [3]. 110 nations, and recently the new US administration, have embarked on work to address this important challenge. The US DOE has released a roadmap to enable the further development of sustainable aviation fuel (SAF) in the hopes that it could meet all of aviation’s fuel needs by 2050 [4]. However, SAF fuel price and sufficient future feedstock availability remains a concern [5]. Considering the first commercial biofuel flight demonstration 14 years ago [6] and that SAF still only comprises less than 0.1% of jet fuel use, the question arises as how it can ramp up to 100% use in the next 27 years. One option that has the potential to substantially reduce the need for SAF is to implement light-weight Solid Oxide Fuel Cells (SOFCs) that can efficiently utilize SAF or other sulfur-free hydrocarbon fuels. As opposed to lower temperature PEM (Proton Exchange Membrane) fuel cells that can use high-purity hydrogen, SOFC’s fuels are very flexible, ranging from low cost liquefied natural gas (LNG), renewable liquefied natural gas (RLNG), to SAF, to generate clean electrical power for use in aviation propulsion and auxiliary power units [7] [8]. Research progress is needed to enable SOFCs to achieve 3.0 kW/kg power density, making them viable for aviation [9]. The DOE’s Advanced Research Projects Agency – Energy (ARPA-E) has therefore initiated an aviation SOFC R&D program that is anticipated to dramatically reduce aircraft fuel use though the implementation of “Range Extenders for Electric Aviation with low Carbon and High efficiency” (REEACH) [1] for medium range commercial aircraft. This report summarizes the progress during phase 1 of the REEACH program.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

North Slope Alaska and Tethered Balloon Systems: ARM Facilities Monthly Status Update

In support of the DOE Office of Science, Sandia National Labs is one of nine national laboratories which oversees the Atmospheric Radiation Measurement (ARM) Program. The Sandia ARM team has an obligation to fulfill its mission to provide the nation with data to improve the understanding of climate processes and the representation of those processes in climate models. Sandia’s ARM team’s ability to provide detailed and accurate descriptions of the Earth’s atmosphere in diverse climate regimes assists the DOE in development of sustainable solutions to the nation’s energy and environmental challenges. Sandia Labs manages ARM atmospheric facilities along the North Slope of Alaska (NSA) at Utqiagvik as well as the Tethered Balloon System (TBS). Activities conducted at NSA and with the TBS aide in data collection for the ARM data archive. An overview of these activities for the month of December follows.

54 ENVIRONMENTAL SCIENCES↗

PCAST: Report to the President on Supporting the U.S. Public Health Workforce

The President’s Council of Advisors on Science and Technology (PCAST) is the sole body of advisors from outside the federal government charged with making science, technology, and innovation policy recommendations to the President and the White House. Established by Executive Order, it is an independent Federal Advisory Committee comprised of distinguished individuals from industry, academia, and non-profit organizations with a range of perspectives and expertise. On May 1, 2023, PCAST sent a report to the President with recommendations for developing and sustaining the robust public health workforce that is essential for the United States to make long-needed, permanent improvements to our nation’s approach to public health.

99 GENERAL AND MISCELLANEOUS↗

ARM Aerial Instrument Workshop Report

The mission of the U.S. Department of Energy’s (DOE) Biological and Environmental Research (BER) program is to “support transformative science and scientific user facilities to achieve a predictive understanding of complex biological, earth, and environmental systems for energy and infrastructure security, independence, and prosperity.” (https://science.osti.gov/ber) Aligned with the BER central mission, the Earth and Environmental Systems Sciences Division (EESSD) plays a vital role in supporting the fundamental research to understand and predict Earth’s climate and environmental systems, and is also in a unique position to inform the development of sustainable solutions to the nation’s energy and environmental challenges. Specifically, EESSD manages two scientific user facilities: the Atmospheric Radiation Measurement (ARM) user facility and the Environmental Molecular Sciences Laboratory (EMSL). These facilities provide the broader scientific community with scientific expertise, technical capabilities, and unique data sets to facilitate science in areas of importance to DOE. As a multi-platform scientific user facility, ARM aims to fulfill the needs predominantly within the EESSD Atmospheric System Research (ASR) and the Earth and Environmental System Modeling (EESM) mission areas, and provide the critical measurements required to improve understanding of aerosol and cloud life cycles and their interactions, and their coupling with the Earth’s surface. Over the years, ARM has carried out piloted and unmanned aircraft campaigns under different organizational and operational paradigms (Schmid et al. 2014, 2016). Building on its success, the ARM Aerial Facility (AAF) continues to complement the ground-based observations with airborne in situ cloud, aerosol, and trace gas observations as well as measurements of atmospheric state and atmospheric radiation. During the past three years, ARM has managed field campaigns using unmanned aerial systems (UAS) and tethered balloon systems (TBS) at Oliktok Point in Alaska to improve understanding of atmospheric processes in the Arctic. In 2019, following a careful evaluation of scientific community needs, ARM acquired a Bombardier Challenger 850 regional jet to replace the vintage Grumman Gulfstream-159 turboprop aircraft previously used by AAF. With this new “laboratory in the sky”, AAF is evaluating its current and future aerial observation capabilities to continue satisfying the needs of the research community.

54 ENVIRONMENTAL SCIENCES↗